• 한국전기전자재료학회논문지
• /
• 제21권12호
• /
• pp.1130-1134
• /
• 2008

Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

• 전력전자학회:학술대회논문집
• /
• 전력전자학회 2012년도 추계학술대회 논문집
• /
• pp.67-68
• /
• 2012

최근 스마트폰 시장은 기하급수적인 성장세를 지속하고 있다. 또한 소비자들의 사용패턴 또한 기존의 음성통화에서 데이터 통신으로 변화되면서 소비전류 및 사용시간이 증대되고 있는 실정이다. 이러한 사용자의 불만을 해소하기 위해서는 배터리의 용량 증대가 필요하나 공간상의 제약으로 인해 한계점에 도달한 상태이다. 따라서 제한된 체적내에서 최대의 용량을 사용하기 위해 배터리팩의 과충전 차단전압은 점차 높아지고 과방전 차단전압은 점차 낮아져서 배터리팩의 가용영역을 확대하고 있는 추세에 있다. 이러한 사용전압영역의 확대는 배터리팩의 안전성 및 수명 등에 악영향을 미치나 배터리의 신소재 개발, 보호회로의 채용 등으로 이러한 단점을 보완하고 있다.

• 한국세라믹학회지
• /
• 제37권6호
• /
• pp.552-558
• /
• 2000

LiMn2O4 thin fiolm cathodes for Li-ion secondary battery were fabricated by r.f. magnetron sputtering technique. As-deposited films were amorphous. A spinel structure could not be obtained LiMn2O4 films by in-situ thermal annealing. After post thermal annealing over $700^{\circ}C$ in oxygen atmosphere, LiMn2O4 films prepared above 100 W r.f. power could be crystallized into a spinel structure. The electrochemical property of the LiMn2O4 film cathodes was tested in a Li/1 M LiClO4 in PC/LiMn2O4 cell. From cyclic voltammetry at scan rate of 2mV/sec of 2.5~4.5V, LiMn2O4 electrode prepared by post annealing at 75$0^{\circ}C$ showed good initial capacity. LiMn2O4 electrode prepared by post annealing at 80$0^{\circ}C$ showed the best crycling performance.

• 센서학회지
• /
• 제27권1호
• /
• pp.36-39
• /
• 2018

Transparent olivine $LiNiPO_4$ thin films on sapphire substrates were fabricated by radio frequency (RF) magnetron sputtering. The X-ray diffraction patterns show these thin films have the phase of $LiNiPO_4$ with an ordered olivine structure indexed to the orthorhombic Pmna space group. $LiNiPO_4$ thin films deposited on sapphire substrates exhibit transmittance of about 83 %. It was confirmed that the $LiNiPO_4$ thin film exhibits a high potential of 5 V-class.

• 세라미스트
• /
• 제22권4호
• /
• pp.381-392
• /
• 2019

Recently, demands for lithium-ion batteries (LIB) in various fields are increasing. In particular, understanding of the reaction mechanism occurring at the electrode-electrolyte surface/interface is significant for the development of advanced LIBs. Meanwhile, research and development of LIBs highly requires a new specific characterization approach. For example, atomic force microscopy (AFM) has been utilized to the LIB research field for various purposes such as investigation of topography, electrochemical reactions, ion transport phenomena, and measurement of surface potential at high resolution. Advances in the AFM analysis have made it possible to inspect various material properties such as surface friction and Young's modulus. Therefore, this technique is expected to be a powerful method in the LIB research field. Here, we review and discuss ways to apply AFM to LIB studies.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1997년도 하계학술대회 논문집 C
• /
• pp.1600-1602
• /
• 1997

We have studied microstructure of carbn fiber and graphite using scanning electron microscope, x-ray diffractommetry and x-ray photoelectron spectroscopy. According to the results, intercalation of lithium ion affected formation of film on carbon surface and changed structural parameter. Also, we found that film on carbon surface included lithium ion. And, the results of XPS indicated that surface of lithiated carbon materials existed P and F consisting electrolyte. Thus, We expected electrolyte cointercalated with lithium.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2000년도 하계학술대회 논문집
• /
• pp.667-670
• /
• 2000

The electrochemical characterization was conducted by the addition of chemically synthesized polyaniline on LiCoO$_2$electrode. From the results of XRD and SEM, the phase transition and microstructure were not found. Initial electrochemical characteristics of LiCoO$_2$electrode for lithium secondary battery were evaluated through the charge/discharge within the range of 4.3 V to 3.0 V versus Li/Li$^{+}$. Discharge capacity of LiCoO$_2$electrode without addition of Polyaniline were 160.21 mAh/g. But after addition of polyaniline, lower discharge capacities 25.7 mAh/g was found.d.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
• /
• pp.602-606
• /
• 2003

Silicon has been developed as an alternate anode material for lithium secondary batteries. A simple approach to improve the electrical contact of silicon powder has described. Carbon-coated and silver-coated silicon have been prepared by chemical vapor deposition and electroless plating respectively. Assembled cells, which consisted of surface modified silicon, lithium foil and $Li^+$ contained organic electrolyte, have been studied using electrochemical methods. Carbon-coated silicon was improved in the electrochemical performance such as reversibility and resistance compared to surface-unmodified silicon.

• 분석과학
• /
• 제13권6호
• /
• pp.705-711
• /
• 2000

리튬 이차전지용 부극 재료로 페놀 수지로 부터 유도된 boron을 doping한 polyacene에 구조적 특성, 표면 특성 및 전기적 특성을 연구하였다. Polyacene탄소질에 boron의 함유량을 각각 5%, 10%, 15%, 20% 첨가하여 특성화하였다. X-선 회절 결과에 따르면, 이들 시료들은 대표적인 무정형 탄소의 회절형태를 나타내었다. 표면 상태는 반구형의 표면상태를 가지고 있음을 SEM 결과로부터 알 수 있었다. 전지의 이온과 전자전달효과를 알아보기 위한 전기 화학적 충전/방전 특성과 임피던스 측정의 결과에 의하면, 10%와 15% boron이 첨가된 시료는 다소 우수한 특성을 나타내고 있다.

• 한국재료학회지
• /
• 제8권4호
• /
• pp.323-327
• /
• 1998

재충전이 가능한 Li/PEO-$LiClO_{4}$-PC/$LIMn_2O_4$구조의 전고상 전지를 제작하였다. $LIMn_2O_4$박막은 RF 마그네트론 스퍼터링 법으로 제작하였으며, $750^{\circ}C$ 부근에서의 급속열처리를 통하여 스피넬 상으로 결정화시킬 수 있었다. 상온 충.방전 시험을 행한 결과, 평균 전압 4V(vs. Li)의 평탄한 방전 전압과 우수한 재충전 능력을 나타내었다.