• The Journal of the Petrological Society of Korea
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• v.26 no.3
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• pp.281-295
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• 2017

We determined chemical compositions like abundance of major and trace elements, Sr and Nd isotope compositions for two tektites from the Thailand and Vietnam. Their chemical compositions are similar to each other, and seem to be similar to those of PAAS (Post Archean Australian Shale) rather than upper continental crust. In particular, primitive mantle-normalized spider diagrams and chondrite-normalized REE patterns for two tektites are the same, suggesting that they might be derived from the same source material. The $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios from Thailand tektite are $0.718870{\pm}0.000008(2{\sigma}_m)$ and $0.512024{\pm}0.000012(2{\sigma}_m)$, respectively, and those from Vietnam are $0.717022{\pm}0.000008(2{\sigma}_m)$ and $0.511986{\pm}0.000013(2{\sigma}_m)$, respectively. The $^{87}Sr/^{86}Sr$ and $^{143}Nd/^{144}Nd$ ratios from Thailand tektite are slightly enriched than those of Vietnam tektite. $^{87}Sr/^{86}Sr$ ratios from the Vietnam and Thai tektites were plotted on the range of Australasian tektites reported previously. $^{143}Nd/^{144}Nd$ ratio of Vietnam tektite from this study was lower than the range of $^{143}Nd/^{144}Nd$ ratio from the Australasian tektite reported previously whereas that of Thai tektite was included in the range of $^{143}Nd/^{144}Nd$ ratio from the Australasian tektite. The geochemical characteristics from two tektites in this study indicate that they may be derived from the very similar source materials.

• Economic and Environmental Geology
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• v.38 no.4 s.173
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• pp.481-492
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• 2005

The purpose of this study is to determine geochemical characteristics for stream sediments in the Gwangju area. We collect the stream sediments samples by wet sieving along the primary channels and dry these samples slowly in the laboratory and grind to under 200mesh using an alumina mortar fur chemical analysis. Major elements, trace and rare earth elements are determined by XRF, ICP-AES and NAA analysis methods. For geochemical characteristics on geological groups of stream sediments, we separate geologic groups which are derived from Precambrian granite gneiss area, Jurassic granite area and Cretaceous Hwasun andesite area. Contents range of major elements for stream sediments in the Gwangju area are $SiO_2\;51.89\~70.63\;wt.\%,\;Al_2O-3\;12.91\~21.95\;wt.\%,\;Fe_2O_3\;3.22\~9.89\;wt.\%,\;K_2O\;1.85\~4.49\;wt.\%,\;MgO\;0.68\~2.90\;wt.\%,\;Na_2O\;0.48\~2.34\;wt.\%,\;CaO\;0.42\~6.72\;wt.\%,\;TiO_2\;0.53\~l.32\;wt.\%,\;P_2O_5\;0.06\~0.51\;wt.\%\;and\;MnO\;0.05\~0.69\;wt.\%.$ According to the AMF diagram for stream sediments and rocks, the stream sediments are plotted on boundary of tholeiitic series and calk alkaline series, which shows that contents of $Fe_2O_3$ are higher in stream sediments than rocks. According to variation diagram of $SiO_2$ versus $(K_2O+Na_2O),$ stream sediments are plotted on subalkaline series. Contents range of trace and rare earth elements for stream sediments in the Gwangiu area are Ba$590\~2170$ppm, Be1\~2.4$ppm, Cu$13\~79$ppm, Nb$20\~34$ppm, Ni$10\~50$ppm, Pb$17\~30$ppm, Sr$70\~1025$ ppm, V$42\~135$ppm, Zr$45\~171$ppm, Li$19\~77$ppm, Co$4.3\~19.3$ppm, Cr$28\~131$ppm, Cs$3.1\~17.6$ppm, Hf$5\~27.6$ppm, Rb$388\~202$ppm, Sb$0.2\~l.2$ ppm, Sc$6.4\~17$ppm, Zn$47\~389$ppm, Pa$8.8\~68.8$ppm, Ce$62\~272$ppm, Eu$1\~2.7$ppm and Yb$0.9\~6$ppm.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.2
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• pp.121-131
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• 2021

Magnesium (Mg) present in carbonate minerals as impurities has been used as a geochemical proxy to infer the environmental conditions where the minerals precipitated. The reliability of Mg geochemical proxies requires fundamental understanding of Mg incorporation into minerals based on accurate speciation of Mg ²⁺ in the crystal structure, which is determined mainly by application of X-ray absorption spectroscopy (XAS). However, high uncertainties are involved in interpreting the XAS spectra of minerals containing trace amount of Mg ²⁺. Because density function theory (DFT) can predict an XAS spectrum for a crystal structure, DFT calculations can reduce the uncertainties in the interpretation of the XAS spectrum. In this study, we calculated ab initio Mg K-edge absorption spectra of Mg silicates and (hydr)oxides based on DFT and analyzed the correlation between the calculated spectra and Mg structural parameters. Our ab initio Mg K-edge absorption spectra well reproduced the key features of the experimental spectra. The absorption-edge positions of the calculated spectra showed the weak positive correlation with the average Mg-O bond distance or Mg effective coordination number. The current study shows that DFT-based core-level spectroscopy method is a powerful tool in providing standard Mg K-edge spectra of diverse Mg minerals and determining the Mg chemical species within carbonate minerals.

• Journal of the Korean Chemical Society
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• v.64 no.6
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• pp.327-333
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• 2020

Performance of a portable GC that can be utilized for the real time determination of volatile organic compounds in air was evaluated. It employs purified/compressed ambient air as the carrier gas eliminating the need for high pressure gas tanks. The compact system with dimensions of 35 × 26 × 15 ㎤ and weight of 5 kg is powered by either a 24 V DC external adapter or battery pack. Chromatograms of the mixture sample including benzene, toluene, ethylbenzene, and oxylene at concentrations of 1 ppmv and 20 ppmv represent a good reproducibility: 3.79% and 0.48% relative standard deviations (RSDs) for peak area variations; 0.40% and 0.08% RSDs for retention times. The method detection limit was 0.09 ppmv. A 30 m long, 0.28 mm I.D. column operated at an optimal condition yielded a peak capacity of 61 with good resolution for a 10 min isothermal analysis. The relative standard deviations (RSD) of the peak area variations and retention times during consecutive measurements over 27 h were less than 2.4%RSD and 0.5%RSD, respectively. Thus, this instrument makes it suitable for continuous and field analysis of low-concentration VOC mixtures in the indoor/outdoor environment as well as the spillage accident of hazardous chemicals.

• Journal of the Korean earth science society
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• v.27 no.1
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• pp.49-60
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• 2006

The purpose of this study is to investigate geochemical characteristics for stream sediments in the Naju area. We collected 139 stream sediments samples from primary channels. Samples were dried slowly in the laboratory and chemical analysis was carried out using XRF. ICP-AES and NAA. In order to investigate geochemical characteristics, the geological groups categorized into granitic gneiss area, schist area, granite area, arenaceous rock area, tuff area, andesite area, and rhyolite area. Average contents of major elements for geological groups are $SiO_2\;58.37{\sim}66.06wt.%,\;Al_2O_3\;13.98{\sim}18.41wt.%,\;Fe_2O_3\;4.09{\sim}6.10wt.%,\;CaO\;0.54{\sim}1.33wt.%,\;MgO\;0.86{\sim}1.34wt.%,\;K_2O\;2.38{\sim}4.01wt.%,\;Na_2O\;0.90{\sim}1.32wt.%,\;TiO_2\;0.82{\sim}1.03wt.%,\;MnO\;0.09{\sim}0.15wt.%,\;P_2O_5\;0.11{\sim}0.18wt.%$. According to the comparison of average contents of major elements, $Al_2O_3\;and\;K_2O$ are higher in granitic gneiss area, $Fe_2O_3,\;CaO,\;P_2O_5$ are higher in tuff area, MgO and $TiO_2$ are higher in andesite area, $Na_2O_$ is higher in rhyolite area, $SiO_2$, and MnO are higher in arenaceous rock area. Average contents of minor and rare earth elements for geological groups are $Ba\;1278{\sim}1469ppm,\;Be\;1.1{\sim}1.5ppm,\;Cu\;18{\sim}25ppm,\;Nb\;25{\sim}37ppm,\;Ni\;16{\sim}25ppm,\;Pb\;21{\sim}28ppm,\;Sr\;83{\sim}155ppm,\;V\;64{\sim}98ppm,\;Zr\;83{\sim}146ppm,\;Li\;32{\sim}45ppm,\;Co\;7.2{\sim}12.7ppm,\;Cr\;37{\sim}76ppm,\;Cs\;4.8{\sim}9.1ppm,\;Hf\;7.5{\sim}25ppm,\;Rb\;88{\sim}178ppm,\;Sc\;7.7{\sim}12.6ppm,\;Zn\;83{\sim}143ppm,\;Pa\;11.3{\sim}37ppm,\;Ce\;69{\sim}206ppm,\;Eu\;1.1{\sim}1.5ppm,\;Yb\;1.8{\sim}4.4ppm$. According to the comparison of average contents of minor and rare earth elements for geological groups, Pb, Li, Cs, Hf, Rb, Sb, Pa, Ce, Eu, and Yb are higher in granitic gneiss area; Ba, Co, and Cr in schist area; Nb, Ni, and Zr in arenaceous rock area; Sr in tuff area: and Be, Cu, V, Sc, and Zn are such in andesite area.

• Economic and Environmental Geology
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• v.35 no.6
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• pp.509-521
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• 2002

The purpose of this study is to find out geochemical characteristics of stream sediments which are good indicator of geochemical hazard valuation and water in primary channels of the Jangheung area. We separated three groups which were granitoid area, granite gneiss area and tuffeous area by petrological properties. Physical and chemical characteristics of stream water such as temperature, pH, and EC were measured in the field between 1999 and 2001 and stream sediments samples were collected from April to May in 1999. For the chemical analysis of stream sediments samples, XRF, ICP-AES and NAA were used. The contents of the major elements had a similar contents in three groups and those of rare earth elements in granite gneiss area were lower value than those of other two groups. Zn and Cu were higher value than the other toxic elements. Through the enrichment factor and enrichment index features of the elements, we knew that $Fe_2O_3$, MgO, $TiO_2$, MnO and Eu, Yb of the tuffeous area samples and Co, Cr, Zn were enriched.

• Journal of the Korean earth science society
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• v.21 no.1
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• pp.67-80
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• 2000

We studied petrological and geochemical characteristics of the Mesozoic volcanic rocks in the Da Hinggan Ling area northeast China, and discussed tectonic settings and origin of the Mesozoic volcanic rocks in northeast Asia. Volcanic rocks in Da Hinggan Ling area are composed of alkaline to subalkaline basalt-basaltic andesite-andesite-dacite-rhyolite, showing typical BAR(basalt-andesite-rhyolite) association. However, most of the volcanic rocks are basaltic and rhyolitic in composition, and andesitic rocks are relatively rare, which shows bimodal characteristics. Rb, Ba, Th and other incompatible element contents in the volcanic rocks are enriched, but the contents decrease with increasing the compatibility. REEs are fractionated and REE patterns of volcanic rocks are characterized by a high LILE/HFSE. On the tectonomagmatic discriminant diagram of Hf-Th-Nb, they fall into the fields for subduction-related destructive plate margin basalts and its differentiates. We suggest that the tectonomagmatic setting of Da Hinggan Ling area was located at the continental margin arc related with subduction environment during the Mesozoic time or may be derived from mantle plume contaminated geochemically from subducting slabs, although it is, at present within the Asia continent.

• Economic and Environmental Geology
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• v.24 no.4
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• pp.447-463
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• 1991

Petrological and chemical studies of Precambrian dikes in the southern Lake Superior region were conducted with the objects of evaluating magma source and constraining models for the paleo-tectonic environment. Forty-six samples were analyzed for major, trace, and rare earth elements. Chemical data of the studied dikes are typical of continental tholeiites and showing iron-enrichment fractionation trend. With wallrock contamination carefully evaluated, a series of tectonic discriminating methods utilizing immobile trace elements indicate that the source magma was a high-Ti tholeiitic basalt similar to present-day T-type MORB. Effect of chemical contamination from wallrock assimilation accmulates with increasing differentiation. Evolved rocks show LREE enriched patterns and have enhanced levels of LIL elements (e.g., Rb, K, Ba, Th), but low levels of high field strength elements (e.g., Nb, P, Ti) with respect to their neighboring elements. It is suggested from this study that this enrichment possibly due to a combination of a feature inherited from the subcontinental lithosphere and crustal contamination. Geochemical signatures of these rocks are distinctively different from those of arc-related volcanics. Comparisons with chemistries of modern magmas show a pattern of overlap between Within-plate and ocean-floor characteristics, and chemical signatures of these rocks favor a model of intrusion into a crustal environment undergoing lithospheric attenuation.

• Korean Journal of Environmental Agriculture
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• v.28 no.3
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• pp.227-232
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• 2009

Land application of animal manure, such as pig slurry(PS), has been considered as valuable organic source to supply necessary nutrients for crop growth. On the other hand, little information is available on the effect of consecutive application of PS on agricultural soils. This study was conducted to evaluate the influence on change in soil chemical properties and yield of Chinese cabbage in soils amended with slurry composting and bio-filtration pig slurry (SCB) for four consecutive crop cultivations (2007-2008). Among total application rates required, a basal fertilizer (35%) was applied with SCB or chemical fertilizer (CF). The CF was applied as a side dressing was applied in all treatments. There was no significant effect of SCB and CF on Chinese cabbage yield during four cropping seasons. In addition, soluble sugar, vitamin C contents and yields of Chinese cabbage between SCB and CF did not show statistically significant difference. During the experiment, soil chemical properties between SCB and CF treatment showed similar pattern, however, the contents of exchangeable sodium (Na) in soil has been increased (P<0.05) since the second cropping season because of higher Na contents in SCB. Therefore, the use of SCB as a substitute of CF is available for growth and yield of chinese cabbage while its long-term application might leads to an accumulation of Na in soil.

• Proceedings of the Korea Water Resources Association Conference
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• 2011.05a
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• pp.137-137
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• 2011

급격한 세계인구의 증가에 의해 물 부족지역이 세계 각지로 확산되고 있다. 이에 따라, 건전한 수자원으로써 하수처리수의 재이용이 주목을 받고 있다. 하수처리수의 재이용시에는 특히, 재이용수의 미생물학적 안전성과 더불어 화학물질 등으로부터 기인할 수 있는 인체 및 생태계에의 리스크를 고려해야 한다. 미국 EPA는 병원성 미생물 뿐만 아니라 화학물질에 대한 안전성을 확보 차원에자외선/과산화수소 등의 고도산화처리법을 검토하였다. 1일 $10m^3$ 처리규모의 연속실험장치를 이용, 검토된 공정별 실제 하수 2차 처리수중에 존재하는 의약품류의 제거효과, 에너지 소비량 및 생태리스크 저감효과 등을 비교, 평가하였다. 에너지 소비량에 있어서는 공정별로 다소 차이가 있었으나, 본 실험동안 검출된 38종의 의약품류 제거에는 각 공정 모두 매우 효과적이었다. 에너지 소비측면에서는 오존 단독공정이 가장 적은 에너지 소비량에서 타 공정과 동일한 수준의 의약품류 서 막처리나 자외선 처리 등의 고도처리시설에 대한 정보를 재이용수 가이드라인에 제시하고 있는 반면, 우리나라에서는 재이용수중에 일정농도 이상의 염소가 잔류하도록 함으로써, 재이용수의 미생물학적 안전성 확보만을 고려하고 있다. 최근, 수환경분야에서는 의약품류라는 화학물질이 유럽, 미국 및 일본 등지를 중심으로 주목을 받아오고 있으며, 이들은 ng/L-${\mu}g$/L 수준으로 수환경중에서 검출되고 있다. 이들의 주요 발생원으로 하수처리시설이 지목되고 있으며, 따라서 하수처리수의 재이용시 잔류 의약품류에 의한 리스크 발생 가능성이 우려되고 있다. 이를 배경으로, 하수처리시설에서 의약품류를 효과적으로 제거할 수 있는 공정으로 오존 및 오존/자외선, 제거효과가 얻어졌다. 한편, 오존처리시 발암성 물질인 브로메이트($BrO_3^-$) 등과 같은 부생성물 생성 가능성을 고려하면, 오존 단독공정보다 상대적으로 많은 에너지를 소비하는 오존/자외선, 자외선/과산화수소 등의 고도산화처리법이 높은 적용성을 갖는 것으로 나타났다. 향후, 수자원 부족문제로 재이용수의 용도가 훨씬 다양해 질 것으로 예상된다. 그에 따라, 재이용수의 안전성 확보를 위해 보다 폭넓은 검토가 예상되지만, 현 단계에서는 오존을 포함, 다소 많은 에너지 소비가 예상되는 자외선을 이용한 고도산화처리법이 다양한 미량 화학물질의 제거에 유효한 공정으로 판단된다.