• Journal of Navigation and Port Research
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• v.47 no.1
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• pp.25-36
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• 2023

To limit greenhouse gas emissions from ships, numerous environmental regulations and standards have been taken into effect. As a result, alternative fuels such as liquefied natural gas (LNG), liquefied petroleum gas (LPG), ammonia, and biofuels have been applied to ships. Most of these alternative fuels are low flashpoint fuels in the form of liquefied gas. Their use is predicted to continue to increase. Thus, management regulations for using low flash point fuel as a ship fuel are required. However, they are currently insufficient. In the case of LNG, ISO standards have been prepared in relation to bunkering. The Society for Gas as a Marine Fuel (SGMF), a non-governmental organization (NGO), has also prepared and published a guideline on LNG bunkering. The classification society also requires safety management areas to be designated according to bunkering methods and procedures for safe bunkering. Therefore, it is necessary to establish a procedure for setting a safety management area according to the type of fuel, environmental conditions, and leakage scenarios and verify it with a numerical method. In this study, as a feasibility study for establishing these procedures, application status and standards of the industry were reviewed. Classification guidelines and existing preceding studies were analyzed and investigated. Based on results of this study, a procedure for establishing a safety management area for bunkering in domestic ports of Korea can be prepared.

• Korean Chemical Engineering Research
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• v.56 no.4
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• pp.496-523
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• 2018

The objective of this study is to evaluate the economic feasibility of two fast pyrolysis and biooil upgrading (FPBU) plants including feed drying, fast pyrolysis by fluidized-bed, biooil recovery, hydro-processing for biooil upgrading, electricity generation, and wastewater treatment. The two FPBU plants are Case 1 of an FPBU plant with steam methane reforming (SMR) for $H_2$ generation (FPBU-HG, 20% yield), and Case 2 of an FPBU with external $H_2$ supply (FPBUEH, 25% yield). The process flow diagrams (PFDs) for the two plants were constructed, and the mass and energy balances were calculated, using a commercial process simulator (ASPEN Plus). A four-level economic potential approach (4-level EP) was used for techno-economic analysis (TEA) under the assumption of sawdust 100 t//d containing 40% water, 30% equity, capital expenditure equal to the equity, $H_2$ price of $1050/ton, and hydrocarbon yield from dried sawdust equal to 20 and 25 % for Case 1 and 2, respectively. TCI (total capital investment), TPC (total production cost), ASR (annual sales revenue), and MFSP (minimum fuel selling price) of Case 1 were $22.2 million, $3.98 million/yr, $4.64 million/yr, and $1.56/l, respectively. Those of Case 2 were $16.1 million, $5.20 million/yr, $5.55 million/yr, and $1.18/l, respectively. Both ROI (return on investment) and PBP (payback period) of Case 1(FPBU-HG) and Case 2(FPBU-EH) were the almost same. If the plant capacity increases into 1,500 t/d for Case 1 and Case 2, ROI would be improved into 15%/yr.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.53-59
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• 2015

Combustion characteristics for co-firing of biomass (Walnut Shell) as blending fuel in coal fired boiler have investigated using thermogravimetric analyser (TGA) and drop tube reactor (DTR). The results show that devolatilization and char combustion for WS occurs at lower temperature than those of existing coals and has lower activation energy value, which is resulting in higher reactivity. When the WS is blended with coal, TGA results show linear profiles depending on blending ratio for each fuel. However, DTR results exist the non-additive phenomena for blending of WS. As blending ratio of WS increase, the UBC decrease at BBR 5%, but the UBC rather increase from BBR 10% due to oxygen deficiency formed from rapid combustion of WS. This paper propose that fuel lean condition by oxygen rich lead to higher blending ratio of biomass by solving the oxygen deficiency condition.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.4
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• pp.525-529
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• 2016

Biomass co-firing to existing thermal power plants is one of the most economical and efficient way to reduce $CO_2$ emission from the plant. There are several methods of co-firing and it can be categorized into (1) Parallel co-firing, (2) Indirect co-firing, and (3) Direct co-firing. Parallel co-firing is the most expensive way to high-ratio co-firing because it requires biomass dedicated boiler. Direct co-firing is widely used because it does not need high capital cost compared with the other two methods. Regarding the direct co-firing, it can be classified into three methods- Method 1 does not need retrofit of the facilities because it uses existing coal mills for pulverizing biomass fuels. In this case high-ratio co-firing cannot be achieved because of poor grindability of biomass fuels. Method 2 needs biomass-dedicated mills and revision of fuel streams for the combustion system, and Method 3 needs additional retrofit of the boiler as well as biomass mills. It can achieve highest share of the biomass co-firing compared with other two methods. In Korea, many coal power plants have been adopting Method 1 for coping with RPS(Renewable portfolio standards). Higher co-firing ratio (> 5% thermal share) has not been considered in Korean power plants due to policy of limitation in biomass co-firing for securing REC(Renewable Energy Certificate). On the other hand, higher-share co-firing of biomass is widely used in Europe and US using biomass dedicated mills, following their policy to enhance utilization of renewable energy in those countries. Technical problems which can be caused by increasing share of the biomass in coal power plants are summarized and discussed in this report. $CO_2$ abatement will become more and more critical issues for coal power plants since Paris agreement(2015) and demand of higher share of biomass in the coal power plants will be rapidly increased in Korea as well. Torrefaction of the biomass can be one of the best options because torrefied biomass has higher heating value and grindability than other biomass fuels. Perspective of the biomass torrefaction for co-firing is discussed, and economic feasibility of biomass torrefaction will be crucial for implementation of this technology.

• Journal of the Korean Wood Science and Technology
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• v.41 no.4
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• pp.358-373
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• 2013

In this study, both mild acid and alkali treatments with 1.0 wt% and 2.0 wt% of $H_2SO_4$ and NaOH solution were applied to evaluate the effects on chemical compositions of wood biomass. Yellow poplar (Liriodendron tulipifera L.) and larch (Larix kaempferi C.) were chosen due to major species planted in Korea. Chemical treatments of biomass were carried out by being soaked in either acid or alkali solution with 1:20 ratio for 72 hours at ambient temperature. Afterward, lignin, 5 major reduced sugars, ash contents and elemental composition were determined. To statistically understand the relationship between samples and chemical treatments, the Tukey test, simple linear regression model and ANOVA analysis were introduced using a statistical software R. As results from both wet chemistry and statistical analysis, yellow poplar was more affected on the lignin and xylose contents by acid treatments under these experimental conditions. Meanwhile, larch was more affected on the composition of galactose and lignin by alkali treatments. A series of results in this study would show that equivalent chemical treatment makes a change the chemical composition of each species.

• Clean Technology
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• v.29 no.3
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• pp.163-171
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• 2023

Hydrogen has been gaining a lot of attention as a possible clean energy source that can aid in reaching carbon neutrality. Currently, hydrogen production has relied on the steam reforming of fossil fuels. However, due to the carbon dioxide emissions caused by this process, hydrogen production based on the steam reforming of bio-oil derived from biomass has been proposed as an alternative approach. In order to use this alternative approach efficiently, one of the key issues that must be overcome is that the complexity of bio-oil, which has a large molecular weight and diverse functional groups of hydrocarbons, promotes the catalytic deactivation of nickel-based catalysts. In this review, research efforts to improve nickel-based catalysts for the steam reforming of bio-oil have been discussed in terms of the active phase, support, and promoters. The active phases are involved in activating C-C and C-H bonds of high-molecular-weight hydrocarbons, and noble and transition metals can be utilized. In terms of the support and promoters, the catalytic deactivation of Ni-based catalysts can be inhibited by utilizing reactive lattice oxygen for support or by suppressing the acidity. The development of active and stable Ni-based reforming catalysts plays a critical role in clean hydrogen production based on bio-oils.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.119-119
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• 2017

부레옥잠은 대량 재배 및 수확이 가능한 수질정화용 식물로 생활하수, 축산폐수, 공장폐수 등의 수질정화 기능이 뛰어나고, 수확물은 건조 및 발효과정을 거쳐 가축 사료, 유기질 비료, 버섯 배지로 사용이 가능하고, 별도의 공업적 처리를 거치면 고부가가치의 바이오 연료, 연소용 연료로 사용이 가능한 친환경 농업 생산물로 본 연구에서는 부레옥잠의 고형연료 제조를 위한 수면에서 수확장치 개발을 위한 견인 특성을 파악하고 장치개발 가능성을 파악하고자 하였다. 부력구조물 부력, 부레옥잠 견인력, 부력을 측정하기 위한 실험 장치를 제작하여 부레옥잠 중량, 견인방식, 견인속도에 따른 견인력을 측정하였고, 경남 거제시에 위치한 저수지에서 실제 견인실험을 수행하였다. 실험결과 견인중량 및 견인 속도가 증가할수록 견인력은 증가하였으며 인력으로 부레옥잠을 견인하는 경우 부레옥잠 중량당 견인력은 약 $0.9{\sim}1.39kg_f$로 나타났으며 이는 향 후 부레옥잠 견인장치를 설계할 경우 부레옥잠 견인중량에 따른 견인력 산정 시 참고 자료로 매우 유용하게 활용 가능할 것으로 판단되었다. 저수지에서 견인실험 결과 견인속도 증가에 따른 유속저항으로 경운기에 의한 견인작업은 불가능하였으며 인력에 위한 견인 실험결과 부레옥잠 단위중량당 견인력은 견인바 3 m의 경우 1.5 ~ 2.6 N/kg, 견인바 6 m의 경우 2.1 ~ 5.4 N/kg로 비교적 크기로 나타났으나, 견인용 바에 따른 요인을 고려한 경우는 0.36 ~ 0.91 N/(kg-m)로 비교적 일정한 값을 보였다. 견인용 바 6 m, 무부하에서 인력과 경운기로 견인하는 경우 견인력은 39.24 N, 153.03 N으로 인력으로 견인하는 경우가 견인력이 작게 측정되었음. 이는 속도증가에 따라 물의 저항력이 증가함으로 나타난 결과로 부레옥잠 견인 시 견인속도는 0.36 m/s가 가장 적합한 것으로 판단되었다.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.348-361
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• 2015

To reduce the effects of greenhouse gas (GHG) emissions, the government has announced the special platform of technologies as parts of an effort to minimize global climate change, and the government distributed biodiesel since 2006 as the further efforts. Although there are some debates about some quality specifications and unbalanced of source (44% from palm oil), more than 400kton/year of biodiesel was produced in 2013. Moreover the amounts will be increased when the RFS is activated. To solve the unbalanced situation and to achieve the diversity of feeds, it is essential that many researches should be considered. Especially, free and bond glycerines are one of the important properties seriously affected to the combustion system in vehicle & cold properties. Previous method (KS M 2412) couldn't cover the biodiesel derived from lauric oil($C_{12:0}$) such as PKO (Palm Kernel Oil), Coconut oil because those compositions are lighter than other conventional biodiesel sources. In this study, we review the existed method and figure out the factors should improve to analysis the glycerine from PKO and Coconut oil biodiesel. Modifying the analysis conditions to enhance the resolution and change the internal standards to avoid the overlapped- peaks between Capric acid ME ($C_{10:0}$) and standard#1(1,2,4-butantriol). From this revised method, we could solve the restrictions of previous methods. And check the possibility of new method to analyze the glycerine in biodiesel regardless of sources.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.5
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• pp.223-229
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• 2020

Biodiesel produced using microorganisms, which are recognized as the third-generation biomass, is among the various known renewable energy sources that can replace fossil fuels used in conventional transportation. Scenedesmus obliquus has been identified as an excellent species for biodiesel production, as it grows faster and can accumulate up to 40-50 percent of the dry cell weight. Enhancing production using S. obliquus requires measuring the cell mass for controlling the cultivation process. In the current study, S. obliquus was cultured for 75 days, and growth changes of the microalgae were measured by absorbance, microscopic imaging, and Raman spectroscopy. Between days 60 to 75 of culture, the change in absorbance was observed to be less than 3%, whereas the number of microalgae observed microscopically was more than three times higher. Moreover, the Raman spectroscopy results showed three strong peak values of β-carotene at 997 cm^-1, 1148 cm^-1, and 1515 cm^-1, with peak values of β-carotene showing greater than 3-fold increase during the culture period. Therefore, we predict that application of Raman spectroscopy will help in identifying the growth elements and growth degree in microalgae culture during increased biomass production.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.2
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• pp.261-267
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• 2017

The interest in biodiesel is increasing rapidly. As a result, the price of vegetable oil that is used as a raw material for biodiesel is skyrocketing. Studies of biodiesel using animal waste as a means of solving these problems are underway. Biodiesel produced from animal fat contains considerably more saturated fatty acids than that produced from vegetable oil. In addition, it has a high cetane number and a high heating value. On the other hand, the fluidity decreases at lower temperatures because of the large amount of saturated fatty acids. For the biodiesel production, waste chicken oil and soybean oil were first purified. The raw materials were mixed at various ratios from 1:9 to 9:1. The methanol / oil molar ratio was also changed from 7 mol to 15 mol. The entire reaction time was one hour. The results showed that the optimal mixing ratio of soybean oil to waste chicken oil was 3:7, and the optimal methanol / oil molar ratio was 13. Moreover, the BD yield was 90.2%, the FAME content was 96.6%, and the LAME content was 4.1%. This result satisfied the Korea Industrial Standard (KSM2413).