• Title/Summary/Keyword: 무기질소 공급

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Fluoride and nitrate removal by electro-coagulation for decentralized water treatment plants (전기응집을 이용한 소규모 수도시설의 불소 및 질산성질소 이온의 제거)

  • Han, Song-Hee;Chang, In-Soung;Back, Soun-Ok;Joung, Seun-Young;Lee, Cheol-Ku
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.115-116
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    • 2010
  • 광역상수도의 경우 수자원공사 및 지방상수도 사업자들에 의해 전문적으로 수질을 관리하고 음용수를 보급하고 있으나 소규모 수도시설의 경우 전문능력을 갖춘 관리자가 아닌 마을의 대표자가 맡아 관리함에 따라 안정성 및 유지관리의 어려움이 자주 제기되고 있다.[1] 또한 소규모 수도시설의 경우 취수원으로 지하수나 계곡수를 이용하여 여과나 염소소독을 거쳐 음용수로 이용함에 따라 중금속 및 무기이온 등 각종 오염물질이 효과적으로 제거되지 않아 이를 사용하는 주민들이 불편함을 겪고 있는 실정이다. 환경부의 법정 수질 검사에 따르면 부적합 판정을 받은 곳의 대부분은 마을상수도와 소규모 급수시설인 것으로 나타났으며 초과 항목으로는 무기이온 중 특히 불소와 질산성질소 인 것으로 나타났다.[2] 이러한 문제점을 해결하고자 기존의 고도 정수처리 시설인 막여과, 오존처리, 활성탄 흡착 공정 등을[3-5] 적용하고 있으나 소규모 수도시설에 적용하기에는 유지관리, 규모, 경제적 측면 등 여러 한계점을 지니고 있다. 따라서 본 연구에서는 이러한 문제점을 해결하기 위한 방안으로 전기응집기술을 이용하여 음용수 수질기준을 초과하는 무기이온 중 불소와 질산성 질소를 제거하고자 하였다. 전기응집기술은 제거효율이 높고, 운전이 용이하며 부가적인 화학약품의 첨가가 불필요하다.[6,7] 또한 기존의 고도정수처리 기술에 비해 전기응집 공정은 처리효율과 경제적인 측면 모두를 만족시키고 있어 소규모 수도시설의 불소와 질산성질소를 효과적으로 제거할 수 있는 방안으로 판단된다. 본 연구에 사용된 실험장치는 직류전원공급장치 (DC power supply), 반응조, 전극으로 구성되어 있다. 직류전원공급장치는 최대전압 30 Volt, 최대 전류 30 Amper 까지 조절 가능하였으며 반응조의 크기는 14.5cm(w) ${\times}$ 9cm(L) ${\times}$ 22cm(H) 이고 실용적 1.5L이다. 반응조의 상부에는 전극이 고정될 수 있도록 0.5cm 간격의 홈을 만들어 제작 하였다. 전극은 가용성 전극인 알루미늄 (Al), 스테인레스스틸(SUS304)를 이용하였다. 이를 통해 전류밀도, 전극간격 등의 변수를 두어 최적의 전기응집 운전 조건을 파악하였으며 이는 소규모 수도시설의 수질개선 향상에 도움이 될 수 있을 것으로 판단된다.

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Limiting Nutrient on Phytoplankton Growth in Gwangyang Bay (광양만에서 식물플랑크톤증식의 제한영양염)

  • Lee, Jae-Seong;Jung, Rae-Hong;Kim, Soung-Soo;Go, Woo-Jin;Kim, Kui-Young;Park, Jong-Soo;Lee, Young-Sik
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.6 no.3
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    • pp.201-210
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    • 2001
  • Salinity, DIN, DIP, DIN/DIP and indigenous algal assay were determined to estimate the limiting nutrient for phytoplankton growth in Gwangyang Bay, South Sea of Korea. Seawater samples were collected at surface and bot-tom water in 4 November 1999 (dry season) and 2 September 2000 (after heavy rain). In 4 November 1999, the salinity, DIN, DIP and DIN/DIP were 29.92 psu, 13.59 ${\mu}M$, 3.41 ${\mu}M$ and 4.14 respectively. In 2 September 2000, These values were 24.62 psu, 27.77 ${\mu}M$, 2.82 ${\mu}M$ and 9.79 respectively. The DIN and DIP concentrations in this study were higher than Deukryang, Yeoja and Gamak Bay, South Sea of Korea. Especially, DIP concentration was 8 times high compared to Deutryang, Yeoja and Gamak Bay. The main sources of nitrogen seem to be freshwater runoff from Somjin River and industrial wastewater. But, the main sources of phosphorus seem to be industrial wastewater around Gwangyang Bay. The limiting nutrient was nitrogen at all station in 4 November 1999. The limiting nutrient was also nitrogen in 2 September 2000 in spite of heavy rain observed because of relatively much volume of phosphorus sup-plied from point sources than nitrogen. In case of below 20 psu in salinity by heavy rain, the limiting nutrient willbe shift from nitrogen to phosphorus at some area of Somjin River estuary. But the limiting nutrient will be never shift to phosphorus throughout Gwangyang Bay, eastern coast of Yeoja and Dolsan because of much volume of phosphorus runoff from point source in coastal area of Gwangyang Bay.

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A Fundamental Study on the Effect of Ocean Fertilization by Deep Sea Water (해양심층수에 의한 해역 비옥화 효과에 관한 기초 연구)

  • Shiokari, Megumi;Tabeta, Shigeru;Kato, Takayoshi
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.3
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    • pp.198-207
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    • 2012
  • In this study, we investigated the effect of ocean fertilization by deep sea water, using an ecosystem model which contains not only phytoplankton but also zooplankton. The model is based on NEMURO which consists of eleven compartments - two species of phytoplankton, three species of zooplankton, $NO_3$, $NH_4$, $Si(OH)_4$, particulate organic nitrogen, dissolved organic nitrogen and particulate silicon. We introduced nitrogen cell quota in the both species of phytoplankton, and silicon cell quota in the large phytoplankton in addition to the eleven compartments of NEMURO. We made the experiment at Izu Oshima Island in order to investigate the effect of ocean fertilization. In this experiment, we could not find clear differences between the cases with and without deep sea water. We investigated the causes of the experiment results by the model simulations. One of the causes was high concentrations of nutrients in surface seawater used in the experiment. Another was that the increase of total concentration of inorganic nitrogen does not necessarily accelerate the photosynthetic rate because inorganic nitrogen uptake rate is related to the ratio of $NO_3$ to $NH_4$. Because the model can represent the results of the experiment, we investigated the effect of ocean fertilization by deep sea water using this model. We found that the effect of ocean fertilization hardly appeared when the interval of the addition of deep sea water was too short, or the amount of deep sea water was too much. It is supposed that if the addition of deep sea water is too frequent or too much, the dilution of plankton's concentrations will exceed the effect of promoting phytoplankton's photosynthesis.

Impacts of Cover Crops on Early Growth, Nitrogen Uptake and Carbohydrate Composition of Pepper Plants (고추의 초기생장, 질소흡수 및 탄수화물 합성에 대한 녹비작물 시용효과)

  • Sung, Jwa-Kyung;Lee, Sang-Min;Lee, Yong-Hwan;Choi, Du-Hoi;Kim, Tae-Wan;Song, Beom-Heon
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.1
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    • pp.44-49
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    • 2008
  • Sufficient inorganic nitrogen supply for crop growth is crucial for economically sustainable organic farming. The effects of an application of cover crop biomass on crop growth, nitrogen utilization and carbohydrate composition were investigated during early stage. Short-term changes in soil nitrogen after incorporating fresh hairy vetch and rye shoots were measured. The inorganic nitrogen from cover crops reached the peak at 15 ($NH_4-N$) and 24 ($NO_3-N$) days after incorporation, and then decreased rapidly. The highest concentration of soil nitrate showed at 27 days of incorporation in hairy vetch and at 18 days in rye, and three fold differences exhibited between two treatments. Crop growth under hairy vetch or rye incorporation significantly differed. At 20 DAT, dry matter production in NPK and hairy vetch was about two fold greater than that in rye. Difference in decomposing rates of hairy vetch and rye had also influence on nitrogen status in leaves and roots of pepper plants. Total nitrogen was greater in NPK and hairy vetch than in rye until 20 DAT, whereas inorganic nitrogen (nitrate and nitrite) concentration was higher in rye. Temporal changes in soluble sugars and starch in pepper plants among treatments were similar, although difference in the amount existed. It was suggested that hairy vetch as an alternative nitrogen source promoted crop growth and mineral utilization during early growth stage, whereas an obvious effect in rye was not found.

Study on Nutrient Balance in Paddy Field of Fluvio-Marine Deposit (하해혼성(河海混成) 논토양(土壤)의 양분수지(養分收支)에 관한 연구)

  • Yoo, Chul-Hyun;Yang, Chang-Hyu;Kang, Seung-Weon;Han, Sang-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.5
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    • pp.253-263
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    • 2002
  • To test for the effect of applied fertilizer and nutrients on uptake and transport for paddy rice, two paddy field trials were conducted with Dongjinbyeo in degenerated salt paddy field of Jeonbuk series from 1999 to 2000. After experiment, soil acidity, content of organic matter phosphate, silicate, potassium, calcium, and total nitrogen was increased by application of fresh cattle manure(FCM). Content of Nitrogen in soil layer leached inorganic nitrogen $NO_3$ was higher that that of $NH_4$ and was high in treatment of FCM. Content of $PO_4$ was higher in FCM than other treatments. But content of potassium was in high control. During the growth of rice plant, the amount of water consumption was 477mm. The amount of supplied nitrogen was high in treatment of no nitrogen(NN), 20% reduced application of LCU(LCU-20%), and no fertilizer. In case of phosphate, the supplied amount was more than the consumed amount with the exception of treatment "no phosphate(NP) and no fertilizer(NF)". In case of potassium, the consumed amount was more than the supplied amount in all treatments. The amount of applied nitrogen in the nutrient infiltrated water was high in treatment soil test(ST), C+FCM+Si(Silicate) and the ratio of recovered nitrogen was high in 20% reduced application of LCU. The amount of applied phosphate in the nutrient infiltrated water was high in FCM and that of applied potassium was high in 20% reduced application of LCU. Nitrogen use efficiency of paddy rice was high in 20% reduced application of LCU and use efficiency of phosphate and potassium was high in C+Si(Silicate). Grain yield of rice was high in order of 20% reduced application of LCU>C+Si=C+FCM+Si>C+FCM.

Nutrient Uptake and Leaching Under Different Fertilizer Treatment for Corn and Potato Growth in Volcanic Ash Soil (화산회토에서 옥수수와 감자의 시비처리에 따른 양분 흡수 및 용탈)

  • 강봉균;박양문;강영길
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.46 no.3
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    • pp.253-259
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    • 2001
  • The purpose of this study was loused on understanding of uptake of nutrients by plants, the behaviors of nutrients in soil and the possibility of leaching loss when N fertilizer (urea) and mature compost were applied. Lysimeters (volume 0.15㎥, diameter 62cm, height 62.8cm) were installed for collecting leachate in the Jeju volcanic ash soils. Lysimeter study consisted of thirteen treatments: fellow, fellow with weeding, cropping without fertilizer and compost, three N fertilizer soil surface applications (16, 32, and 64 kg/10a), three N fertilizer and compost soil surface applications (16+800i 32+1600, and 64+3200 kg/10a), two water dissolved N fertilizer applications(16 and 32 kg/10a), and low and high plant densities. The growth of corn (preceding crop) and potatoes (succeeding crop) and leaching loss were determined during the experimental period. The amount of leachate from lysimeter was remarkably greater at bare conditions than at cropping conditions for corn and potatoes. The N content of plants (corn and potatoes) tended to increase as fertilizer rate increased. Fertilization of urea dissolved in water to soil was more efficient than surface fertilization for the growth, yield, and the N uptake N of corn and potatoes. There were no differences in dry matter yield of plants between medium and high N rates, but N, Ca, K and Mg concentrations of plants were higher at higher N rates. There were significant correlations between N uptake and each of Ca, K and Mg uptakes in corn and potatoes. Total N uptake by plants increased with increased N fertilizer and compost applications. Plane absorbed 54.9% of applied N at low N rate and 31.0 to 34.0% at high N rates. The proportion of N leaching losses was lower at low N rate and high plant density.

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Relation of Organic Matter Content and Nitrogen Mineralization of Soils Collected from Pepper Cultivated Land (고추 재배 밭에서 채취한 토양의 유기물 함량과 질소 무기화 량의 관계)

  • Lee, Yejin;Lee, Seulbi;Kim, Yangmin;Song, Yosung;Lee, Deogbae
    • Korean Journal of Environmental Agriculture
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    • v.38 no.3
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    • pp.119-123
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    • 2019
  • BACKGROUND: Estimation of soil nitrogen supply is essential to manage nitrogen fertilization in arable land. In Korea, nitrogen fertilization is recommended based on the soil organic matter content because it is difficult to assess nitrogen (N) mineralization of upland soils directly. In this study, the relationship between soil organic matter (SOM) content and N mineralization was investigated to explore the limitation of using SOM in predicting soil N mineralization. METHODS AND RESULTS: Soil samples from the 0 to 10 cm depth were collected from 18 individual pepper cultivated fields in Tae-an and Chung-yang provinces before fertilization. N mineralization in the soils was quantified using incubation for 70 days at $30^{\circ}C$. The mineralizable soil N (MSN) was positively correlated with SOM, and the relation equation between MSN and SOM was '$MSN(kg\;10a^{-1})=0.2933{\ast}SOM(g\;kg^{-1})+0.0897$ ($r^2=0.6224$, p<0.001)'. However, the differences of N mineralization among the soils with the similar concentrations of soil organic matter were about 3 to 4.6 times, suggesting that the other soil factors such as total N concentration or EC should affect N mineralization. CONCLUSION: We concluded that SOM alone could not reflect the capacity of soil to supply N that is used for recommendation of N fertilization rate. Therefore, other soil properties should be considered to improve N fertilization management in arable land for sustainable agriculture.

Growth and Soil Chemical Property of Small Apple Trees as Affected by Organic Fertilizers and Mulch Sources (비료원과 멀칭재료에 따른 사과 유묘의 생장 및 토양이화학성 변화)

  • Choi, Hyun-Sug;Rom, Curt;Lee, Youn;Cho, Jung-Lai;Jung, Seok-Kyu;Jee, Hyeong-Jin
    • Korean Journal of Environmental Agriculture
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    • v.30 no.1
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    • pp.9-15
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    • 2011
  • BACKGROUND: This study was conducted to evaluate the effects of the fertilizer sources and ground cover mulches on nutrient release, growth, and photosynthesis in small one-year-old apple (Malus ${\times}$ domestica Borkh.) trees in controlled conditions. METHODS AND RESULTS: Treatments included no fertilizer (NF), commercial organic fertilizer (CF), and poultry litter (PL) for fertilizer treatments, and wood chips (WC), shredded paper (SP), green compost (GC), and grass clippings (GR) for cover mulch treatments. All treatments were applied proportionally based on the volume ratio equivalent to the soil. CF, PL, and GR treatments that had optimum carbon (C) and nitrogen (N) ratios (less than 30:1) for N mineralization through the microbes released the greatest $NH_4^+$ concentrations in the pot media at 90 days after the treatments, but GC mulch with the optimum C:N ratio did not. CF-, PL- and GR-treated plants had the largest leaf area, thickest stem diameter, longest shoot extension, and greater dry matter production. CONCLUSION(s): CF and PL showed an suitable organic nutrient source for improving plant growth in an orchard. Interestingly, GR also could be a nutrient source for tree growth, if vegetation competition is controlled by maintaining vegetation height and recycling enough grass clippings to the soil in an orchard.

Spatio-Temporal Distribution of Nutrients in the Surface Waters of Deukryang Bay 1. Seasonal Variation of Nutrients and Limiting Factors for Primary Production (득량만 표층수중 영양염류의 시공간적 분포특성 -1. 영양염류의 계절변화와 기초생산 제한인자-)

  • YANG Han-Soeb;KIM Soung-Soo;KIM Guebuem
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.4
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    • pp.475-488
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    • 1995
  • In order to see the seasonal variation of nutrients and the limiting factors to the primary production in Deukryang Bay, both dissolved inorganic nutrients and salinity were measured in the surface waters during the periods from July 1992 to March 1993. The mean value of salinity was the lowest in ?all and the highest in early spring. Dissolved inorganic nitrogen (DIN) was the highest in winter and the lowest in summer. However, both phosphate and silicate were the highest in summer and the lowest in fall. Salinity was generally higher in the outer region than in the inner region of the bay.DIN content was nearly depleted (less than $2{\mu}M$) in summer. From fall to spring, DIN content was nearly depleted in the inner region and relatively high in the outer region of the Day. Phosphate was the highest in summer showing an opposite distribution pattern to salinity, and it was nearly depleted (less than $0.1{\mu}M$) in fall and winter. In spring, however, phosphate content was slightly high in the outer region. Silicate content showed an opposite distribution pattern to salinity in summer. in other seasons, However, the distribution pattern of silicate was similar to the salinity. DIN seemed to be a limiting factor for the primary production at all area of the bay in summer and at the inner region in other season. However, phosphate seemed to be a limiting factor at all area of the bay in fall and winter and at the inner region in spring. Silicate may limit the production of diatoms at the inner region of the bay in winter and spying. Both phosphate and silicate showed a good inverse relationship with salinity in summer, which indicates inputs of these nutrients from the freshwater runoff. In the other seasons, both nitrate and silicate showed a positive linear relationship with salinity in the outer region of the bay, suggesting that these two nutrients were mainly supplied by the inflow of the offshore costal water which had high nitrate content associated with vertical mixing.

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