• Title/Summary/Keyword: 물의 상태변화

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Effects of Sewage Treatment on Characteristics of Sludge as a Composting Material (하수처리가 퇴비화를 위한 하수 슬러지 특성에 미치는 영향)

  • Kim, Jae-Koo;Kim, Jong-Soo
    • Applied Biological Chemistry
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    • v.41 no.2
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    • pp.181-186
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    • 1998
  • The effects of sewage treatment on characteristics of sludge as a composting material were investigated for a year during the initial operation at the full-scale Chunan sewage treatment plant. Due to the shortage of design capacity of belt press, a sludge dewatering unit, non-volatile solids were recirculating and concentrating in the treatment plant, resulting in an increase of MLSS and a decrease in F/M ratio at the activated sludge system. Special attention is required for long term operations since the increase of non-volatile solids in the plant would deteriorates the treatment efficiency. The sewage sludge of the Chunan sewage treatment plant showed 79.5% of water content, 11.6% of organic content, and C/N ratio of 6.1, and contained As 1.8 mg/kg, Cd 27 mg/kg, Hg <0.1 mg/kg, Pb 54 mg/kg, T-Cr 370 mg/kg, and Cu 1,100mg/kg of heavy metals. In order to be used as raw material for optimum composting, the sewage sludge requires bulking agents for moistrure/porosity control and a carbon source for adjusting C/N ratio. However, the sewage sludge is not adequate as a soil conditioner after composing due to a high content of heavy metals. If the sewage sludge has to he used as a soil conditioner after composting, it as required to identify and remove tire industrial wastewater portions in tire influent of the plant since heavy metals in the influent were mostly concentrated in dewatered sludge.

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Vegetation and Landscape Analysis and Management Methods of Ip-am Wetland in the Naejang National Park (내장산국립공원 입암습지의 식생 및 경관 변화와 관리방안)

  • Lee, Seon-Mi;Myeong, Hyeon-Ho
    • Korean Journal of Ecology and Environment
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    • v.48 no.1
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    • pp.26-31
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    • 2015
  • This study was performed to evaluate the Ip-am wetland located in the Naejang National Park by analyzing vegetation and landscape and to suggest management plans. We carried out field survey in 2013 and analyzed aerial photos in 1976 and 2010 for landscape change. As a result, the places that were paddy fields in the past were dominated by 5 communities such as Salix koreensis Community (21.6%), Persicaria thunbergii Community (2.8%), Phragmites communis Community (1.1%), Molinia japonica Community (4.9%), Persicaria thunbergii-Molinia japonica Community (0.5%). On the other hand, the places that were upper fields in the past were occupied mostly by Rosa multiflora Community (6.8%), Humulus japonicus-Rosa multiflora Community (42.0%), Humulus japonicus Community (10.6%). In order to maintain and manage the wetland, water should be supplied continuously by making use of the six among the seven reservoirs located in the upper part through the hydrological survey should be accomplished. In addition, it was necessary to reinforce the banks for minimizing water outflow. It contributes to prevent dry peat and decrease in decomposition speed. Thus, it is hard to invade and settle of terrestrial plants and then secondary succession would be delayed.

Study of a Supercritical Fluid Process for the Preparation of Hydroxypropyl-β-cyclodextrin Inclusion Complexes (Hydroxypropyl-β-cyclodextrin 포접복합체 제조를 위한 초임계유체 공정 연구)

  • Lee, Sang-Yun;Kim, Jeong-Kyu;Kim, Woo-Sik;Ryu, Jong-Hoon;Lim, Gio-Bin
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.110-117
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    • 2005
  • In this work, solid-state inclusion complex powders of itraconazole and $2-hydroxypropyl-{\beta}-cyclodextrin(HP-{\beta}-CD)$ were produced by a supercritical anti-solvent (SAS) process. In order to evaluate the degree of complexation, the thermal behavior of the microparticulate complexes was investigated using differential scanning calorimetry. The experimental results obtained for the solubility and dissolution rate of the microparticulate inclusion complexes in a buffer solution of pH 1.2 showed that the complexation of itraconazole with $HP-{\beta}-CD$ results in a significant increase in the solubility and dissolution rate of itraconazole. The particle size of the SAS-produced inclusion complexes was dramatically reduced ($<0.1-0.5{\mu}m$) compared with untreated itraconazole ($30-50{\mu}m$) and $HP-{\beta}-CD$ ($50-100{\mu}m$). The solubility of itraconazole was increased with the increase of pressure at a constant temperature to ca. $758.6{\mu}g/mL$ in an aqueous medium of pH 1.2. The dissolution rate of itraconazole was observed to be significantly improved and about 90% of itraconazole was found to be dissolved within 5-10 min.

Effect of Temperature on Formation of Polymer in Oxidation of Methyl Linoleate (Methyl Linoleate 산화중 중합체 형성에 미치는 온도의 영향)

  • Kim, In-Hwan;Kim, Chul-Jin;Kim, Dong-Hoon
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.446-450
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    • 1996
  • To investigate the effect of heating conditions on the polymerization of methyl linoleate, the esters were heated at $60^{\circ}C,\;90^{\circ}C,\;120^{\circ}C$ and $150^{\circ}C$, respectively, with sparging oxygen for different periods of time. On the basis of the peroxide curve obtained at each of the four temperatures, four heating times were chosen for the analysis of the polymers and total oxidation products. Significant linear relationships were found between polymer contents and total oxidation product contents. The contents of polymers and their linkage types were analyzed by High Performance Size Exclusion Chromatography. The polymers formed at four temperatures were qualitatively identified as dimers. The dimers with peroxide linkages were detected from methyl linoleate oxidized at $60^{\circ}C\;and\;90^{\circ}C$ but they were not detected from methyl linoleate oxidized at $120^{\circ}C\;and\;150^{\circ}C$. Therefore, all dimers formed at $120^{\circ}C\;and\;150^{\circ}C$ seemed to be the ones with ether linkage or carbon to carbon linkage. The degradation rate of the dimers with peroxide linkages at $90^{\circ}C$ was faster than at $60^{\circ}C$.

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Behaviors of Trace Elements Caused by the Precipitation of Minerals in Acid Mine Drainage (산성광산배수에서 광물의 침전에 따른 미량 원소의 거동)

  • Yoon, Young Jin;Lee, Ji Eun;Bang, Sang Je;Baek, Young Doo;Kim, Yeongkyoo
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.3
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    • pp.173-182
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    • 2018
  • The precipitation and phase transformation processes of iron minerals in acid mine drainage have a great influence on the behavior of trace elements in drainage. However, it is not easy to accurately trace these processes in natural environments, and therefore, most studies have carried out in the laboratory to obtain the information on the precipitation and transformation of those minerals. In this study, the precipitation of minerals and the changes of trace elements in drainage water were investigated at different pH values in actual acid mine drainage collected from the Dalsung mine. The amount of some precipitated minerals was not enough for the mineral identification. However, from the minerals identified, amorphous minerals were formed first, and then goethite was precipitated probably from schwertmannite. When the pH of the sample was high (10), amorphous phases of minerals were still observed at even high pH (pH 10). With increasing time, the pH values decreased by precipitation and transformation of minerals. All the elements showed low concentrations at high pH (8, 10), which might be due to the precipitation of minerals at high pH and the effect of surface charge, and the concentrations of elements gradually increased with time. In the case of sulfur, it also increased in water due to the transformation of schwertmannite to goethite.

FUNDAMENTAL STUDIES OF THE LOWER PART OF THE NAKTONG RIVER FOR FISHERIES EXPLOITATION 2. Temperature and Quality of the River Water (낙동강 하류의 수산 개발을 위한 기본 조사 2. 수온 및 수질)

  • KIM In-Bae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.3 no.1
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    • pp.65-70
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    • 1970
  • This report is a part of the studies of the lower part of the Naktong River. The temperature and quality of the river water were investigated from May 1967 to June 1968. Except for Hadan which is a point located at the mouth of the river and much Influenced by sea water the average water temperature is generally below $10^{\circ}C$ up to the end of March, 10 to $20^{\circ}C$ from the beginning of April to the 1st-2nd ten days of May, and thereafter becomes above $20^{\circ}C$ which is adequate for the growth of warm-water fishes. The water again becomes below $20^{\circ}C$ at the beginning of October and becomes below $10^{\circ}C$ in December The difference of water temperature between at 7.00 a.m. and 4.00 p.m. is considerably great at Hadan, the mouth of the river, where the water is relatively stagnant. It shows an average monthly difference of 2.6 to $6.8^{\circ}C$ with a total average difference of $4.6^{\circ}C$. At the Kupo and Samrangjin stations the difference is very small For the basic data In the management of rivers, the water temperature should be measured twice a day at its highest and lowest temperatures, and the long term fluctuation of temperature should be investigated.

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Effects of Liquid Surface Tension on the Heat Transfer Coefficient in a Three-Phase Slurry Bubble Column (삼상슬러리 기포탑에서 액상의 표면장력이 열전달 계수에 미치는 영향)

  • Lim, Ho;Lim, Dae Ho;Jin, Hae-Ryong;Kang, Yong;Jung, Heon
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.499-504
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    • 2012
  • Characteristics of overall heat transfer were investigated in a three-phase slurry bubble column with relatively low surface tension media, which has been frequently encountered in the fields of industry. The heat transfer phenomena was examined in the system which was composed of a coaxial vertical heater and a proper of bubble column. The heat transfer coefficient was estimated from the measured mean value of temperature difference between the heater surface and the column proper at the steady state condition. Effects of gas velocity ($U_G$), solid fraction in the slurry phase ($C_S$) and surface tension (${\sigma}_L$) of continuous liquid media on the overall heat transfer coefficient (h) in the bubble column were determined. The mean value of temperature difference was estimated from the data of temperature difference fluctuations with a variation of time. The amplitude and mean value of temperature difference fluctuations with respect to the elasped time appeared to decrease with decreasing the surface tension of liquid phase. The overall heat transfer coefficient between the immersed heated and the bubble column increased with an increase in the gas velocity or solid fraction in the slurry phase, but it decreased with an increase in the surface tension of continuous liquid media. The overall heat coefficient in the slurry bubble column with relatively low surface tension media was well correlated in term of operating variables and dimensionless groups within this experimental conditions.

A Fundamental Research on Determining Segregation Boundary using Rheological Parameters for 21 and 24MPa grade of Normal Strength Concrete (레올로지 정수를 이용하여 21, 24MPa급 일반강도 콘크리트의 재료분리 경계를 판단하기 위한 기초연구)

  • Lee, You-Jung;Lee, Young-Jun;Han, Dongyeop
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.5
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    • pp.399-407
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    • 2020
  • The aim of the research is to provide the boundary conditions for segregation of normal strength grade and high fluidity concrete mixture (so called mid-fluidity concrete) with rheology parameters. Since the normal strength grade concrete mixture has a relatively high water-to-cement ratio and no SCMs, it is easy to be segregated when superplasticizer is added. Hence, to achieve the mid-fluidity concrete of normal strength grade and high fluidity, preventing segregation of the mixture is inevitable. In this research, using two superplasticizers with different solid concentrations, the flow behaviors and rheological behaviors were assessed by increasing fluidity until the segregation happened. According to the experiment in this research, an unusual behavior in rheology parameters was observed when the concrete mixture started to be segregated. From this results and report, it is expected to contribute on the definition of segregation with rheological test methods.

A Study on Rainfall-Pattern Analysis for determination of Design flow in small watershed (소유역의 설계유량 산정을 위한 강우현상 분석에 관한 연구)

  • 박찬영;서병우
    • Water for future
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    • v.14 no.4
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    • pp.13-18
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    • 1981
  • The rainfall pattern analysis on time distribution characteristics of rainfall rates in important in determination of design flow for hydraulic structures, particularly in urban area drainage network system design. The historical data from about 400 storm samples during 31 years in Seoul have been used to investigate the time distribution of 5-minute rainfall in the warm season. Time distribution relations have been deveolped for heavy stroms over 20mm in total rainfall and represented by relation percentage of total storm rainfall to percentage of total storm time and grouping the data according to the quartile in which rainfall was heaviest. And also time distribution presented in probability terms to provide quantitative information on inter-strom variability. The resulted time distribution relations are applicable to construction of rainfall hyetograph of design storm for determination of design flow hydrograph and identification of rainfall pattern at given watershed area. They can be used in conjuction with informations on spatstorm models for hydrologic applications. It was found that second-quartile storms occurred most frequently and fourth-quartile storms most infrequently. The time distribution characteristics resulted in this study have been presented in graphic forms such as time distribution curves with probability in cumulative percent of storm-time and precipitation, and selected histograms for first, second, third, and fourth quartile stroms.

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Evaluation on the External Restraint Stress in Mass Concrete (매스콘크리트의 외부구속응력에 관한 검토)

  • 강석화;정한중;박칠림
    • Magazine of the Korea Concrete Institute
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    • v.8 no.5
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    • pp.111-122
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    • 1996
  • The effects of external restraint on the thermal stresses i n mass concrete are investigated through a series of parametric study. Two major factors affecting the degree of external restraint such as the ratio of length to height of the placed structure (L/H) and the elastic modulus of base structure ($E_r$) are employed as the parameters in a condition which a placing height H is 1.0m. Various conditions of I,/H and E, are analysed by a FEM program and the relationship between these two parameters is examined. The shape of stress distribution due to the external restraint is shown as linearity on the height direction of the section, and is influenced by L/H, $E_r$, and strength development of placed concrete. The external restraint can be devided by two part. One is an axial restraint and the other is a flexural restraint. When the level of external restraint is low, the structure behavior is mainly governed by flexural restraint, otherwise it is dependent on axial restraint. Comparing the calculated stress by the method of the ACI 207 committee with a finite element analysis, the fbrmer overestimates the external restraint stress when the degree of external restraint is weak, and underestimates when it is strong.