• 한국연소학회:학술대회논문집
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• 1997.06a
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• pp.89-102
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• 1997

대향류 확산 화염의 매연 생성 특성에 대한 실험적 연구가 수행되었으며, 그 결과 에틸렌 ($C_2H_4$)-프로판($C_3H_8$) 혼합 연료의 경우 매연 생성 상승 효과 (synergistic effect)가 관측되었다. 프로판과 에틸렌의 PAH 생성 양상이 상이하게 나타났으며, 소량의 프로판을 에틸렌 확산 화염에 첨가할 경우 순수 연료에 비하여 매연 및 PAH (다중 고리 방향족 탄화수소; polycyclic aromatic hydrocarbon) 생성이 증대되었다. 단조적으로 변화하는 아세틸렌($C_2H_2$) 농도와 단열 화염 온도를 고려할 때, 이러한 결과는 HACA (H-abstraction-$C_2H_2$-addition) 반응만으로는 확산 화염에서의 매연 발생 및 성장을 설명할 수 없음을 의미한다. 수치해석과 실험 결과의 비교로부터 초기 PAH의 생성 과정을 규명하였으며 이 과정에서 C3 화학종의 재결합 반웅이 매우 중요함을 확인할 수 있었다. 또한, 이러한 C3 화학종과 C2 화학종의 상호 보완적인 역할에 의하여 에틸렌-프로판 혼합 연료에서 매연 생성이 증대됨을 밝혔다.

• Fire Science and Engineering
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• v.26 no.5
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• pp.35-40
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• 2012

Numerical investigation was performed to study on the soot formation characteristics in the WSR according to the CO addition. Ethylene and pure air were used as a fuel and an oxidizer, respectively, and three different equivalence ratios (2.0, 2.5, 3.0) were used in the calculation. The resulted CO mole fraction of 10 % CO addition showed the maximum value in spite of the least CO supply. This means that the conversion of CO to soot and other carbon compounds is weakened under incipient soot formation. The soot volume fraction was decreased with increasing the CO addition because the important species for soot formation such as pyrene and acetylene, were decreased with the addition of CO. When the equivalence ratio was 2.5, the soot volume fraction shows the highest value, which results from the contribution of fuel rich condition and reacting temperature. Furthermore, surface growth rate and species concentrations justified the HACA mechanism for soot formation.

• 한국연소학회:학술대회논문집
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• 2002.11a
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• pp.123-128
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• 2002

The synergistic effect of ethylene/propane and ethylene/methane mixtures on soot formation is studied experimentally with a concentric co-flow burner. The integrated soot volume fractions, laser light scattering signal and PAH concentrations are measured for different fuel supply configurations. The synergistic effect in ethylene/propane diffusion flames is found to be affected not only by the composition of mixture but also by the way of mixing. Comparing to the homogeneously mixed ethylene/propane case, the increase of soot formation is observed when propane is supplied through the inner nozzle, while the decrease is observed when propane is supplied through the outer nozzle. However, the measured PAH concentration distributions are inconsistent with the current view of the synergistic effect of ethylene./propane mixture on soot formation. Virtually no synergistic effect is observed in ethylene-methane flames regardless of the fuel supply configuration, which suggests the important role of $C_3$ species produced during the propane pyrolysis process for the synergistic effect.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.5
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• pp.962-978
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• 1989

A new model of the combustion rates of soot particle in turbulent flames has been suggested. This model applies the combustion rate of soot particles in laminar flames and uses local time-averaged quantities in order to consider the effect of the chemical reaction on the soot combustion in turbulent flames. The proposed rate equation has been tested for two propane-air turbulent round-jet diffusion flames and gives better predictions for the soot concentration field of two flames than the model previously used, especially in low temperature regions. A modified Monte carlo Method for analyzing radiative heat transfer of a flame also has been suggested and tested, which reveals good results.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.6
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• pp.389-395
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• 2017

This study was performed to provide the information of the soot formation behavior of octane single fuel droplet under the identical combustion conditions. To achieve this, this experimental study provide the results of the soot formation characteristics of octane droplet in accordance with different initial droplet diameter($d_0$), at the same time, experiment was conducted under the same combustion conditions which are 1.0atm of ambient pressure($P_{amb}$), 21% of oxygen concentration($O_2$) and 79% of nitrogen concentration($N_2$). Visualization of octane droplet combustion was performed by visualization system with high speed camera. The results of maximum soot volume fraction($f_{vmax}$) was almost the same under the equivalent ambient conditions regardless of initial droplet diameter. Furthermore, maximum soot volume fraction was showed the higher value in the measuring direction between $135^{\circ}$ and $315^{\circ}$ since the soot-tail is generated during two opposing igniters movement process.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.8
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• pp.807-815
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• 2013

A numerical study on soot formation in a laminar ethylene diffusion flame at atmospheric pressure was conducted to obtain a better understanding of the effects of buoyancy on sooting flames under 0g and 1g using a gas-phase reaction mechanism and thermal and transport properties. A simple model was employed to predict soot formation, growth and oxidation with interactions between the gas phase chemistry and the soot chemistry taken into account. Results showed that the flames in 0g are much wider than that of 1g because of the thicker diffusion layer and reduction in axial velocity. The reduction in the axial velocity in 0g results in longer residence times, and resulting in greatly enhanced soot volume fraction. And, under zero-gravity, due to the lack of a buoyancy-induced instability, flame instability disappears.

• Journal of the Korean Society of Marine Environment & Safety
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• v.29 no.4
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• pp.356-362
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• 2023

The risk of climate change has been long acknowledged, and ongoing efforts to overcome this issue, within the shipping sector, with the international maritime organization playing a central role. Conducting research on characteristics of soot formation is crucial to control its occurrence within the combustion process. In this study, the laser extinction method and chemical reaction numerical analysis were employed to examine the alterations in the state of chemical species associated with flame temperature, flame visual, and soot formation by mixing nitrogen, an inert gas, in the counterflow diffusion flame based on ethylene gas. The findings of the study suggest that as the mixing ratio of nitrogen increased, both the flame temperature and soot volume fraction decreased. Additionally, the area in which soot particles were distributed also decreased, and the volume fraction decrease rate declined when the mixing ratio increased by more than 30%. The mole fraction of the chemical species involved in soot growth also decreased. the chemical species associated with the HACA reaction were affected by variations in the hydrocarbon fuel ratio, and the chemical species related to the odd carbon path were confirmed to be affected by the flame temperature as well as the hydrocarbon fuel ratio.

• Journal of the Korean Society of Marine Environment & Safety
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• v.16 no.3
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• pp.301-306
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• 2010

DME(Di-Methyl Ehter, $CH_3OCH$) is currently attracting worldwide attention due to its environmentally friendly characteristics. Until now it was researched as a major alternative fuel of diesel automobile because it is a clean fuel producing low soot. Therefore, in this study, in order to investigate the effect of DME mixing on number density and size of soot particle, DME has been mixed in opposed-flow ethylene diffusion flame with the mixture ratios 5%, 14% and 30%. A laser extinction/scattering technique has been adopted to measure the volume fraction, number density, and size of soot particles. The experimental results showed that the soot concentration of mixture flames with the mixture ratios 5% and 14% produces soot more, even though that of 30% was decreased. This means that even though DME has been known to be a clean fuel for soot formation, the mixing of DME in diffusion flame of ethylene, where acetylene maintains high concentration in soot formation regions, could produce enhanced production of soot.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.5
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• pp.1222-1233
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• 1990

The formation and oxidation processes of soot particles in a diesel flame were investigated with a rapid compression machine. A cloud of soot particles was successfully visualized by means of the instantaneous laser shadow photographs technique and the equivalence ratio of the soot formation zone was estimated from a measured fuel concentration distribution in a nonevaporating spray. The temporal and spatial variation of soot concentration in the flame was also correlated with the rate of heat release. Soot particles appears first in a region near the flame tip when diffusion combustion period starts, and its concentration is a maximum at about the end of injection, then decreases due to oxidation. The reason for soot being formed in a fuel lean region near the flame tip is the evaporated fuel requires time to be pyrolized as it travels through the burning fuel rich zone towards the flame tip.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.1
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• pp.55-60
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• 2012

In order to investigate the effect of n-heptane mixing on PAH and soot formation, small amount of n-heptane has been mixed in counterflow ethylene diffusion flame. Laser-induced incandescene and laser-induced fluorescene techniques were employed to measure soot volume fraction and polycyclic aromatic hydrocarbon(PAH) concentration, respectively. Results showed that the mixing of n-heptane in ethylene diffusion flame produces more PAHs and soot than those of pure ethylene flame. However, signals of LIF for 20% n-heptane mixture flame were lower than that of pure ethylene flame. It can be considered that the enhancement of PAH and soot formation by the n-heptane mixing of ethylene can be explained by methyl($CH_3$) radical in the low temperature region. And it can be found that reaction rate of H radical for 10% n-heptane plays a crucial role for benzene formation.