• Resources Recycling
• /
• v.5 no.3
• /
• pp.24-30
• /
• 1996

The computcr s~mulatiun model in vanaus s~nelllng process for melling waste cashhg sand was developed by using energy and malcrial balance concept. This modcl can prcdict the coal, flux and oxygen conaumptron and thc volume and temperature of off-gas The ~niljor critical varlablcs for smclting process can be crplained by using the analysis of energy and malc~ialb alance. Thc Innst lmportarlt variables lor smelting process were h i ~ hpo st-combust~anr atla, high heat transfer crficiency and refractory pratcclion lechnalogy. For saving encrg), in this smelting proccss, selection of caw marerials i.e coal, flus was important, cspacially ubi~go f low volatile coal was prufitahle.

• Journal of Institute of Convergence Technology
• /
• v.5 no.1
• /
• pp.1-5
• /
• 2015

SI thermochemical hydrogen production process achieves water splitting into hydrogen and oxygen through three chemical reactions. The process is comprised of three sections and one of them is HI decomposition into $H_2$ and $I_2$ called as Section III. The production of $H_2$ included processes involving EED for concentrating a product stream from Section I. Additionally an $I_2$ crystallization would be considered to reduce burden on EED by removing certain amount of $I_2$ out of a process stream prior to EED. In this study, the current thermodynamic model of SI process was briefly described and the calculation results of the applied Electrolytes NRTL model for phase equilibrium calculations was illustrated for ternary systems of Section III. We calculated temperature and heat duty of an $I_2$ crystallizer and heat duty of heaters using UVa model and heat balance equation of simulation tool. The results were expected to be used as operation information in optimizing HI decomposition process and setting up material balance throughout SI process.

• Journal of the Korean Institute of Gas
• /
• v.2 no.4
• /
• pp.73-78
• /
• 1998

This paper considers the applicability of a pseudosteady-state approach to the long-time behavior of real gas flow in a closed reservoir. The method involves a combination of a linearized gas diffusivity equation using a normalized pseudotime and a material balance equation. For the simulation of field-scale problems with multiple wells of differing production rates over extended production periods, the pseudosteady-state equation was solved successively for each flow period. Results from this study show that the approach provides a fast and accurate method for modeling the long-time behavior of gas reservoirs under depletion conditions.

• Resources Recycling
• /
• v.12 no.3
• /
• pp.38-45
• /
• 2003

ionic equilbria of nickel chloride in hydrochloric acid solutions were analyzed by considering chemical equilibria, mass and charge balance equations. The activity coefficients of solutes were calculated by using Bromley equation. It was found that most of species containing nickel existed as $Ni^{2+}$ 와 $NiCl^{+}$. The mole fractions of nickel hydroxides were very low in the con-centration ranges considered in this study and the mole fraction of$Ni_4$ $(OH)_{4}^{4+}$ increased greatly with the pH of the solution. The pH values of $NiCl_2$ $-HCl-NaOH-H_2$O system at $25^{\circ}C$ calculated in this study agreed well with those experimentally measured up to ionic strength of 9.4m.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2012.05a
• /
• pp.736-736
• /
• 2012

유수의 침식과 퇴적작용은 지형의 변화를 일으키며, 이런 지형변화는 하천 흐름, 지하수 흐름 등의 변화를 가져오며 이는 다시 지형변화의 원인이 된다. 이런 일련의 과정이 되풀이되는 것을 지형발달이라 하며, 이는 수문 현상에도 지대한 영향을 미친다. 지형발달의 주요 인자에는 강우와 지반 융기 등이 있으며 각 주요 인자들은 복합적으로 지형발달에 영향을 준다. 하지만 지형발달 탐구 시 실제 지형을 대상으로 탐구하기에는 한계가 분명히 있다. 그래서 본 연구에서는 컴퓨터를 이용해 수식을 계산하여 수치적으로 지형발달을 모의하는 모형을 이용하여, 지형발달에 영향을 주는 강우와 지반 융기를 중점적으로 탐구하였다. 지형발달모형을 이용하면 더욱 다양한 관점에서 지형발달과정의 역동성을 파악하는 새로운 시도들이 가능하다. 특히 특정 환경 조건에서의 논리적인 지형의 반응을 통한 해석이 가능해져, 환경 변화로 어떠한 지형변화 또는 지표물질 수지 변화가 있을지를 예측할 수 있다(변종민, 2011). 또한, 지형발달 일련의 과정들을 살펴볼 수 있기 때문에 시 공간적 제약에서 벗어날 수 있다. 그러므로 지형발달모형은 강우와 융기 조건에 따른 지형발달을 모의하기에 적합하다. 본 연구는 LEGS을 이용하여 강우와 융기 조건에 따른 지형발달 모의를 진행하였다. LEGS는 지표수의 흐름을 탐색하는 방법으로 GD8을 이용한 물리 기반의 수치적 지형발달모형이다(Paik, 2012). 본 연구에서는 강우의 변동과 융기 조건의 변화가 지형발달에 상당한 영향을 미치는 것을 발견하였다. 특히, 유역의 표고차이 등과 같은 정량적인 지표의 변화에 주목하여 각종 분석을 하고, 물리적 원인을 고찰하였다.

• Clean Technology
• /
• v.3 no.2
• /
• pp.74-86
• /
• 1997

Recently the treatment of industrial wastes by membrane processes has drawn much attention due to increasing demands for clean technology. In the process investigated in this study, metal species in the acidic wastes are precipitated as metal hydroxide forms in a neutralization tank, and acid and base solutions are regenerated by water-splitting electrodialysis(WSED) to be reused in the process. Material balances of the processes for treating pickle liquor and mixed wastewater were calculated to explain conceptual design of the process. Experiments for neutralization precipitation with KOH and NaOH for mixed wastewater were carried out to precipitate metal hydroxide and to recover salt solution as supernatant. Also WSED of the salt solutions producing acid and base was tested in 2 or 3 compartment stacks using KCl and NaCl to investigate the effects of stack configurations on the WSED performance.

• Clean Technology
• /
• v.3 no.2
• /
• pp.47-56
• /
• 1997

This Paper Proposes new pollution indices as a quantitative measure of environmental impact. The pollution index for a process is defined by using pollution balance equations. Three pollution indices were defined on the basis of waste characteristics: mass, BOD, and toxicity. Such pollution indices can be effective and valuable tools for minimizing the waste production of a process in terms of environmental impacts, and, when used with cost estimates, for objectively determining the optimal process. In this paper, the application of these indices was demonstrated in a case study involving the production of detergent, as reported in the literature. Pollution indices for the existing process and two improved processes were calculated and compared to evaluate environmental impacts of these processes.

• Water for future
• /
• v.26 no.3
• /
• pp.125-135
• /
• 1993

This study was conducted for two purposes. The first was the selection of the proper model for the urban runoff, and NPS(non-point source) loads and the second was the adjustment of the selected model through the calibration and the verification of the observed data on an urban drainage basin. The selected model for this study was the Storm Water Management Model(SWMM) developed and maintained by the US Environmental Protection Agency(EPA). In particular, the Runoff Block for the surface discharge and the Transport Block for the flow routing was used. The study basin is Youngdu basin, which is a typical developed urban drainage basin. The four rainfall events for the runoff and the two for the four NPS pollutants(SS, BOD, COD and TN) were used for the calibration and the estimation of the model parameters. This study performed the calibration with regard to the peak discharge, the time to peak discharge, the volume and the relative error for three items. It was shown that SWMM can successfully be used for the prediction of the runoff and the NPS pollutants discharge. The result of this study can be used as the basis for the analysis of the correlation between the runoff and the NPS pollutants discharges, and the analysis of the mass balance with the monthly and annual NPS loads in an urban drainage basin.

• Journal of Digital Contents Society
• /
• v.11 no.4
• /
• pp.463-471
• /
• 2010

In the management of a wastewater treatment plant which is a combination system of physical, chemical, and biological processes, computer simulator is an indispensable part for analysis of the operation status and evaluation of the treatment performance due to its fast computing speed. As an application software carrying out the data input-output operations and the mathematical calculations of the models, simulator is to be a powerful tool for estimating the treatment reaction and calculating mass balance of substrates, microorganisms, and chemicals within the treatment system in a given condition. Qualitative and quantitative prediction of treatment performance provides the plant manager with validity of decision-making through implementing modeling and simulation as a role of knowledge-based expert system in charge of automation and control. This paper shows the proceeding of design and development of the "WEC-Sim" software which is owned the various functions of data acquisition, monitoring, simulation, and control.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.11a
• /
• pp.158.1-158.1
• /
• 2010

국내 최초의 생활폐기물고형연료(RDF) 생산플랜트인 원주시 RDF플랜트의 2009년도 운영실적을 정리하여 폐기물 처리단가를 분석하였으며 에너지 생산 효과도 분석하였다. 실적분석에 사용된 자료는 원주 RDF플랜트 위탁운영업체가 운영비를 청구 및 정산하기 위해서 원주시에 상시 측정 및 보고하는 항목으로서, 내용은 트럭으로 플랜트에 반입되는 폐기물 전체량, RDF생산 전체량, 불순물 매립 전체량, 건조 및 탈취용 연료사용 전체량, 전기사용 전체량 등이다. 2009년도 원주시 RDF플랜트에 반입된 폐기물 량은 총 17,504톤이었고, RDF를 총 7,044톤 생산하였으며, 4,120톤의 불연물을 선별하였다. 1년간 사용한 건조 및 탈취용 연료는 총 596,268 리터였으며 연료인 부생유의 가격은 리터 당 평균 864.6원이었다. 사용한 전기량은 총 2,435,397 kWh였고, 이 중에서 성형공정에 사용된 전기량은 총 사용량의 19%였다. 이상의 기록자료들을 분석해 본 결과, 폐기물 1톤을 처리하는데 전기 비용이 14,334원이었고, 연료비가 29,452원이었다. 여기에 폐기물 1톤당 불연물 매립비 6,573원과 위탁인건비를 합하면 폐기물 1톤당 처리비용은 약 116,573원으로 나타났다. 현재 원주시 RDF는 톤당 25,000원에 판매되고 있으므로 이 비용을 감안하면 폐기물 1톤당 처리비용은 105,298원으로 산출되었다. 현재 알려진 유사 규모의 소각로 운영비가 폐기물 1톤당 136,736원인데, 이것은 RDF기술보다 31,438원/톤-폐기물 정도 처리비용이 비싸다. 따라서 100톤 이하 규모의 폐기물처리시설 설치를 할 경우에는 RDF 시설이 경제적으로 타당함을 나타낸다. 원주시 RDF플랜트의 물질수지를 분석해 본 결과, RDF생산 수율은 40.2%였으며 총 투입된 에너지는 8,0587 Gcal였다. 생산된 에너지 총량은 RDF발열량 4,500 kcal/kg으로 했을 때 31,699 Gcal로 나타났다. 투입대비 생산에너지 비율은 25.4%로 계산되었고, 전기의 발전효율을 40%로 감안했을 경우에는 35.3%로 계산되었다. 성형하는데 사용되는 총 에너지는 전체 투입에너지의 4.9%로 나타났고, 비용으로는 폐기물 1톤당 2,723원 이었다.