Browse > Article
http://dx.doi.org/10.5369/JSST.2018.27.1.36

Optical and Electrochemical Properties of LiNiPO4 Thin Film for Transparent Thin Film Lithium Secondary Battery  

Lee, HyunSeok (Center for Electronic Materials, Korea Institute of Science and Technology)
Parmar, Narendra S. (Center for Electronic Materials, Korea Institute of Science and Technology)
Kim, Kwang-Bum (Department of Material science and Engineering, Yonsei University)
Choi, Ji-Won (Center for Electronic Materials, Korea Institute of Science and Technology)
Publication Information
Journal of Sensor Science and Technology / v.27, no.1, 2018 , pp. 36-39 More about this Journal
Abstract
Transparent olivine $LiNiPO_4$ thin films on sapphire substrates were fabricated by radio frequency (RF) magnetron sputtering. The X-ray diffraction patterns show these thin films have the phase of $LiNiPO_4$ with an ordered olivine structure indexed to the orthorhombic Pmna space group. $LiNiPO_4$ thin films deposited on sapphire substrates exhibit transmittance of about 83 %. It was confirmed that the $LiNiPO_4$ thin film exhibits a high potential of 5 V-class.
Keywords
Transparent; Thin film battery; Olivine structure; $LiNiPO_4$;
Citations & Related Records
연도 인용수 순위
  • Reference
1 P. Gorrn, M. Sander, J. Meyer, M. Kroger, E. Becker, H.H. Johannes, W. Kowalsky, and T. Riedl, "Towards seethrough displays: Fully transparent thin-film transistors driving transparent organic light-emitting diodes", Adv. Mater., Vol. 18(6), pp. 738-741, 2006.   DOI
2 S.H. Ju, J. Li, J. Liu, P.C. Chen, Y.G. Ha, F. Ishikawa, H. Chang, C.W. Zhou, A. Facchetti, D. B. Janes, and T. J. Marks, "Transparent active matrix organic light-emitting diode displays driven by nanowire transistor circuitry", Nano Lett., Vol. 8(4), pp. 997-1004, 2008.   DOI
3 S.H. Ko Park, C.S. Hwang, J.I. Lee, S.M. Chung, Y.S. Yang, L.M. Do, and H.Y. Chu, "Transparent ZnO thin film transistor array for the application of transparent AMOLED display", SID Symp. Dig. Tech. Pap., Vol. 37, pp. 25- 28, 2012.
4 Y. Yang, S. Jeong, L. Hu, H. Wu, S. W. Lee, and Y. Cui, "Transparent lithium-ion batteries", PNAS, Vol. 108(32), pp. 13013-13018, 2011.   DOI
5 Y. Xu, W.Y. Ching, and Y. Chiang, "Comparative studies of the electronic structure of $LiFePO_4$, $FePO_4$, $Li_3PO_4$, LiMn- PO4, $LiCoPO_4$, and $LiNiPO_4$", J. Appl. Phys., Vol. 95(11), pp. 6583-6585, 2004.   DOI
6 A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, "Phospho-olivines as positive-electrode materials for rechargeable lithium batteries", J. Electrochem. Soc., Vol. 144(4), pp. 1188-1194, 1997.   DOI
7 B. Zhang, X. Wang, H. Li, X. Huang, "Electrochemical performances of $LiFe_{1−x}Mn_xPO_4$ with high Mn content", J. Power Sources, Vol. 196(16), pp. 6992-6996, 2011.   DOI
8 J. Wolfenstine, and J. Allen, "$Ni^{3+}/Ni^2$+ redox potential in $LiNiPO_4$", J. power sources, Vol. 142(1), pp. 389-390, 2005.   DOI
9 M.R. Roberts, G. Vitins, G. Denuault, and J.R. Owena, "High throughput electrochemical observation of structural phase changes in $LiFe_{1−x}Mn_xPO_4$ during charge and discharge", J. Electrochem. Soc., Vol. 154(4), pp. A381-A386, 2010.   DOI
10 G. Kobayashi, A. Yamada, S. Nishimura, R. Kanno, Y. Kobayashi, S. Seki, Y. Ohno, and H. Miyashiro, "Shift of redox potential and kinetics in $Li_x(MnyFe_{1−y})PO_4$", Power Sources, Vol. 189(1), pp. 397-401, 2009.   DOI
11 M. Piana, M. Arrabito, S. Bodoardo, A. D'Epifanio, D. Satolli, F. Croce and B. Scrosati, "Characterization of Phospho- olivines as Materials for Li-ion Cell Cathodes", Ionics, Vol. 8(1), pp. 17-26, 2002   DOI
12 M. Minakshia, P. Singh, D. Appadoo, D. E. Martin, "Synthesis and characterization of olivine LiNiPO4 for aqueous rechargeable battery", Electrochim. Acta, Vol. 56(11), pp. 4356-4360, 2011   DOI
13 S.P. Ong, V.L. Chevrier, and G. Ceder, "Comparison of small polaron migration and phase separation in olivine $LiMnPO_4$ and $LiFePO_4$ using hybrid density functional theory", Phys. Rev. B, Vol. 83(7), pp. 7-15, 2011.
14 L. Wang, Y. Huang, R. Jiang, D. Jia, "Preparation and characterization of nano-sized $LiFePO_4$ by low heating solidstate coordination method and microwave heating", Electrochim. Acta, Vol. 52(24), pp. 6778-6783, 2007.   DOI
15 X. Rui, X. Zhao, Z. Lu, H. Tan, D. Sim, H.H. Hng, R. Yazami, T.M. Lim, and Q. Yan, "Olivine-type nanosheets for lithium ion battery cathodes", ACS Nano, Vol. 7(6), pp. 5637-5646, 2013.   DOI
16 Y. Ge, X. Yan, J. Liu, X. Zhang, J. Wang, X. He, R. Wang, H. Xie, "An optimized Ni doped $LiFePO_4$/C nanocomposite with excellent rate performance", Electrochim. Acta, Vol. 55(20), pp. 5886-5890, 2010.   DOI
17 J. Yang, and J.J. Xu, "Synthesis and characterization of carbon- coated lithium transition metal phosphates $LiMPO_4$ (M = Fe, Mn, Co, Ni) prepared via a nonaqueous sol-gel route", J. Electrochem. Soc., Vol. 153(4), pp. A716-A723, 2006.   DOI