• Title/Summary/Keyword: 물질전달모델

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A Numerical Model for Heat and Mass Transfer Processes within a Vertical Tube GAX Absorber (수직원관형 GAX 흡수기 내부의 열 및 물질전달과정에 대한 수치모델)

  • 천태식;정은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.102-111
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    • 2000
  • A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

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Sensory Physiology of Sex Pheromone and Its uses for Insect Pest Management (성페로몬 감각생리와 해충관리기술)

  • Kim, Yonggyun
    • Korean journal of applied entomology
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    • v.60 no.1
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    • pp.15-47
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    • 2021
  • Sex pheromone is used for chemical communication for mating in a species-specific manner in insects. Insect antennae possess sensory receptors specific to sex pheromone components and generate receptor potential to be perceived by the brain to evoke mating behavior. The sex pheromones have been used for monitoring specific species of insect pests to predict their subsequent occurrences based on a temperature-dependent growth model. Sex pheromones are also used for controlling pest insects using several different strategies such as mass capture, lure-and-kill, or mating disruption. This review explains the sensory physiology and insect pest management techniques related with sex pheromone.

Characteristics of Hydrodynamics, Heat and Mass Transfer in Three-Phase Inverse Fluidized Beds (삼상 역 유동층의 수력학, 열전달 및 물질전달 특성)

  • Kang, Yong;Lee, Kyung Il;Shin, Ik Sang;Son, Sung Mo;Kim, Sang Done;Jung, Heon
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.451-464
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    • 2008
  • Three-phase inverse fluidized bed has been widely adopted with its increasing demand in the fields of bioreactor, fermentation process, wastewater treatment process, absorption and adsorption processes, where the fluidized or suspended particles are small or lower density comparing with that of continuous liquid phase, since the particles are frequently substrate, contacting medium or catalyst carrier. However, there has been little attention on the three-phase inverse fluidized beds even on the hydrodynamics. Needless to say, the information on the hydrodynamics and transport phenomena such as heat and mass transfer in the inverse fluidized beds has been essential for the operation, design and scale-up of various reactors and processes which are employing the three-phase inverse beds. In the present article, thus, the information on the three-phase inverse fluidized beds has been summarized and reorganized to suggest a pre-requisite knowledge for the field work in a sense of engineering point of view. The article is composed of three parts; hydrodynamics, heat and mass transfer characteristics of three-phase inverse fluidized beds. Effects of operating variables on the phase holdup, bubble properties and particle fluctuating frequency and dispersion were discussed in the section of hydrodynamics; effects of operating variables on the heat transfer coefficient and on the heat transfer model were discussed in the section of heat transfer characteristics ; and in the section of mass transfer characteristics, effects of operating variables on the liquid axial dispersion and volumetric liquid phase mass transfer coefficient were examined. In each section, correlations to predict the hydrodynamic characteristics such as minimum fluidization velocity, phase holdup, bubble properties and particle fluctuating frequency and dispersion and heat and mass transfer coefficients were suggested. And finally suggestions have been made for the future study for the application of three-phase inverse fluidized bed in several available fields to meet the increasing demands of this system.

Analysis of water quality smart meter data using dynamic time warping (Dynamic Time Warping을 이용한 수질 스마트미터 데이터 분석)

  • Lim, Soyeon;Jung, Donghwi
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.173-173
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    • 2021
  • 현재까지 상수도관망 내 수질적 거동에 대한 분석은 (1) 네트워크 수질 모델(EPANET 수질모의 등)에 기반한 방법과 (2) 시공간적 저해상도 데이터에 기반한 데이터 분석법이 주를 이루었다. 그러나 현존 네트워크 수질 모델은 수질 사고의 복잡한 물리·화학적 거동을 상세히 모의하기 어렵다. 반면 계측 및 통신기술의 발달로 고해상도 수질 데이터의 실시간 수집이 가능해지면서 사고의 사전감지, 발생시 즉각적 탐지 및 대응을 위한 데이터 분석법에 관심이 증가하고 있다. 서울 문래동, 인천, 포항의 경우에서도 알 수 있듯이, 수질사고 발생 시 원인물질의 시공간적 이송 또는 전파에 대한 정보는 사고대응에 유용하게 활용된다. 본 연구는, 비정상적인 수질변화의 계통 내 전달 시간을 계산하기 위해 고해상도 수질 스마트 미터 데이터에 기반한 데이터 분석법을 개발하였다. 물공급 하류방향의 수질변화 전달 시간 정량화를 위해 화음탐색법 기반 동적시간워핑(Dynamic time warping; DTW) 기술을 이용하였고, 원데이터의 전처리를 위해 이동평균필터링을 수행하였다. 개발된 분석법은 A시 생산 및 배·급수과정의 감시지점에서 10초 단위로 계측된 다양한 수질변수(pH, 탁도, 잔류염소, 전기전도도, 수온 등)의 공간적 변이 전파시간을 결정하기 위해 적용되었다. 분석에 활용한 데이터는 데이터 통신 및 측정 기기에 의한 이상값과 운영상황의 변화에 따라 변동한 값을 처리하기 이전의 데이터이다. 데이터 품질에 의한 영향을 배제하기 위해 이상값이 발생하지 않은 기간을 파악한 후, 그 기간에 대하여 분석하였다. 계통 내 위계에 따라 두 지점의 측정값의 전파시간을 정량화한 결과, 지점에 따라 전파시간이 다르게 나타났다. 또한, 같은 두 지점에 적용한 결과라도 DTW를 적용하는 기간과 이동평균필터링의 크기에 따라 수질변화 전달 시간이 다르게 나타나는 것을 확인할 수 있었다. 본 연구에서 개발된 분석법은 다변량 수질변수 간의 영향관계를 파악하는데 확장 적용이 가능하다. 또한, 이 방법의 실시간 적용을 통해 동적으로 변화하는 전달시간을 주기적, 공간적으로 갱신하여 관망 수질 변화 모니터링이 가능하다.

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Dynamic Motion of Polyelectrolyte in a Composite Membrane: II. Molecular Study (막에서 전하고분자의 동적 현상 II. 미시적 연구)

  • Park, Young;Lim, Hwa A.
    • Membrane Journal
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    • v.4 no.2
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    • pp.96-105
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    • 1994
  • Theoretical model for membrane transport of large polye!ectroiyte is presented. When the electric field is applied, the molecular conformation quickly orients in the field direction showing overshooting orientation. the predicted dependence of overshoot time and orientation upon field intensity and molecular size aids to understand the dynamic motion of molecules in membrane transport. The dynamics of the overshoot is associated with self-trapping conformations of molecule. The understanding of these effects supports evidences for the electrophoretic filtration of polydectrolyte in the polymeric membrane. This paper shows one example for molecular study in the theoretical review paper of membrane transport.

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Unsteady Mass Transfer Around Single Droplet Accompanied by Interfacial Extraction Reaction of Succinic Acid (숙신산 추출반응이 일어나는 단일 액적계에서의 비정상상태 물질 전달)

  • Jeon, Sangjun;Hong, Won Hi
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1021-1026
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    • 2012
  • The transient mass transfer in a single droplet system consisting of 1-octanol (continuous phase)/aqueous succinic acid solution (dispersed phase) was investigated in the presence of chemical reaction, which is acid/anion exchange reaction of succinic acid and tri-n-octylamine (TOA). This succinic acid extraction by TOA can be considered to occur at the interface between organic and aqueous phase, that is, heterogeneous reaction system. The basic properties of the system such as viscosity, density, distribution coefficient, terminal velocity of droplet, and diffusion coefficient were measured experimentally or calculated theoretically, and used for theoretical calculation of characteristic parameters of mass transfer later. The effects of succinic acid concentration on the terminal velocity was negligible in the existence of TOA, although the terminal velocity increases with succinic acid concentration in the absence of TOA. On the contrary, the terminal velocity decreases with TOA concentration. While droplets falls through organic phase, the trajectory of droplets is observed to oscillate around its vertical path. A mass trnasfer cell was prepared to monitor the mass transfer behavior in a single droplet and used to measure the mean concentration of succinic acid inside droplet. The results are expressed with dimensionless parameters. Under 50 g/L succinic acid condition, the system with 0.1 mol/kg TOA showed that the molar flux decreases in proportion to the decrease of concentration gradient, while in the case of 0.5 mol/kg TOA Sh increases rapidly with time indicating the molar flux of succinic acid decreases relatively slowly compared to the decrease in concentration gradient.

Adsorption Characteristics of Antibiotics Amoxicillin in Aqueous Solution with Activated Carbon Prepared from Waste Citrus Peel (폐감귤박으로 제조한 활성탄을 이용한 수중의 항생제 Amoxicillin의 흡착 특성)

  • Kam, Sang-Kyu;Lee, Min-Gyu
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.369-375
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    • 2018
  • Batch experiments were conducted to investigate the effects of operating parameters such as the temperature, initial concentration, contact time and adsorbent dosage on the adsorption of antibiotics amoxicillin (AMX) by waste citrus peel based activated carbon (WCAC). The kinetics and isotherm experiment data can be well described with the pseudo-second order model and the Langmuir isotherm model, respectively. The maximum adsorption capacity of AMX by WCAC calculated from the Langmuir isotherm model was 125 mg/g. The adsorption of AMX by WCAC shows that the film diffusion (external mass transfer) and the intraparticle diffusion occur simultaneously during the adsorption process. The adsorption rate is more influenced by the intraparticle diffusion than that of the external mass transfer as the particle size of WCAC increases, and the intraparticle diffusion is the rate controlling step. The thermodynamic parameters indicated that the adsorption reaction of AMX by WCAC was an endothermic and spontaneous process.

Control of Hot Spots in Plug Flow Reactors Using Constant-temperature Coolant (등온 냉각액을 활용한 plug flow reactor 내의 과열점 제어를 위한 제어모델 개발)

  • Rhyu, Jinwook;Kim, Yeonsoo;Lee, Jong Min
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.77-84
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    • 2021
  • To control hot spot in a plug flow reactor (PFR) is important for the yield and purity of products and safety. In this paper, coolant temperature is set as a state variable, and radial distributions of heat and mass are considered to model the PFR more realistic than without considering radial distributions. The model consists of three state variables, reactant concentration, reactant temperature, and the coolant temperature. The flow rate of the isothermal coolant is a manipulated variable. This paper shows that the controller considering the radial distributions of heat and mass is more effective than the controller without them. Assuming that u3,0 is 0.7, the suggested control equation was robust when St is bigger than 1.3, and Ac/A is smaller than 2.0. Under this condition, the hot spot temperature changed within the relative error of one percent when the temperature of input altered within the range of five percent.

Neural Circuits Mediating Stress (스트레스의 신경생물학적 이해)

  • Yu, Bum-Hee;Woo, Jong-Min
    • Korean Journal of Psychosomatic Medicine
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    • v.9 no.1
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    • pp.81-92
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    • 2001
  • Stress has been linked to the pathophysiology and pathogenesis of various psychiatric illnesses. Over the past few years, our understanding of the brain and neuroendocrine systems that are linked to stress responses has increased enormously. This article reviews a series of animal and human studies to understand what are the central pathways by which stress is perceived, processed, and transduced into a neuroendocrine response. We focus on the limbic-hypothalamic-pituitary-adrenal(LHPA) axis and several neurotransmitter systems such as norepinephrine, CRF, serotonin, acetylcholine, and dopamine. LHPA stress circuit is a complex system with multiple control mechanisms which are altered in pathological states. CRF and related peptides in the central nervous system appear to enhance behavioral responses to stressors. Norepinephrine systems are also activated by stressors and cause the release of catecholamines from the autonomic nervous system. CRF-norepinephrine interaction makes a feed-forward system which may be important for an organism to mobilize not only the pituitary system but also the central nervous system, in response to environmental challenges. The interactions among several neurotransmitters and endocrine systems appear to play key roles in mediating various behavioral and psychological stress responses involving abnormal responses to stressors such as anxiety and affective disorders.

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Performance Improvement of Speech Recognizer in Noisy Environments Based on Auditory Modeling (청각 구조를 이용한 잡음 음성의 인식 성능 향상)

  • Jung, Ho-Young;Kim, Do-Yeong;Un, Chong-Kwan;Lee, Soo-Young
    • The Journal of the Acoustical Society of Korea
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    • v.14 no.5
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    • pp.51-57
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    • 1995
  • In this paper, we study a noise-robust feature extraction method of speech signal based on auditory modeling. The auditory model consists of a basilar membrane, a hair cell model and spectrum output stage. Basilar membrane model describes a response characteristic of membrane according to vibration in speech wave, and is represented as a band-pass filter bank. Hair cell model describes a neural transduction according to displacements of the basilar membrane. It responds adaptively to relative values of input and plays an important role for noise-robustness. Spectrum output stage constructs a mean rate spectrum using the average firing rate of each channel. And we extract feature vectors using a mean rate spectrum. Simulation results show that when auditory-based feature extraction is used, the speech recognition performance in noisy environments is improved compared to other feature extraction methods.

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