• Polymer(Korea)
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• v.28 no.3
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• pp.218-224
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• 2004

The adhesion and proliferation of mammalian cells on polymeric biomaterials depend on the surface characteristics such as wettability, chemistry, charge and roughness. In order to recognize the correlation between the adhesion and proliferation of human bone marrow derived stem cells (BMSCs) and surface property, radio frequency generated plasma treatment on low density polyethylene (LDPE) has been carried out. The modified LDPE surfaces were characterized by measuring the static water contact angle. The adhesion and proliferation of cells on LDPE films were characterized by cell counting and reverse transcription-polymerase chain reaction (RT-PCR). The water contact angle of the film surface decreased with plasma treatment time. Proto-oncogenes (c-myc, c-fos) and tumor suppressor gene (p153) showed maximum expression with contact angle of 60 ∼ 70$^{\circ}$ range of LDPE film. By cell counting, we confirmed that the rate of cell proliferation appeared the higher on the film surface of the contact angle of 60∼70$^{\circ}$ We concluded that the surface wettability is an important role for the growth and differentiation of BMSCs.

• Membrane Journal
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• v.34 no.1
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• pp.58-69
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• 2024

Reverse electrodialysis (RED) is an electro-membrane process employing ion-exchange membranes (IEMs) that can harvest electric energy from the concentration difference between seawater and river water. Multivalent ions contained in seawater and river water bind strongly to the fixed charge groups of the IEM, causing high resistance and reducing open-circuit voltage and power density through uphill transport. In this study, a pore-filled anion-exchange membrane (PFAEM) with excellent monovalent ion selectivity and electrochemical properties was fabricated and characterized for RED application. The monovalent ion selectivity of the prepared membrane was 3.65, which was superior to a commercial membrane (ASE, Astom Corp.) with a selectivity of 1.27 under the same conditions. Additionally, the prepared membrane showed excellent electrochemical properties, including low electrical resistance compared to ASE. As a result of evaluating RED performance under seawater of 0.459 M NaCl/0.0510 M Na₂SO₄ and river water of 0.0153 M NaCl/0.0017 M Na₂SO₄, the maximum power density of 1.80 W/m² was obtained by applying the prepared membrane, which is a 40.6% improved output performance compared to the ASE membrane.

• Membrane Journal
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• v.34 no.1
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• pp.70-78
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• 2024

A photo-crosslinked anion exchange membrane (AEM) based on quaternary-aminated polyacrylates was developed for reverse electrodialysis (RED). Although reverse electrodialysis is a clean and renewable energy generation system, the low power output and high membrane cost are serious obstacles to its commercialization. Cross-linked AEMs without any polymer supporters were fabricated through photo-crosslinking between polymer-typed acrylates with anion conducting groups, in particular, polymer-typed acrylates were synthesized based on engineering plastic with outstanding mechanical and chemical property. The fabricated membranes showed outstanding physical, chemical, and electrochemical properties. The area resistance of the fabricated membranes (CQAPPOA-20, CQAPPOA-35, and CQAPPOA-50) were ~50% lower than that of AMV (2.6 Ω cm²). Moreover, the transport number of CQAPPOA-35 wase comparable to that of AMV, despite the thin thickness (40 ㎛) of the fabricated membranes. The RED stack with the CQAPPOA-35 membrane provided an excellent maximum power density of 2.327 W m^-2 at a flow rate of 100 mL min^-1, which is 15% higher than that (2.026 W m^-2) of the RED stack with the AMV membrane. Considering easy fabrication process by UV photo-crosslinking and outstanding RED stack properties, the CQAPPOA-35 membrane is a promising candidate for REDs.

• Membrane Journal
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• v.27 no.2
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• pp.109-120
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• 2017

The reverse electrodialysis (RED) is an energy generation system to convert chemical potential of saline water directly into electric energy via the combination of current derived from a redox couple electrolyte and ionic potential obtained when cation ($Na^+$) and anion ($Cl^-$) pass through cation exchange membrane (CEM) and anion exchange membrane (AEM) into fresh water, respectively. Ion exchange membrane, a key element of RED system, should satisfy requirements such as 1) low swelling behavior, 2) a certain level of ion exchange capacity, 3) high ion conductivity, and 4) high perm-selectivity to achieve high power density. In this paper, research trends and prospects of ionomer materials and ion exchange membranes are dealt with.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.9 no.4
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• pp.435-445
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• 1997

It was studied the phenomena of transient freezing of an inclined water-saturated enclosure. One side of the test section was cooled and the other sides were insulated. The effects of the initial temperature, the inclination angle on the temperature field and the shape of the ice-water interface were observed. In the beginning of freezing, with increasing the inclination angle the freezing rate was increased and in the stable density layer centered $4^{\circ}C$, the freezing was fast as the convective fluid flow became small. When the initial temperature was above the $4^{\circ}C$, the frozen thickness in the upper part of inclined surface was thinner than that in the lower part, but with time the frozen thickness of upper part was thicker than that of lower part, below the $4^{\circ}C$, the frozen thickness in the upper part was thicker than that of lower part from the begining, and above the $8^{\circ}C$ in the beginning upper part was thinner with concave, but with time thicker the upper part, vanishing concave.

• Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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• 2004.03a
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• pp.487-492
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• 2004

본 연구에서는 인공신경망 기법을 이용하여 산사태 발생원인에 대한 가중치를 구하였다. 여름철 집중호우시 산사태가 많이 발생하는 강원도 강릉시 사천면 사기막리 와 주문진읍 삼교리에 해당한다. 산사태가 발생할 수 있는 요인으로 지형도로부터 경사, 경사방향, 곡률, 수계추출을, 정밀토양도로부터 토질, 모재, 배수, 유효토심, 지형을, 임상도로부터 임상, 경급, 영급, 밀도를, 지질도로부터 암상을, Landsat TM 영상으로부터 토지이용도와 추출하여 격자화 하였으며, 아리랑1호 영상으로부터 선구조를 추출하여 l00m 간격으로 버퍼링 한 후 격자화 하였다. 이렇게 구축된 산사태 발생 위치 및 발생요인 데이터 베이스를 이용하여 인공신경망 기법을 적용하여 산사태 발생 원인에 대한 상대적인 가중치를 구하였다. 인공신경망의 역전파 알고리즘을 이용한 사기막리 지역과 삼교리 지역의 산사태 가중치를 보면 GPS를 이용한 현장조사와 위성영상을 이용한 변화탐지 기법모두의 경우모두와 훈련지역을 실제 산사태 발생 지역과 경사도가 0°인 지역, 실제 산사태 발생 지역과 Frequence ratio를 이용하여 작성한 취약성도에서 산사태 발생이 낮을 것으로 예상되는 지역, Frequence ratio를 이용한 취약성도에서 산사태 발생이 높을 것으로 예상되는 지역 과 낮을 것으로 예상되는 지역의 경우에서도 경사도는 1.5～2.5배정도 높은 상대적 가중치를 나타냈다. 이러한 가중치는 산사태 취약성도를 작성하는데 활용될 수 있다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.4
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• pp.350-358
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• 2009

This paper describes a result of the guidance and control for re-entry vehicle during TAEM phase. TAEM phase (Terminal Aerial Energy Management phase) has many conditions, such as density, velocity, and so on. Under these conditions, we have optimized trajectory and other states for guidance in TAEM phase. The optimized states consist of 7 variables, down-range, cross range, altitude, velocity, flight path angle, vehicle's azimuth and flight range. We obtained the optimized reference trajectory by DIDO tool, and used feedback linearization with neural network for control re-entry vehicle. By back propagation algorithm, vehicle dynamics is approximated to real one. New command can be decided using the approximated dynamics, delayed command input and plant output, NARMA-L2. The result by this control law shows a good performance of tracking onto the reference trajectory.

• Applied Chemistry for Engineering
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• v.21 no.6
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• pp.621-626
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• 2010

Anion exchange membranes can be used for reverse electrodialysis for electric energy generation, and capacitive deionization for water purification, as well as electrodialysis for desalination. In this study, anion exchange membranes of poly((vinylbenzyl) trimethylammonium chloride-2-hydroxyethyl methacrylate)/poly(vinyl alcohol) were prepared through the polymerization of (vinylbenzyl)trimethylammonium chloride and 2-hydroxyethyl methacrylate in aqueous poly(vinyl alcohol) solutions, esterification with glutaric acid, and cross-linking reaction with glutaraldehyde. We investigated electrochemical properties for the anion exchange membranes prepared according to experimental conditions. Ion exchange capacity and electrical resistance for the membranes were changed with a variation in the monomer ratio in polymerization. Water uptake and conductivity for the membranes decreased with an increase in the content of glutaric acid in esterification. The change in the time of crosslinking reaction with the formed film and glutaraldehyde affected electrochemical properties such as water uptake, conductivity, or transport number for the membranes. Chronopotentiometry and limiting current density for the anion exchange membranes prepared were measured.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.3 no.1
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• pp.34-44
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• 1998

Analysis of gravity, magnetic, and seismic reflection data from the Ulleung Basin, East Sea has provided some insights into the opening mechanism and crustal type of the basin. Free-air gravity anomaly data show positive anomalies of about 40~60 mgal near the Korea Plateau and Oki Bank and of about -20~20 mgal in the central basin. Bouguer gravity anomaly data exhibit NE-SW trending positive anomalies of about 150 mgal in the central basin which is interpreted to be related to high-density crustal material. Abrupt changes in both Free-air and Bouguer gravity anomaly profiles across the basin margins may be due to transition between continental and oceanic crusts. Magnetic anomalies in the basin are generally less than -400 nT. No stripe pattern is evident in the magnetic anomaly map but a NW-SE trending symmetric pattern is seen in some magnetic profiles. The symmetric pattern is probably associated with the high-density crustal material in the central basin suggested by Bouguer gravity anomaly. The acoustic basement in the deep part of the basin has only a small amount of local relief. No graben or half-graben structures are seen in the acoustic basement from which mechanical extension might be inferred. The lack of high-relief structures in the acoustic basement may suggest that the basin is underlain by oceanic crust or that the basement is overlain by thick volcanic layer which obscures the structures and relief of the basement. High-density crust in the central basin inferred from gravity data, abrupt changes in gravity anomalies across the basin margins, symmetric pattern seen in some magnetic anomaly profiles, and lack of relief in the acoustic basement may suggest sea-floor spreading origin of the Ulleung Basin.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.341-348
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• 2016

At present, about 40 million tons of concrete is dismantled each year, which accounts for the largest portion of the total amount of construction waste with 60.8%. It is known about 97.5% of it is recycled. However, most of the usage of waste concrete is limited to lower value-added business areas, and considering the increasing amount of waste concrete generated due to the deterioration of structures, the need for converting waste concrete to structural concrete is urgent. Therefore, this study aims at estimating the period for the optimum carbonation reforming to improve the quality of recycled aggregate, by making use of the method of accelerated carbonation reforming of the bonding heterogeneous (cement paste and mortar) for the purpose of converting recycled aggregate to structural concrete. Based on the period appropriate for the heterogeneous thickness and each bonding thickness of recycled aggregate which was drawn from previous studies, the changes in the characteristics and physical properties of pore structure according to progress of accelerated carbonation were analyzed. The result shows that with the progress of carbonation, the pore volume and the percentage of water absorption of the bonding heterogeneous decreased and the density increased, which indicates improvement of the product quality. But after certain age, the tendency was reversed and the product quality deteriorated. Synthesizing the results of previous studies and those of the present study, this study proposed 4 days and 14 days respectively for the period for the optimum carbonation reforming of recycled fine aggregate and recycled coarse aggregate.