• Title/Summary/Keyword: 리놀레산

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Lipids and Fatty Acid Composition of Barley Grain (보리의 지방질 성분에 관한 연구)

  • Shin, Hyo-Sun;Gray, J. Ian
    • Korean Journal of Food Science and Technology
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    • v.15 no.2
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    • pp.195-201
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    • 1983
  • Lipids isolated from three barley samples were identified and quantitated by column, thin layer and gas liquid chromatographic techniques. These lipids were shown to consist of 69.3-73.1% neutral lipids, 9.6-16.5% glycolipids, and 14.2-17.9% phospholipids. Among the neutral lipids, triglycerides were predominant (54.2 to 55.7%) with smaller amounts of 1,2-diglycerides, 1,3-diglycerides, free sterols, free fatty acids, steryl esters, and three unknown being present. Among the glycolipids, digalactosyl diglycerides (31.3 to 33.2%) and monogalactosyl diglycerides (26.2 to 29.6%) were the most abundant. Esterified steryl glycosides, steryl glycosides, cerebrosides, sulfolipids, and an unknown component were present as minor components. Of the phosopholipids, phosphatidyl cholines and serines, lysophosphatidyl cholines, and phosphatidyl ethanolamines were the major components, comprising over 80% of this class. The major fatty acids in the total and the three lipid classes were palmitic, oleic, linoleic and linolenic acids. However, the neutral lipids fraction contained more oleic acid than other lipid fractions, and the phospholipids fraction contained more palmitic acid than the other lipid fractions.

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The Comparison in the Physicochemical Properties of Sesame Seeds by Producing Areas (산지에 따른 참깨종자의 이화학적 특성 비교)

  • Lee, Min-Jung;Kim, Ki-Hong
    • Applied Biological Chemistry
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    • v.48 no.2
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    • pp.128-131
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    • 2005
  • Sesame seed is known as a good nutritional source containing high oil (51%) and protein (20%). Sesame oil contains a very high oxidative stability compared to other vegetable oils. To obtain basic information for quality evaluation, imported and domestic sesame seeds were investigated to measure general components (ash, protein, moisture and oil), fatty acid composition and lignan content. Although the protein contents were the highest in domestic sesame seeds, yet the lipid contents were the highest in imported sesame seeds. Unsaturated fatty acids such as oleic acid and linoleic acids were the highest in the domestic sesame seeds. Lignan contents, the most important component known as antioxidant, were significantly higher in domestic sesame seeds than other imported sesame seeds. These results suggest that domestic sesame seed may have the best quality in terms of the functional components.

Comparison of Autoxidative Stability and Minor Compounds in Oils Extracted from Bran and Germ of Keumkang Wheat and Dark Northern Spring Wheat (금강밀과 dark northern spring밀의 기울과 배아에서 추출한 기름의 자동산화 안정성 및 미량성분 비교)

  • Choi, Hyun-Ki;Choe, Eun-Ok
    • Korean Journal of Food Science and Technology
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    • v.41 no.6
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    • pp.628-635
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    • 2009
  • Autoxidative stability of wheat bran and germ oil extracted from Keumkang wheat (WBG-K) or Dark Northern Spring wheat (WBG-DNS) at $50^{\circ}C$ in the dark was compared by peroxide values (POV) and fatty acid composition by gas chromatography. Changes of minor compounds were monitored by HPLC. WBG-K showed significantly higher linoleic but lower oleic acid content than WBG-DNS. WBG-DNS contained more phospholipids but less tocopherols and carotenoids than WBG-K. POV of oils was increased during storage, with no significant difference in the oxidation rates between two oils. Tocopherols, carotenoids, and phospholipids in both oils were degraded during the autoxidation. Total phospholipids content showed the highest correlation with the degree of oxidation in WBG oils. The results clearly showed that both fatty acid composition and contents of tocopherols, carotenoids, and phospholipids co-affected the autoxidation of WBG oil.

Production of Fungal Lipid (Part IV) Effect of Cultural Conditions on the Growth and Lipid Accumulation of Mucor plumbeus (곰팡이 유지 생산에 관한 연구 (제 4 보) 배양조건이 Mucor Plumbeus의 유지 생산에 미치는 영향에 대하여)

  • 유진영;이형춘;신동화;서기봉
    • Microbiology and Biotechnology Letters
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    • v.10 no.2
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    • pp.87-93
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    • 1982
  • The cultural conditions of Mucor plumbeus FRI 0007 were investigated for the maximum production of felt and lipid. It was found that the lower the pH and the higher the incubation temperature, the higher accumulation of the felt and lipid. Shake culture rendered higher lipid accumulation and lower felt accumulation than static culture. Maximum production of felt and lipid content were 47.8 g/$\ell$ and 50.73%, respectively, when the organisms were static-cultured at a temperature of 37$^{\circ}C$ and pH of 3.5 for 25 days latroscan thinchrographic analysis showed that the higher amount of triglyceride was obtained when static-cultured at a low pH. Fatty acid composition of the microbial lipid was affected by the incubation temperature, types of nitrogen source and speed of agitation: lower degree of saturation was observed as the incubation temperature decreased and the speed of agitation increased. Fatty acids of monoglyceride and diglyceride were mainly palmitic and oleic acids and those of triglycerides were mainly palmitic, oleic acids.

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Fractionation and Quantitative Analysis of Lipid Components in Korean Yam (Dioscorea) Tubers (한국산 마의 지질 성분의 분리 및 분석)

  • Chung, Hae-Young
    • Applied Biological Chemistry
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    • v.37 no.6
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    • pp.509-515
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    • 1994
  • Using the lipids extracted from Korean yam(Dioscorea) tubers, D. batatas, D. aimadoimo and D. japonica, fractionation and identification of lipid components and their fatty acid compositions were analysed. Lipid contents determined by Folch's method in D. batatas, D. aimadoimo and D. japonica were 11.0 mg/g, 11.4 mg/g and 6.6 mg/g, respectively. Lipids extracted were fractionated into neutral lipid, glycolipid and phospholipid by silicic acid column chromatography. The content of neutral lipid was over about 60% in lipid. Neutral lipid was composed of sterol ester, triglyceride, 1,3-diglyceride, 1,2-diglyceride and monoglyceride. Main constituents of glycolipid were acylsterylglycoside, monogalactosyldiglyceride, sterylglycoside, digalactosyldiglyceride and sulfolipid, and phospholipid contained phosphatidylethanolamine, phosphatidylcholine and phosphatidylinositol. The fatty acids of the total lipid and its three lipid fractions were analyzed by GC. The major fatty acids were palmitic and linoleic acids. Content of the saturated fatty acids was less than that of the unsaturated fatty acids.

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Biological Activities of a Korean Traditional Prescription, Nogyongdaebotang (전통 한약탕제인 녹용대보탕의 생리활성 효과)

  • 이경애;정혜영
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.1
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    • pp.28-33
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    • 2004
  • This study was performed to examine in vitro biological activities such as antioxidative, nitrite scavenging effect, tyrosinase inhibitory effect and antithrombotic activity of a Korean traditional prescription, Nogyong-daebotang, composed of oriental medical herbs and antler, nourishing the blood, helthiness, strengthening of vital power and promotion of growth. The concentration of total phenolic compounds of the prescription sample was 151.3$\pm$2.6 mg%. The electron donating abilities (EDA) by reduction of 2.2'-diphenyl-1-picrylhydrazyl (DPPH) was 80.9%, inhibition rate of lipid peroxidation in thiocyanate method used linoleic acid was 88.1%. Nitrite scavenging effects of the sample were more than 70% at acidic pH, but it was pH dependent, showing the highest at pH 1.2 and the lowest at pH 6.0. Inhibition rate against tyrosinase of the sample was above 80%. Platelet aggregation induced by ADP (adenosine-5'-diphosphate) was inhibited up to 30% and the inhibitory effect was dependent on concentration of the sample.

Effect of Fatty Acid on the Membrane Fluidity of Liposomes (지방산 첨가가 리포좀 유동성에 미치는 영향에 관한 연구)

  • Lee, JinSun;Chi, Gyeong-Yup;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.177-185
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    • 2017
  • In the present work, the interaction of fatty acid with vesicle membrane of phospholipids was investigated using 3 different kinds of fatty acids such as stearic acid (SA), oleic acid (OA) and linoleic acid (LA). Basically, the same trend has been found in 3 fatty acid systems. The addition of fatty acid produced a close packing of liposome due to the penetration of fatty acid molecules into liposome vesicles, which resulted in a decrease in size and an increase in zeta potential of liposome. However, excessive addition of fatty acid produced a transition from liposomes to aggregates of lipid particles having polymorphic structure. The membrane fluidity, characterized by measuring membrane deformability and fluorescence anisotropy ratio of liposomes, was in good agreement with measurement results of transmission electron microscopy (TEM) and particle size. The minimum size and closest packing of liposome with SA, OA and LA were found when the molar ratios of fatty acid to lecithin were 0.70, 0.50, and 0.25 respectively.

Antioxidative Characteristics of Melanoidin Related Products Fractionated from Fermented Soybean Sauce (양조간장에서 분리한 멜라노이딘 관련물질의 항산화 작용 특성)

  • 최홍식;이정수;이창용
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.5
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    • pp.570-575
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    • 1993
  • Antioxidative characteristics of melanoidin related products(MRPs) fractionated from fermented soybean sauce were studied during the oxidation process of model systems. MRPs were prepared from soybean sauce fermented for 6 months after inoculation Aspergillus oryzae by the fractionation through the Sephadex G-10 column and the freeze drying of collected fractions. MRPs inhibited the formation of peroxides during the oxidation of linoleic acids mixture in ethanolic phosphate buffer solution at $50^{\circ}C$ with the increasing tendency by their concentration in reaction systems. MRPs had hydrogen doner properties during the reaction with ${\alpha},\;{\alpha}'-diphenyl-{\beta}-picrylhydrazyl$ and also MRPs inhibited the iron and lipoxygenase catalytic oxidation. MRPs were found to be fairly stable with no loss of antioxidative effect after storage at $50^{\circ}C$ for 15days.

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Comparison of Physicochemical Characteristics of Alkali Refined and Esterified Rice Bran Oils (알칼리 정제(精製)와 에스테르화에 의한 미강유의 이화학적(理化學的) 특성(特性)의 비교(比較))

  • Kim, Hyun-Ku;Shin, Dong-Hwa;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.17 no.3
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    • pp.175-179
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    • 1985
  • The alkali refined rice bran oil (ARBO) and the esterified rice bran oil (ERBO) with glycerol were analyzed for their physicochemical charateristics and the compositions. Specific gravity, refractive index and yellowness of ERBO was higher than ARBO but smoking point was 60-$80^{\circ}C$ higher than ERBO. The free fatty acid content was 0.05% a ARBO and 0.88-1.36% ERBO. The wax was not detected in ARBO but the soft and hard waxes were detected in ERBO. The lipids were composed of 98-99% neutral lipid, 0.2-0.5% glycolipid and 0.1-0.5% of phospholipid in all samples. The triglyceride content of neutral lipid was 96.3% ARBO and 93.0-94.1% ERBO, and its monoglyceride content was 0.11% ARBO and 0.39-0.69% ERBO. The major fatty acid composition of samples were 41-42% oleic, 36-40% linoleic and 17-18% of palmitic acid.

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Antioxidative Effect of Soybean Sauce on the Lipid Oxidation of Cooked Meat (우육지방질(牛肉脂肪質)의 산화(酸化)에 미치는 간장의 항산화작용(抗酸化作用)에 관한 연구(硏究))

  • Moon, Gab-Soon;Cheigh, Hong-Sik
    • Korean Journal of Food Science and Technology
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    • v.18 no.4
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    • pp.313-318
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    • 1986
  • Four model systems of ground cooked meat (GCM), GCM-water (W), GCM-brine (B) and GCM-soybean sauce (S) were prepared and stored at $6^{\circ}C$ for 5 weeks. The oxidative behavior of lipids in the systems and the antioxidative effects of soybean sauce on the lipid oxidation were studied during the period of storage.Tiobarbituric acid values and peroxide values of the systems of GCM, GCM-B and GCM-W were increased significantly with the storage time, however, those values of GCM-S were hardly changed during the time of t u·eeks storage. The decreases in the contents of dienoic/polyenoic fatty acids of neutral or phospholipid fraction in GCM-S system were found to be the lowest among the systems during the 5 weeks storage. And also the least development of rancid flavor evaluated by sensory score during storage were observed in GCM-S system. These results are suggested that soybean sauce in the systems plays an important role as an antioxidative material on the lipid oxidation.

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