• Title/Summary/Keyword: 물의 상태변화

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Optimization of Wool Dyeing with Yellow Dye from Carthamus Tinctorius L. (홍화 황색소를 이용한 모염색의 최적화)

  • Shin, Youn-Sook;Son, Kyung-Hee;Yoo, Dong-Il
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.12
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    • pp.1971-1978
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    • 2009
  • This study investigated the adsorption of safflower yellow dye on wool protein fiber and the optimum dyeing conditions to test color reproducibility. In addition, the effects of mordants on dye adsorption, color, fastness, and photofading rate were also studied. The prepared dye in powder form was characterized with UV-vis spectroscopy and FT-IR spectrometric analysis. The color of dyed fabrics was characterized by CIE $L^*a^*b^*$ coordinates, H V/C, and K/S values. The color reproducibility of the dyed wool fabrics was examined. The amount of dye adsorption increased and also, the shade of the dyed wool fabrics became deeper and more saturated with increasing temperature, time, and dye concentration. The maximum color strength was obtained at pH 3.0. The shade of dyed wool fabrics ranged from light yellow to dark mustard yellow as the pH of the dye bath shifted from alkaline to acidic. Color reproducibility was reliable with color differences in the range of 0.53~1.75. Fastness to dry cleaning was relatively good at 4/5 rating irrespective of mordanting. Fe and Cu mordants showed the least color change of the dyed wool fabrics after exposure to light. Mordants did not contribute to improve dye uptake and color fastness, although they made variations in color tone. Safflower yellow dye can be used satisfactorily without mordants and will not cause damage to the environment.

The Analysis of Structure and Electron Energy State of Potassium-Graphite Fiber Intercalation Compounds (칼륨-흑연 섬유층간화합물의 구조와 전자 에너지 상태의 분석)

  • Oh, Won-Chun;Kim, Myung-Kun;Ko, Young-Shin
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.479-487
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    • 1993
  • Potassium-Graphite Fiber Intercalation Compounds(K-GFIC) have been prepared from well oriented pitch-based Graphite fiber by the transformed two-bulbs method with variation of reaction temperatures of graphite($T_g$ : $450^{\circ}C$, $400^{\circ}C$, $350^{\circ}C$, $300^{\circ}C$, $250^{\circ}C$). The stage transition process of K-GFICs was studied by X-ray diffraction methods, and we have observed peaks with d-values of (001) diffraction of $5.40{\AA}$ and $8.78({\pm}0.01){\AA}$, which are charecteristic for the stage 1 and stage 2, respectively. The stage stability and energy states of K-GFICs were studied by UV/VIS spectrophotometer. As a results, We found that the minimum values of reflactance of K-GFICs with pure stage was moved to higher energy pristine Graphite fiber's. But because of mixtured stage, we could not observe minimum reflectance in the visible region at high reaction temperatures($400^{\circ}C$, $450^{\circ}C$). From X-ray diffraction and UV/VIS sepctrophotometry data, we can suggest that K-GFICs with lower stage has many charge carriers existed between C atoms of graphite Layers. And then, these results also provides information on the electrical and other physical properties of K-GFICs.

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A Study on Reducing Method for Stack Effect in High-rise Building (고층 건축물 연돌효과 저감 방법에 대한 연구)

  • Kim, Jin Soo
    • 한국방재학회:학술대회논문집
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    • 2011.02a
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    • pp.66-66
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    • 2011
  • 중위도 이북의 건물에서 고층건물의 혹한기 연돌효과는 건물의 여러 가지 기능에 큰 영향을 미치며, 승강기 승강로는 화재시 차압 때문에 연기의 주된 전파통로가 된다. 외피의 밀폐성능을 높여 건물 내부의 연도효과를 줄일 수 있으나, 외피의 밀폐기능은 비상시 피난을 위해 피난경로를 개방하는 순간 일시에 무력화된다. 또한 건물 외피의 밀폐성능이 우수할수록 연돌효과 그 자체로써 건물외피에 미치는 구조적 영향이 커진다. 고층부의 연돌효과는 외피를 밖으로 밀어내는 작용이므로 풍하측에서는 마이너스 풍압에 더하여 건물 외피에 부담을 증가시킨다. 그러므로 고층건물에 발생하는 혹한기 연돌효과의 영향을 정리하자면 다음과 같다. ${\bullet}$ 건물 외벽 및 창문에 미치는 구조적 영향 ${\bullet}$ 제연 시스템의 기능 저해 ${\bullet}$ 승강기 문 개폐 장애와 소음 등 설비 기능의 부정적 영향 ${\bullet}$ 공조기능 장애 ${\bullet}$ 화재시 승강기 승강로 등 수직 샤프트를 통한 연기 전파 혹한기 건물 안팎의 온도차가 40K일 때 높이 600m인 초고층 건물 최상층에 발생하는 연돌효과에 의한 차압은 풍속으로 환산할 때 32m/s에 달한다. 그러므로 초고층 건물 설계시에는 최상층의 풍하측에 설계상의 예상 최대풍속에다 이러한 환산풍속을 더한 고속 풍력이 창문을 밖으로 밀어내는 것으로 보아야 한다. 또한 공조 및 환기시스템에서는 이러한 차압을 고려하지 않으면 고층부에서 환기 성능이 무력화될 수 있다. 다음과 같은 방법들을 이용하여 고층건물의 연돌효과를 효과적으로 줄일 수 있다. 1) 계단실의 연돌효과 저감 방법 계단실에 발생하는 연돌효과에 의한 차압은 계단실에 상승기류를 발생시킨다. 이러한 차압과 상승기류는 계단실 상하부를 개방하면 자연적으로 평형을 이루게 되므로 별도의 제어가 필요 없게 된다. 또한 화재감지기와 연동하여 상하부 외벽의 개구부를 열어두게 되면 피난상황에 따라 문이 여닫힘으로써 발생하는 압력상태의 변화를 고려할 필요가 없게 된다. 2) 승강기 승강로의 연돌효과 승강로의 상하부에 대규모 개구를 두면 대규모의 외기가 도입되어 상승 유동 후 배출되므로 승강로 내부 온도 저하로 연돌효과가 저감되고, 승강로로 유입된 연기는 대규모의 외기에 희석되어 농도가 낮아지고 대부분 외부로 배출된다. 3) 샤프트 복합효과를 이용하는 방법 거실 평면적에 비해 승강기나 계단이 아주 많고 누설틈새 등 개구의 면적 합계가 크면 샤프트들이 서로 복합효과를 이루어 연돌효과에 의한 차압이 줄어든다. 연돌효과 제어용 샤프트를 하나 더 보조적으로 설치함으로써, 보조샤프트에 의해 발생하는 차압으로 거실을 가압 혹은 감압하여 문제가 되는 차압을 어느 정도 상쇄할 수 있다.

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Gut Microbiome and Gastrointestinal Diseases (장내 세균총과 위장관 질환)

  • Hwang, Soonjae;Kim, Sung Hoon;Rhee, Ki-Jong
    • Korean Journal of Clinical Laboratory Science
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    • v.50 no.1
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    • pp.11-19
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    • 2018
  • The gut microbiome has been studied extensively over the past decade with most scientific reports focused on the adverse role of the gut microbiome on gastrointestinal diseases. For example, the altered gut microbiome exacerbates the development of immune system-mediated damage in many diseases. The most studied pathologies include irritable bowel syndrome, inflammatory bowel diseases, and colitis-associated cancer. On the other hand, intestinal microflora is also beneficial and contributes to the intestinal physiology by the synthesis of vitamins, production of short chain fatty acids and bile acid metabolism, thereby maintaining gut homeostasis. Therefore, the balance between commensal and pathogenic bacteria populations influences mainly the maintenance of intestinal health. Changes in the intestinal microflora have been suspected to be the underlying causes of multiple diseases. Despite the immense amount of published data, the optimal gut microbiome composition is still controversial. This review briefly outlines the connection between the gut microbiome and critical gastrointestinal diseases focusing on three prominent intestinal disorders: irritable bowel syndrome, inflammatory bowel diseases, and colitis-associated cancer disorders. Finally, intervention strategies using natural products for the alleviation of these diseases and the maintenance of a health gut microbiome are suggested.

Effect of Salts and Isomeric Butanols on the Mixed Micellar Properties of Cetylpyridinium Chloride with Triton X-100 (Cetylpyridinium Chloride와 Triton X-100의 혼합 미셀화에 미치는 염 및 부탄올 이성질체들의 효과)

  • Chung, Jong-Jae;Lee, Sang-Hak;Kim, Yung-Cheol;Lee, Byung-Hwan
    • Applied Chemistry for Engineering
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    • v.9 no.7
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    • pp.968-973
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    • 1998
  • The critical micelle concentrations($CMC^*$) of the mixed surfactant systems of cationic surfactant cetylpyridinium chloride(CPC) and nonionic surfactant Triton X-100(TX-100) in aqueous solutions of salts(KCl and $Na_2CO_3$) and isomeric butanols(tert-butanol, iso-butanol and n-butanol) were determined by UV spectroscopy method. The various thermodynamic values in aqueous solutions of salts and isomeric butanols were compared with the values in pure water, calculated by means of the equation derived from the pseudo-phase separation model. Thermodynamic parameters($X_1$, $\beta$, ${\gamma}i$, $ai^M$, $C_i$ and ${\Delta}H_{mix}$) were found to have great effects of salts and isomeric butanols on the mixed micellization of CPC/TX-100 mixtures, and also in good agreements with the nonideal mixed micelle model. They showed all negative deviations from the ideal mixed micellar behavior.

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Study on Identification and Purification of Germanium-fortified Yeast (게르마늄강화효모의 게르마늄결합 단백질의 분리 및 확인에 관한 연구)

  • Lee, Sung-Hee;Lee, Sang-Kwang;Lee, Hyun-Joo;Yi, Yong-Sub;Park, Eun-Woo
    • Applied Biological Chemistry
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    • v.49 no.1
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    • pp.55-59
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    • 2006
  • This study was designed to investigate the optimum manufacturing condition of germanium-fortified yeast, and the binding properties of germanium (Ge) in germanium-fortified yeast. The nutritional optimum conditions were glucose 3.0 (w/v) %, yeast extracts 0.3 (w/v) % and peptone 0.5 (w/v) %, and the amounts of yeast cells were 67.4 mg/ml. And, the standard germanium-fortified yeast was produced under the condition at the ratio of yeast cell and germanium solution was 1 : 0.5 (50%), pH 6.5 and $35-40^{\circ}C$ during fermentation. In results of the identification, binding of germanium-protein showed structural difference between the inorganic Ge $(GeO_2)$ added during fermentation process and germanium-fortified yeast. Therefore, germanium-fortified yeast made by biosynthetic technology formed structurally safe organic germanium during fermentation process. Germanium-fortified yeast can be applied as a new functional material far the improvement of health, the prevention and treatment of chronic degenerative disease like cancer, and the enforcement of immune system.

Differences in Clinical Practice Stress, Sleep Quality, and Daytime Sleepiness before and after Nursing Students (간호 대학생의 실습 전, 후 임상실습 스트레스, 수면의 질 및 주간 졸림증의 차이)

  • An, Mi-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.5
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    • pp.121-130
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    • 2020
  • This study identified the differences and relationships between clinical practice stress, sleep quality, and daytime sleep disorder before and after clinical practice of college nursing students. The subjects were 130 students in the third year of nursing science. The results showed that the average clinical stress of the study subjects was 3.15 out of 5 points. Out of the external factors for clinical practice stress, the score for the task was 3.64. There was a significant difference in gender (t=-3.88, p<).001), subjective health status (F=5.78, p=.004), residence (F=3.20, p=.026). Nursing students showed lower sleep quality (80.0% before practice, 70.0% after practice), and those with daytime sleepiness (26.9% before practice, 42.3% after practice) were more than those of general college students. There was a difference between sleep quality (χ2=4.06, p=.004) and daytime sleepiness (χ2=6.08, p=.009) before and after clinical practice. There was also a negative correlation between daytime sleepiness and sleep quality (r=-.259, p<0.01). Therefore, strategies to reduce clinical practice stress and improve the quality of sleep are needed for the physical and mental health of nursing college students. The quality of nursing can be improved in the future by helping nursing students adapt to the clinical practice of changing nursing education field.

Assessment on the Monitoring System for KURT using Optical Fiber Sensor Cable (광섬유센서케이블을 이용한 지하처분연구시설의 감시시스템 운영 평가)

  • Kim, Kyung-Su;Bae, Dae-Seok;Koh, Yong-Kwon;Kim, Jung-Yul
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.4
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    • pp.293-301
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    • 2010
  • Optical fiber cable, as a sensor, was installed on the wall of KAERI(Korea Atomic Energy Research Institute) Underground Research Tunnel(KURT) in order to monitor the physical stability of the tunnel, which was constructed for technical development and demonstration of radioactive waste disposal. This monitoring system has two simultaneous measurements of temperature and strain over time using Brillouin backscatter. According to the results of the monitoring from Jan. 2008 to Nov. 2009, there is no significant displacement or movement at the tunnel wall However, the cumulative volume of total strain increased slightly as time passes with the comparison of the reference observation, which was measured in Jan. 2008. The change in cumulative volume of total strain indicates that the strain level had been affected by saturation and de-saturation phenomena due to groundwater fluctuation at several points at KURT. This system is based on the distributed sensing technique concept, not point sensing. By using this system, a displacement can be detected with the range from $20{\mu}{\varepsilon}$ to $28,000{\mu}{\varepsilon}$ every 1m interval in minimum. A temperature variation can be monitored at every 0.5m interval with the resolution of 0.01 in minimum. Based on the study, this monitoring system is potentially applicable to long term monitoring systems for radioactive waste disposal project as well as other structures and underground openings.

A Study of Heterogeneity Corrections for Radiation Treatment Planning (방사선 치료계획 시 불균질 보정에 관한 고찰)

  • Lee, Je-Hee;Kim, Bo-Gyum;Park, Heung-Deuk
    • The Journal of Korean Society for Radiation Therapy
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    • v.18 no.2
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    • pp.89-96
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    • 2006
  • Purpose: To study effectiveness of heterogeneity correction of internal-body inhomogeneities and patient positioning immobilizers in dose calculation, using images obtained from CT-Simulator. Materials and Methods: A water phantom($250{\times}250{\times}250mm^3$) was fabricated and, to simulate various inhomogeneity, 1) bone 2) metal 3) contrast media 4) immobilization devices(Head holder/pillow/Vac-lok) were inserted in it. And then, CT scans were peformed. The CT-images were input to Radiation Treatment Planning System(RTPS) and the MUs, to give 100 cGy at 10 cm depth with isocentric standard setup(Field Size=$10{\times}10cm^2$, SAD=100 cm), were calculated for various energies(4, 6, 10 MV X-ray). The calculated MUs based on various CT-images of inhomogeneities were compared and analyzed. Results: Heterogeneity correction factors were compared for different materials. The correction factors were $2.7{\sim}5.3%$ for bone, $2.7{\sim}3.8%$ for metal materials, $0.9{\sim}2.3%$ for contrast media, $0.9{\sim}2.3%$ for Head-holder, $3.5{\sim}6.9%$ for Head holder+pillow, and $0.9{\sim}1.5%$ for Vac-lok. Conclusion: It is revealed that the heterogeneity correction factor calculated from internal-body inhomogeneities have various values and have no consistency. and with increasing number of beam ports, the differences can be reduced to under 1%, so, it can be disregarded. On the other hand, heterogeneity correction from immobilizers must be regarded enough to minimize inaccuracy of dose calculation.

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Analysis of Hygrothermal Performance for Standard Wood-frame Structures in Korea (국내 농어촌 표준 목조주택의 hygrothermal 성능 분석)

  • Chang, Seong Jin;Kang, Yujin;Wi, Seunghwan;Jeong, Su-Gwang;Kim, Sumin
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.3
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    • pp.440-448
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    • 2016
  • As recent buildings become more air tight, the natural ventilation rate is significantly reduced and it leads to difficulty in removing accumulated moisture in buildings. Hot and humid weather in summer and the large amount of moisture caused by indoor activity are the major factors of moisture problem in Korea. The hygrothermal behavior of building environment has to be considered carefully to reduce condensation risk and mold growth potential, and comfortable indoor environment. In this study, we evaluated hygrothermal behavior of Standard Wood-frame Structure published in the Korea Rural Community Corporation Using WUFI simulation program. The results indicated that the total water contents of wood wall measured in 2014 was lower than wood wall in 2010. As a result of evaluation by separating the farming and fishing areas, Moisture problems in fishing area became larger. The walls had a significant impact on the relative humidity than the temperature each areas. Furthermore, excessive water content problem of the wood-based material was reduced in the wall that could be applied in the fishing villages by changing the outdoor finishing materials. And Mold growth risk on the interior materials could be removed through the different setting of the indoor temperature during summertime.