• Title/Summary/Keyword: 물성 및 전단 특성

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A Novel Bioresorbable Bone Cement Using Tooth Apatite, Chitosan, and Cyanoacrylate for Bone Tissue Engineering - Handling & mechanical properties, cytotoxicity and biocompatibility- (골 조직공학을 위한 치아인회석, 키토산, 시아노아크릴레이트를 이용한 새로운 생체흡수성 골시멘트)

  • J. H. Chung;Lee, W.;P. H. Choung;J. E. Davies
    • Journal of Biosystems Engineering
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    • v.29 no.4
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    • pp.347-356
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    • 2004
  • 치아인회석, 키토산, 시아노아크릴레이트 등의 생분해성 생체재료를 이용해 새로운 생체흡수성 골시멘트를 개발하고자 하였다. 이들 골시멘트들에 대해서 중합온도, 응고시간 등의 조작특성과 압축강도, 전단강도 등의 물성을 분석하였다. 특히, 치아인회석과 키토산의 미립가루와 부틸 시아노아크릴레이트의 강력접착제를 이용한 시멘트(B)에 대해서는 직접 접촉방법과 XTT 방법을 통해 세포독성을 분석하였고, 또한 쥐를 이용한 동물실험에서 시멘트(B)의 처리그룹에 따라 생체적합성을 분석하였다. 시아노아크릴레이트를 이용한 골시멘트의 최대중합온도는 약 33$^{\circ}C$, 조작(응고)시간은 3-6분, 압축강도는 약 15-25㎫, 전단강도는 약 0.4-l.7 ㎫를 나타내었다. 첨가제로 사용된 Lipiodol은 골시멘트의 주사성과 강력접착제의 초기 중합지연도를 높였고, 특히 송진가루는 시아노아크릴레이트의 초기중합을 지연시켰다. 시아노아크릴레이트를 이용한 시멘트(B)의 세포독성을 분석한 결과, 대부분의 처리 그룹에서 낮게 나타났고, 특히 키토산과 치아인회석을 사용한 경우 각각 세포 독성이 더 낮게 나타났다. 그리고 골시멘트(B)의 동물 생체적합성 실험의 방사선상 및 조직학적 분석에서도 뼈 형성 및 결합이 우수하게 나타났다.

Improvement on Interfacial, Thermal, and Water Resistance Properties of Wood Sandwich Composites for Stone Bed using CNT-Animal Glue Adhesive (탄소나노튜브/아교 접착제를 이용한 돌침대용 목재 샌드위치 복합재의 계면, 열적 및 방수특성 증가)

  • Kim, Jong-Hyun;Kwon, Dong-Jun;Shin, Pyeong-Su;Baek, Yeong-Min;Park, Ha-Seung;Moon, Sun-Ok;Park, Joung-Man
    • Composites Research
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    • v.30 no.4
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    • pp.235-240
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    • 2017
  • Animal glue, a water-soluble adhesive, has been used historically for high-performance traditional furniture despite the disadvantage of weakness against moisture. Many scientists studied the ways to improve water resistance of animal glue. Improvements on the interfacial, thermal, and water resistance properties of wood sandwich composites (WSC) was studied with carbon nanotube (CNT) wt% in animal glue. Real-time temperature of WSC was measured after WSC was heated with increasing CNT wt%. Lap shear test was performed to determine the interfacial properties of wood and animal glue with CNTs. Water resistance properties of animal glue were determined by lap shear test using specimens dipped in water and the results were compared with the dry case. Hydrophobicity of animal glue by static contact angle was correlated with the variation of lap shear test. Interfacial, thermal, and water resistance properties for animal glue were improved with properly added CNTs.

Effect of Process Aids on Rheological and Mechanical Properties of Styrene-Butadiene Rubber Compound (가공조제가 Styrene-Butadiene Rubber 배합고무의 유변특성 및 기계적 물성에 미치는 영향)

  • Kang, Yong-Gu;Jung, Hoon;Kim, Tae-Nyun;Kim, Wan-Doo;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.170-176
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    • 2002
  • Effects of type and loading level of process aids on the rheological and mechanical properties of styrene-butadiene rubber (SBR) compound were investigated. Five commercial grades of process aids composed of fatty acids and their various derivatives such as metal salts, esters, alcohols and amides were selected. The reduction in Mooney and shear viscosities was higher for metal salt-type process aids but lower for the process aids containing high molecular weight fatty acid alcohols and esters with increasing the loading of process aids. Tensile modulus generally decreased, while heat-build-up increased with increased process aids content. No considerable effect was observed for ulimate properties such as tensile strength and elongation at break.

Engineering Characteristics of the Light Weight Soil Using Phosphogypsum and EPS Beads (인산석고-EPS 조각을 활용한 경량혼합토의 공학적 특성)

  • Kim, Youngsang;Suh, Dongeun;Kim, Wonbong;Lee, Woobum
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.6
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    • pp.19-25
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    • 2009
  • The current study developed light-weighted mixed soil that can solve problems related with soft soil such as ground subsidence, sliding and lateral displacement of ground. By reducing weight of reclaimed soil through mixing phosphogypsum and recycled EPS beads with the weathered granite soil. A series of geotechnical laboratory tests including physical index test, compaction test, CBR test, and direct shear test were performed and engineering properties were reviewed in order to assess applicability of the light-weighted mixed soil for roads and abutment and various back-filling materials at the reclamation area. Based on the laboratory test results, it was found that the maximum dry unit weight of the light-weighted soil ranges $14.32{\sim}15.79kN/m^3$ and the optimum water content ranges 21.91~24.23%, which means there is 11~19.3% weight decrease effect when comparing with general weathered granite soil. Also it was found that the corrected CBR value ranges 10.4~18.4% satisfying the domestic regulations on road subgrade and back-filling material. In addition, as for shear strength parameter, cohesion ranges 10.79~18.64 kPa and internal frictional angle ranges $35.4{\sim}37.2^{\circ}$, which are similar with those of general construction soil and back-filling material used in Korea. So it can be concluded that light-weighted mixed soil with phosphogypsum can be used effectively for soft reclamation ground as actual filling material and back-filling material. From the current study, it was found that light-weighted mixed soil with phosphogypsum has not only weight reduction effect, but also has no special problems in shear strength and bearing capacity. Therefore, it is expected that phosphogypsum can be recycled in bulk as road subgrade and back-filling material at the reclamation area.

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자두(Dried Plums)를 첨가한 White sausage의 물성 및 저장성에 관한 연구

  • Lee, Gwan-Ho;Seo, Sang-Won;Cha, Jae-Ung;Hong, Jong-Hyeok;Kim, Sang-Hyeon;Kim, Eun-Ju;Ju, Ung-Gwang;Choe, Do-Yeong;Choe, Gang-Deok;Choe, Il-Sin
    • Proceedings of the Korean Society for Food Science of Animal Resources Conference
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    • 2005.05a
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    • pp.247-252
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    • 2005
  • 본 연구는 파슬리 등의 야채를 첨가하여 제조되는 화이트소시지의 물성 및 저장성에 미치는 자두 분말의 효과를 조사하기 위해 실시되었다. 물성의 변화로서 pH는 자두의 첨가율이 증가함에 따라 상대적으로 감소 하였는데 3% 첨 가시 전 저장 기간 중 가장 낮게 ($pH\;5.11\;{\sim}\;4.44$) 나타났다. 육색(meat color)은 자두의 첨가량에 비례하여 적색도(redness)를 나타내는 a-value에서 높게 나타났으며 명도 (light ness)를 나타내는 L-value에서는 상대적으로 낮은 수치를 보여주었다. 전단력(Shear stre ngth) 측정에서는 저장 기간 중 자두 분말의 첨가량에 비례 하여 근소한 차이를 나타냈는데 저장 7일째에서 가장 높았다. 자두 분말 첨가구 에서의 다소 높은 전단력의 결과는 보수력 (WHC) 측정 에서도 같은 경향을 나타내었는데 자두 분말의 증가량에 따라 3% 첨가구가 대조구 (0%)보다 낮게 나타나 약한 보수성을 보여 주었다. 저장성에 미치는 결과로서 총세균수의 측정결과 저장 3일이 경과한 구간에서 Sorbic acid (0.07%)의 첨가구와 자두 분말(3%) 첨가구 에서 비슷한 항균 효과를 나타내었다. 이 같은 동일한 수준의 항균 효과는 저장 9일째에도 같은 경향으로 나타났다. VBN 측정에는 저장 기간에 따라 증가된 수치를 나타냈는데 저장 7일 및 8일, 9일째 측정 결과는 3% 자두분말 첨가구와 0.07% Sorbic acid 첨가구 와 비슷한 수준을 나타내어 동일한 저장효과를 보여 주었다. 관능검사 실시 결과 총체적인 풍미에 있어서는 자두 분말 첨가구 1.5%가 가장 우수 했으며 다음으로는 3%, Sorbic acid 첨가구 및 공시료 순으로 나타났다.간에 유의차는 나타나지 않았다.pm을 spiking한 후 SPE상에서 SCX(Strong cation exchange column)을 통한 clean-up과정을 거친 후의 STP의 limit of quantification(LOQ)는 약 0.44ppm이었으며, 이에 대한 회수율은 89.7${\pm}$2.3%(n=6)를 나타냈다. 실제 CODEX에서 권장한 우유의 MRL이 0.6ppm인 점을 감안하면 CODEX권고치에 도달할 수 있는 것으로 판단되었다. 따라서 본 연구에서 개발 된 시험법은 지금까지 국내적으로 STP에 대한 시험법이 확립되어 있지 않은 것으로 이와 아울러 간편한 parallux와 병용해 STP에 대한 정량 및 정성 분석을 유도체화 장치 및 형광검출기를 이용해 잔류항생물질 STP에 대한 분석시험법을 개발하였다.화와 네트워크 조직망 구축을 위한 지역중심의 복합 생활문화 공간이 필요할 것이며, 이를 촉진키 위한 mentor academy시스템 접근을 통해 점점 고령화되어 가고 있는 재래시장에 대해 차별적 특성이 반영된 종합적이고 체계적 접근 방법연구가 필요하다./TEX> 자체기술개발, 선진기술 도입, 산업간 및 산업내 기술확산, 국제기술협력 ${\rightarrow}$ 기술혁신의 촉진 ${\rightarrow}$ 총요소생산성과 기업경쟁력(자원 및 역량, 프로세스 경쟁력, 품질경쟁력, 시장경쟁력, 고객성과, 시장성과, 재무성과)의 제고 ${\rightarrow}$ 가격경쟁력(임금, 금리, 물류비용, 환율 등)과 비(非)가격경쟁력(디자인, 에프터서비스, 품질, 운송 등)의 제고 ${\rightarrow}$ 국가경쟁력의 제고 ${\rig

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Rheological Characteristics of Highly Concentrated Polymer Bonded Explosive Simulant: Wall Slip, Thixotropy, and Flow Instability (고농축 복합화약 시뮬란트의 유변학적 특성: 벽면 미끄러짐, 틱소트로피, 유동불안정성)

  • Lee, Sangmook;Hong, In-Kwon;Ahn, Youngjoon;Lee, Jae Wook
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.213-219
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    • 2014
  • The rheological characteristics of highly concentrated polymer bonded explosive simulant were studied. Hydroxyl terminated polybutadiene (HTPB) and polyethylene plastomer (Exact) were used as binders. Sugar and Dechlorane particles whose physical properties are similar to research department explosive (RDX) were used as fillers. When HTPB was used, diethyl hexyl adipate (DEHA or DOA) was used as a plasticizer together for some cases. Highly concentrated suspensions were mixed in a batch melt mixer (Rheomixer 600, Haake) and rheological properties were measured by plate-plate and capillary rheometers. Wall slip phenomena, thixotropy with shear hysteresis, and flow instability were investigated as shear rate and amount of fillers changed.

Characteristics Changes of Weathered Soil by Weathering (풍화에 따른 풍화토의 특성 변화)

  • 권오순;정충기
    • Geotechnical Engineering
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    • v.14 no.5
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    • pp.53-66
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    • 1998
  • Since weathered soils are made by weathering process, the characteristics of weathered soils are strongly related to the originated rock and its forming process. Investigations on the originated rock and the weathering environments that decide the forming process are indispensable for the appropriate analysis on weathered soils. In this study, forming process of weathered soil is investigated by geological viewpoint. Test results show that weathering of rock is closely related to the distribution of rock-forming mineral and forming process. Weathered granite soils have the isotropic in-situ stress state and shearing behavior caused by the non-directional characteristics of originated rock. And weathered gneiss soils have the directional characteristics that mechanical behavior is determined by internal discontinuities. It it proved that the weathering resistance of Quarte is greater than that of feldspar and mica, and it is concluded that the thickness of weathered region is greatly influenced by the distribution of rock-forming mineral.

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Characteristics of Flexuarl-Shear Behavior of Beam Using Demonstrated CFRP Rod (국내 시범 생산 CFRP rod를 적용한 보 부재의 휨-전단 특성)

  • Choi, So-Yoeng;Kim, Il-Sun;Choi, Myoung-Sung;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.86-94
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    • 2022
  • Replacement of FRP rod as steel reinforcement has been attracted significantly to prevent the degradation of the concrete structure due to corrosion. So, the technology development to extend the structure's service life by improving FRP properties has been proceeded worldwide. Accordingly, it is necessary to develop Korea's CFRP rod and CFRP grid, including the manufacturing techniques to improve the properties of high-strength and high-stiffness. Moreover, the research should be conducted to evaluate the structural behavior of the beams using the CFRP rod or grid. This study investigates the flexural and shear behavior of reinforced concrete beam using demonstrated CFRP rod as reinforcement according to the reinforcement ratio and shear span to depth ratio. From the results, when the reinforcement ratio is out of a specific range, it is seemed that the effect on performance improvement of the beam using CFRP rod is cancelled or not significant. Meanwhile, when the CFRP rod was used as reinforcement, the possibility of shear failure occurred, even steel stirrups were installed in the beam with CFRP rod as tensile reinforcement according to the Korean Design Standard. Therefore, when the CFRP rod is used as tensile reinforcement in a beam, it should be prepared that a specific limitation of reinforcement ratio and an investigation against shear failure. Also, the ductility of the beam using the CFRP rod is determined by the deformation energy evaluation method. So, the ductility should be investigated by applying the deformation energy evaluation method that reflects the structural behavior of the beam.

The Effect of Chemical Properties of Comonomer on Adhesion Properties of Acrylic Pressure Sensitive Adhesives (공단량체의 화학적 구조에 따른 아크릴 접착제의 접착특성)

  • Choi, Woon-Jin;Kim, Ho-Gyum;Cho, Kwang-Soo;Lee, Dong-Ho;Min, Kyung-Eun
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.369-373
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    • 2007
  • In this study, solvent-free pressure sensitive adhesives (PSA) using acrylic copolymer was prepared by UV radiation to investigate the effect of comonomer on the adhesion properties. Adhesive force value of PSA was increased with the amount of comonomer having shorter side chain due to the enhanced intrinsic surface energy. Peel and shear strength were also influenced by chemical properties of comonomer. The addition of comonomer, ethyl and n-butyl acrylate allows PSA sample with high peel and shear strength. This nay be explained in terms of correlation between loss modulus and glass transition temperature of PSA. As the addition of acrylic comonomers with long side chain length decreases the loss modulus of PSA, the deformation of PSA can not be inhibited.

Simulation of Dynamic in-situ Soil Properties for the Centrifuge Test (Hualien Site in Taiwan) (원심 모형 시험을 위한 동적 현장 지반 모사 기법 연구(대만 화련 지반))

  • Ha, Jeong-Gon;Lee, Sei-Hyun;Choo, Yun-Wook;Kim, Se-Hee;Kim, Dong-Soo
    • Journal of the Earthquake Engineering Society of Korea
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    • v.16 no.4
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    • pp.27-36
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    • 2012
  • The simulation of the field dynamic soil properties for soil modeling in the centrifuge test is important. In this study, the process of soil modeling based on the shear wave velocity profile is developed. From the resonant column test in each confining pressure, the shear wave velocity profile is expected and the modeling condition is determined by comparing it with that in the field. During the dynamic centrifuge test, the bender element test is performed for measuring the in-flight shear wave velocity profile, and the applicability of the proposed method was verified. This modeling method is applied to the centrifuge test of the Hualien Large-Scale Seismic test.