• Title/Summary/Keyword: 무기화합물

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Chemical Compositions and Antioxidative Activity of Leek (Allium tuberusum) Seeds (부추(Allium tuberusum) 씨의 이화학적 특성과 항산화 활성)

  • 차재영;김성규;김현정;송재영;조영수
    • Journal of Life Science
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    • v.10 no.3
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    • pp.273-278
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    • 2000
  • The chemical compositions as amino acids, minerals, fatty acids, and total polyphenolic compounds of the seeds of leek (Allium tuberusum) were analyzed. The antioxidative activity of water soluble extract from leek seeds was also tested in DPPH ($\alpha$, $\alpha$ - diphenyl-$\beta$ -picrylhydrazyl) method. The chemical compositions of leek seeds were moisture 4.4%, curde protein 25.7%, crude fat 16.6%, and crude ash 2.9%. Major amino acid compositions were proline 11 g, glutamic acid 4.9 g, arginine 2.1g, aspartic acid 1.6g, leucine 1.3g, valine 1.2 g, and methionine 1.1 g as per 100g. Mineral contents were K 215 ppm, Ca 142 ppm, Fe 124 ppm, and Mg 100 ppm. Major fatty acid compositions were linoleic acid 71.9%, oleic acid 12.7%, palmitic acid 8.6%, and stearic acid 1.4%. The changes of contents in polyphenolic compound from leek seeds caused by heat treatment were also listed in the following order; $20^{\circ}C$(364mg/100g), $40^{\circ}C$(462 mg/100g), and $60^{\circ}C$(551 mg/100g). Antioxidative activity as electron donating ability showed in the following order; 0.05% BHT(butylated hydroxytoluene)(45.6%)>0.05% water-extract(31.3%)>0.1% water extract(30.3%). On the basis of chemical analysis, the leek seedsshowed to have relatively high contents of nutrients as amino acids, minerals, fatty acids.

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Estimation of verticle fluxes of nitrogen compounds in tidal flats of the Keum river estuary (금강하구 갯벌내 질소화합물질의 연직적인 플럭스 평가)

  • Kim Do Hee;Yang Jae Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.2
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    • pp.3-10
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    • 2000
  • The main purpose of this study were to estimate the benthic fluxes of dissolved inorganic nitrogen (DIN) from the sediment and denitrification rates in tidal flats of the Keum river estuary. Sediment specimens were collected by a core sampler from three stations along the Keum river estuary in April, August and December, 1999. The sediments were composed of 1.18 %, 29.34 % and 69.49 % of gravel and sand, sand and silt, respectively. The mean ignition loss of the sediment was found 6.7 % and its Oxidation Reduction Potential (ORP) was measured -12 mV. The total hydrogen sulfides was determined about 0.26 mg/gㆍdry. The estimated outflux of ammonium was found 11.2 m mole N/m²ㆍday from the sediment, whereas -1.09 m mole N/m²ㆍday of influx was obtained for nitrate and nitrite through the incubation experiment of sediment cores. Total DIN flux was 10.2 m mole N/m²ㆍday outflux from the sediment. From the incubation experiments executed with the flux studies, mean denitrification rate was found 30.6 m mole N₂/m²ㆍday measured by the direct assay of N₂ production technique. On the basis that DIN flux and denitrification rate in sediment of tidal flat of the Keum river estuary are may be effects to control the algal biomass in the coastal environment, it seems inevitable to pay more attention to investigate the flux of DIN and denitrification rate in tidal flat of the Keum river estuary.

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Purification and Properties of Arylsulfatase of Serratia marcescens (Serratia marcens Arylsulfatase의 정제와 성질)

  • Yim, Moo-Hyun
    • Microbiology and Biotechnology Letters
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    • v.5 no.4
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    • pp.177-184
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    • 1977
  • Arylsulfatase catalyzes the release of SO$\sub$4//sup2/- from sulfate esters of simple phenols. Arylsolfatase occurs widely in animal tissues and in microorganisms including soil bacteria. Its widespread distribution suggests that it has a rather fundamental function and environmental meaning. It has been shown previously that arylsulfatase of Klebsiella was purified and characterized. A condition of arylsulfatase synthesis was tested with several strains of Serratia. Serratia marcescens could not utilize some sugars, such as xylose, rhamnose, glucosamine and arabinose hut glucose and mannitol as a sole carbon source. However, arylsulfatase synthesis was repressed by glucose but not by mannitol. The enzyme synthesis was repressed ob inorganic sulfate and methionine, and this repression was relieved by addition of tyramine. Arylsulfatase of S. marcescen was purified by fractionation with ammonium sulfate and followed by chromatographies on DEAE-Cellulose CM-Cellulose, and DEAE-Sephadex A-25. The molecular weight of arylsulfatase was determined to be 46,000 by SDS-Gel electrophoresis and 49,000 by Sephadex G-100 column chromatography. The enzyme showed some different properties with that of K. aerogenes. The activity was maximum at pH 6.8. The Km and Vmax values for p-nitrophenyl sulfate were 2.5${\times}$10$\^$-4/ M and 20 nmoles/min/mg protein, respectively. The enzyme showed high activities toward phenyl sulfate, ο-and p-nitro phenyl sulfates, and p-nitrocatechol sulfate. The inhibition of enzyme was strongly affected by hydroxylamine, inorganic fluoride, sulfide and phosphate, but by inorganic sulfate. Like Klebsiella arylsulfatase, tyramine, octopamine, and dopamine gave signifcant inhibitory effect.

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Chemical Characteristics of Water Soluble Components in Fine Particulate Matter at a Gwangju area (광주지역 PM2.5 입자 수용성 성분의 화학적 특성조사)

  • Park, Seung Shik;Cho, Sung Yong;Kim, Seung Jai
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.20-26
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    • 2010
  • Water soluble organic and inorganic species are important components in atmospheric aerosol particles and may act as cloud condensation nuclei to indirectly affect the climate. To characterize organic and elemental carbon(OC and EC), water-soluble organic carbon(WSOC) and inorganic ionic species contents, daily $PM_{2.5}$ measurements were made during the wintertime at an urban site of Gwangju. Average concentrations of WSOC, $NO_3^-$, $SO_4^{2-}$ and $NH_4^+$, which are major components in the water-soluble fraction in PM2.5, are 2.11, 5.73, 3.51 and $3.31{\mu}g/m^3$, respectively, representing 12.0(2.9~23.9%), 21.0(12.9~37.6%), 11.6(2.5~25.9%) and 11.7%(3.8~18.6%) of the $PM_{2.5}$, respectively. Abundance of water soluble organic compounds ranged from 5.4 to 35.9% of total water soluble organic and inorganic components with a mean of 17.6%. Even though the sampling was performed during the winter, the average contributions of secondary OC and WSOC, as deduced from primary OC/EC(or WSOC/EC) ratio, were relatively high, accounting for 17.9%(0~44.4%) of the total OC and 11.2%(0.0~51.4%) of the total WSOC, respectively. During the sampling period, low $SO_4^{2-}/(SO_4^{2-}+SO_2$) ratio of 0.14(0.03~0.32) and relative humidity condition in the winter time suggest an possibility of impact of long-range transport and/or aqueous transformation processes such as metal catalyzed oxidation of sulfur, in-cloud processes, etc.

Analysis of Components in the Different Parts of Ailanthus altissima (가죽나무(Ailanthus altissima)의 부위별 성분 분석)

  • Lee, Yang-Suk
    • Food Science and Preservation
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    • v.15 no.2
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    • pp.261-268
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    • 2008
  • This study was carried out to analyze the components of the roots, stems, and leaves of Ailanthus altissima to obtain basic data on the nutritional and functional materials developed a functional food with A. altissima. Among the general components, crude ash (9.20%) in the roots, crude protein (11.36%) in leaves, and carbohydrates (81.74%) in stems were higher than other parts. The content of soluble protein was the highest 9,839.52 mg% in leaves. Reducing sugar and free sugar in roots were 1,813.94 mg% 1,140.20 mg% and 1,670.98 mg% 1,190.42 mg% in leaves, respectively. The contents of free amino acid (2,018.58 mg%) in roots were higher than leaves (1,070.88 mg%) and stems (427.55 mg%). Especially arginine (1,446.63 mg%) and aspartic acid (252.82 mg%) in roots were the highest. Total content of amino acid derivatives were 780.70 mg% in leaves and 430.95 mg% in roots. Especially, taurine was 61.68 mg% in roots. In the results of mineral analysis, the contents of Ca, K and Mg which account for 83% to 98% of mineral contents, were high in all parts. The polyphenol compounds in leaves and water extract of leaves were 821.58 mg% and 8,040.35 mg%. And contents of flavonoids were 2,501.67 mg% in leaves and 13,592.20 mg% in ethanol extract of leaves, respectively.

Cooking Characteristics of Coated Rice with Water Homogenate of Citrus Fruits Peel (감귤과피 물 균질액으로 가공한 유색미의 취반 특성)

  • 서성수;김미향;노홍균;김순동
    • Journal of the East Asian Society of Dietary Life
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    • v.12 no.4
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    • pp.318-325
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    • 2002
  • Cooking characteristics of coated rice with water homogenate of citrus fruit peels (1% for rice) were investigated. The color of the coated rice both before and after cooking was dark yellow. The total content of carotenoids, hesperidin and naringin were 10.74, 2173.12 and 1468.40 mg% for citrus fruit peels, 0.46, 108.65 and 73.35 % for its water homogenate, 0.12, 21.73 and 14.62 mg% for coated rin, and 0.05, 8.67 and 5.87 mg% fur cooked coated rice, respectively. Citrus fruits peel contained 94.22 mg% of asparagine, 24.88 mg% of methionine, 19.64 mg% of alanine, and 15.37 mg% of ${\gamma}$-aminoisobutyric acid as the majority free amino acids, accounting for 70% of the total free amino acids present. Total free amino acid content of the cooked coated rice increased by 15% compared to those of cooked uncoated rice. The majority of minerals in the citrus fruit peels were K and Ca, accounting for 56% of total minerals present. The mineral content of cooked coated rice was generally higher than that of the cooked uncoated rice. The cooked coated rice showed comparable hardness, gumminess and brittleness, but higher cohesiveness and springiness than the cooked uncoated rice. There were no differences in sweet and bitter taste between the cooked uncoated and coated rice. However, the cooked coated rice showed higher sensory scores fur color acceptability, savory taste and overall acceptability than the cooked uncoated rice.

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Effect of Calcium on the Apple Varieties Resistance to Alternaria Leaf Spot and Mycelial Growth of Alternaria mali Roberts (Ca물질(物質)이 사과나무 반점낙엽병(斑點落葉病) 발생(發生) 및 병원균(病原菌)의 균사생육(菌絲生育)에 미치는 영향(影響))

  • Yoon, J.T.;Lee, J.T.
    • Korean journal of applied entomology
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    • v.26 no.4 s.73
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    • pp.239-244
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    • 1987
  • This studies was carried out to find the effect of inorganic matters of Apple Leaves on the occurrence of Alternaria leaf spot and calicium compounds on mycelial growth of Alternaria mali. Diseased leaf rate of Alternaria leaf spot of susceptible apple varieties was 84.8%, moderate resistant 8.1% and resistant 0.3% respectively and in No. of lesion per leaf, the tendency was same. CaO contents of apple leaves was contained much in the resistant varieties than susceptible one. It was estimated that calcium is one of factors on resistance to apple leaf spot by the results of relations among CaO contents and diseased leaf rate from July to August and No. of lesion per leaf was correlated significantly as r=-0.551, r=-0.585, -0.485 but in T-N, $P_2O_5,\;K_2O,\;MgO,\;Na_2O$, there was no difference among varieties. Then, growth of Alternaria mali was possible in the media of which pH ranged up to $11{\sim}13$, and calcium has effect of inhibition on growth of Alternaria mali.

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The Effect of Submergence on Phosphorus Adsorption Characteristics in Soils II. Phosphorus Adsorption and Fractions of Inorganic Phosphorus (담수처리(湛水處理)가 토양(土壤)의 인산(燐酸) 흡착(吸着) 특성(特性)에 미치는 영향(影響) II. 인산흡착(燐酸吸着)과 무기태(無機態) 인산(燐酸) 분획(分劃))

  • Kim, Chan-Sub;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.4
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    • pp.248-253
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    • 1991
  • This study examines the effect of submergence on transformations of inorganic phosphorus and the relation between fractions of inorganic phosphorus and adsorbed phosphorus in Gangseo (paddy soil), Yesan (non-cultivated soil), and Jungdong soil (upland soil). The soils were submerged with glucose sol'n at $28^{\circ}C$ for 17 days. After, the soils were incubated with phosphate solution at $25^{\circ}C$ for 24 hours. The seguential fractionation of inorganic phosphorus and of iron were conducted to investigate transformations of them. Results obtained are as follows; 1. By submergence, Bray I-P were decreased from 53mgP/kg to 48mgP/kg in Gangseo, from 3mgP/kg to 1mgP/kg in Yesan, and from 120mgP/kg to 56mgP/kg in Jungdong soil. 2. $NH_4F$ extractable P was dominant fraction of adsorbed P. It was transformed into NaOH extractable P by submergence in Jungdong soil. 3. Dithionite-citrate-bicarbonate extractable iron (crystalline Fe) was transformed to oxalate extractable iron (amorphous Fe) by submergence in Yesan soil.

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Current Researches on the Protection of Exterior Wood from Weathering (목재의 기상열화 방지에 관한 최근의 연구 동향)

  • Kim, Yeong-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.5
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    • pp.449-470
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    • 2018
  • A review of research trends on wood surface protection for exterior use obtained the following conclusions: It has been reported that inorganic compounds such as chrome and copper used as wood preservatives can protect wood from weathering. It has been shown that precoating with hydrophobic substances such as wax and oil, UV absorbers, and HALS (Hindered Amine Light Stabilizers) enhances weathering resistance on the surface of ACQ-treated wood. Opaque coatings of paint/stains and semitransparent stains on the surface of preservative treated wood can increase the synergistic effects on prevention of weathering deterioration. Also the need for repainting periodically for the protection of the preservative treated wood surface has also been suggested. ZnO or $TiO_2$ of fine particles, metal ions such as Co, Cr, Fe, Mn, Ni and Ti, and UV absorbers such as tris-resorcinol triazine derivatives, triazine and benzotriazole were introduced as additives for preventing UV in the transparent coating on wood. Several reports showed that chemical modification such as methylation, acetylation, or alkylations have made some increases the effects of preventing weathering with the increasing weight gain of chemical formulas. In heat-treated wood, there were various contradictory reports on the resistance of weathering, and there were some other reports emphasizing the necessity of painting with UV resistance, which leads to the necessity of more advanced studies.

Material Characteristics and Conservation Treatment for Floral Wall in Lee Sang-beom's House and Atelier (이상범 가옥 및 화실 내 꽃담의 재료학적 특성과 보존처리)

  • Kim, So-Jin;Han, Min-Su;Lee, Won-Dong;Han, Byoung-Il
    • Journal of Conservation Science
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    • v.27 no.3
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    • pp.313-322
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    • 2011
  • The floral wall of Lee Sang-beom's House and Atelier, which is No. 171 of the Registrated Cultural Heritage was conserved. In addition, materials characteristics and manufacturing technique have revealed through the scientific analysis. As a result of the analysis, samples were divided into three sections; the support layer that is made from block bricks, the paint layer and the cement mortar layer on the paint layer for the reinforcement of the construction. The higher layer lies, the finer grains it has. Furthermore, a little it was generated a small quantity of pores and calcium carbonates ($CaCO_3$) generated due to aeration of cement mortar. The patterns of letters, animals and plants pattern were expressed in the paint layer by relief and openwork. The results of qualitative analysis of the pigments of the paint layer were detected components of carbon black (C), Fe oxide ($Fe_2O_3$) and oyster shell white ($CaCO_3$, or quicklime). On the other hands, as the conservation of the floral wall, stainless frames were set up for the structural stability, the cement mortar were removed from the surface and the partly damaged and cracked areas were filled with KSE Filler A, B.