• Title/Summary/Keyword: 물-증기

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Effect of 2-butoxyethanol Additive in the Casting Solution on the Characteristics of Nonsolvent Vapor Induced Phase Inversion PES Membranes (비용매증기 유발 상 전이 공정을 이용한 PES 멤브레인 제조에 있어 2-butoxyethanol 첨가 효과)

  • Kim, No-Won
    • Membrane Journal
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    • v.20 no.1
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    • pp.76-86
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    • 2010
  • This study investigated the effect of 2-butoxyethanol (BE) as a nonsolvent additive, relative humidity and air contact time on the structure formation of microfiltration membranes, permeation and morphology properties in phase inversion process. The membranes were prepared by using polyethersulfone (PES)/Dimethyl formamide (DMF)/p-toluenesulfonic acid (TSA)/Polyvinylpyrrolidone (PVP)/BE casting solution and water coagulant. Casting solutions containing various concentration of BE were exposed to a water vapor, under 60 and 80% of relative humidity for 40 and 90 sec, which would be absorbed on. The correlations between the membrane permeation properties and surface/inner structures of membrane were investigated. The characterization of membranes was carried out by a capillary flow porometer, a FE-SEM and a water permeation test apparatus. The surface structure of PES membranes was affected by the exposure time as well as the relative humidity strongly. Furthermore, the addition of BE helped control surface and inner structure at certain humidity and exposure time.

The Characteristics of Exhaust Gas in Diesel Engine by Corana Discharge-EGR System (코로나 방전-EGR 조합시스템에 의한 디젤기관의 배기 가스 특성)

  • Park, Jae-Yoon;Jung, Jang-Gun;Kim, Jong-Suk;Ha, Hyun-Jin
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.7
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    • pp.39-44
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    • 2005
  • A great part of flint fuel is Hydrogen and carbon's combination, they should be generated steam and carbon gas when combine with oxygen for perfect combustion in the inside of engine but, the pollutive material are discharged, even though perfect combustion condition especially $NO_x$ and Smoke. they are really harmful for health. In this paper was shown the result of discharging gas' reduction quality. which used combination of corona discharge using the high voltage source of common frequency with EGR. $NO_x$ is increased in entire load erea in proportion to increasing of EGR rate and impression voltage. Smoke is increased slowly under 75[%] in load rate but it is increased rapidly in entire load erea and the reduction rate of Smoke is increased in proportion to increasing of impression voltage.

LiCl 감압 증류를 위한 폐쇄형 및 개방형 장치 기초 실험

  • Park, Byeong-Heung;Lee, Sang-Hun;Jeong, Myeong-Su;Jo, Su-Haeng;Heo, Jin-Mok
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.11a
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    • pp.345-345
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    • 2009
  • 전기화학적 환원 기술을 이용한 고온 용융염 전해환원의 결과 생산되는 금속전환체는 다공성 특성에 의해 전해환원의 매질인 용융염을 함유하게 된다. 전해환원과 후속 전기화학 공정인 전해정련의 전해질은 각각 LiCl과 LiCl-KCl 공융염으로 상이하기 때문에 이렇게 금속전환체에 포함된 LiCl 염이 동반되어 전해정련 공정에 도입될 경우 전해정련 공정의 공융염 조성을 어긋나게 한다. 이에 따라 금속전환체의 잔류염은 효과적으로 제거되어야 하며 공정으로 감압 증류에 의한 잔류염 제거 공정이 고려되고 있다. LiCl은 증기압이 비교적 낮기 때문에 감압의 고온 조건이 공정에 필요하다. 그러나 상평형도 분석 결과 전해환원 공정에서 산화물을 담아 음극으로 사용되어 환원된 금속전환체와 함께 도입되는 SUS 재질의 바스켓과 사용후핵연료 금속전환체의 주된 원소인 우라늄과는 공융할 수 있기 때문에 LiCl 증발 온도는 $720^{\circ}C$ 이하로 유지되어야 한다. 이와 같은 조건에서 LiCl 증발 속도를 높이기 위해서는 감압 조건이 필수적이다. 본 연구에서는 감압조건에서 LiCl 휘발 실험을 위해 폐쇄형 및 개방형 반응기를 제작하여 압력 조건 및 Ar 유량 등에 따른 LiCl 휘발율을 측정하였다. 증발된 LiCl은 일정 감압 조건에서 분말형으로 냉각부위에 회수 될 수 있었으나 완전 진공 조건에서는 결정형으로 냉각 부위에 응축되는 것으로 확인 되었으며 일정 진공 조건에서는 Ar 유량에 따라 증발량이 의존하지 않는 것으로 나타났다. 연구 결과 증발염의 취급 빛 이송을 위해 분말형 회수를 목표로 설정할 수 있었으며 공정조건으로 일정 수준의 감압 조건을 제시하였다. 이 후 후속 연구로 장치의 대형화 및 증발 속도 향상을 위한 추가적인 연구가 계획되어 있으며 연구 결과에 기초하여 공학규모 파이로 공정 시설인 PRIDE에 도입될 장치의 기초 설계 자료를 생산할 예정이다.

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A Research on the improvement scheme for manufacturing bronze warm forging die through environment-friendly workshop (황동제 온간단조용 금형제작과 환경친화형 작업장 개선에 관한 연구)

  • Kim, Sei-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.420-425
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    • 2010
  • In the process of warm forging, billet is heated up to $800^{\circ}C$ and located in the upper part of die block impression. The scattered oxidized scale may cause workers burn and shortening of die life sticking to the die block impression. The separating materials sprayed in die block cause harmful dust, harmful mist, fume, and bad odor which contaminate workshop environment. The process is classified as one of the avoided jobs and make the planned output achievement difficult. Development of an elimination device to clear out the contaminating materials in the workshop and improvement of the unsatisfactory maintenance method to fix the abrasion of die block impression which delays the dead line, cost increases needs to be developed. In this research, I tried to solve the problems caused in warm forging of bronze pipe joint such as the billet heating process, die maintenance, and manufacturing cost through improvement of warming forging manufacturing method and die maintenance method and eliminating harmful gas which will make the workshop more environment friendly.

A Study on the Simulation of LPG Refrigeration Cylcle Using Pure Propane Refrigerant (순수한 프로판 냉매를 사용한 액화석유가스 냉동사이클의 모사에 관한 연구)

  • Cho Jung-Ho
    • Journal of the Korean Institute of Gas
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    • v.10 no.1 s.30
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    • pp.38-42
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    • 2006
  • In this study, a simulation technology for refrigeration cycle which can liquefy and store liquified petroleum gas (LPG) using pure propane as a refrigerant has been introduced. Cooling water as the second cooling medium was used for the liquefaction of propane. Peng-Robinson equation of state was used for the entire refrigeration cycle. A new alpha formulation proposed by Twu et al. was used for the more accurate prediction of vapor pressures of pure propane component and LPG constituents. API method for the accurate estimation of liquid densities of propane and LPG was used instead of using Peng-Robinson equation of state. PRO/II with PROVISION release 7.1, a general purpose chemical process simulator was used for the simulation of the overall refrigeration system. Through this work, we can successfully simulate the real propane refrigeration plant operating at domestic site.

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Wafer-Level MEMS Capping Process using Electrodeposition of Ni Cap and Debonding with SnBi Solder Layer (Ni 캡의 전기도금 및 SnBi 솔더 Debonding을 이용한 웨이퍼 레벨 MEMS Capping 공정)

  • Choi, J.Y.;Lee, J.H.;Moon, J.T.;Oh, T.S.
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.4
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    • pp.23-28
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    • 2009
  • We investigated the wafer-level MEMS capping process for which cavity formation in Si wafer was not required. Ni caps were formed by electrodeposition on 4" Si wafer and Ni rims of the Ni caps were bonded to the Cu rims of bottom Si wafer by using epoxy. Then, top Si wafer was debonded from the Ni cap structures by using SnBi layer of low melting temperature. As-evaporated SnBi layer was composed of double layers of Bi and Sn due to the large difference in vapor pressures of Bi and Sn. With keeping the as-evaporated SnBi layer at $150^{\circ}C$ for more than 15 sec, SnBi alloy composed of eutectic phase and Bi-rich $\beta$ phase was formed by interdiffusion of Sn and Bi. Debonding between top Si wafer and Ni cap structures was accomplished by melting of the SnBi layer at $150^{\circ}C$.

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Ejector Optimization for SOFC Anode Off-Gas Recirculation System (SOFC 산화전극 배기가스 순환 시스템을 위한 이젝터 최적 설계)

  • Jo, Sung Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.2
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    • pp.139-148
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    • 2013
  • In this study, an ejector was designed to recirculate the anodic off-gas of SOFC, and a parametric study of the system performance was conducted at various ejector entrainment ratios. Aspen Plus, a chemical engineering program, was used to calculate the operational conditions of the ejector. To minimize the calculation load of the CFD and to ensure the global optimum, a genetic algorithm and Kriging model were used for the optimization. The optimization results showed that the dominant design variables of the sonic ejector are the throat diameter and the first flow nozzle position. The designed ejector has enough flexibility for different operating conditions of a 1-kW SOFC system. When the ejector was applied to the SOFC, it reduced 56% of the steam and 8.4% of the fuel compared to the reference case.

Hydrothermal Kinetics and Mechanisms of Lime and Quartz Used Solid State Reaction Equations (고상반응식을 이용한 석회-석영의 수열반응속도와 반응메카니즘)

  • Lim, Going
    • The Journal of Engineering Research
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    • v.3 no.1
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    • pp.223-233
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    • 1998
  • The kinetic and mechanism of the hydrothermal reaction between lime and quartz used solid state reaction equations have been investigated. Hydrothermal reaction on the starting materials was carried out in an autoclave that quartz mixed with calcium hydroxide in CaO/$SiO_2$ ratio of 0.8-1.0 for 0.5-8 hour at saturated steam pressure of $180-200^{\circ}C$. The rate of reaction was given from the ratio of uncombined lime and quartz content to the total lime and quartz content. The rate of reaction was obtained the results by the Jander's equation $[1-(1-\alpha)^{1/3}]^N=Kt$. The reaction of lime is controlled mainly by the dissolution such as N=1, and the reaction of quartz is controlled mostly by the diffusion such as $N\risingdotseq2$. The rate of hydrothermal reaction in the calcium silicate hydrates system is suggested to be determined generally by the mass transfer through the product laver formed around the reactant particles. The rate equation for whole hydrothermal reaction is shown that it is converted into the rate determining step by the diffusion from the boundary reaction such as approximately $N=1-2$.

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Chlorodifluoromethane (CHClF2) Thermal Decomposition by DC Nitrogen Plasma (질소 플라즈마 공정을 이용한 염화이불화메탄(CHClF2) 열분해)

  • Ko, Eun Ha;Yoo, Hyeonseok;Jung, Yong-An;Park, Dong-Wha;Kim, Dong-Wook;Choi, Jinsub
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.171-176
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    • 2017
  • The nitrogen plasma thermal decomposition and recovery processes for $CHClF_2$ (Chlorodifluoromethane) refringent were investigated. The steam generator was employed to provide superheated steam reactor, supporting the decomposition reaction of refringent. Even though over 94% of R-22 was decomposed on the condition of 60 A and 9.0 kW, a higher power and specific energy density were required to achieve the complete combustion of carbon materials. In the operating condition of 60 A and 12.6 kW, $O_2$/R-22 ratio in reactants gases are a key factor to obtain much higher decomposition ratio during process. It should be noticed that injecting the mixture of $O_2$ and air was much more effective than injecting the air consisting equivalent $O_2$ amount.

A Stduy on Model Development of Boiler Combustion System on Coal Fired Power Plant (석탄화력발전소 보일러 연소계통의 모델개발에 관한 연구)

  • Moon, Chae-Joo;Kim, Yong-Gu;Chung, Hwan-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.3
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    • pp.65-73
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    • 2004
  • The bolier systems of coal fired power plants are large, non-linear systems with numerous interactions between its component parts. In the analysis of such complex systems, dynamic simulation is recognized as a powerful method of keeping track of the myriad of interactions. The boiler system consists of air/gas system and water/steam system. Due to recent reinforcement of environmental regulation on pollutant discharge and requirements of design validation on properites of boiler, the commercial programs are used for the analysis of boiler system. This paper addressed to the development of model using MMS(Modular Modeling System) developed by EPRI(Electric Power Research Institute) as the simulation tool. The developed model using MMS is tested for the design and local data on boiler combustion system of korea standard coal fired power plant boiler. The simulation results show that the developed model well reproduces responses of the combustion system with less than ${\pm}$5% error under steady state and transient state conditions. The developed model for analysis of the combustion system in this paper is general and applicable to any type of coal fired power plant.