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http://dx.doi.org/10.7467/KSAE.2013.21.4.135

A Study on Evaluation of Oxidation Degradation of Bidiesel and Biodiesel Blended Fuel Distributing in Domestic  

Min, Kyong-Il (Green Technology R&D Center, Korea Institute of Petroleum Management)
Yim, Eui Soon (Green Technology R&D Center, Korea Institute of Petroleum Management)
Na, Byung-Ki (Department of Chemical Engineering, Chungbuk National University)
Jung, Choong-Sub (Green Technology R&D Center, Korea Institute of Petroleum Management)
Publication Information
Transactions of the Korean Society of Automotive Engineers / v.21, no.4, 2013 , pp. 135-143 More about this Journal
Abstract
In this study, we suggested effective countermeasure of biodiesel oxidation problems by investigating the oxidation degradation of biodiesels derived from variable resources and the level of oxidation stability of current distributing biodiesel blended fuels (2%) in Korea, and oxidation stability change according to storage time (for 3 month) and biodiesel blending ratio (2, 5, 7, 10%). By the composition analysis results of biodiesel from various resources which are possible to distribute in Korea, the biodiesel from animal fat has poor oxidation stability and cold performance, while the biodiesel from coconut and palm kernel which are considered as future potential raw material showed good oxidation stability and cold performance. The oxidation stability level of current distributing biodiesel blended fuels in Korea was excellent with showing over 30 hours (average 68 hours) stability, but the oxidation stability of the blended fuel with animal fat biodiesel having poor oxidation property (1.22 hours) was rapidly decreased to below 32 hours by mixing only 2%. Therefore, we have to pay attention to quality control of oxidation property, because the oxidation stability problem can be caused by increasing biodiesel blending ratio and diversifying raw materials those have worse property.
Keywords
Oxidation stability; Biodiesel; Biodiesel blended fuels; Fatty acid methyl ether; Quality specification;
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  • Reference
1 Biodiesel Handling and Use Guide, 4th Edn., NREL Report, NREL/TP-540-43672, 2009.
2 Establishment of the Guidelines for the Development of Biodiesel Standards in the APEC Region, APEC Report, EWG 02/2007A, 2009.
3 A. Monyem and J. H. V. Gerpen, "The Effect of Biodiesel Oxidation on Engine Performance and Emissions," Biomass. Bioenerg. Vol.20, pp.317-325, 2001.   DOI   ScienceOn
4 Petroleum and Petroleum Alternative Fuels Law, MKE Law, Korea, 2012.
5 K. J. Boo and J. H. Bae, A Study on Establishment of the 3rd Basic Plan for New and Renewable Energy Technology Development, Application, and Deployment, MKE Report, Korea, 2008.
6 E. S. Yim and J. G. Kim, Study for Introducing Renewable Fuel Standard (RFS), MKE Report, Korea, 2010.
7 H. S. Gwon and S. M. Jo, Establishment Plan of Biodiesel Resources Supply and Demand System, MKE Report, Korea, 2011.
8 G. Y. Jeong and L. H. Kim, Test of Biodiesel Oxidation Property, K-PETRO Report, Korea, 2007.
9 E. S. Yim and C. H. Jeon, Property and Performance Test of Biodiesel Fuels, MKE Report, Korea, 2007.
10 S. K. Hoekman, A. Broch, C. Robbins, E. Ceniceros and M. Natarajan, "Review of Biodiesel Compositions, Properties, and Specifications," Renew. Sust. Energ. Rev., RSER-1549, 2009.
11 Y. Abe, M. Toba, T. Mochizuki and Y. Yoshimura, "Influence of Degree of Unsaturation of Fatty Acid Methyl Ether on Oxidative Deterioration Behavior of Model Biodiesel Mixed Diesel Fuel," J. Jpn. Petrol. Inst., Vol.52, No.6, pp.359-360, 2009.   DOI   ScienceOn
12 J. A. Waynick, Characterization of Biodiesel Oxidation and Oxidation Products, NREL Report, CRC Project No.AVFL-2b, 2005.
13 T. T. Kivevele, M. M. Mbarawa, Á. Bereczky and M. Zoldy, "Evaluation of the Oxidation Stability of Biodiesel Produced from Moringa Oleifera Oil," Energ. Fuel, Vol.25, pp.5416-5421, 2011.   DOI   ScienceOn
14 N. A. Santos, S. S. Damasceno, P. H. M. deAraújo, V. C. Marques, R. Rosehhaim, V. J. Fernandes, N. Queiroz, I. M. G. Santos, A. S. Maia and A. G. Souza, "Caffeic Acid: An Efficient Antioxidnat for Soybean Biodiesel Contaminated with Metals," Energ. Fuel, Vol.25, pp.4190-4194, 2011.   DOI   ScienceOn
15 A. Obadiab, R. Kannan, A. Ramasubbu and K. S. Vasanth, "Studies on the Effect of Antioxidnats on the Long-term Storage Stability and Oxidation Stability of Jatropha Biodiesel," Int. J. Res. Chem. Environ, Vol.2, Issue 1, pp.130-139, 2012.
16 G. Karavalakis and S. Stournas, "Impact of Antioxidant Additives on the Oxidation Stability of Diesel/Biodiesel Blends," Energy & Fuels, Vol.24, Issue 6, pp.3682-3686, 2010.   DOI   ScienceOn
17 S. Jain and M. P. Sharma, "Correlation Development for the Effect of Metal Contaminants on the Thermal Stability of Jateropha Curcas Biodiesel," Energ. Fuel, Vol.25, pp.1276-1283, 2001.
18 M. M. Conceiḉao, V. J. Fernandes, A. S. Araujo, M. F. Farias, I. M. G. Santos and A. G. Souza,. "Thermal and Oxidative Degradation of Castor Oil Biodiesel," Energ. Fuel, Vol.21, pp.1522-1527, 2007.   DOI   ScienceOn
19 Y. Abe, M. Toba, T. Mochizuki and Y. Yoshimura, "Oxidative Degradation Behavior of Fatty Acid Methyl Ester in Fish Oil Biodiesel and Improvement of Oxidation Stability by Partial Hydrogenation," J. Jpn. Petrol. Inst., Vol.52, No.6, pp.307-315, 2009.   DOI   ScienceOn
20 C. S. Jung, Y. J. Lee and J. I. Dong, "Life Time Estimation of Biodiesel and Biodiesel Blend Fuel from the Oxidation Stability Analysis," Journal of The Korean Society for New and Renewable Energy, Vol.3. No.22, pp.17-23, 2007.
21 C. Y. Lin and C. C. Chiu, "Effects of Oxidation during Long-term Storage on the Fuel Properties of Palm Oil-based Biodiese," Energ. Fuel, Vol.23, pp.3285-3289, 2009.   DOI