• Journal of Korean Society of Environmental Engineers
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• v.22 no.4
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• pp.689-698
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• 2000

The quality of stormwater runoff has been a major concern in water quality preservation. Characteristics of heavy metals and conventional pollutants in surface runoff from industrial complex, during the first flush, were not completely understood, Generally, separated sewer system is known for their water quality with untreated wastewater during storm events. In this study, the quality and characteristics of surface runoff from the industrial complex were investigated. The target area in the industrial complex catchment was divided 4 sub-areas, and the quality of stormwater runoff from the selected drainage areas was investigated using a grab sampling method. The petro-chemical industry and the junkyard discharged relatively high concentration of conventional pollutants, such as BOD, COD, SS, and TN through the first flush runoff samples. On the other hand, a higher level of heavy metals was found in the first flush runoff from the metal-mechanical industry and the scrap storage yard. For metals, Fe, Zn and Cu were the most prevalent species found in the first flush runoff from all sites for every surface runoff samples, while Pb, As, Cd, Cr and Ni were the least prevalent species and Hg was not found in any sample at any site. These results suggest that the nature of pollutants in surface runoff from the industrial complex was related to the type of industry, and the concentration of pollutants was determinated by the degree of exposed pollutant sources and the characteristic of rainfall events at the sites.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.353-357
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• 2012

The new qualitative and quantitative analytical method for hydrocarbon compounds in DME-LPG blending fuel, mixing dimethyl ether (DME) with liquefied petroleum gas (LPG), by using gas chromatography (GC) was investigated. It is difficult to analyze all components of DME-LPG blending fuel by using single column in GC due to consisting of the non-polar LPG and the polar DME which is oxygen-containing compound. Therefore, it has been introduced the Deans switching system, which are useful for analyzing mixtures of a very different nature and/or target analytes in very complex matrix. This technique is to control the pressure between two columns and to selectively change the path of effluent flows to either one of two columns. As a result, we found that DME and LPG can be completely separated at the different columns and the determination of all hydrocarbon compounds in DME-LPG blending fuel can be achieved to this method qualitatively and quantitatively during the operation of one injection. In addition, this method can be applied to the determination of trace components of by-product, such as methanol, methyl formate and ethyl methyl ether, which will be derived from DME synthesis process.

• Korean Chemical Engineering Research
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• v.53 no.4
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• pp.496-502
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• 2015

Hydrocarbon dew point(HCDP), a property which is the most generally used for describing natural gas condensation, is a very important parameter of natural gas quality specifications. HCDP is strongly influenced by the concentration of the heavier hydrocarbon components, especially $C_6+$, so, along with compliance with gas quality specifications, build up of procedures for obtaining accurate HCDP is essential for gas transmission company, because hydrocarbon condensation present may cause serious operational and safety problems. This study has been carried out in an attempt to measure HCDP accurately by the automatic hydrocarbon dew point meter under the actual field conditions. Measured HCDP also has been compared with calculated HCDP using the composition determined by gas chromatograph and industry accepted equation of state at multiple pressures, along with the cricondentherm. The test results are 1) the automatic hydrocarbon dew point meter was able to measure stable HCDP continuously 2) the automatic hydrocarbon dew point meter has been performed reference measurement by pure propane with a known dew point from literature, and 3) A meaningful differences was observed when comparing the automatic hydrocarbon dew point meter and gas chromatograph results for synthetic standard gas mixtures and real gas mixtures.

• Food Science and Preservation
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• v.9 no.4
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• pp.391-395
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• 2002

Thinned fruits, apple, pear and peach were investigated into chemical components and physiological activities. On proximate compositions, crude protein, crude fat and ash of thinned fruits were higher than those of ripe fruits, showing lower carbohydrate in thinned fruits. The contents of inorganic substance were Ca, Mg, P, Na, K and B in order. On heavy metals, As, Cd, Cr and Hg were not detected and Ge, Mo, Ni and Pb were trace. Organic acid in thinned apple and peach were detected as tartaric acid, citric acid, malic acid and succinic acid, but thinned pear did not contain citric acid. Free sugars in thinned pear and peach were composed of glucose, fructose and sucrose but sucrose was not detected in thinned apple. Contents of insoluble dietary fiber in thinned fruits were higher than soluble dietary fiber. The thinned apple extracts showed high antioxidant activity. Nitrite scavenging activity of thinned apple and pear extracts were 71∼80 e/o and 61∼63% at pH 1.2, respectively. Tyrosinase inhibitory activity of thinned pear extracts was 61.0∼89.4 ％, however peach extinct showed no activity.

• Journal of The Korean Society of Grassland and Forage Science
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• v.12 no.3
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• pp.64-129
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• 1992

최근 초지중심 사양형태의 증가와 초지면적의 확대에 따라 단순한 사료로서가 아니라 영양가치가 높고 기호성이 높은 목초생산이 요구되고 있다. 그러나, 고위생산을 위해 다량으로 사용된 질소질비료에 의하여 질산태 중독 등의 문제가 야기되고 있어 목초의 생리 및 영양에 관한 연구가 필요하게 되었다. 사료성분 혹은 영양가치에 대한 연구는 이미 일찍부터 다루어져 왔으나, 주로 야초류, 청예작물 및 농가부산물 등의 일반성분 특히, 조단백질과 조섬유함량의 연구가 주가 되었고 다년생 목초류에 대한 연구는 1975년경부터 본격화 되기 시작하였다. 그동안 한국초지학회지와 축산학회지($1972\sim1991$)에 게재된 총 151편의 생리 및 영양에 관한 연구 중에서 다년생 목초류를 취급한 것은 불과 63편에 머물고 있다. 이 분야의 연구는 각종 목초 사료작물에 대한 재배조건과 생육단계에 따른 생리생태학적 연구와 사료성분, 소화율 및 가소화양분 함량의 일반적인 변화, 경향을 검토하여 사료 가치 평가를 위한 기준으로 삼았다. 그러나 다년생 목초류는 물론 사료 작물에 있어서 육종 생리분야의 연구는 매우 미흡한 상태로써 단지 발아, 생육, 저장탄수화물 및 유독성분 등 단편적인 연구만이 행해지고 있을 뿐이다. 또한 사료 성분이 가축의 기호성에 미치는 영향을 구명하기 위한 연구는 거의 이루어지고 있지 않으므로 금후 탄수화물과 미량 요소에 대한 자세한 연구 검토가 필요하다고 생각된다. 특히 목초와 사료작물의 화학적인 조성과 가축의 생리에 관련한 여러가지 문제들도 앞으로 보다 깊이 연구되어야 할 과제라고 생각된다.권을 잡기 위해 10년지기였던 IBM과 MS사는 각각 OS/2와 윈도즈를 내세우고 양보할 수 없는 힘겨루기에 들어갔다. 또 이들 양사는 펜컴퓨터,멀티미디어등 차세대제품의 운영체제 시장을 둘러싸고 일찍부터 격전에 들어갔으며 IBM과 MS사의 혼전을 틈타 썬마이크로시스템을 필두로한 워크스테이션 업체 및 유닉스진영까지 고성능 PC시장을 겨냥한 OS를 속속 개발, 90년대의 OS 전쟁은 한치 앞을 내다볼 수 없는 안개국면으로 접어들고 있다. DOS에서 32비트시대,펜컴퓨터, 멀티미디어에 이르는 차세대제품을 둘러싼 업계의 OS 쟁탈전을 통해 OS의 발전동향과 미래를 전망해 본다. results in the large change of the objective function, the sum of squares of deviations of the observed and computed groundwater levels. 본 논문에서는 가파른 산사면에서 산사태의 발생을 예측하기 위한 수문학적 인 지하수 흐름 모델을 개발하였다. 이 모델은 물리적인 개념에 기본하였으며, Lumped-parameter를 이용하였다. 개발된 지하수 흐름 모델은 두 모델을 조합하여 구성되어 있으며, 비포화대 흐름을 위해서는 수정된 abcd 모델을, 포화대 흐름에 대해서는 시간 지체 효과를 고려할 수 있는 선형 저수지 모델을 이용하였다. 지하수 흐름 모델은 토층의 두께, 산사면의 경사각, 포화투수계수, 잠재 증발산 량과 같은 불확실한 상수들과 a, b, c, 그리고 K와 같은 자유모델변수들을 가진다. 자유모델변수들은 유입-유출 자료들로부터 평가할 수

• Journal of the Korean earth science society
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• v.33 no.6
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• pp.481-496
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• 2012

REE, major and trace elements, and Sr-Nd isotopic ratios of surface sediments around Jeju Island were analyzed for identifying the origin of the sediments. The Chemical Index of Alteration (CIA) between 44.2 to 68.9 (av. 59.4) shows a similarity with the Huanghe sediment. The most sediments found within the study areas show a very similar chondrite-normalized REE pattern that has enriched LREE ($La_{(N)}/Sm_{(N)}$ >3) and small negative Eu anomaly, typically of average shales. The UCC-nornalized REE patterns of the southwestern offshore sediment samples show a very similar pattem with the Changjiang sediment with enriched in most REE and more convex REE pattern than those of the Huanghe and Keum rivers sediments, which indicates that the Changjiang River's suspended sediments have been transported into the western part of Jeju Island. The $^{87}Sr/^{86}Sr$ isotopic ratios vs ${\varepsilon}_{Nd}(0)$ values were thus used as a tracer to discriminate the provenance of sediments in the study area. Based on the discriminated diagram, it clearly showed that most sediments in the western and northwestern part were closely plotted with sediments of the Huanghe River. However, the sediments in the southwestern part near the Changjianf estuary were closely plotted with submerged delta sediments of the Changjiang River. In contrast, the sediment samples of the northeastern part showed discriminative figures from those of the Chinese rivers. It suggests that sediments around Jeju Island must be originated from diverse sources.

• Journal of the Korean Electrochemical Society
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• v.16 no.3
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• pp.184-189
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• 2013

$Ba_2SiO_4:Eu^{2+}$ ($B_2S:Eu^{2+}$) powders were prepared by firing the dry gel obtained by the sol-gel and the hybrid process (sol-gel and combustion), respectively, and their structure and luminescence were investigated. Tetraethyl orthosilicate (TEOS) was used as a Si source. The phase transition was observed with the TEOS content. With 1.2M TEOS, the powders prepared by the sol-gel process without prior calcination were composed of the $B_2S:Eu^{2+}$ single phase, whereas those by the sol-gel and the hybrid process with prior calcination consisted of the dominant $B_2S:Eu^{2+}$ and minor $BaSiO_3:Eu^{2+}$ ($BS:Eu^{2+}$) phases and their emission intensities were approximately two times higher than those without prior calcination. The hybrid process could reduce the process time innovatively compared to the sol-gel process, even though the former was a little inferior to the latter in the emission intensity of $B_2S:Eu^{2+}$. With 1.1M TEOS, the $B_2S:Eu^{2+}$ single phase was obtained by the hybrid process, and its green emission was observed at 505 nm originated from the $4f^65d^1{\rightarrow}4f^7$ transition of $Eu^{2+}$ ions.

• Journal of Conservation Science
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• v.6 no.1 s.7
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• pp.15-30
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• 1997

The chamical and physical properties of the fragments of an ancient pottery such as earthenware, gliazed pottery and celadon excavated in Chonnam province has been investigated by X-ray diffraction inductively coupled plasma spectroscopy(ICP), thermal mechanical analysis(TMA). Glazed pottery fragments of Chonnam province are cotaining Fe2O3 $4\~7\%$ by the analyis of ICP, firing temperature range was presumed to $1100-1150^{\circ}C$ by TMA. Celadon fragments of Chonnam province are containing Fe2O3 $2\~3\%$ by the analyis of ICP, firing temperature range was presumed to $1140\~1200^{\circ}C$ by TMA. The charateristics in the trace element composition of an ancient pottery of Chonnam provinceis are similar, it is an reflection of similar geological charateristics. The charateristic elements of Chonnam provincical ancient pottery were Rb, Sr, V, Zr, Y, Nd, Sc, La, Ce, Nb, Sm, Eu, Dy and Yb of the analyzed 21 trace elements. By Fe2O3-Zn ditribution diagram, potteries excavated in Yong-am, celadons excavated in Haenam, Kangjin, Buan and glazed pottery excavated in Hae-nam are grouped into the same class.

• Journal of Conservation Science
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• v.31 no.1
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• pp.47-64
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• 2015

The excavated potteries and raw clays of the Bronze Age from the archaeological sites in the Cheonan-Asan area were studied on material scientific characteristics and homogeneity. Under the microscope, grainsize of the tempers in the potteries were distributed from less than 1mm to 10mm. Microtexture of the potteries showed various shapes and sizes of pores. In addition to the main minerals such as quartz, feldspar, mica, hornblende, chlorite and talc were found from the X-ray diffraction analysis of potteries, while talc was not found in the raw clay. Therefore, it was considered as an artificially added mineral. Firing temperature of the potteries, which did not contain chlorite, are assumed that they were baked below $850^{\circ}C$. On the other hand, the potteries which had mica and talc, are assumed that they were fired below $900^{\circ}C$. The geochemical characteristics of the potteries and raw clays showed very similar patterns, that means the potteries were produced by using the raw clay sources from each site.

• Analytical Science and Technology
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• v.17 no.4
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• pp.322-336
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• 2004

The improved derivatization technique of tamoxifen metabolite in human urine is described for the acylation method that they are substituted by derivatization reagent like acyl anhydride for use of gas chromatography/mass spectrometry. The hydroxyl group of tamoxifen metabolite was derivatized by trifluoroacetic anhydride (TFAA), pentafluoroacetic anhydride (PFPA) and heptaflorobutylic anhydride (HFBA). It was investigated to the gas chromatography/mass spectrometry (GC/MS) technique use negative ion chemical ionization (NCI), positive ion chemical ionization (PCI) and electron impact (EI). In acylation of the metabolites of tamoxifen, the effective reaction temperature and time were shown to be at $50^{\circ}C$ for 30 min. The 4-hydroxytamoxifen, which is known to major metabolite of tamoxifen, was not detected in human urine, whileas the hydroxymethoxytamoxifen was detected. We thought that this result was from the single dose of tamoxifen.