• Title/Summary/Keyword: 막 오염

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초임계압 보일러 용수제조와 막분리 공정

  • 최낙균
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.06a
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    • pp.155-176
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    • 1996
  • 막분리 공정의 향후 전망으로 발전설비의 대용량화에 따른 고온, 고압화로 순수의 요구 수질은 엄격해지는 반면 발전용원수의 주공급원인 지표수의 오염은 가속화되고 있다. 따라서 발전용 초순수제조 공정은 종래의 Deionizer를 보완하는 설비로 막분리 공정의 채택이 증가할 것으로 전망된다.

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Permeation behavior of kaolin solution in dead-end microfiltration (카올린 용액의 Dead-end형 정밀여과투과)

  • 장규만;정건용
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.10a
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    • pp.133-136
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    • 1998
  • 0.1 내지 $4 \mum$의 입도분포를 가진 kaolin용액을 dead-end형 여과 장치(Amicon Cell, 8050)를 이용하여 공칭세공이 $0.2 \mum$인 PTFE막으로 농도 및 운전압력에 따른 투과실험을 하였다. Kaolin 용액의 투과유속은 케이크 저항이 지배적이었으며 초기에는 분리막 표면에 케이크가 형성되고 그 후에 분리막 세공의 오염이 발생하는 것으로 관찰되었다.

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Physicochemical Effect on Permeate Flux in a Hybrid Ozone-Ceramic Ultrafiltration Membrane Treating Natural Organic Matter (자연유기물을 처리하는 혼합 오존-세라믹 한외여과 시스템에서 물리화학적 특성이 투과플럭스에 미치는 영향)

  • Kim, Jeong-Hwan
    • Membrane Journal
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    • v.18 no.4
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    • pp.354-361
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    • 2008
  • Effects of operational conditions and solution chemistry on permeate flux in a hybrid ozone-ceramic ultra-filtration (UF) membrane system treating natural organic matter (NOM) were investigated. Results showed that the extent of permeate flux decline was higher at higher cross-flow velocity and ozone dosage, but it was higher at lower transmembrane pressure (TMP). The mechanism of fouling mitigation was found to be more dependent upon reaction between ozone and natural organic matter at/near catalytic membrane surface than scouring effect due to ozone gas bubbles. Addition of calcium into model NOM solution at high pH led to significant decline in permeate flux while the calcium effect on permeate flux decline was less pronounced at lower pH. After permeate flux decline during the early stage of filtration, the flux started recovering and approached fully to the initial value of it due to degradation of NOM by catalytic ozonation at ceramic membrane surface in the hybrid ozone-ceramic membrane system.

Effect of Fractionated Organic Matter on Membrane Fouling (분류된 천연유기물질을 이용한 막 오염 특성 평가)

  • Lee, Byung-Gu;Son, Hee-Jong;Roh, Jae-Soon;Hwang, Young-Do;Jung, Chul-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1321-1326
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    • 2005
  • As a results of this research, the Nakdong River consisted of 43% of hydrophobic fraction, 39% of hydrophilic fraction, and 18% of transphilic fraction. The hydrophobic fraction in this raw water was mostly fulvic acid. Fulvic acid comprised of 62% and the rest was humic acid(38%). There was more carboxylic acid functional roup(64%) than phenolic group(36%). HPI-N and HPI-C comprised of 17% and 22% in the hydrophilic portion, respectively. The results of the membrane fouling test using UF membrane according to NOM fractions. HPI-N caused more fouling than HPI-C. Humic acid caused more fouling than fulvic acid probably due to higher adsorption capacity. Since humic acid has higher adsorption capacity than fulvic acid, it would be more adsorbed onto the membrane pores. The carboxylic acid functional group caused more fouling than the phenolic group.

Improving Physical Fouling Tolerance of PES Filtration Membranes by Using Double-layer Casting Methods (PES 여과막의 물리적 막오염 개선을 위한 기공 구조 개선 연구)

  • Chang-Hun Kim;Youngmin Yoo;In-Chul Kim;Seung-Eun Nam;Jung-Hyun Lee;Youngbin Baek;Young Hoon Cho
    • Membrane Journal
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    • v.33 no.4
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    • pp.191-200
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    • 2023
  • Polyethersulfone (PES) is a widely employed membrane material for water and industrial purification applications owing to its hydrophilicity and ease of phase separation. However, PES membranes and filters prepared using the nonsolvent induced phase separation method often encounter significant flux decline due to pore clogging and cake layer formation on the dense membrane surfaces. Our investigation revealed that tight microfiltration or loose ultrafiltration membranes can be subject to physical fouling due to the formation of a dense skin layer on the bottom side caused by water intrusion to the gap between the shrank membrane and the substrate. To investigate the effect of the bottom surface porosity on membrane fouling, two membranes with the same selective layers but different sub-layer structures were prepared using single and double layer casting methods, respectively. The double layered PES membrane with highly porous bottom surface showed high flux and physical fouling tolerance compared to the pristine single layer membrane. This study highlights the importance of physical optimization of the membrane structure to prevent membrane fouling.