• Journal of Korea Soil Environment Society
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• v.4 no.1
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• pp.97-108
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• 1999

Reduction 2, 4, 6-trinitrotoluene by zero valent iron was studied in a batch reactor under anoxic conditions. Results showed that the removal of trinitrotoluene (TNT)followed a pseudo-first order reaction and the rate was linearly dependent on the available reactive surfau area of the zero valent iron surface area, resulting a rate constant of 0.0981min$^{1}m$$^{-2}m$. High concentrations of the final product, presumably triaminotoluene which needs to be treated by other means, accumulated in the solution. However , little amount of TAT was extracted from the metal surface by using acetonitrile or phosphate buffered water (pH 7.0). Other common major intermediate in biological TNT degradation, a group of aminodinitrotoluenes, was not detected in the solution. Therefore, it is postulated that the reduction of nitro group by $Fe^0$ occurs simultaneously in all three positions and a TNT reduction model by zero valent iron was suggested.

• Journal of the Mineralogical Society of Korea
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• v.27 no.1
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• pp.53-62
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• 2014

In order to remove Fe impurity from low-grade pyrophyllite ore, the effect of certain variables such as particle size, concentration of sulfuric acid, amount of ammonium sulfate, added hydrogen peroxide, and temperature were studied. The euhedral cubic pyrites were observed in the low-grade pyrophyllite ore by reflected light microscopy, and quartz and dickite were identified in the sample by XRD analysis. The results of the Fe removal experiments showed that the best Fe removal parameters were when the particle size was at -325 mesh, the addition of $H_2SO_4$, $(NH_4)_2SO_4$ and $H_2O_2$ was at a 2.0 M, 10.0 g/l, and 3.0 M concentration, respectively, and at a $70^{\circ}C$ leaching temperature. In the dissolution kinetics analysis, the dissolution of Fe from the pyrite surface was a controlled chemical reaction, and the Fe dissolution reaction was proportioned to 0.066/R, $[H_2SO_4]^{1.156}$, $[(NH_4)_2SO_4]^{0.745}$, $[H_2O_2]^{0.428}$.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.1
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• pp.5-13
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• 1997

The Island of Cheju plans massive ground water development to meet predicted water demand. Effective management of ground water resources requires impact assessment study. Due to the nature of the island, effects of sea water must be considered. In this work, salt water intrusion, due to hypothetical ground water development in Eastern and Central Cheju Watersheds, is predicted using a sharp-interface model. The model considers simultaneously hydrodynamics of both freshwater and saltwater. The hypothetical ground water development was designed such that it follows closely the regional ground water development plan. The numerical model predicted that the saltwater wedge may intude over 1km depending on the location. This observation leaves doubt on impact assement studies based on freshwater-flow only modeling.

• The Journal of the Korea Contents Association
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• v.9 no.10
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• pp.444-450
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• 2009

We have investigated biosorption kinetics and equilibrium of $Pb^2+$ and $Cr^2+$ using waste sludge, and separation efficiency of waste sludge by dissolved air flotation was evaluated in the various A/S ratio. The biosorption capacity and contact time were shown as a simulation of biosorption equilibrium and kinetics models. Biosorption equilibrium of the $Pb^2+$ and $Cr^2+$ onto the waste sludge could be fitted by the Langmuir, Freundlich, Redlich-Peterson, and Koble-Corrigan equation. The kinetics could be fitted by a pseudo-second-order rate equation more than a pseudo-first-order rate equation. The separation efficiency of waste sludge using DAF was kept above 90%.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.3 s.174
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• pp.661-666
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• 2000

Optimization of the elastic joint of train is performed according to the minimization of ten responses which represent driving safety and ride comfort of train and analyzed by using the each response se surface model from stochastic design of experiments. After the each response surface model is constructed, the main effect and sensitivity analyses are successfully performed by 2nd order approximated regression model as described in this paper. We can get the optimal solutions using by nonlinear programming method such as simplex or interval optimization algorithms. The response surface models and the optimization algorithms are used together to obtain the optimal design of the elastic joint of train. the ten 2nd order polynomial response surface models of the three translational stiffness of the elastic joint (design factors) are constructed by using CCD(Central Composite Design) and the multi-objective optimization is also performed by applying min-max and distance minimization techniques of relative target deviation.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.12 no.6
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• pp.461-468
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• 2002

Computer simulation is essential to design the suspension elements of railway vehicle. By computer simulation, engineers can assess the feasibility of the given design factors and change them to get a better design. But if one wishes to perform complex analysis on the simulation, such as railway vehicle dynamic, the computational time can become overwhelming. Therefore, many researchers have used a surrogate model that has a regression model performed on a data sampling of the simulation. In general, metamodels(surrogate model) take the form y($\chi$)＝f($\chi$)＋$\varepsilon$, where y($\chi$) is the true output, f($\chi$) is the metamodel output, and is the error. In this paper, a second order polynomial equation is used as the RSM(response surface model) for high speed train that have twenty-nine design variables and forty-six responses. After the RSM is constructed, multi-objective optimal solutions are achieved by using a nonlinear programming method called VMM(variable matric method) This paper shows that the RSM is a very efficient model to solve the complex optimization problem.

• Journal of Industrial Technology
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• v.27 no.A
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• pp.203-209
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• 2007

본 연구는 목재로서 활용가치가 적은 수피(bark)를 활용하여 수질오염물질을 제거할 수 있는 여과 시스템에 대한 기초연구로서 소나무의 일종인 loblolly pine(Pinus taeda L.) 수피의 인 ($PO_4-P$) 흡착특성을 연구하였다. 실험에 사용된 수피는 입상형태로서 polyallylamine hydrochloride로 전처리하여 회분식 등온 흡착실험을 수행하였다. 회분식 등온흡착실험은 수용액 pH 3~pH 8범위에서, 인의 농도별(10, 20, 30, 40 mg/L)로 수행하였다. pH 5에서 가장 높은 인 제거 효율을 나타냈으며, 수용액의 pH는 실험 후 pH 3으로 감소하였다. 이러한 감소는 수피에 의한 phosphate의 흡착이 Lewis acid-base 반응으로서 이 과정에서 $H^+$의 방출로 인하여 나타난 현상인 것으로 여겨지며, 주된 반응 메카니즘은 더 연구할 필요성이 있다. 인 흡착은 초기에 빠른 속도로 진행되었으며 대략 200분 이후에 평형에 도달하였고, 시간이 지날수록 흡착양이 증가하는 경향을 보였다. 인의 흡착특성 결과는 Langmuir 등온흡착식과 Freundlich 등온흡착식으로 설명될 수 있으며, 등온흡착식 적용결과, 흡착제에 대한 최대 흡착능은 7.14 mg/g 이며 다른 흡착제와 비교하여 더 높았다. 실험결과와 모델에 의한 흡착능을 비교하고자 pseudo second-order model을 적용하여 흡착 동역학 상수를 구하였다. 또한 EDXA분석으로 회분식 흡착실험 후 수피와 인이 결합되어있는 것을 확인할 수 있었다.

• Journal of the Korean Society for Precision Engineering
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• v.26 no.8
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• pp.104-111
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• 2009

In this paper, the gear design program is presented. The profile of gears is created using classical mathematic formulations. In each gear, a kinematic joint is applied and one can define the 20 contact condition between gear pairs. Initial and boundary conditions such as force, torque, velocity, acceleration, etc. can be set. Thus, it is possible to analyze dynamic characteristics of gear pairs such as reaction moment and the variation of angular velocity. In order to find the optimal profile of gear pairs, two optimization methods based on design of experiments are inserted in the program; One is the Taguchi method and the other is the response surface analysis method. To verify the program, the rack & pinion gear is created and analyzed. Simulation results show that the developed program is useful and result data is reliable.

• Proceedings of the KIEE Conference
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• 2000.07d
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• pp.3238-3240
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• 2000

본 논문의 목적은 음주섭취로 인한 혈중 알코올 농도에 따른 뇌의 활동도변화를 측정, 분석하는데 있다. 1차원 시계열데이터인 EEG신호는 생체 비선형 동역학 시스템으로부터 발생하는 Deterministic Nonlinear Chaos신호로써 무작위적인 신호와는 구분되어질 수 있다. EEG시계열데이터를 위상공간에 적절한 어트랙터로 재구성하여 상관차원 최대발산지수 등의 카오스 지수들을 추출하여보면 EEG시계열데이터가 무작위적인 계에서 발생하는 랜덤한 신호가 아닌 카오스계에서 기인함을 알 수 있고, 인간의 정신상태에 따른 뇌의 활동도를 정성적, 정량적으로 판별해 볼 수 있다. 이러한 카오스 분석방법을 토대로 음주전의 뇌의 활동도와 음주후 혈중알코올 농도에 따른 뇌의 활동도변화를 EEG의 카오스 지수들의 변화를 통해 분석해 보았다.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.2 s.257
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• pp.145-151
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• 2007

Impulsive excitation on vehicle produces shock-type vibration on the seat, which has major frequencies and damping ratios dependent on the characteristics of the suspension, the tire, the seat cushion and so on. The response of single degree of freedom model to a half-sine force input was considered as simple shock-type vibration signal. Quasi-apparent-mass for fifteen subjects was measured with the shock-type vibration generated on a rigid seat mounted on the simulator, so its nonlinearity was apparently found over 6.3 Hz according to the difference of magnitude of the shock.