• Title/Summary/Keyword: 바이오 플라스틱

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Effect of Temperature on the Formation of Vaterite in Ca(OH)2-CH3OH-H2O-CO2 System (Ca(OH)2-CH3OH-H2O-CO2계에서 바테라트의 생성에 미치는 반응온도의 영향)

  • Park, Jong-Lyuck;Choi, Sang-Kuen;Kim, Byoung-Gon;Lee, Jae-Jang
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1143-1148
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    • 2002
  • Precipitated calcium carbonate is one of the most versatile mineral fillers and is consumed in an wide range of products including paper, paint, plastics, rubber, textiles, sealants, adhesives and printing ink and can be produced by several methods. Calcium carbonate has three isomorphism; vaterite, aragonite and calcite, with numerous variations of morphology in the natural mineral or organism. Formation process of vaterite in the reaction of system $Ca(OH)_2-CH_3OH-H_2O-CO_2$ were investigated by measuring the electrical conductivity, $Ca^{2+}$ ion concentration, pH in the slurries and by means of X-ray diffraction and electron microscopic observation. It was clearly established that the reaction temperature is important variable in the carbonation process; in general over 50${\circ}C$, the vaterite was precipitated with the calcite and aragonite. SEM and XRD observations revealed that the vaterite formation could be prepared the temperature range of 40 to 50${\circ}C$ and mean size of particles in this range is controlled from 0.5 to 0.8 ${\mu}m$.

Features of Foreign Marine Debris on the Dune Beach of U-i Island, Korea (우이도 사구 해안의 외국기인 해양쓰레기 특성)

  • Lee, Jong-Myoung;Jang, Yong-Chang;Hong, Sun-Wook;Choi, Hyun-Woo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.2
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    • pp.167-174
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    • 2012
  • Transport of marine debris between countries is a potential source of diplomatic conflicts. U-i Island in Shinan County, Jeonnam Province has been reported by media as being damaged by marine debris from foreign countries. However, scientific researches on those marine debris have not been published. So, the features of foreign marine debris on Seongchon Beach in U-i Island were surveyed on Feb. 2012. The ratio of marine debris from foreign countries was 34.7% by number of items, 56.3% by weight, and 48.5% by volume in $200m^2$ transacts. Most of them, 98.9% in number, were inferred to be originated from China. The most abundant items were plastic beverage bottles and black floats. The total number of black floats was 539 within the 1,100m beach. Fifteen of them had information on manufactured locations, of which 87.6% were Liaoning Province in northern China. As domestic policy cannot prevent the inflow of the marine debris from foreign countries, countermeasures should be sought out from the international cooperation with the neighboring countries. For the black floats, recycling method should be developed as lots of the same types of black floats are drifted ashore in winter. And, as the U-i Island is a National Park with its valuable natural heritages, methods should be designed to minimize impacts on dune topography and ecology.

Processing and Storage of Spinach Products Using Cook-chill and Sous Vide Methods (Cook-Chill 및 Sous Vide 방법에 의한 시금치 식자재의 가공 및 저장)

  • 김기태;구경모;백현동;류은순;이동선
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.6
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    • pp.1095-1101
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    • 2001
  • Spinach was minimally processed into the unseasoned side dish to be used for Korean food service industry, using the techniques of cook-chill and sous vide. Spinach was blanched at 10$0^{\circ}C$ for 6 minutes, vacuum-packaged in the unit of 500 g by plastic film of low gas permeability, pasteurized at 9$0^{\circ}C$ and then cooled rapidly at 3$^{\circ}C$. The chilled products were then stored at 3 and 1$0^{\circ}C$ with measurement in their quality. Six log cycle (6D) inactivation of Listeria monocytogenes and 13 log (13D) thermal destruction of Streptococcus faecalis were compared as two pasteurization conditions, which corresponded to heating for 22.8 and 30.0 minutes at 9$0^{\circ}C$, respectively. Milder heat processing based on 6D process of L monocytogenes gave better quality of color, texture, ascorbic acid and chlorophyll than the conditions of 13D process of S. faecalis. Any microbial growth in total aerobic, psychrophilic and anaerobic bacteria was not observed until 8 days at 1$0^{\circ}C$ and 14 days at 3$^{\circ}C$, which might be regarded as strict guidelines of shelf life. Storage times based on the changes in physical and chemical quality were longer than those based on strict microbial quality in case of the products pasteurized by 6D process of L. monocytogenes. The seasoned vegetables prepared from sous vide processed spinach were found to be inferior in sensory quality to those from freshly blanched one.

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Preparation of MA-PLA Using Radical Initiator and Miscibility Improvement of PLA/PA11 Blends (라디칼 개시제를 이용한 MA-PLA 제조 및 바이오플라스틱 PLA/PA11 블렌드의 상용성 개선)

  • Lee, Jong-Eun;Kim, Han-Eol;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.76-85
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    • 2019
  • Recently, various investigation of vegetable oil which is extracted from natural resources is being progressed because of its low cost and environmental aspect. However, double bonds in vegetable oil should be substituted to other high reactive functional group due to its low reactivity for synthesizing bio-polymeric materials. ${\alpha}$-eleostearic acid, which is consist of conjugated triene, is the main component of tung oil, and the conjugated triene allows tung oil to have higher reactivity than other vegetable oil. In this study, tung oil is copolymerized with styrene and divinylbenzene to make thermoset resin without any substitution of functional group. Thermal and mechanical properties are measured to investigate the effects of the composition of each monomer on the synthesized thermoset resin. The result shows that the products have only one Tg, which means the synthesized thermoset resins are homogeneous in molecular level. Mechanical properties show that tung oil act as soft segment in the copolymer and make more elastic product. On the other hand, divinylbenzene acts as hard segment and makes more brittle product.

Development of Filter Sorting Process for Cigarette Butt Recycling and Extraction of Cellulose Acetate (담배꽁초 재활용을 위한 필터 선별공정 개발 및 셀룰로오스 아세테이트의 추출)

  • Minseon Park;Minjung Jung;Noh-sup Lee;Soochul Rhee;Namhoon Lee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.2
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    • pp.5-14
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    • 2024
  • A study approached the development of a process for efficiently recycling discarded cigarette butts, reported as a major source of microplastic pollution in aquatic environments. Cigarette butts were sorted to extract filters, and cellulose acetate, the raw material of the filters, was extracted to a high degree of purity. The sorting of filters from cigarette butts was conducted through both wet and dry processes, each with optimized sorting conditions. Wet stirring sorting considered factors such as solid-liquid ratio, stirring speed, and stirring temperature. The highest efficiency of wet stirring sorting, at 46.21%, was observed with a solid-liquid ratio of 1:45, stirring speed of 200 rpm, and stirring temperature of 50℃. Dry wind power sorting took into account moisture content and residence time. The filter sorting efficiency reached its peak at 57.10% with a moisture content of 20% and a residence time of 5 minutes. There was no significant difference in the recovery rate of cellulose acetate between the two sorting processes. Dry wind power sorting was deemed a more advantageous process in terms of energy and environmental considerations within the scope of this study.

Technology to Remove Trace Pollutants in Sewage Treatment Water Using Jellyfish Characteristics (해파리의 특성을 활용한 하수처리장 처리수 내 미량오염물질 제거 기술)

  • Hyeok Jin Park;Eun Jin Kim;Kyung Sil Choo;Joo Eun Shim;Min-Kyeong Yeo
    • Applied Chemistry for Engineering
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    • v.35 no.1
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    • pp.54-60
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    • 2024
  • The present study was aimed to evaluate the removal of the trace pollutants (heavy metals and microplastics) in the sewage treatment plant by using the jellyfish Extract at Immunity reaction (JEI) of Aurelia coerulea. The experiment was conducted on two different scales: the lab scale using a Jar-tester and the Pilot system scale equipped with two newly developed devices in the laboratory, the active tube connection mixed system and the concentration integrated separation device. Compared to anionic polymers currently used in the field, JEI showed similar or higher efficiency to remove the trace pollutants. When JEI was added to the effluent through the Pilot system, the combination of JEI and the trace pollutants was maximized through two mixing processes, and as a result, the removal rate of the trace pollutants was greatly improved. Based on these results, we propose the present technology as an alternative to removing trace pollutants that can reduce ecosystem risk and minimize the generation of inorganic waste, away from the existing method.

Analysis of Relationship between Tomato Growth, Vital Response, and Plant-induced Electrical Signal in a Plastic Greenhouse due to Carbon Dioxide Enrichment Treatment (플라스틱 온실 내 이산화탄소 시비에 따른 토마토 생육과 생체 반응 및 Plant-induced Electrical Signal 간 관계 분석)

  • Hee Woong Goo;Gyu Won Lee;Wook Jin Song;Do Hyeon Kim;Hyun Jun Park;Kyoung Sub Park
    • Journal of Bio-Environment Control
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    • v.32 no.4
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    • pp.484-491
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    • 2023
  • Tomatoes in greenhouse are a widely cultivated horticultural crop worldwide, accounting for high production and production value. When greenhouse ventilation is minimized during low temperature periods, CO2 enrichment is often used to increase tomato photosynthetic rate and yield. Plant-induced electrical signal (PIES) can be used as a technology to monitor changes in the biological response of crops due to environmental changes by using the principle of measuring the resistance value, or impedance, within the crop. This study was conducted to investigate the relationship between tomato growth data, vital response, and PIES resulting from CO2 enrichment in greenhouse tomatoes. The growth of tomato treated with CO2 enrichment in the morning was significantly better in all items except stem diameter compared to the control, and PIES values were also higher. The growth of tomato continuously applied with CO2 was better in the treatment groups than control, and there was no significant difference in chlorophyll fluorescence and photosynthesis. However, PIES and SPAD values were higher in the CO2 treatment group than control. CO2 enrichment have a direct relationship with PIES, growth increased, and transpiration increased due to the increased leaf area, resulting in increased water absorption, which appears to be reflected in PIES, which measures vascular impedance. Through this, this study suggests that PIES can be used to monitor crops due to environmental changes, and that PIES is a useful method for non-destructively and continuously monitoring changes of crops.

Effect of Vermicast Application of Earthworm Feeding Food Waste in Vegetable Plants (Radish and Chinese Cabbage) Growth (음식물 쓰레기를 먹이로 한 지렁이분립이 채소류(열무와 엇갈이배추) 생육에 미치는 영향)

  • Choi, I-Jin;Kwon, Hyuk-Hyun;Lee, Han-Ho;Son, Hyoung-Gi;Hong, Sang-Kil;Park, Yu-Soon;Kang, Jong-Woon
    • Korean Journal of Organic Agriculture
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    • v.20 no.4
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    • pp.715-725
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    • 2012
  • This study was performed to make the method of food waste manufacturing for feeding to earthworm and different ratio of earthworm cast was investigated for applying vegetable plants that cultivated in a family or roof garden. We made conventional treatment of gardening soil and prepared soils with earthworm cast (the only fertilizer) at 30, 50, 70 and 100% for planting vegetable plants and then we studied its growth feature. The treatment was repeated three times with 12 weeks for each time. The cultivation of radish and chinese cabbage were managed at the same cultivation level for RDA standard cultivation method, and each sample of soils and plants was analyzed by appropriate analysis method. The growth investigation was performed 12 week after planting, and as for growth characteristics, height, leaf diameter, leaf number, leaf length, fresh weight and dry weight were investigated. The chemical characteristics, soils and plants, were surveyed. As for the growth characteristics investigated, radish and chinese cabbage showed the biggest growth in 70% and 50% treatment with average growth of all characteristics, height, leaf diameter, leaf number, leaf length, fresh weight and dry weight, respectively. Applying these results, a new equation for vermicast recommendation for radish and Chinese cabbage in summer (June-August) was presented. The earthworm cast 50% level with the gardening soil showed the high production in chinese cabbage. In case of radish, earthworm cast 70% with gardening soil level showed great growth, significantly.

Effect of Cardanol Content on the Antibacterial Films Derived from Alginate-PVA Blended Matrix (알지네이트-폴리비닐알콜 블랜드 항균 필름 제조를 위한 카다놀 함량의 영향)

  • Ahn, Hee Ju;Kang, Kyung Soo;Song, Yun Ha;Lee, Da Hae;Kim, Mun Ho;Lee, Jae Kyoung;Woo, Hee Chul
    • Clean Technology
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    • v.28 no.1
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    • pp.24-31
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    • 2022
  • Petroleum-based plastics are used for various purposes and pose a significant threat to the earth's environment and ecosystem. Many efforts have been taken globally in different areas to find alternatives. As part of these efforts, this study manufactured alginate-based polyvinyl alcohol (PVA) blended films by casting from an aqueous solution prepared by mixing 10 wt% petroleum-based PVA with biodegradable, marine biomass-derived alginate. Glutaraldehyde was used as a cross-linking agent, and cardanol, an alkyl phenol-based bio-oil extracted from cashew nut shell, was added in the range of 0.1 to 2.0 wt% to grant antibacterial activity to the films. FTIR and TGA were performed to characterize the manufactured blended films, and the tensile strength, degree of swelling, and antibacterial activity were measured. Results obtained from the FTIR, TGA, and tensile strength test showed that alginate, the main component, was well distributed in the PVA by forming a matrix phase. The brittleness of alginate, a known weakness as a single component, and the low thermal durability of PVA were improved by cross-linking and hydrogen bonding of the functional groups between alginate and PVA. Addition of cardanol to the alginate-based PVA blend significantly improved the antibacterial activity against S. aureus and E. coli. The antibacterial performance was excellent with a death rate of 98% or higher for S. aureus and about 70% for E. coli at a contact time of 60 minutes. The optimal antibacterial activity of the alginate-PVA blended films was found with a cardanol content range between 0.1 to 0.5 wt%. These results show that cardanol-containing alginate-PVA blended films are suitable for use as various antibacterial materials, including as food packaging.

AN EXPERIMENT ON THE HEARING OF RAINBOW TROUT IN THE INDOOR AQUARIUM IN BUSAN (부산지방에서 실내수조를 이용한 무지개송어의 사육실험)

  • KIM In-Bae;JO Jae Yoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.10 no.4
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    • pp.267-273
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    • 1977
  • Rainbow trout were reared in a small indoor aquarium which was equipped with a simple recirculating biofilter combined with a small amount of inflowing water for 199 days from April 25 to November 10, 1977 in Busan where very hot summer air temperature is encountered, and results obtained were promissing as following; 1. The aquarium has dimensions of $1m\;\times\;1m\;\times\;67cm(depth)$, and a bottom center sedimentation chamber of conical type through which out-flowing water is pushing fecal matter and other detritus outward. The conical sedimentation chamber measures 20 cm depth and 20 cm diameter at its upper mouth and tapers to the bottom end which is connected to 4 cm diameter draining pipe. The draining pipe goes through under the tank and then is elevated on the side. The water depth was maintained at about 40 cm depth by adjusting the heigh of draining pipe. The filter bed contained 16 l of $3\~5\;mm$ zeolite gravels, and water circulation rate was about 1030 l/hr. 2. Continuous inflowing water resulted in a good elimination of waste materials through its outflowing water thus reducing waste loading in the filter. 3. Mean temperature of water in the rearing aquarium containing about 400 l water volume was maintained at around 20 to $22^{\circ}C$ by 0.59 l/min of the inflowing well water which usually maintained the temperature of $17^{\circ}C$ during the hot summer season from the first of July to the first of October when the 10-days-mean air temperature ranged from $20^{\circ}\;to\;27.3^{\circ}C$ $(total\;mean\;24.6^{\circ}C) $ and under this condition the fish continued normal growth. 4. The production per 1 l/min of inflowing water with this simple biofilteration reached 30 hg. 5. The total cost including all feed and power during this experimental rearing period fell well within the economic establishment and if the feed and filteration system are improved the benefit-cost ratio will be much increased.

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