• Title/Summary/Keyword: 막 오염

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A Proposition on Reasonable Termination Procedure in Remaining-oil Recovery Work from a Sunken Tanker in Korean Territory (국내 침몰유조선 잔존유 회수작업의 합리적 종료절차 제안)

  • Kang, Kwang-Gu;Shim, Yoo-Taek;Kang, Sin-Young
    • Journal of Navigation and Port Research
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    • v.38 no.4
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    • pp.379-384
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    • 2014
  • In case of sunken tankers, remaining-oil recovery operation should be conducted due to possible oil spill accident. However, the deep sea operation make difficulties in checking the completion of remaining oil recovery process, therefore the work termination procedure is very important. In this paper, a reasonable work termination procedure through the comparison and analysis of two cases(Youil No.1 and Osung No.3, Kyung-Shin) which were performed in different method, using disparate equipment. By investigating previously applied methods and techniques, work speed, safety and expenses were compared. The proposed ending procedure of the remaining-oil recovery project is to recover the remaining oil from each cargo tanks and to clean up such tanks whilst an independent surveyor proceeds to a confirmation procedure whereby said surveyor checks out whether any remaining oil exists by putting a stick in each cleaned up tanks and opening up the hatch cover of the tanks or the top place of the tanks to confirm the cleanness of oil. Such procedure shall be done through discussion by the ordering party, contractor and the independent surveyor all together with a flexible application.

Changes of Hematological Constituents in the Mullet, Mugil cephalus Exposed to Chromium (크롬 노출에 따른 숭어, Mugil cephalus의 혈액성분 변화)

  • Ahn, Tae-Young;Jeong, Dal Sang;Kim, Jun-Hwan;Kang, Ju-Chan
    • Journal of fish pathology
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    • v.26 no.2
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    • pp.89-97
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    • 2013
  • The study was carried out to investigate the changes of hematological parameters induced by waterborne exposure of chromium (Cr) in the mullet, Mugil cephalus. The mullet was exposed to sub-chronic concentrations of chromium (0, 25, 50, 100, $200{\mu}g/L$ Cr) for 4 weeks. The major hematological findings were significant decreases in the red blood cell (RBC) count and hematocrit value in mullet exposed to ${\geq}50{\mu}g/L$ Cr. Although serum calcium concentration was significantly reduced at ${\geq}50{\mu}g/L$ Cr, magnesium concentration was found to be significantly increased at ${\geq}100{\mu}g/L$ Cr. The serum glucose and total protein concentrations were significantly increased at $200{\mu}g/L$ Cr. However, serum triglyceride concentration did not show any noticeable changes in the range of $25{\sim}200{\mu}g/L$ Cr of chromium compared to control group during the experimental period. A significant increment of GOT (glutamic oxalate transminase) and GPT (glutamic pyruvate transminase) activities was noticed at ${\geq}100{\mu}g/L$ Cr. These results indicate that hematological and serum biochemical changes in the mullet by waterborne exposure to chromium are affected at more than $50{\mu}g/L$ Cr.

Transport behavior of a surfactant tracer(CPC) with Langmuir type adsorption isotherm on NAPL-water interface in a homogeneous porous medium (NAPL-물 계면에서 Langmuir형 흡착특성을 보이는 계면추적자(CPC)의 다공성 균질매질내 유동특성)

  • 김헌기;문희수;이상훈
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.3-13
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    • 2001
  • It has been known that nonlinear characteristics of sorption affect the transport behavior of water soluble pollutants in soils. However detailed experimental studies have not been performed to verify the effect of non-linearity of adsorption isotherm on transport of chemicals in porous media. In this research, the distortion of breakthrough curves of a cationic surfactant (cetylpyridinium chloride, CPC) in a engineered stainless steel column packed with glass beads were investigated. Glass beads with about 110 $\mu\textrm{m}$diameter coated with a thin n-decane film were used as the media providing the sorption surface for CPC. The CPC adsorption isotherm on the surface of n-decane from aqueous solution was a typical Langmuir type. The breakthrough curve of CPC using step Input showed a late breakthrough on the front side and early breakthrough on the back side accordance to the shape of the isotherm. The retardation factor of CPC was found to be a strong function of the input concentration, which also a manifestation of the non-linearity of the isotherm. The retardation factors for the CPC with step input agreed with those of pulse input that the maximum concentrations are controlled to be the same as the step input concentrations. This results support the validity of the unproven field practices of using hydrogeotracers with non-linear adsorption isotherms to determine the hydrogeological parameters, e.g., NAPL saturation, air-water or NAPL-water interfacial areas.

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Fluoride and nitrate removal by electro-coagulation for decentralized water treatment plants (전기응집을 이용한 소규모 수도시설의 불소 및 질산성질소 이온의 제거)

  • Han, Song-Hee;Chang, In-Soung;Back, Soun-Ok;Joung, Seun-Young;Lee, Cheol-Ku
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.115-116
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    • 2010
  • 광역상수도의 경우 수자원공사 및 지방상수도 사업자들에 의해 전문적으로 수질을 관리하고 음용수를 보급하고 있으나 소규모 수도시설의 경우 전문능력을 갖춘 관리자가 아닌 마을의 대표자가 맡아 관리함에 따라 안정성 및 유지관리의 어려움이 자주 제기되고 있다.[1] 또한 소규모 수도시설의 경우 취수원으로 지하수나 계곡수를 이용하여 여과나 염소소독을 거쳐 음용수로 이용함에 따라 중금속 및 무기이온 등 각종 오염물질이 효과적으로 제거되지 않아 이를 사용하는 주민들이 불편함을 겪고 있는 실정이다. 환경부의 법정 수질 검사에 따르면 부적합 판정을 받은 곳의 대부분은 마을상수도와 소규모 급수시설인 것으로 나타났으며 초과 항목으로는 무기이온 중 특히 불소와 질산성질소 인 것으로 나타났다.[2] 이러한 문제점을 해결하고자 기존의 고도 정수처리 시설인 막여과, 오존처리, 활성탄 흡착 공정 등을[3-5] 적용하고 있으나 소규모 수도시설에 적용하기에는 유지관리, 규모, 경제적 측면 등 여러 한계점을 지니고 있다. 따라서 본 연구에서는 이러한 문제점을 해결하기 위한 방안으로 전기응집기술을 이용하여 음용수 수질기준을 초과하는 무기이온 중 불소와 질산성 질소를 제거하고자 하였다. 전기응집기술은 제거효율이 높고, 운전이 용이하며 부가적인 화학약품의 첨가가 불필요하다.[6,7] 또한 기존의 고도정수처리 기술에 비해 전기응집 공정은 처리효율과 경제적인 측면 모두를 만족시키고 있어 소규모 수도시설의 불소와 질산성질소를 효과적으로 제거할 수 있는 방안으로 판단된다. 본 연구에 사용된 실험장치는 직류전원공급장치 (DC power supply), 반응조, 전극으로 구성되어 있다. 직류전원공급장치는 최대전압 30 Volt, 최대 전류 30 Amper 까지 조절 가능하였으며 반응조의 크기는 14.5cm(w) ${\times}$ 9cm(L) ${\times}$ 22cm(H) 이고 실용적 1.5L이다. 반응조의 상부에는 전극이 고정될 수 있도록 0.5cm 간격의 홈을 만들어 제작 하였다. 전극은 가용성 전극인 알루미늄 (Al), 스테인레스스틸(SUS304)를 이용하였다. 이를 통해 전류밀도, 전극간격 등의 변수를 두어 최적의 전기응집 운전 조건을 파악하였으며 이는 소규모 수도시설의 수질개선 향상에 도움이 될 수 있을 것으로 판단된다.

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Application of Microbubble in MBR Process for Night Soil Treatment (분뇨처리를 위한 MBR공정에서 Microbubble의 적용)

  • Lim, Ji-Young;Kim, Jin-Han
    • Journal of the Korea Organic Resources Recycling Association
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    • v.25 no.1
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    • pp.93-101
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    • 2017
  • In this study, the microbubbles were applied to the MBR process for night soil treatment, and the removal efficiency was estimated. As a result of the this study, when the microbubble was supplied directly to the aerobic tank in which the membrane was submerged, excessive scum was generated so could not stable operation of the process. The SS removal efficiencies in the pre-treatment tank were 74.3%, 82.8%, 75.0%, 52.1% on average at the 2 kg, 4 kg, 6 kg, and $8kg\;COD_{Cr}/m^3$, respectively. The mean removal efficiencies were more than 99.4%, 94.0%, 74.1% for SS, $TCOD_{Cr}$, $SCOD_{Cr}$ by MBR process. On the other hand, when the microbubble are directly supplied to the aerobic tank, the microbubble and the scum are attached each other to accelerate the fouling. Therefore, it can be confirmed that stable treatment can be achieved by applying microbubble to the front of the bioreactor for removal of SS and oxidation of organic matters in high concentration organic wastewater treatment such as night soil.

The Practical Study for the Treatment of Fish Processing Saline Wastewater Using Immersed MBR (iMBR 공정을 이용한 수산물가공폐수 처리에 관한 실증적 고찰)

  • Park, Seung Kyun;Lee, Dong Jun
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.9
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    • pp.469-475
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    • 2016
  • The study is the result of an practical operation analysis for the full scale fishery product wastewater treatment plant with immersed MBR (iMBR) process. Since fishery product industries show a wide range of wastewater generation by the season, design and operation of the equalization basin are very important factor. The aeration system for the equalization basin mixing can save the chemical consumption for followed system through the restriction of acid fermentation. The concentrations of wastewater primary DAF process treated were BOD 2,291 mg/L, $COD_{Mn}$ 530 mg/L, SS 256.8 mg/L, T-N 38 mg/L, T-P 13.5 mg/L respectively. It was considered that iMBR is the most efficient biological process for high salinity content wastewater since It is irrelevant to the capability of the sludge precipitation. SADp and SADm were 0.31, $26.5m^3/hr{\cdot}m^3$ respectively. In iMBR process, the critical F/M ratio was derived at 0.08~0.10 gBOD/gMLSS by analysing the correlations between MLSS, normalized TMP and temperature. The effluent concentrations were BOD 1.8 mg/L, $COD_{Mn}$ 12.4 mg/L, SS 1.0 mg/L, T-N 7.85 mg/L, T-P 0.1 mg/L and removal efficiencies were 99.9%, 97.6%, 96.3%, 95.7%, 97.8% respectively.

A Study on the Improvement of Salvage Procedures through the Collision Accident of Ships (충돌사고 사례분석을 통한 구난시스템 개선에 관한 연구)

  • Jung, Chang-Hyun;Nam, Taek-Kun;Jeong, Jung-Sik
    • Journal of Navigation and Port Research
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    • v.36 no.10
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    • pp.851-856
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    • 2012
  • There has been increasing the possibility of occurring the marine accident and become bigger the extent of damage with the growing number and high speed of ships. Also, there were tremendous loss of lives and properties in accidents of Hebei spirit in 2007 and Cheon Ahan war ship in 2010 with the insufficient salvage response and the lack of emergency response systems. When a ship has suffered an incident, the best way of preventing damage or pollution from its progressive deterioration would be to providing a place of refuge and to repair the damage rapidly. Therefore, it was examined the recent collision accident broken out near the Nam-Hae, and then suggested that it was necessary to be improved of the domestic salvage systems. It requires the procedures of providing a place of refuge, and the towing support system which make the damaged ship moved to the safe area, and joining of the ISU.

Removal of Color and non-biodegradable organic matter from biologically treated effluent by coagulation. (응집에 의한 생물학적 처리수의 색도 및 난분해성 유기물 제거)

  • Seo, Tae-Gyeong;Park, Sang-Min;Park, No-Baek;Jeon, Hang-Bae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.859-863
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    • 2008
  • 축산폐수, 침출수 등의 고농도 폐수를 생물학적으로 처리할 경우 최종 방류수는 강한 색도를 띠며 고분자량의 유기물질을 다량 함유한다. 이는 생물학적으로 분해하기 어려운 유기성 복합체와 생화학적 반응에 의한 중간생성물로 색도를 띠는 천연유기물질(NOM)을 포함한다. 생물학적 처리수의 색도는 심미적인 불안감, 방류수역의 수질오염 및 공중보건상의 잠재적 위해성을 갖는다. 또한, 수자원 이용측면에서 정수처리공정에서의 약품투입량 증가와 특히, 소독부산물 생성이라는 잠재적 문제점이 뒤따른다. 따라서 이러한 문제점을 해소하기 위한 생물학적 2차 처리수의 후속처리가 요구되며, 실제로 난분해성 유기물과 색도를 제거하기 위한 흡착, 막 분리, 고급산화(AOP) 및 화학적 응집 등의 물리-화학적 공정에 대한 연구가 수행되어왔다. 특히, 화학적 응집은 무기응집제 또는 고분자중합체(Polymer)를 이용하여 콜로이드성 입자와 색도를 띠는 난분해성 유기물을 전기적 불안정화를 유도함으로서 흡착 및 응집과정을 통해 제거하는 공정으로 많은 연구자들에 의해 연구되어왔다. 그러나 난분해성 유기물과 색도제거는 대상원수의 성상과 화학적 특성 등에 따라 각각의 제거효율과 최적 운전조건이 상이하게 나타난다. 화학적 응집공정은 비교적 높은 제거효율을 보이지만, 운전 및 유지관리의 기술적 어려움, 경제적 비효율성 등으로 인하여 적용에 어려움을 겪고 있는 실정이다. 본 논문에서는 생물학적 혐기-호기성 공정에서 방류되는 축산폐수의 2차 처리수를 대상으로 화학적 응집에 의한 색도 및 난분해성 유기물의 제거거동을 고찰하였다. 대상 처리수의 $TCOD_{Cr}$ 농도는 평균 410 mg/L인 반면, $BOD_5$는 7-15 mg/L 범위로 난분해성 유기물을 다량 함유하고 있음을 알 수 있었다. 이에 황산알루미늄(Aluminium sulfate; $Al_2(SO_4){\cdot}14H_2O$)과 염화철(ferric chloride)의 무기응집제를 이용하여 자 테스트(jar test)를 수행한 결과, 동일한 응집제 주입량에서 염화철의 유기물 제거 효율이 높은 것으로 나타났다. 황산알루미늄과 염화철의 경우 각각의 응집제 주입율 5.85mM에서 89%, 7.03mM에서 97.5%의 최대 유기물 제거효율을 보여주었으며, 이 때 최종 pH는 4.0-5.6 범위이었다. 한편, 대상 원수 내의 콜로이드성 입자 또는 용존성 유기물의 작용기(functional group)는 일반적으로 음으로 하전 되어 있어 응집에 의해 잘 제거되지 않는 특성을 가지고 있다. 따라서 과량의 응집제를 주입하여 다가의 양이온성 금속염을 흡착시켜 전기적으로 중화시키고, 생성된 침전성 수화물 내에 포획 또는 여과시켜 제거하게 된다. 이 때, 금속염 수화종의 전하밀도가 응집효율에 영향을 주는 것으로 알려져 있는데, 다가의 양이온은 전기적 이중층(Double layer) 압축에 의한 불안정화를 향상시킬 수 있기 때문에다. 또한, 2가 금속염은 색도유발물질과 흡착하여 humate 또는 fulvate 등의 착화합물(complex)을 형성시켜 응집효율을 향상시킬 수 있다. 따라서 본 연구에서는 생물학적 2차 처리수의 화학적 응집처리에 있어서 알루미늄염 등의 다가이온 첨가가 응집에 미치는 영향을 관찰하고, 후속되는 플록형성 및 침전공정에 의한 제거효율을 비교, 평가함으로써 2차 처리수로부터 난분해성 유기물과 색도를 보다 효과적이고 경제적으로 제거할 수 있는 최적인자를 도출하고자 하였다.

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Minimizing Nutrient Loading from SCB Treated Paddy Rice Fields through Water Management (SCB 액비 시용 논에서 물관리를 통한 양분의 수계 부하 최소화 방안)

  • Kim, Min-Kyeong;Kwon, Soon-Ik;Kang, Seong-Soo;Jung, Goo-Bok;Hong, Seung-Chang;Chae, Mi-Jin;So, Kyu-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.671-675
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    • 2012
  • This study was conducted to establish the BMPs (Best Management Practices) for preventing pollutant loadings from paddy rice field applied livestock liquid manure from 2008 through 2011. Cultivated paddy rice fields (Gyeonggi province, Korea) were treated with SCB (Slurry composting and bio-filtration process) liquid fertilizer. The BMPs for paddy rice field developed in this study includes: 1) the controlling a drainage water gate in paddy rice field from right after SCB liquid fertilizer application to 3 weeks after rice transplanting; 2) livestock liquid fertilizer application to paddy rice soils in 20 days before rice transplanting to encourage the utilization of liquid fertilizer; 3) preservation of surface water depth to 5 cm in a paddy field right after SCB liquid fertilizer applied to minimize a water pollution and enhance the utilization of liquid fertilizer; and 4) blocking a water gate at least for 2 days to inactivate E. coli survival. The findings of this study will provide useful and practical guideline to applicators of agricultural soil in deciding appropriate handling and time frames for preventing pollution of water quality for sustainable agriculture.

Seawater Desalination Pretreatments and Future Challenges (해수담수화 전처리 기술과 향후 도전)

  • Jang, Hoseok;Kwon, Deaeun;Kim, Jeonghwan
    • Membrane Journal
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    • v.25 no.4
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    • pp.301-309
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    • 2015
  • Importance of pretreatment for seawater desalination is growing rapidly. Proper selection of pretreatment is critical for the successful, long-term operation in the seawater desalination plant such as seawater reverse osmosis (SWRO). The purposes of seawater pretreatment are to remove particulate, colloidal materials, organic, inorganic materials, microorganisms and their by-products present in the seawater, and thus to improve the performance of seawater desalination systems. However, pretreatment is most challenging for designing and operating seawater desalination plants because of fluctuations of water qualities, site specifications and wide ranges of target materials present in the seawater to be treated. In addition, it is also becoming evident increasingly that microscopic algae are a major cause of operational problems, for example, membrane fouling which is long-standing problem in SWRO process. Pretreatment strategies prior to the operation of seawater desalination technologies should be even more complicated by algae blooms and release of their harmful by-products in marine environment. This paper reviews the roles of various pretreatment methods in seawater desalination process. Benefits and drawbacks are described, which should be taken into account in future studies on selecting pretreatment for seawater desalination process.