• Title/Summary/Keyword: 모의핵연료

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Fly ash를 이용한 사용후핵연료의 유리화 가능성 및 내침출성 분석

  • 전관식;신진명;김종호
    • Proceedings of the Korean Nuclear Society Conference
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    • 1995.05b
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    • pp.781-786
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    • 1995
  • 석탄화력발전소 산업부산물인 Fly ash를 이용한 고준위방사성폐기물의 붕규산 유리고화 가능성을 분석하였다. Fly ash SiO$_2$, NaNO$_3$, B$_2$O$_3$에 DUPIC 핵연료 제조공정으로부터 발생되는 모의 scrap waste를 20 wt% 혼합하여, l15$0^{\circ}C$ 에서 3시간 용융시켜 붕규산유리화시켰다. 또한 붕규산유리고화체의 침출성을 평가하기 위하여 2일동안의 soxhlet 침출실험결과 양호한 내침출성을 보였다. 또한 고체폐기물의 안정화물질로 fly ash를 사용할 경우 fly ash 함량을 57%까지 첨가하여도 붕규산유리고화체의 제조가 가능함을 확인하였으며, fly ash의 첨가로 인한 유리화원료 재료비를 30% 까지는 절감시킬 수 있을 것으로 예상된다.

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Fabrication of Nitride Fuel Pellets by Using Simulated Spent Nuclear Fuel (모의 사용후 핵연료를 이용한 질화물 핵연료 소결체 제조)

  • Ryu, Ho-Jin;Lee, Jae-Won;Lee, Young-Woo;Lee, Jung-Won;Park, Geun-Il
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.87-94
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    • 2008
  • In order to investigate a nitriding process of spent oxide fuel and the subsequent change in thermal properties after nitriding, simulated spent fuel powder was converted into a nitride pellet with simulated fission product elements through a carbothermic reduction process. Nitriding rate of simulated spent fuel was decreased with increasing of the amount of fission products. Contents of Ba and Sr in simulated spent fuel were decreased after the carbothermic reduction process. The thermal conductivity of the nitride pellet was decreased by an addition of fission product element but was higher than that of the oxide fuel containing fission product elements.

Data Analysis of International Joint Road and Sea Transportation Tests Under Normal Conditions of Transport (국제공동 육해상 정상운반시험의 데이터 분석)

  • Lim, JaeHoon;Cho, Sang Soon;Choi, Woo-seok
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.2_spc
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    • pp.275-289
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    • 2020
  • In 2017, multimodal transportation tests for evaluating road, sea, and rail transport were performed by research institutes in the US, Spain, and the Republic of Korea. In this study, acceleration and strain data determined through road and sea tests were analyzed. It was investigated whether the load generated for each transport mode was amplified or attenuated according to the load transfer path. From the results, it was confirmed that the load transfer characteristics differed according to the transportation mode and loading path. The effects of strain determined through each test on the structural integrity of the spent nuclear fuel were also investigated. It was found that the magnitude of the measured strain had a negligible effect on the structural integrity of the spent nuclear fuel, considering its fatigue strength. The results for the acceleration and strain data analyses obtained in this study will be useful for scheduled domestic transportation tests under normal transport conditions.

Separation and Purification for the Determination of Zirconium and Its Isotopes in PWR Spent Nuclear Fuels (PWR 사용후핵연료 중 Zr 및 Zr 동위원소 정량을 위한 분리 및 정제)

  • Kim, Jung Suk;Jeon, Young Shin;Park, Yong Joon;Lee, Chang Heon;Kim, Won Ho
    • Analytical Science and Technology
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    • v.11 no.6
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    • pp.421-428
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    • 1998
  • A method has been studied to separate Zr from various fission products in PWR spent nuclear fuels. A solution containing metal ions in place of radioactive fission products was prepared. The Zr was separated with 5 M HCl followed by eluting metal ions such as Ce, Nd, Cs, Rb, Ba, Sr, Ru, Rh, Pd, Ag and Cd with 12 M HCl on Dowex $1{\times}8$, anion exchange resin. The recovery of Zr was more than 95%. The purification of Zr was carried out on anion exchange resin, Dowex $1{\times}8$, in 5 M HCl in order to remove Mo causing isobaric effect during mass spectrometry. The method was applied to separate Zr from a spent PWR fuel. From mass spectrometric measurement, the purified Zr portion was not showed the isobars from other elements such as Mo and Sr.

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A Study on the Separation of Neodymium from the Simulated Solution of $U_3Si/Al$ Spent Nuclear Fuel (모의 사용후분산핵연료($U_3Si/Al$) 용해용액으로부터 네오디뮴 분리에 관한 연구)

  • Choi, Kwang Soon;Kim, Jung Suk;Han, Sun Ho;Park, Soon Dal;Park, Yeong Jae;Joe, Kih Soo;Kim, Won Ho
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.584-591
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    • 2000
  • The separation of Nd from the simulated $U_3Si/Al$ spent fuel solution with sequential two-step anion exchange separation has been studied. To prepare the simulated $U_3Si/Al$ spent nuclear fuel, unirradiated $U_3Si/Al$ whose composition consists of small $U_3Si$ particle dispersed in an Al matrix with Al cladding was dissolved with a mixture of 4 M HCl and 10 M $HNO_3$ and 8 or 15 fission product elements were added to the dissolved solution. The trace amount of silica in the solutions was removed by evaporating to dryness with HF and the U was adsorbed on the first anion exchange resin. Neodymium can be purely isolated from the fission product elements with a methanol-nitric acid eluent using the second anion exchange resin. A large excess of Al didn't influence on the elution velocity of Nd, but reduced the eluted contents of Nd, Al, Eu, Gd, Sm and Sr, A large amount of Al was removed first from the column with 3 mL of loading solution (0.8 M $HNO_3$/99.8% MeOH) before Nd elution by the eluent [0.04 M $HNO_3$-99.8% MeOH(1:9)]. The recovery of Nd was more than 94%, regardless of Al contents. Taking the 9 to 13 mL fraction of eluate was effective to purely isolate Nd.

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대용량 피동형원자로의 안전계통 성능 분석

  • 김성오;황영동;정병렬;최철진;정법동;장문희
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.423-428
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    • 1996
  • 피동형원자로 AP600을 참조발전소로하여 설정된 1000MWe급 대용량 피동형원자로의 계통개념에 대한 안전계통 성능 평가 및 코드의 적용성 평가를 목적으로 RELAP5/MOD3코드를 사용하여 대형냉각재상실사고를 모의 해석하였다. 피동형 안전계통으로 축압기, CMT IRWST를 모델하였으며 가압기에 연결된 1단계부터 3단계까지의 자동감압밸브계통을 모델링 하고 4단계 자동감압밸브계통은 각 루프의 고온관에 연결되어 있는 것으로 모델링 하였다. 피동형 안전계통의 모델이 향상된 RELAP5/MOD3.2와 그 이전의 코드인 RELAP5/MOD3.1의 냉각재상실사고 모의계산결과 원자로내의 압력변화, 노심냉각수 주입유량 및 핵연료 피복재 온도 거동이 거의 유사하게 나타났으며 1000MWe급 대용량 피동형원자로의 안전계통은 냉각재 상실사고시 충분한 노심냉각능력을 가지는 것으로 분석되었다.

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Experimental Investigation of the CHF for the Narrow Rectangular Channel in the Downward Flow (좁은 사각 유로 내 하향류 유동 조건에서 임계열유속 실험 연구)

  • Kim, Hui Yung;Yun, Byong Jo;Bak, Jin Yeong;Park, Jong Hark;Chae, Heetaek;Park, Cheol
    • Journal of Energy Engineering
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    • v.25 no.1
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    • pp.153-162
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    • 2016
  • Experimental investigation was carried out on the CHF(Critical Heat Flux) under downward flow condition in narrow rectangular channels simulating subchannel of plate-type-fuel for JRTR(Jordan Research and Training Reactor). The experiments covers the license requirement of the research reactor. Two test sections used in this study simulate full scale subchannels for fission moly uranium target and plate-type-fuel, respectively. From the experimental results, the parameters affecting on the CHF are investigated. By using experimental data, the existing CHF prediction models were evaluated. Finally, the applicability of correlations were analysed to predict CHF in the narrow rectangular channel under the downward flow condition.

Oxidation Behavior of Simudated Metallic U-Nb Alloys in Air (모의 금속전환체 U-Nb 합금의 공기중 산화거동)

  • Lee Eun-Pyo;Ju June-Sik;You Gil-Sung;Cho il-Je;Kook Dong-Hak;Kim Ho-Dong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.4
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    • pp.239-244
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    • 2004
  • In order to enhance an oxidation resistance of the pure uranium metal under air condition, a small quantity of niobium(Nb) which is known to mitigate metal oxidation is added into uranium metal as an alloying element. A simulated metallic uranium alloy, U-Nb has been fabricated and then oxidized in the range of 200 to $300^{\circ}C$ under the environment of the pure oxygen gas. The oxidized quantity in terms of the weight gain(wt%) has been measured with the help of a thermogravimetric analyzer. The results show that the oxidation resistance of the U-Nb alloy is considerably enhanced in comparison with that of the pure uranium metal. It is revealed that the oxidation resistance of the former with the niobium content of 1, 2, 3, and 4 wt% is : 1) 1.61, 7.78, 11.76 and 20.14 times at the temperature of $200^{\circ}C$ ; 2) 1.45, 5.98, 10.08 and 11.15 times at $250^{\circ}C$ ; and 3) 1.33, 4.82, 8.87 and 6.84 times at $300^{\circ}C$ higher than that of the latter, respectively. Besides, it is shown that the activation energy attributable to the oxidation is 17.13~21.92 kcal/mol.

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The Grid Strap Vibration Characteristics of the 5×5 Nuclear Fuel Mock-up (5×5 핵연료 모의 집합체의 지지격자 스트랩 진동특성)

  • Kim, Kyoung-Hong;Park, Nam-Gyu;Kim, Kyoung-Ju;Suh, Jung-Min
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.7
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    • pp.619-625
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    • 2012
  • Since the fuel is always exposed to turbulent flow, the grid strap shows flow induced vibration characteristics that impact on the nuclear fuel soundness. The dynamic behavior of grids in nuclear fuels is quite complex, since two pairs of spring and dimple support are contacted with rods by friction in the limited space. This paper focuses on investigation of the grid strap(test fuel strap, TFS) vibration in one cell. TFS consists of a single spring and double dimples. To identify the grid strap vibration, modal analysis of the strap is performed using finite element method(FEM). Modal testing on a $5{\times}5$ grid structure without rods is performed. The modal testing results are compared to analytic results. In addition, random test considering rod effect is performed about a $5{\times}5$ grid with rods under real contact condition in the air. Finally, the strap vibration of a $5{\times}5$ fuel bundle in investigation of flow induced vibration(INFINIT) facility is measured in real fluid velocity condition without heating. It is shown that modal frequencies from the test are almost equal to those peak frequencies in the INFINIT test.