• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.589-593
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• 2007

재생 가능한 자원인 동식물성 기름을 원료로 제조되는 수송용 연료 바이오디젤은 낮은 대기오염물질 배출과 $CO_2$ Neutral 특성으로 환경친화적인 연료로 인정을 받으며 전세계적으로 그 생산량이 급격히 증가하고 있다. 대부분의 상용화 공정은 염기촉매를 이용한 전이에스테르화 반응에 근거하고 있으며 높은 생산성을 위해 연속 공정을 채택하고 있다. 원료유 중의 유리지방산(free fatty acid, FFA)은 염기 촉매와 반응하여 지방산염(Soap)과 수분을 생성하며 반응촉매의 투입양을 증가시카고 반응 후에 글리세롤과 지방산 메틸에스테르와의 분리를 어렵게 만든다. 높은 수율과 후속공정의 부하를 줄이기 위해서는 식물성 원료유 중의 FFA는 고체 산촉매 하에서 메탄올과 에스테르화 반응시켜 전환 제거되어야 한다. 본 연구에서는 고체산 촉매인 Amberlyst-15을 충전한 4단 PBR(Packed Bed Reactor, 충전율 60%(v/v))에서 반응시간과 반응온도에 따른 대두원유의 전처리 효율을 조사하였으며 최적 전처리 조건을 도출하였다. 최적 전처리 조건에서 대두원유는 초기 산가 1.6에서 0.4-0.6으로 연속 전처리할 수 있었다. 본 연구에서는 연속 흐름 반응기인 PFR(Plug Flow Reactor)와 4단 CSTR(Continuous Stirred Tank Reactor)에서 균질계 촉매인 KOH 존재하에 대두유와 메탄올과의 전이에스테르화 반응 특성을 조사하였으며 각 연속 반응시스템에서 최적 운전 조건을 도출하였다. PFR 반응기에서 반응온도, 반응시간, 반응물 흐름방향, static mixer(SM) 개수에 따른 반응특성을 조사한 결과, PFR에서의 최적 반응조건은 하향류 흐름 방향과 3개의 SM를 설치한 조건에서 반응시간 5.8분, 반응온도 90$^{\cdot}C$, 메탄올:오일 몰비 9:1, KOH 농도 0.8%로 도출되었다. CSTR 반응기에서는 반응온도와 체류시간에 따른 반응특성을 조사하였으며 최적반응 조건으로 반응온도 80$^{\cdot}C$, 메탄올/오일 몰비 9:1, KOH 농도 0.8%, 체류시간 18.4분, 교반속도 250rpm로 조사되었다.

• 사료
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• s.62
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• pp.54-57
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• 2013

차랑 등의 수송연료인 휘발유나 경유에 일정비율을 식물에서 뽑아낸 신재생연료 즉 바이오 연료를 혼합하여 공급하도록 의무화하여 온실가스 배출을 줄이기 위한 신재생연료 혼합의무제도(RFS) 국내 시행방안과 관련한 공청회가 지난 2월 15일 서울교육문화회관에서 지식경제부 주최와 한국석유관리원 주관으로 개최됐다. 정부는 2020년까지 경유나 휘발유에 바이오 디젤 에탄올을 4~5% 섞게 하여 동 기간까지 온실가스 감축목표량 중 8~10%까지 달성한다는 계획을 세워놓고 있다. 하지만 녹색연대 등 민간단체들은 온실가스 감축 효과는 매우 불확실하며 특히 어떤 원료를 쓰느냐에 따라 오히려 기후변화를 악화시킬 수 있다는 주장과 산림훼손, 세계 곡물가 상승, 국내 유가 상승 등 많은 문제점들이 있음을 우려해 강하게 반대를 표명하고 있는 입장이다. 우리 협회에서도 곡물을 이용한 에탄올의 혼합의무가 시행되는 경우 옥수수 등 사료원료가격의 상승으로 가뜩이나 어려운 축산업의 경영상황을 더욱 약화시키게 될 것이 예견되는 바, 동 혼합의무제도의 시행을 적극 반대하는 대 국회 및 정부활동을 전개한 바 있다. 그 결과 지난 4월 17일 국회 지식경제위원회 법률심사소위원회에서는 신재생연료 혼합의무제도의 시행 시기를 2년간 유보하고 혼합의무연료에서 에탄올을 제외시키는 방안을 논의한 바 있어 향후 입법과정에 관심이 모아지고 있다. 이에 따라 본지는 이번 RFS의 국내 시행과 관련하여 어떠한 문제점들이 있는지 관련 업계 종사자의 글을 통해 알아본다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2010.04a
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• pp.79-85
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• 2010

• Proceedings of KOSOMES biannual meeting
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• 2007.11a
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• pp.133-137
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• 2007

An experimental study is conducted to evaluate and compare the use of BiodieseDI Fuel supplements at blend ratio of 10/90(BDF10) and 20/80(BDF20), in four stroke, direct injection diesel engine located at the authors' laboratory. especially this Biodiesel is produced from Rape oil at the authors' laboratory. The tests are conducted using each of the above fuel blends, in the engine working at a speed of 1800rpm and at a various loads. In each test, specific fuel consumption, exhaust emissions such as nitrogen oxides(NOx), carbon monoxide(CO) and Soot are measured. The results of investigation at various operating conditions are as follows (1) Specific fuel consumption is increased average 1.52%, maximum 1.84% at load 25% in case of BDF10, and average 1.98%, maximum 2.80% at load 25% in case of BDF20. (2) CO emission is decreased average 5.14%, maximum 6.09% at load 0% in case of BDF10, and average 7.75%, maximum 9.13% at load 0% in case of BDF 20. (3) NOx emission is increased average 2.97%, maximum 3.74% at load 0% in case of BDF10, and average 3.84%, maximum 4.67% at load 0% in case of BDF20. (4) Soot emission is decreased average 9.36%, maximum 10.85% at load 75% in case of BDF10, and average 11.99%, maximum 13.95% at load 75% in case of BDF20.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.2
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• pp.43-48
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• 2008

The exhaust emissions of diesel engine are recognized as a major cause influencing environment strongly. In this study, the possibility of biodiesel fuel and oxygenated fuel(dimethoxy methane; DMM) was investigated as an alternative fuel for a naturally aspirated direct injection diesel engine. The smoke emission of blending fuel(biodiesel fuel 90vol-%+DMM 10vol-%) was reduced approximately 70% at 2500rpm, full load, in comparison with the diesel fuel. But, power, torque and brake specific energy consumption showed no significant differences. But, NOx emission of biodiesel fuel and DMM blended fuel increased compared with commercial diesel fuel due to the oxygen component in the fuel. It was needed a NOx reduction counterplan that EGR method was used as a countermeasure for NOx reduction. It was found that simultaneous reduction of smoke and NOx emission was achieved with BDF(95 vol-%) and DMM(5 vol-%) blended fuel and cooled EGR method(15%).

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.4
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• pp.75-80
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• 2008

Biodiesel fuel(BDF) can be effectively used as an alternative fuel in diesel engine. However, BDF may affect the performance and exhaust emissions in diesel engine because it has different physical and chemical properties from diesel fuel such as viscosity, compressibility and so on. To investigate the effect of injection timing on the characteristics of performance and exhaust emissions with BDF in IDI diesel engine, it was applied the BDF derived from soybean oil in this study. The engine was operated at seven different injection timings from TDC to BTDC $12^{\circ}CA$ and six loads at a single engine speed of 1500rpm. When the fuel injection timing was retarded, better results were showed, which may confirm the advantages of BDF. The simultaneous reduction of smoke and NOx was achieved at some fixed fuel injection timings of an IDI diesel engine.

• Transactions of the Korean Society of Automotive Engineers
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• v.21 no.4
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• pp.135-143
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• 2013

In this study, we suggested effective countermeasure of biodiesel oxidation problems by investigating the oxidation degradation of biodiesels derived from variable resources and the level of oxidation stability of current distributing biodiesel blended fuels (2%) in Korea, and oxidation stability change according to storage time (for 3 month) and biodiesel blending ratio (2, 5, 7, 10%). By the composition analysis results of biodiesel from various resources which are possible to distribute in Korea, the biodiesel from animal fat has poor oxidation stability and cold performance, while the biodiesel from coconut and palm kernel which are considered as future potential raw material showed good oxidation stability and cold performance. The oxidation stability level of current distributing biodiesel blended fuels in Korea was excellent with showing over 30 hours (average 68 hours) stability, but the oxidation stability of the blended fuel with animal fat biodiesel having poor oxidation property (1.22 hours) was rapidly decreased to below 32 hours by mixing only 2%. Therefore, we have to pay attention to quality control of oxidation property, because the oxidation stability problem can be caused by increasing biodiesel blending ratio and diversifying raw materials those have worse property.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.1048-1056
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• 2018

Non-edible oil sources (i.e., Palm Acid Oil, waste animal fat) usually contain relatively high amount of free fatty acids (FFA) that make them inadequate for direct base catalyzed transesterification reaction. Enzymatic biodiesel synthesis can solve several problems posed by the alkaline-catalyzed transesterification, and has certain advantages over the chemical catalysis of transesterification, as it is less energy intensive, allows easy recovery of glycerol and the transesterification of glycerides with high free fatty acid contents. In this study, we synthesized biodiesel through enzymatic catalyzed process using high free fatty acid containing waste oil in biodiesel reactor (1 ton/day) and optimized the biodiesel production processes.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.5
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• pp.59-65
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• 2014

Diesel engines have the superior combustion efficiency and fuel economy that they are widely used for industry, heavyduty vehicles, etc. However, its exhaust emissions have become the major concerns due to their environmental impacts. Moreover, the depletion of fossil fuels is the main issue. Therefore, it is important to look for alternative sources of energy. Bio-diesel is one of the ideal energy which has proved to be ecofriendly for more than fossil fuels. The experimental tests analysed the engine performance and emission characteristics of a diesel engine using diesel and biodiesel blended of BD25, BD45 and BD65, in order to study the use of clean fuel to meet the increasingly stringent emission regulations. The engine performance was examined by using engine dynamometer while an exhaust gas analyzer was used to examine the emission characteristics. The effect of biodiesel on engine performance were lower to diesel through comparing their HP and torque but fuel consumption was slightly increased because of biodiesel has lower heating value and higher density than diesel. However, due to the better lubricity, the brake thermal efficiency of biodiesel was higher than diesel. The emission characteristics were strongly affected by the blending ratio of diesel and biodiesel. The results showed that the smoke opacity, hydrocarbons (HC) and carbon monoxide (CO) emissions decreased while the nitrogen oxides (NOX) slightly increased.

• Journal of ILASS-Korea
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• v.18 no.4
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• pp.182-187
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• 2013

This study was performed to investigate the effect of biodiesel derived from waste cooking oil on the spray behavior and macroscopic spray characteristics. To analyze quantitative characteristics of test fuels, injection quantity was measured at various injection pressures and the spray images of injected fuels in the pressurized chamber were obtained by using a high speed camera and image analysis system. Based on the measured spray images, the spray tip penetration and spray cone angle were investigated at various energizing timings and injection pressures. In this work, the experimental results showed that the injection quantity of waste cooking biodiesel indicated the higher quantities than diesel at high injection pressure. As the injection pressure was increased, the spray tip penetrations of biodiesel were higher value than diesel. The difference of penetration between biodiesel and conventional diesel fuel was reduced in accordance with the increase of injection pressure. Also, the spray angles of diesel were larger than that of biodiesel because diesel fuel has lower viscosity than biodiesel. In addition, the spray evolution processes of biodiesel fuel at various injection pressures and the elapsed time after the injection were compared to the conventional diesel fuel.