• The Journal of the Convergence on Culture Technology
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• v.9 no.1
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• pp.711-716
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• 2023

A large amount of stone is required as a high-end strategy for building new construction and remodeling work, and aggregates have to be collected from many stone mountains due to the lack of river sand and gravel required for concrete production. This study examines the case of development of stone materials for construction, conduct and analyze residents' attitudes, find out residents' thoughts on stone mountain development, develops the area as an alternative to the devastation caused by stone mountain development, and recycles it as an efficient resource. We intend to conduct basic research to propose a plan. As a result, Local residents have a lot of antipathy against the use of quarry, so it is necessary to use the area that is far from the residents' areas as a quarry. It was concluded that it was desirable to restore and develop in the right direction.

• Journal of Soil and Groundwater Environment
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• v.29 no.1
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• pp.72-83
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• 2024

Most of the slags generated from steel-making industry in Korea are recycled into media-contact aggregates such as fill and cover materials. For their use as media-contact aggregates, the slags must meet not only the waste quality criteria, but also the Daphnia magna acute toxicity test criteria. In this study, Korean Leaching Test ES 06150.e (Korea), Japanese Leaching Test JIS K 0058-1(Japan), Detuch Leaching Test DIN 19529 (Germany), Toxicity Characteristic Leaching Procedure (USA) were conducted for batch leaching test of slags from 6 Korean steel-making companies. In addition, Korean Standard up-flow percolation test (ES 06151.1) mimicking field conditions was conducted to assess the impact of the slag leachate on the surrounding environment indirectly. Heavy metals such as Cr⁶⁺ and Zn²⁺ were detected from both extractant and leachate samples, but all of them did not exceed waste quality criteria of each country. However, Daphnia magna acute toxicity tests using the leachate samples from up-flow percolation test with slag alone and slag/natural soil conditions exceeded ecotoxicity standard (TU=2) due to their high pH (11.3-12.5). After neutralizing the pH of the slag leachate to 6.5~8.5, the Daphnia magna mortality and immobilization were reduced to satisfy ecotoxicity standard. As the reducing pH of slag leachate would be extremely difficult, appropriate recycling management considering the physicochemical characteristics of he slags should be stuided further.

• Resources Recycling
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• v.33 no.1
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• pp.48-57
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• 2024

This study aimed to improve utilization of the Class C vinyl waste generated in rural areas based on a preliminary investigation on the use of eco-powder, generated through pyrolysis, as a raw material for plastic. The efficiency of pre-processing treatments in controlling ash content of the generated eco-powder and its effect on the basic properties of manufactured plastic were evaluated. The basic properties included ash content of the compressed eco-powder at different levels of ash content, impact strength, flexural strength, and tensile strength. The experimental results confirmed that pre-processing improved the separation efficiency of soil particles and vinyl waste through physical impact. The eco-powder with ash content of less than or equal to 26% was found to satisfy the target performance during impact strength, flexural strength, and tensile strength evaluation. Thus, it was confirmed that the Class C vinyl waste, having low utilization and recovery rates, could be effectively utilized as a plastic raw material after optimum thermal treatment and physical processing using the eco-powder.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.28 no.5
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• pp.211-216
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• 2018

The recovery of rare earth elements (REE) including La, Nd and Ce from spent batteries is important issues to reuse scarce resources. Herein, we present a simple recovery process to obtain lanthanum oxide ($La_2O_3$) from spent Ni-MH batteries, and demonstrate the conversion mechanism from $NaLa(SO_4)_2{\cdot}H_2O$ to $La_2O_3$. This strategy requires the initial preparation of $NaLa(SO_4)_2{\cdot}H_2O$ and subsequent metathesis reaction with $Na_2CO_3$ at $70^{\circ}C$. This metathesis reaction resulted in the crystalline lanthanum carbonate hydrate ($La_2(CO_3)_3{\cdot}xH_2O$) powder with plate-like morphology. On the basis of TGA result, the $La_2(CO_3)_3{\cdot}xH_2O$ powder was calcined in air at three different temperatures, that is, $300^{\circ}C$, $500^{\circ}C$, and $1000^{\circ}C$. As the calcination temperature increased, the morphology of powder was changed; prism-like ($NaLa(SO_4)_2{\cdot}H_2O$) ${\rightarrow}$ platelike ($La_2(CO_3)_3{\cdot}xH_2O$) ${\rightarrow}$ aggregated irregular shape ($La_2O_3$). Futhermore, XRD results indicated that the crystalline $La_2O_3$ could be synthesized after the metathesis reaction with $Na_2CO_3$, followed by heat-treatment at $1000^{\circ}C$, along with a change of crystallographic structures; $NaLa(SO_4)_2{\cdot}H_2O$ ${\rightarrow}$ $La_2(CO_3)_3{\cdot}xH_2O$ ${\rightarrow}$ $La_2O_3$.

• Journal of The Korean Society of Grassland and Forage Science
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• v.34 no.4
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• pp.296-306
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• 2014

This study was conducted to survey and analyze the quantity of various organic wastes and to vitalize the utilization of agri-food by-products as raw materials for Total mixed ration (TMR), to improve feed cost savings and the quality of animal products. On-the-spot obstacles for animal farmers, along with legal and institutional alternatives are presented. The results are as follows. First, organic wastes in Korea are managed by the Allbaro system created in the Wastes Control Act, which processes 10,488 tons of cooking oil waste, 832,493 tons of animal and plant residues, 5,740 tons of animal carcasses, 1,171,892 tons of animal residues, and 2,172,415 tons of plant residues including 12,905 tons of rice hull and bran, for a total of 4,205,931 tons. Raw materials for TMR, namely rice hulls and bran as well as plant residues, accounted for 51.7% of the total national organic waste. The top 10 municipalities process 76~100% of all organic wastes and a supply management system is needed for the waste. Second, the 10 major agri-food by-products used as raw materials for TMR are bean curd by-product, rice bran, oil-cake, brewers dried grain, Distiller's Dried Grains with Solubles (DDGS), barley bran, soy sauce by-product, citrus fruit by-product, mushroom by-product and other food by-product (bread, noodles, snacks, etc.). Third, the biggest difficulties in using agri-food by-products are legal obstacles. Because agri-food by-products are regulated as industrial wastes by the Waste Control Act, animal farmers that wish to use them have legal reporting obligations including the installation of recycling facilities. To enable the use of agri-food by-products as raw materials for TMR, waste management system improvements such as 'the end of waste status' and the establishment of more than 10 public distribution centers nationwide are deemed essential.

• Journal of the Korean Institute of Traditional Landscape Architecture
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• v.30 no.2
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• pp.90-100
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• 2012

This study centering on 10 village - Bangjuks analyzed multifunctionality value of village Bangjuks which have been main water treatment system in Korean traditional villages. On the basis of understanding the structure and character of components such as the well, common spring, village waterway and others which making water-flow and consisting of aquatic system in Korean traditional village Bangjuk, the conclusion as the instrumental device of social and ecological role and ecological watershed management, securing the ecosystem soundness of the damaged or deteriated aquatic ecosystem due to the industrialization and urbanization is as below; 1. The traditional village Bangjuk was environmentally friendly hydraulic system which gathers waterways of village into a point including sewage water, retains and flows out to village through agricultural waterway. Through this Bangjuk, they have managed sewage and rainfall runoff flowed out village efficiently. It is not only a detention system of water but a kind of eco-friendly system that flow out water into the rivers after reusing and filtering it. 2. Around five traditional villages and five villages after modernization, this study classified the types of village Bangjuk as three types considering geographic location, size, etc; marsh type of low swamp, high water -low rice field type of natural flow stucture, low water - high rice field type requiring artificial irrigation facility. All the five traditional villages were turned out to be marsh type of low swamp. Geoji, Sanjeri, Ma-am, Yangchon of the agricultural villages were high water-low rice filed type, and Sangchoenri village was classified low water-high rice field type. 3. This study checked up the function of water purification of village Bangjuk. In Wonteo and Geji villages affected by discharge of village sewer and domestic sewage, the efficiency of ammonia nitrogen($NH_3-N$) and total phosphorus(T-P) was 56~95%, which was high. In Sangcheonri and Sanjeri villages strongly affected by stall and farmland, the efficiency of suspended solids(SS) was 70~85%, and that of total nitrogen(T-N) and total phosphorus(T-P) was 5.3~65%. 4. A water purification system can be found out in the system of village Bangjuk that filter out village sewage and rainfall runoff flowed through the settle and filter of pollution source and denitrification of plants. Through this system of village Bangjuk, it must be used as the basic facilities for the ecological watershed management. The sewage management system of village Bangjuk as a eco-filter must be used and studied as an eco-friendly facility for the ecological watershed management around the subwatershed and catchment.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.794-800
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• 2011

To develop biochar for soil conditioner using water plants, characteristics of nutrients release of biochars were investigated under different water plants, manufacturing times and manufacturing temperatures. Under different water plants for manufacturing biochar, the concentrations of T-N and $P_2O_5$ in the water with biochars were higher in the order of CRXDM > ZIZLA > PHRCO > TYHOR > MISSA. The concentrations of $K_2O$ in the water were in the order of TYHOR ${\fallingdotseq}$ CRXDM > ZIZLA > PHRCO > MISSA. Under different manufacturing times for biochar, the concentrations of T-N, $P_2O_5$ and $K_2O$ in the water with biochars were higher in the order of 2 hr > 30 min ${\fallingdotseq}$ 1 hr. The concentrations of T-N, $P_2O_5$ and $K_2O$ in the water with biochars were on the order of $350^{\circ}C$ > $500^{\circ}C$ > $600^{\circ}C$ under different manufacturing temperatures. Total amounts of T-N and $K_2O$ releases in the water with biochars were higher in the order of CRXDM > ZIZLA > PHRCO > TYHOR > MISSA. Using biochars by water plants, total amounts of $P_2O_5$ releases in the water with biochars were on the order of CRXDM > ZIZLA > MISSA >PHRCO > TYHOR. The results of this study suggest that biochars by water plants can supply some of the nutrient requirements of crops and can be a valuable fertilizer.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.3
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• pp.136-144
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• 2013

In this study, in order to establish a plan that will enable safe use of renewable resources such as diverse industrial by-products and urban recycled materials, we conducted experiments that focused on flow, bleeding, compressive strength and environmental pollution evaluation to evaluate the material properties of low strength concrete using BFS and SS. In the case of low strength concrete using BFS and SS, blending of at least BFS 6000 within a 30% range regardless of the type of sand used was found to be the most effective approach for improving the workability by securing the minimum unit quantity of water, restraining the bleeding ratio and establishing compressive strength by taking account of the applicability at the work site. In particular, in view of the efficient use of SS, the optimal mixing condition was found to be the mixing of BFS 8000 with in the 30% range, not only for improving the workability restraining the bleeding ratio and establishing the compressive strength but also for application to the work site. Further, the results of tests on hazardous substance content and those of elution tests conducted on soil cement using SS indicated that all values satisfied the environmental standards without any harmful effects on the surrounding environment.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2013.04a
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• pp.116-116
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• 2013

마그네슘은 스마트폰, 전자기기 케이스, 내화벽돌과 아크용접봉 제조시의 첨가물 등으로 사용되고 있는데, 최근에는 재활용을 위한 마그네슘 용해로를 취급하거나 가공하는 사업장이 증가하고 있어 사고위험성이 높아지고 있다. 금속분을 취급하는 사업장에서의 금속분진은 저장이나 축적 등과 같이 주로 퇴적물로서 존재한다. 퇴적분진의 발화온도는 퇴적물 형상과 두께, 입경, 분위기 가스의 유속, 산소농도, 부유분진의 농도, 퇴적밀도, 수분 등의 많은 영향인자가 관여하기 때문에 이론적 예측이 힘들고 실험적인 측정에 의존할 수 밖에 없는 것이 현실이다. 본 연구에서는 연소성이 높고 화재폭발사고사례가 많은 마그네슘(Mg) 분진을 사용하여 승온속도 변화에 따른 열분해특성을 조사하였다. 퇴적분진의 열적특성을 조사하기 위하여 METTLER TOLEDO의 TGA/DSC1를 사용하였으며, Mg 시료의 평균입경은 38, $142{\mu}m$이다. 입경 $38{\mu}m$의 Mg 시료의 열중량분석 결과, 중량증가는 $400{\sim}500^{\circ}C$의 범위에서 시작되며 $550^{\circ}C$에서 급격하게 중량이 증가하고 있으며, 증량증가개시온도(Temperature of weight gain)는 $460^{\circ}C$에서 시작하여 $900{\sim}950^{\circ}C$ 범위에서 중량 증가 포화값에 도달하였다. 입경 $142{\mu}m$의 Mg에 대하여 공기중 승온속도를 5, 10, $20^{\circ}C/min$으로 변화시키면서 실온에서 $900^{\circ}C$까지 가열 시키는 경우의 시료의 중량 변화에 따른 열분해 특성은 승온속도가 증가할수록 2단계의 S자 곡선은 완만하게 상승을 나타내며 중량증가개시온도가 높아지는 경향을 보이고 있다. 중량증가개시온도가 승온속도에 따라 변화하는 결과를 나타내고는 있지만, 시료량의 증가에 따른 영향을 열중량분석 실험방법의 제약으로 인하여 확인할 수 가 없었다. 그러나 만일 시료량이 크게 증가하는 경우에는 동일한 승온조건에서 중량증가 개시온도는 낮아질 가능성이 있다. 중량증가는 시료의 산화반응에 의한 것이므로 시료량의 증가는 시료 내부에의 열의 축적을 용이하게 하여 보다 낮은 온도에서도 산화반응이 충분히 일어나는 조건이 형성되기 때문이다. 승온속도가 증가할수록 산화 반응한 괴상형태의 연소입자가 크게 증가하고 있는 것을 알 수 있다. 승온속도에 따른 중량개시온도 곡선을 보면 [그림 24]와 같으며 승온속도 5, 10, $20^{\circ}C/min$의 증가에 따라 중량개시온도는 각각 490, 510, $530^{\circ}C$가 얻어졌으며 승온속도의 증가에 따라 중량개시온도가 증가하는 경향을 보이고 있다.

• Journal of the Korea Organic Resources Recycling Association
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• v.13 no.1
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• pp.100-114
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• 2005

Organic waste, which is defined as wastes derived from various biological organisms that contain more than 40% of organic materials, is generated about 100 million tons per year in Korea. These organic wastes are now controlled by several governmental entities, under different rules and regulations, leading to the improper management and inefficient treatment. Therefore, integrated management system is primarily needed for the efficient recycling of organic waste. In this study, six kinds of organic wastes, which are food waste, sludges(sewage, waste water, night soil), animal excreta, animals and plants residues, and three kinds of recycling by-products(compost, feed, anaerobic digestion by-products) made of organic wastes, were analyzed for their physical and chemical characteristics. On the basis of this result, a possibility for the efficient recycling of organic waste was investigated.