• Title/Summary/Keyword: 매연의 산화

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The Effects of Carbon Dioxide as Additives on Soot Formatio in Jet Diffusion Flames (제트확산화염에서 이산화탄소의 첨가가 매연생성에 미치는 영향)

  • Ji, Jung-Hoon;Lee, Eui-Ju
    • Fire Science and Engineering
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    • v.24 no.6
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    • pp.170-175
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    • 2010
  • The effect of carbon dioxide addition on soot formation was investigated in jet diffusion flames in coflow. Flame temperature were measured with R-type thermocouple and the boundary temperature between blue and yellow flame was confirmed. Light-extinction method was introduced for the relative soot density (1-I/$I_0$) in the in-flame region. He-Ne laser with wave length at 632.8 nm was used for the light source, and the signal attenuated by absorption and scattering was detected directly. Oxidizer velocity effect on soot formation was studied to know that the thermal influence for soot formation. The results showed that the temperature of both blue and yellow flame were decreased according to the dilution of carbon dioxide but boundary temperature was nearly constant. The relative soot density was lower when carbon dioxide was added in oxidizer stream and oxidizer velocity increased. These were caused by the reduction of flame temperature and shorter residence time for soot growth. Also carbon dioxide addition enhanced the instability of jet flames like flickering, so the flame length was a little longer than pure ethylene/air flame.

A Study on the Diesel Flame by Means of Image Analysis ofn Shadow Photographs (음영사진의 화상해석에 의한 디젤화염에 관한 연구)

  • 장영준;박호준;신본무정
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.5
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    • pp.1222-1233
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    • 1990
  • The formation and oxidation processes of soot particles in a diesel flame were investigated with a rapid compression machine. A cloud of soot particles was successfully visualized by means of the instantaneous laser shadow photographs technique and the equivalence ratio of the soot formation zone was estimated from a measured fuel concentration distribution in a nonevaporating spray. The temporal and spatial variation of soot concentration in the flame was also correlated with the rate of heat release. Soot particles appears first in a region near the flame tip when diffusion combustion period starts, and its concentration is a maximum at about the end of injection, then decreases due to oxidation. The reason for soot being formed in a fuel lean region near the flame tip is the evaporated fuel requires time to be pyrolized as it travels through the burning fuel rich zone towards the flame tip.

Effects of CO Addition on Soot Formation in the Well Stirred Reactor (WSR에서 매연 생성에 관한 CO 첨가 효과)

  • Jeong, Tae-Hee;Lee, Eui-Ju
    • Fire Science and Engineering
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    • v.26 no.5
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    • pp.35-40
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    • 2012
  • Numerical investigation was performed to study on the soot formation characteristics in the WSR according to the CO addition. Ethylene and pure air were used as a fuel and an oxidizer, respectively, and three different equivalence ratios (2.0, 2.5, 3.0) were used in the calculation. The resulted CO mole fraction of 10 % CO addition showed the maximum value in spite of the least CO supply. This means that the conversion of CO to soot and other carbon compounds is weakened under incipient soot formation. The soot volume fraction was decreased with increasing the CO addition because the important species for soot formation such as pyrene and acetylene, were decreased with the addition of CO. When the equivalence ratio was 2.5, the soot volume fraction shows the highest value, which results from the contribution of fuel rich condition and reacting temperature. Furthermore, surface growth rate and species concentrations justified the HACA mechanism for soot formation.

A numerical study on soot formation in ethylene diffusion flames under 1g and 0g (1g와 0g에서의 에틸렌 확산화염 내 매연 생성 특성에 관한 수치적 연구)

  • Choi, Jae-Hyuk;Park, Sang-Kyun
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.807-815
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    • 2013
  • A numerical study on soot formation in a laminar ethylene diffusion flame at atmospheric pressure was conducted to obtain a better understanding of the effects of buoyancy on sooting flames under 0g and 1g using a gas-phase reaction mechanism and thermal and transport properties. A simple model was employed to predict soot formation, growth and oxidation with interactions between the gas phase chemistry and the soot chemistry taken into account. Results showed that the flames in 0g are much wider than that of 1g because of the thicker diffusion layer and reduction in axial velocity. The reduction in the axial velocity in 0g results in longer residence times, and resulting in greatly enhanced soot volume fraction. And, under zero-gravity, due to the lack of a buoyancy-induced instability, flame instability disappears.

Study on Estimation of PM Mass in DPF from Pressure Drop in 3L Diesel Engine (3L급 디젤엔진의 배압이용 DPF 매연포집량 예측에 대한 연구)

  • Kim, Hong-Suk;Lee, Jin-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.5
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    • pp.499-504
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    • 2010
  • It is important to determine the exact soot mass in a DPF system in order to control the timing of PM regeneration. The soot mass accumulated in a filter can be estimated from the pressure drop in the filter and the exhaust gas flow rates. In this study, the soot index is defined as the pressure drop in the DPF divided by the pressure drop in a DOC. An effective signal processing method for determining the soot index is proposed; the results yielded by this method indicate good correlation between the soot index and the amount of soot loaded into the filter for both steady-state and transient-state operating conditions in a 3L diesel engine for passenger vehicles.

Soot Formation and Combustion in Turbulent Flames (난류 화염 내에서의 매연 입자의 생성및 재연소)

  • 정종수;신현동;이춘식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.962-978
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    • 1989
  • A new model of the combustion rates of soot particle in turbulent flames has been suggested. This model applies the combustion rate of soot particles in laminar flames and uses local time-averaged quantities in order to consider the effect of the chemical reaction on the soot combustion in turbulent flames. The proposed rate equation has been tested for two propane-air turbulent round-jet diffusion flames and gives better predictions for the soot concentration field of two flames than the model previously used, especially in low temperature regions. A modified Monte carlo Method for analyzing radiative heat transfer of a flame also has been suggested and tested, which reveals good results.

Experimental Study on Estimation of Oxidation Rate of PM inside of Diesel Particulate Filter (DPF내 포집된 입자상 물질의 산화율 산출을 위한 실험적 연구)

  • Shim, Beomjoo;Park, Kyoungsuk;Jo, Kyuhee;Lee, Hyeongjun;Min, Byeongdu
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.2
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    • pp.98-103
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    • 2013
  • Conventional method to estimate mass of particulate matter accumulated in diesel particulate filter is to use pressure difference between upstream and downstream of the filter. Then measured pressure difference should be compared that of clean condition which is no particulate matter accumulated in DPF. During regeneration soot oxidation is also estimated by same method. This methodology, however, has demerit on accuracy because of pressure difference deviation of clean DPFs and pressure difference caused by non-carbon based PM which is different from that of caused by carbon based PM. This study suggests new methodology to estimate accumulated soot oxidation rate through exhaust gas characteristics during regeneration. Results, more high accuracy of soot oxidation was obtained by analysis of relationship between fuel mass and concentration of carbon dioxide and oxygen.

Predictions on the Flame Structure and Soot Distribution in the Coflowing Laminar Diffusion Flames (동층류 축대칭 확산화염내의 화염구조 및 매연입자 분포의 예측)

  • 이정기;김상수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.8
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    • pp.1583-1594
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    • 1992
  • A numerical calculation on the flame structure and soot particle distribution in a coannular laminar diffusion flame was performed. Flame analysis model utilized basically flame sheet concepts, Shvab-Zel'dovich assumption, and one step overall irreversible reaction. It was also considered the variation of thermodynamics and transport properties, and the stagnation enthalpy was used for solving temperature field. Radiation was taken into account, since it has been found to be important in determining the flame temperature in sooty flames. For soot particle analysis, we adopted the coagulation, suface condensation, and the oxidation model in addition to tesner's two-step formation model. Equations for primary soot particle excluding the agglomeration process were solved. Based on the results, the regions of soot generation, growth, and oxidation in the flame have been observed and radiation strongly influenced flame temperature and soot distribution.

Flamelet Modelling of Soot Formation and Oxidation in a Laminar $CH_4$-Air Diffusion Flame (화염편모델을 이용한 층류확산화염장의 매연 생성 및 산화과정 해석)

  • Kim, Gun-Hong;Kim, Hu-Jung;Kim, Yong-Mo;Kim, Seung-Ku
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.3-9
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    • 2003
  • By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept for simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

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