• Analytical Science and Technology
• /
• v.21 no.5
• /
• pp.383-391
• /
• 2008

International Agency for Research on Cancer (IARC) has classified it as a possible carcinogen and World Health Organization (WHO) has suggested 50 ng/mL as a guideline value for 1,4-dioxane. Considering the toxicity of 1,4-dioxane and ingestion rate of drinking water, the monitoring of 1,4-dioxane in drinking water in Nakdong river is very important. We analyzed 1,4-dioxane four times per year for the 12 samples of treated water and 4 samples of raw water in Nakdong river in Korea from 2000 to 2007 and surveyed the trend of concentrations of 1,4-dioxane. As a results of analysis, 1,4-dioxane was detected from 0.24 to 240.2 ng/mL in treated water and from 0.39 to 81.9 ng/mL in raw water from 2000 to 2007. The average concentrations are 22.68 ng/mL and 19.15 ng/mL in treated water and raw water, respectively. The detected concentrations was decreased but frequency of detection was not changed since establishment of regulation in 2004. Results of comparison of 95 percentile excessive cancer risk of 1,4-dioxane in treated and raw water were each $6.63{\times}10^{-6}$, $3.17{\times}10^{-6}$ before 2004 and $2.10{\times}10^{-6}$, $1.22{\times}10^{-6}$ after 2004. Also, comparing the detected concentration and frequency for each season, these were more detected the concentration and frequency for 1,4-dioxane in treated and raw water from winter to spring.

• Journal of Korean Society of Environmental Engineers
• /
• v.36 no.8
• /
• pp.534-541
• /
• 2014

This study investigated a method to determine an efficient operating condition for the $UV/H_2O_2$ process. The OH radical scavenging factor is the most important factor to predict the removal efficiency of the target compound and determine the operating condition of the $UV/H_2O_2$ process. To rapidly and simply measure the scavenging factor, Rhodamine B (RhB) was selected as a probe compound. Its reliability was verified by comparing it with a typical probe compound (para-chlorobenzoic acid, pCBA); the difference between RhB and pCBA was only 1.1%. In a prediction test for the removal of Ibuprofen, the RhB method also shows a high reliability with an error rate of about 5% between the experimental result and the model prediction using the measured scavenging factor. In the monitoring result, the scavenging factor in the influent water of the $UV/H_2O_2$ pilot plant was changed up to 200% for about 8 months, suggesting that the required UV dose could be increased about 1.7 times to achieve 90% caffeine removal. These results show the importance of the scavenging factor measurement in the $UV/H_2O_2$ process, and the operating condition could simply be determined from the scavenging factor, absorbance, and information pertaining to the target compound.

• Journal of Soil and Groundwater Environment
• /
• v.12 no.3
• /
• pp.75-80
• /
• 2007

This study evaluated groundwater quality around an uncontrolled landfill in W sity, Korea, which was monitored for about two years (2005-2006). Parameters of concern include redox-sensitive indicators such as pH, DO, EC, ORP, DOC (dissolved organic carbon), NH3, NO3 and SO4. About 10 years have elapsed after closing dumping of municipal wastes in the landfill. Leachates showed widely varying concentrations in COD(136${\sim}$263 mg/L), T-N(121${\sim}$186 mg/L), and NH3-N(14${\sim}$369 mg/L). Groundwater at the immediate downgradient of the landfill showed weakly acidic pH condition but very high levels of EC (3,000-4,000 ${\mu}S/cm$), which indicated that the groundwater was largely affected by the landfill leachate. Cl, a conservative ion, showed over 200 mg/L at the landfill border, but a gradually decreasing level with distance from the landfill, representing dispersion and dilution (natural attenuation) due to mixing with surrounding groundwater and replenished rainwater. Redox potential showed negative value at the landfill border but it increased up to 350 mV at downgradient wells, which indicated conversion of redox condition from reducing oxic ones. Ammonia, was largely enriched at most of the monitoring wells and its level greatly exceeded drinking water standard. In summary, all the parameters evidenced occurrence of natural attenuation with distance and with time but further monitoring is still required.

• The Journal of Engineering Geology
• /
• v.23 no.1
• /
• pp.37-46
• /
• 2013

Leakage of leachate from animal carcass disposal is a significant issue because disease can easily spread to humans and other livestock. In this study, we analyzed the physicochemical properties of leachate and tested for the presence of aerobic bacteria in leachate using molecular biology methods, for 16 animal carcass disposals in the first stage (after burial for 5 months). Leachate physicochemical analysis revealed higher total coliforms, TOC, $NH^{4+}$, and $NO^{3-}$ concentrations compared with previously published data. In most leachate samples, the concentrations of $NH^{4+}$ and $NO^{3-}$ exceeded the Korean guideline values for drinking water. In 16S rRNA sequence analysis of the distribution of leachate under aerobic conditions, Bacillus pumilus, Lysinibacillus sphaericus, and B. sphaericus were observed with high frequency, whereas no food-poisoning-related bacteria such as B. cereus or Salmonella were detected. The present findings improve our knowledge of the transport of leachate from animal carcass disposal sites through geologic media, and are useful in risk analysis and for subsequent studies.

• Korean Journal of Mineralogy and Petrology
• /
• v.33 no.3
• /
• pp.233-242
• /
• 2020

As studies and developments of nano-material increase, the release of the nano-sized material to water environment increase. Especially, silver nanoparticles have been found as dissolved and particulate state since nano-silver particle have been intensively used in industrial and our living environment due to the anti-bacterial effect of the nano-particles. The silver nano-particles and silver ion gives adverse effect on ecology and US-EPA set a secondary drinking water standards as 0.1 mg/L. Current study focused on the analysis of silver in groundwater, small scale water supply systems in Gyeongbook area. The results have been compared with the secondary drinking water standards and discussed at the point of characteristics of the local area and purpose of use of the water sample. Among the total of 298 samples, 2 samples exceed the secondary drinking water standards of EPA, 0.64% rate. Community drinking water and simplified water service showed relatively high detection rate and groundwater gave relatively higher concentration of silver indicating anthropogenic source and natural source could contribute simultaneously on groundwater.

• Journal of the Korean Society of Groundwater Environment
• /
• v.4 no.1
• /
• pp.1-4
• /
• 1997

This study was carried out to find out the source of nitrate-nitrogen (NO$_3$-N) contamination in the groundwater in Cheju Island. Among the sites which have exceeded or may exceed the criterion level (10 mg/L) of NO$_3$-N in drinking water, seven sampling sites including two reference sites were chosen. The former regions are mainly agricultural ones (A-1 to A-6) and residential (R). The latter regions are forest (F-1 and F-2). The predicted major source and its contribution to NO$_3$-N concentration at each site, using $\delta$$\^$15/N and NO$_3$-N concentration, were as follow; Those at A-1, R and F-1 was 61.1%, 50.0% and 20.0% to manure or domestic sewage, 27.8%, 45.7% and 40.0% to chemical fertilizers and 11.1%, 4.3% and 40.0% to natural soil, respectively. Those at A-2 to A-6 were 37.8%, 25.0%, 40.9%, 26.2% and 35.7% to manure or domestic sewage, 59.6%, 71.7%, 53.0%, 71.5% and 60.2% to chemical fertilizers and 2.6%, 3.3%, 6.1%, 2.3% and 4.1% to natural soil, respectively.

• Journal of the Korean Chemical Society
• /
• v.44 no.3
• /
• pp.220-228
• /
• 2000

This study deals with the water qualities of Dalgi mineral spring in Cheongsong district.Water samples which were taken from upper, middle and bottorn spring sites were tested for twenty eight important water quality items including minerals, essential and/or toxic trace elements, and the analytical items to affect the taste of mineral water, seasonally from May 1999 to February 2000 The results obtained wereas follows:Each spring site showed much difference in major items. Bottom spring water showed higher value of Mg and Na than others. Middle spring water showed the highest value in all of the items except Mg and Na. The concentration of Hardness, Fe and Mn in mineral water were over than the normal standard for drinking water, but these items are not specified for the mineral water. As, Cd, $Cr^{6+}$ and Hg were not found and Pb was found ln trace level. All of the items proved nearly constant during the four seasons except water temperature. The contribution of mineral water to the nutrition of human was calculated in order to investigate the health effect of drinking water on the bases of Required Daily Allowance,one liter of water drinking and the mineral concentration of the bottom spring. The percentage of consumable minerals of Ca, Mg, Na, K, Mn,Zn and Fe were 35.05,36.43,5.88∼10.63,0.19∼0.57,21.86∼43.72,0.65, and 95.l respectively. This means Dalgl mineral water is pIenty of iron mineral. The K and O indexes of mineraI water appeared to be good for healthy and delicious water.

• Economic and Environmental Geology
• /
• v.37 no.6 s.169
• /
• pp.631-645
• /
• 2004

This study assesses groundwater vulnerability to contaminants in industrial and residential/commercial areas of the city of Changwon, using DRASTIC technique and groundwater data. The DRASTIC technique was originally applied to situations in which the contamination sources are at the ground surface, and the contaminants flow into the groundwater with infiltration of rainfall. Mostly the industrial area has higher DRASTIC indices than the residential/commercial area. However, a part of the residential/commercial area having much groundwater production and great drawdown is more contaminated in groundwater than other industrial and the residential/commercial areas even if it has lowest DRASTIC indices in the study area. It indicates that groundwater contamination in urban areas can be closely related to excessive pumping resulting in a lowering of the water level. The correlation coefficient between minimum DRASTIC indices and the degree of poor water quality for 10 districts is as low as 0.40. On the other hand, the correlation coefficients between minimum DRASTIC indices and the groundwater discharge rate, and between minimum DRASTIC indices and well distribution density per unit area are 0.70 and 0.87, respectively. Thus, to evaluate the potential of groundwater contamination in urban areas, it is necessary to consider other human-made factors such as groundwater withdrawal rate and well distribution density per unit area as well as the existing seven DRASTIC factors.

• Analytical Science and Technology
• /
• v.17 no.5
• /
• pp.423-433
• /
• 2004

This study was examined occurrence of bisphenol A (BPA) and nonylphenol (NP) in waterworks system of Seoul, Korea from September 2002 to December 2003. The levels of BPA and NP in Han-river and its tributaries were as followed: Paldang-dam, ND(not detected)${\sim}0.033{\mu}g/L$ and $ND{\sim}0.823{\mu}g/L$; Kyungahn-creek, $ND{\sim}0.659{\mu}g/L$ and $ND{\sim}3.827{\mu}g/L$; Whangsuk-creek, $ND{\sim}0.528{\mu}g/L$ and $ND{\sim}12.724{\mu}g/L$, respectively. In water of 6 intake-station, the contents of NP and BPA were detected $0.122{\sim}2.724{\mu}g/L$, and $ND{\sim}0.260{\mu}g/L$, respectively. In the finished- and tap-water of three drinking water treatment plants (DWTPs) around Whangsuk-creek, BPA was not detected in all samples, while NP was in ppt levels in whole. Through the process of DWTP, also, the removal ratio of NP was above 80% in all this. Therefore, this result was suggested that levels of BPA and NP in waterworks system depended on non-point contaminants and swage treatment plants in the Han-river shed.

• Journal of Soil and Groundwater Environment
• /
• v.9 no.2
• /
• pp.54-63
• /
• 2004

For the purpose of finding out the distributions of groundwater uses, the effect of facilities on the parameter and the correlations among measurements, various statistical analysis were carried out with the data of groundwater quality measurements from January to December in 2002. (1) The rates of groundwater for drinking water were 10.5% in Yungcheon-Gu, 10.2% in Kangdong-Gu, and 9.9% in Eunpyung-Gu. The rates of other uses of groundwater were shown to be 58.1 %(786 wells) for civil defense emergency, 22.1% (299 wells) for contamination-concerning, 9.8%(133 wells) for water quality monitoring, consisting of 90% of all groundwater. (2) The 52.6% of groundwater for drinking were demonstrated to be appropriate while 91.9% for other uses-domestic, industrial, agricultural uses- were shown to be proper. (3) For drinking water, the maximum values of colar, turbidity, NH3-N, F, and Fe were 766.9 degree, 69.16NTU, 860.0 mg/l, 5.6 mg/l and 49.87 mg/l respectively. (4) Comparision of skewness and kurtosis for Seoul groundwater, pH was found to be 0.022 and -0.524, but the T.colony, color, turbidity, NH$_3$-N, NO$_3$-N, Fe and Mn respectively fumed out to be 11.641 and 174.324, 8.501 and 80.260, 5.675 and 32.821, 19.507 and 380.994, 3.323 and 17.436, 10.544 and 134.093 and 5.979 and 39.124. (5) In cases of drinking water wells for emergency, the results of statistical analysis showed that building year of the wells, depth and pumping rate didn't affect on whether it was proper for that use or not. It were shown that there were linear correlations between depth and NO3-N(-0.171) and F(0.332) while the correlation coefficients were 0.381 and -0.169 between the building year of well and depth and pumping rate respectively.