• Title/Summary/Keyword: 반응도(R)

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Development of an 1-Dimensional Dynamic Numerical Model for BTX Removal Process Analysis by Gaseous-Biofilm Filtration (기체상-생물막 여과 공법의 BTX 제거 공정 해석을 위한 1차원 동적 수치모델 개발)

  • Kim, Yeong-Kwan;Choi, Sung-Chan;Kim, Seog-Ku;Lee, Yong-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.12
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    • pp.689-695
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    • 2015
  • A biofilm filtration for the removal of gaseous pollutants has been recognized as a process with a complex interaction between the gas flow characteristics and the process operating variables. This study aims to develop an one dimensional dynamic numerical model which can be utilized as a tool for the analysis of biofilm filtration process operated in plug flow mode. Since, in a plug flow system, minor environmental changes in a gaseous unit process cause a drastic change in reaction and the interaction between the pollutants is an influencing factor, plug flow system was generalized in developing the model. For facilitation of the model development, dispersion was simplified based on the principles of material balance. Several reactions such as competition, escalation, and control between the pollutants were included in the model. The applicability of the developed model was evaluated by taking the calibration and verification steps on the experimental data performed for the removal of BTX at both low and high flow concentration. The model demonstrated a correlation coefficient ($R^2$) greater than 0.79 under all the experimental conditions except for the case of toluene at high flow condition, which suggested that this model could be used for the generalized gaseous biofilm plug flow filtration system. In addition, this model could be a useful tool in analyzing the design parameters and evaluating process efficiency of the experiments with substantial amount of complexity and diversity.

Isotherms, Kinetics and Thermodynamic Parameters Studies of New Fuchsin Dye Adsorption on Granular Activated Carbon (입상 활성탄에 대한 New Fuchsin 염료흡착의 등온선, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.632-638
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    • 2014
  • Batch adsorption studies including equilibrium, kinetics and thermodynamic parameters for the adsorption of new fuchsin dye using granular activated carbon were investigated with varying the operating variables such as initial concentration, contact time and temperature. Equilibrium adsorption data were fitted into Langmuir, Freundlich, Dubinin-Radushkevich and Temkin isotherms. Adsorption equilibrium was mostly well described by Langmuir Isotherm. From the estimated separation factor of Langmuir ($R_L$ = 0.023), and Freundlich (1/n = 0.198), this process could be employed as an effective treatment for the adsorption of new fuchsin dye. Also based on the adsorption energy (E = 0.002 kJ/mol) from Dubinin-Radushkevich isotherm and the adsorption heat constant (B = 1.920 J/mol) from Temkin isotherm, this adsorption is physical adsorption. From kinetic experiments, the adsorption reaction processes were confirmed following the pseudo second order model with good correlation. The intraparticle diffusion was a rate controlling step. Thermodynamic parameters including changes of free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption. The change of enthalpy (92.49 kJ/mol) and activation energy (11.79 kJ/mol) indicated the endothermic nature of adsorption processes. The change of entropy (313.7 J/mol K) showed an increasing disorder in the adsorption process. The change of free energy found that the spontaneity of process increased with increasing the adsorption temperature.

A Study on the Utilization of By-products from Honeyed Red Ginseng: Optimization of Total Ginsenoside Extraction Using Response Surface Methodology (홍삼정과 제조 부산물 이용에 관한 연구: 반응표면분석을 이용한 총 진세노사이드 추출조건의 최적화)

  • Lee, Eui-Seok;You, Kwan-Mo;Kim, Sun-Young;Lee, Ka-Soon;Park, Soo-Jin;Jeon, Byeong-Seon;Park, Jong-Tae;Hong, Soon-Taek
    • Food Engineering Progress
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    • v.21 no.1
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    • pp.79-87
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    • 2017
  • This study was carried out to extract ginsenosides in by-products from honeyed red ginseng. Response surface methodology (RSM) was used to optimize the extraction conditions. Based on D-optimal design, independent variables were ethanol (extraction solvent) concentration (30-90%, v/v), extraction temperature ($25-70^{\circ}C$), and extraction time (5-11 h). Extraction yield (Y1) and total ginsenosides (Y2) in the extract were analyzed as dependent variables. Results found that extraction yield increased with increasing extraction temperature and time, whereas it was decreased with increasing ethanol concentration. Similar trends were found for the content of ginsenosides in the extracts, except for ethanol concentration, which was increased with increasing ethanol concentration. Regression equations derived from RSM were suggested to coincide well with the results from the experiments. The optimal extraction conditions for extraction yield and total ginsenosides were an extraction temperature of $56.94^{\circ}C$, ethanol concentration of 57.90%, and extraction time of 11 h. Under these conditions, extraction yield and total ginsenoside contents were predicted to be 84.52% and 9.54 mg/g, respectively.

Hydration Properties of Low Carbon type Low Heat Blended Cement (무기질 자극제를 사용한 탄소배출 저감형 저발열형 혼합시멘트의 수화특성에 관한 연구)

  • Choi, Sung-Woo;Ryu, Deuk-Hyun;Kim, Hun-Sang;Kim, Gyu-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.3
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    • pp.218-226
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    • 2013
  • Of construction materials, cement and steel are the representative material that carbon dioxide. to reduce carbon emissions in the use of these materials The purpose of this study is low heat type blended cement, which is manufactured using a amount of cement than ordinary low heat blended cement. Low heat blended cement, mixing ratio of 10%, was investigated hydration properties and adiabatic temperature of concrete. The study in order to activate the reaction mineral admixture, a separate source of CaO and $SO_3$ areneeded. gypsum and lime, it expected amount of cement, low-carbon low-heat blended cement could reduce the hydration heat concrete than currentlyused low heat blended cement.

Validation of Factors Effect on Pretreatment of Brown Algae, Undaria, Using Response Surface Methodology and Prospect of Lactic Acid Production (반응표면분석법을 이용한 갈조류, 미역의 전처리 인자 영향 파악 및 젖산 생산성 검토)

  • Min, Chang Ha;Lee, Doo-Geun;Um, Byung Hwan;Yoon, Jeong-Jun
    • Korean Chemical Engineering Research
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    • v.56 no.4
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    • pp.453-460
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    • 2018
  • Owing to rising oil prices and anthropogenic global warming, focused attempts are being made toward production of industrially important compounds by using renewable biomass. In this context, algal biomass as third-generation biomass is important because it doesn't compatible with food resource, has high yield, and helps abate greenhouse gases. Here, we investigate whether Undaria has the highest sugar content, which would make it the most suitable biomass for lactic acid production among the four algal biomasses tested. For effective pretreatment of Undaria, the response surface methodology was used. The amount of solid loaded and catalyst concentration were related to the extraction rate of total sugar. Lactic acid was produced by pretreatment of Undaria by using four Lactobacilli, and L. alimentarius and L. brevis were found to be suitable for lactic acid production.

Development of L-Threonine Producing Recombinant Escherichia coli using Metabolic Control Analysis (대사 조절 분석 기법을 이용한 L-Threonine 생산 재조합 대장균 개발)

  • Choi, Jong-Il;Park, Young-Hoon;Yang, Young-Lyeol
    • KSBB Journal
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    • v.22 no.1
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    • pp.62-65
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    • 2007
  • New strain development strategy using kinetic models and metabolic control analysis was investigated. In this study, previously reported mathematical models describing the enzyme kinetics of intracellular threonine synthesis were modified for mutant threonine producer Escherichia coli TF5015. Using the modified models, metabolic control analysis was carried out to identify the rate limiting step by evaluating the flux control coefficient on the overall threonine synthesis flux exerted by individual enzymatic reactions. The result suggested the production of threonine could be enhanced most efficiently by increasing aspartate semialdehyde dehydrogenase (asd) activity of this strain. Amplification of asd gene in recombinant strain TF5015 (pCL-$P_{aroF}$-asd) increased the threonine production up to 23%, which is much higher than 14% obtained by amplifying aspartate kinse (thrA), other gene in threonine biosynthesis pathway.

A Comparative Analysis on characteristics and Manufacture of Methane/Natural Gas Hydrates (메탄/천연가스 하이드레이트의 제조 및 특성 비교 분석)

  • Lee Young-Chul;Cho Byoung-Hak;Baek Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.7 no.3 s.20
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    • pp.32-43
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    • 2003
  • As this paper is observed the phase equilibrium diagram of mono- (methane) and multi-component(natural gas) hydrates, and the hydrate growth behavior is analysed and compared by the experiments during the reaction. The difference of mono and multi-component hydrates is an induction delay time and a plateau region. And the concentration of component of gases is changed during the reaction in multi-component hydrates and the concentration of components is changed during the decomposition of hydrate according to each decomposing rates of gases. At 6 MPa, 276.65 K and 600 rpm, the induction delay time of multi-component hydrate formation is observed shorter than that of mono-component hydrate formation because the hydrate nuclei of gases except methane form faster than those of methane. And the plateau region of mono-component hydrate is observed distinctly at 0.055 mole of $CH_4$/mole of water and that of multi-component hydrate is observed at 0.04 mole of $CH_4$/mole of water.

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Flight of Matsucoccus thrubergianae Males and Their Response to the Synthetic Sex Pheromone (Homoptera: Coccoidea ; Margarodidae) (솔껍질깍지벌레 수컷 성충의 비행습성 및 합성페로몬에 대한 반응)

  • ;;K. Mori
    • Korean journal of applied entomology
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    • v.33 no.4
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    • pp.250-256
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    • 1994
  • Flight behavior of Mntsucoccus thunbergianae males and their response to the synthetic sex pheromone, (6R.lOR)-matsuone, were studied in Pinus thunbergiana forests More males were flying around the tree crown than near the ground. A dispenser loaded w~th 50 vg of the pheromone appeared to affect the density of male flights less than 10 meters Sticky traps with 50 pg of the pheromone attracted flylng males, but those with 1 pg were not effectwe in a forest wlth high crown closure, more males were tmpped at upper crown level than near the ground whereas males appeared to be more responsive to pheromone near the ground in a forest with low crown closure Monitoring new scale iniestations with pheromone mps was much more effective than egg sac surveys, the customary detecting procedures Maiing disruption was not achieved by placing 32 mg of pheromone m a space of l X l X l meter.

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Burning Properties of Uncured HTPB Propellant (HTPB 바인더를 이용한 미 경화 추진제의 연소 특성)

  • Kim, Nakhyun;Kim, Jungeun;Hong, Myungpyo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.1
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    • pp.37-42
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    • 2016
  • In this study, we examined the burning rate of the uncured propellant (with and without a curing agent application) in order to inspect the process of the HTPB solid propellant. The burning rate of the uncured propellant, that did not contain the curing agent, was approximately 9.7 mm/s at 1000 psi. In relation to the curing time, the burning rate was constant. The propellant, with the curing agent application, was approximately 8.1 mm/s showed a tendency of slowing as it burned. When the cure reaction rate was low, in accordance to the time, there were small changes in burn rate. However, when the cure reaction rate was high, the difference in burning rate was increased. The burning rate of a fully-cured propellant was approximately 6.8 mm/s, which appeared to be the lowest in order.

Comparison of the Response Inhibitory Event Related Potential between Suicide Attempt and Ideation (자살 시도와 자살 사고 간 반응억제 사건유발전위 비교 연구)

  • Kim, Ji Sun;Kwon, Young Joon;Shim, Se-hoon
    • Anxiety and mood
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    • v.16 no.1
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    • pp.41-48
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    • 2020
  • Objective : There have been limited scientific studies differentiating those who attempt suicide from those who think about suicide but do not attempt suicide. Altered event-related potential (ERP) performance, such as GoNogo ERP has been regarded as the neurocognitive processes associated with behavioral inhibition and poor impulse control. The purpose of this study was to investigate the association between Nogo ERP and suicide attempt. Methods : A total of 63 participants (33 participants with suicide ideation and 30 with suicide attempt) were recruited, and performed GoNogo tasks during the electroencephalogram measurement. Depression, anxiety, emotional regulation and impulsivity were evaluated by self-rating scales. The clinical measures and Nogo P3 component were compared between the groups. The correlational analyse was conducted to evaluate the relationship between the clinical characteristics and the Nogo P3 component. Results : Participants with suicide attempt significantly decreased the Nogo P3 amplitudes at the frontal-central electrode than participants with suicide ideation (p=0.004, FDR adjusted p=0.032). In the correlation analysis, the Nogo P3 amplitude at frontal-central electrode was correlated with the total score of the Barrett impulsivity scale (r=-0.383, p=0.002), attentional impulsivity (r=-0.365, p=0.003) and motor impulsivity (r=-0.389, p=0.002) subscales of the Barrett impulsivity scale. Conclusion : These findings suggest that the decreased Nogo P3 amplitude may be one of the candidates of biological marker for poor impulse control in those who attempt suicide.