• Journal of Environmental Health Sciences
• /
• v.36 no.5
• /
• pp.343-350
• /
• 2010

This study was performed to investigate laboratory workers' exposures to airborne nanoparticles at a university laboratory where acid treatment experiments were conducted on the surfaces of engineered carbon nanotubes (CNTs). The surface area concentrations, number concentrations, and mass concentrations of airborne nanoparticles were measured at personal breathing zones (PBZs) for various tasks using direct reading instruments. For all three metrics, airborne nanoparticle concentrations during the experiments were higher than background levels measured before and after the experiments for all three metrics. Among the various tasks that were performed as part of these experiments, one task that involved filtering a mixture of acid and CNTs showed the highest concentrations in all three metrics, with concentrations of $116.6\;{\mu}m^2$/cc, 24320 pt/cc, and $9.0\;{\mu}g/m^3$, respectively. Nanoparticle surface area concentrations measured at a representative area fluctuated with those at the PBZs in the laboratory. This result indicates that nanoparticles generated during the experiments were not just limited to the PBZs of the workers but were also present throughout the room, potentially exposing co-located workers. CNTs were detected by a transmission electron microscope in an air sample collected while handling the CNTs. All the tasks were performed inside fume hoods, with the sliding sashes open to their required heights. It was noted that the capture velocities of the fume hoods were much lower than the American National Standards Institute (ANSI)'s recommendation level (0.4 to 0.6 m/s). In conclusion, this study showed that, due to inadequate control, laboratory researchers performing acid treatment experiments on surfaces of CNTs were exposed to airborne nanoparticles generated during the tasks.

• Korean Journal of Environmental Agriculture
• /
• v.22 no.4
• /
• pp.284-289
• /
• 2003

Titanium mesoporous materials have received increasing attention as a new photocatalyst in the field for photocatalytic degradation of organic compounds. The photocatalytic degradation of chlorothalonil by mesoporous titanium oxo-phoswhate (Ti-MCM) was investigated in aqueous suspension for comparison with $TiO_2$, (Degussa, P25) using as an effective photocatalyst of organic pollutants. Mesoporous form of titanium Phosphate has been prepared by reaction of sulfuric acid and titanium isopropoxide in the presence or n-hexadecyltrimethylammonium bromide. The XRD patterns of Ti-MCM are hexagonal phases with d-spacings of 4.1 nm. Its adsorption isotherm for chlorothalonil reached at reaction equilibrium within 60 min under dark condition with 28% degradation efficiency. The degradation ratio of chlorothalonil after 9 hours under the UV radiation condition (254 nm) exhibited 100% by Ti-MCM and 88% by $TiO_2$. However, these degradation kinetics in static state showed a slow tendency compared to that of stirred state because of a low contact between titanium matrices and chlorothalonil. Also, degradation efficiency of chlorothalonil was increased with decreasing initial concentration and with increasing pH of solution. As results of this study, it was clear that mesoporous titanium oxo-phosphate with high surface area and crystallinity could be used to photo- catalytic degradation of various organic pollutants.

• Journal of the Korean association of regional geographers
• /
• v.13 no.2
• /
• pp.129-142
• /
• 2007

The Purpose of this study is to evaluate the value of abandoned paddy fields as wetland ecosystems and their suitability as habitats for various species. Physical and chemical characteristics of soils and the change of vegetation in paddy fields were analysed -with the passage of time after cease of cultivation. The results of analyses for soil characteristics, vegetation succession, and functional values of abandoned paddy fields as wetlands were as follows: First, top soils become coarser as years after abandonment increase. Second, as the years of abandonment passed. there were significant differences in organic matter, available phosphorate and calcium, while not in magnesium and cation exchange capacity(CEC). Third, species increased from early stage till middle stage, and decreased in late stage. In similarity analysis of species composition, sites were classified into three groups according to the stage of succession. Upper and lower terraces at Daetgol were classified as early stage of succession. The 1st, 2nd and 3rd terraces at Nonbanggol were in middle stage, while tile 4th and 5th were in late stage. Forth, according to evaluation sheets of MoE and RAM(Rapid Assessment Method) standards, me overall average of functional value of Nonbanggol site were 2.13, classified as "common".

• Journal of Conservation Science
• /
• v.28 no.4
• /
• pp.377-385
• /
• 2012

Anoxic treatments using argon and nitrogen gas in controlled atmospheres have been used as a alternative to methyl bromide for insect disinfection in museums. Anoxic chamber system was manufactured and installed at The National Folk Museum of Korea for the first time in Korea. The internal capacity of anoxic chamber is 0.5m3 in which is able to use argon, nitrogen and carbon dioxide gas. This system is equipped with oxygen concentration, temperature and ralative humidity control devices and automatically controlled oxygen concentration from 0.01 to 20%, temperature from 10 to $50^{\circ}C$ and relative humidity 30 to 80%. To control the oxygen concentration, anoxic chamber system is adopted semi-dynamic method which supplies mixture of humidified gas and dry gas whenever oxygen concentration in chamber becomes higher than setting value. It has kept regularly oxygen concentration, temperature and relative humidity for 20 days using argon gas. To evaluate the disinfection of cigarette beetle larvae and adults and varied carpet beetle larvae, the anoxic chamber system maintained 0.01% of oxygen concentration, $25^{\circ}C$ in temperature and 50% in relative humidity for 30 days. Cigarette beetle larvae were killed in 7 days and adults in 3~5 days. And varied carpet beetle larvae were killed in 3 days. It reaches the conclusion form the evaluation this anoxic chamber system can be used to develop anoxic treatment as an alternative of methyl bromide for insect disinfection of infested cultural properties in museums.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.21 no.2
• /
• pp.81-103
• /
• 1979

The weathered granite soil involves problems in its stability in soil structures depending upon the reduction of soil strength due to the water absorption, crushability, and content of colored mineral and feldspar. As an attemt to solve the problems associated with soil stability, the crushability of weathered granite soil was investigated by conducting tests such as compaction test, CBR test, unconfined compression test, direct shear test, triaxial compression test, and permeability test on the five soil samples different in weathering and mineral compositions. The experimental results are summarized as follows: The ratio of increasing dry density in the weathered granite soil was high as the compaction energy was low, while it was low as the compaction energy was increased. The unconfined compressive strength. and CBR value were highest in the dry side rather than in the soil with the optimum moisture content, when the soil was compacted by adjusting water content. However, the unconfined compressive strength of smples, which were compacted and oven dried, were highest in the wet side rather than in soil with the optimum moisture content. As the soil becomes coarse grain, the ratio of specific surface area increased due to increased crushability, and the increasing ratio of the specific surface area decreased as the compaction energy was increased. The highest ratio of grain crushability was attained in the wet side rather than in the soil with the optimum moisture content. Such tendency was transforming to the dry side as the compaction energy was increased. The effect of water on the grain crushability of soil was high in the coarse grained soil. The specific surface area of WK soil sample, when compacted under the condition of air dried and under the optimum moisture content, was constant regardless of the compaction energy. When the weathered granite soil and river sand with the same grain size were compacted with low compaction energy, the weathered granite soil with crushability had higher dry density than river sand. However, when the compaction energy reached to certain point over limitation, the river sand had higher dry density than the weathered granite soil. The coefficient of permeability was lowest in the wet side rather than in the optimum moisture content, when the soil was compacted by adjusting soil water content. The reduction of permeability of soil due to the compaction was more apparent in the weathered granite soil than in the river sand. The highly significant correlation coefficient was obtained between the amount of particle breakage and dry density of the compacted soil.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.24 no.3
• /
• pp.182-187
• /
• 2011

In this paper, PBTI characteristics of NMOSFETs with La incorporated HfSiON and HfON are compared in detail. The charge trapping model shows that threshold voltage shift (${\Delta}V_{\mathrm{T}}$) of NMOSFETs with HfLaON is greater than that of HfLaSiON. PBTI lifetime of HfLaSiON is also greater than that of HfLaON by about 2~3 orders of magnitude. Therefore, high charge trapping rate of HfLaON can be explained by higher trap density than HfLaSiON. The different de-trapping behavior under recovery stress can be explained by the stable energy for U-trap model, which is related to trap energy level at zero electric field in high-k dielectric. The trap energy level of two devices at zero electric field, which is extracted using Frenkel-poole emission model, is 1,658 eV for HfLaSiON and 1,730 eV for HfLaON, respectively. Moreover, the optical phonon energy of HfLaON extracted from the thermally activated gate current is greater than that of HfLaSiON.

• Korean Security Journal
• /
• no.16
• /
• pp.265-282
• /
• 2008

This research aims to provide a solution for the improvement of private security according to the change in criminal environment. The main cause of crime can be found in the anti-functional dimensions including value set disorder, social phenomenon variation, information-based, globalization and urbanization. In this environment, the private security sector has dramatically increased in a quantitative viewpoint, but it is insufficient in a qualitative viewpoint. This paper recognized this problem and demonstrates a solution for improvement through classifying elements of private security into relevant legislation, education institutions, security companies and security associations. The analysis result is a follows: First, motivation and satisfaction rate of escort and security related major has shown to be high. However, respondents evaluated the guard educational institution negatively. Second, the motivation of entering into the private security sector for internal staffs has shown to be positive and sound. However, the job satisfaction rate has shown to be low due to excessive competition, negative perception of occupation and low earning. Third, respondents gave an average mark to the Security Association's management and operation. In addition, the mutual-aid project received the same mark. Negative feedbacks were given to the protection of member's interest and to association operation and policy, while positive feedbacks were given to the degree of member's cooperation towards association policies.

• Korean Journal of Veterinary Research
• /
• v.35 no.3
• /
• pp.459-469
• /
• 1995

As S-nitrosothiols were proposed as nitrergic carriers in vascular and nonvascular smooth muscle, we have investigated the relaxant properties of several S-nitrosothiols in the porcine retractor penis(PRP) muscle and compared them with the effects of exogenously added NO, electrical field stimulation(EFS) of NANC nerves and sodium nitroprusside(SNP). Also the influences of oxyhemoglobin and hydroquinone on the relaxant responses were investigated. In addition, effects of NO on membrane potentials and its involvement in the generation of inhibitory junction potential(IJP) were investigated with conventional intracellular microelectrode technique. The results were summerized as follows. 1. Frequency-dependent relaxations of PRP muscle were induced by EFS to NANC nerve. Tetrodotoxin($1{\times}10^{-6}M$) abolished the relaxations of PRP muscle induced by EFS, and L-NAME(($2{\times}10^{-5}M$) and methylene blue($4{\times}10^{-5}M$) inhibited the relaxations. L-NAME-induced inhibition of the relaxations was reversed by L-arginine($1{\times}10^{-3}M$), but not by D-arginine. 2. Exogenous NO($1{\times}10^{-5}-1{\times}10^{-4}M$), sodium nitroprusside(($1{\times}10^{-7}-1{\times}10^{-4}M$) induced dose-dependent relaxations of PRP muscle. All S-nitrosothiols($1{\times}10^{-7}-1{\times}10^{-4}M$) tested relaxed the PRP muscle in dose-dependent manner and the potency order was SNAP>GSNO>CysNO>SNAC. 3. Oxyhemoglobin($5{\times}10^{-5}M$) blocked the relaxation induced by exogenous NO and inhibited EFS-, S-nitrosothiols-, and SNP-induced relaxation. 4. Hydroquinone($1{\times}10^{-4}M$) also abolished the relaxations induced by exogenous NO, and reduced the relaxations induced by S-nitrosothiols, but did not affect EFS- and SNP-induced relaxations. 5. SNP($2{\times}10^{-6}-5{\times}10^{-6}M$) relaxed muscle strips but the membrane potentials were not affected. 6. EFS with several pulses(1ms, 2Hz, 80V) produced an inhibitory junction potential(IJP) with muscle relaxation. They were abolished by TTX($2{\times}10^{-6}M$). $N^G$-nitro-$_{\small{L}}$-arginine(L-NNA, $2{\times}10^{-5}M$) abolished the muscle relaxation, but had no effect on IJP.

• Korean Journal of Veterinary Research
• /
• v.35 no.3
• /
• pp.447-458
• /
• 1995

This study was carried out to characterize nonadrenergic, noncholinergic(NANC) relaxation of porcine retractor penis(PRP) muscle induced by electrical field stimulation(EFS) and to investigate the actions of niric oxide(NO) and vasoactive intestinal polypeptide(VIP) as candidates for NANC neurotransmitters. Biphasic relaxations of PRP muscle were induced by EFS to NANC nerve. Rapid-phase relaxation was observed at low frequency(0.5-16Hz) and slow-phase relaxation followed during high frequency(8-60Hz). Both relaxations were frequency-dependent and TTX($1{\times}10^{-6}M$)-sensitive. L-NAME($2{\times}10^{-5}M$) inhibited the rapid-phase relaxation, but not the slow-phase relaxation. The inhibition of the rapid-phase relaxation with L-NAME was reversed by L-arginine ($1{\times}10^{-3}M$) but not by D-arginine($1{\times}10^{-3}M$). Methylene blue($4{\times}10^{-5}M$) reduced the rapid-phase relaxation. Exogenous No(ExoNO, $1{\times}10^{-5}-1{\times}10^{-4}M$) induced dose-dependent relaxations of PRP muscle. Oxyhemoglobin($5{\times}1^{-5}M$) blocked the relaxation induced by ExoNO and inhibited EFS-induced relaxation. Hydroquinone($1{\times}10^{-4}M$) also abolished the relaxation induced by ExoNO, but did not affect EFS-induced relaxation. L-NAME resistant slow-phase relaxation to EFS was inhibited by ${\alpha}$-chymotrypsin(2.5 U/ml). Both methylene blue($4{\times}10^{-5}M$) and Nethylmaleimide($1{\times}10^{-4}M$) reduced the slow-phase relaxation by EFS. [4-Cl-D-$Phe^6$, $Leu^{17}$]-VIP($3{\times}10^{-6}M$) inhibited the slow-phase relaxation by EFS. External applications of VIP ($1{\times}10^{-7}M$) caused relaxations that were simillar to the L-NAME resistant slow-phase relaxations induced by EFS, and relaxant effects of exogenous VIP were blocked by ${\alpha}$-chymotrypsin(2.5 U/ml).

• The Korean Journal of Mycology
• /
• v.23 no.4 s.75
• /
• pp.325-331
• /
• 1995

The effect of cultural conditions on mycelial growth, polysaccharide production in Phellinus linteus and its monosaccharide composition was studied. P. linteus showed the highest growth (0.9 g/100 ml) on glucose but the polysaccharide production was the highest (13.7%) on mannose. The fungus grew very well at neutral pH (0.9 g/100 ml) but the growth was reduced to 0.47 g per 100 ml at alkaline pH. For the different pH, the yield of polysaccharide was in the range of $5{\sim}8%$. The highest yield of 7.94% was obtained at pH 5. Also a variation in monosaccharide composition was observed for different carbon sources and pH. The composition ranges of glucose, mannose, and galactose of polysaccharide were $80{\sim}95%,\;3{\sim}12%,\;and\;2{\sim}10%$ depending on carbon sources, respectively. In contrast, the variation of composition range of three monosaccharides was narrower for different pH than that for carbon sources. These results suggested the possibility of the improvement of production and the physiological modification of the polysaccharide.