• Title/Summary/Keyword: 레올로지

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A Study on the Factors Affecting the High Fluid Mortar Containing Ground Granulated Blast-furnace Slag (고로슬래그 미분말을 함유한 고유동 모르터의 유동성상에 미치는 영향 요인에 관한 연구)

  • Kim, Jae-Hun;Yoon, Sang-Chun;Jee, Nam-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.4
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    • pp.145-152
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    • 2002
  • High fluid concrete unlike OPC concrete is made with various material, and the phase of fresh concrete is considerably different. In order to understand fluidity phase and mix properties of high fluid concrete, concrete is required to access as suspension structure which consists of aggregate and paste. The focus of this paper is to analyze the test results and quantify the effect of mix proportions of mortar and fineness modulus of sand on the properties of fresh mortar. The effect of water-binder ratio. sand-binder ration. contents of ggbs (by mass of total cementitious materials). and various contents of water reducing agent on the yield stress and plastic viscosity of the mix is studied. Based on the experimental results, the fellowing conclusions can be drawn: (1) The mixing time needed for high fluid mortar was approximately two times more than that of ordinary portland mortar. (2) The fluidity phase of mortar could be explained by yield stress of mix and the fluidity of mortar. (3) As the content of ggbs increased, yield stress of mortar was decreased and plastic viscosity of it was increased. (4) For the high fluid mortar, it was appeared that sand-binder ratio should be below 1.5.

Performance Evaluation of Admixture for Durability Improvement of Shielding Materials Used Waste Glass as Fine Aggregate (폐유리를 잔골재로 사용한 차폐채움재의 내구성 개선을 위한 혼화재료의 성능평가)

  • Hwang, Byoung-Il;Kim, Hyo-Jung;Song, Yong-Soon;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.20-27
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    • 2019
  • Compared to the development and manufacturing technology of electronic goods, the development of waste glass recycling technology is relatively insufficient, leading to the acceleration of waste of resources and environmental pollution. Although waste glass recycling technology is being actively developed overseas, waste glass recycling technology is insufficient in Korea, leading to the illegal dumping or burial of waste glass. Waste glass has been confirmed to have pozzolan reaction potential when having hydration reaction with cement. Waste glass is also reported to be effective in reducing bleeding and inhibiting the development of hydration heat by improving the physical properties of concrete and the rheology properties of fresh concrete. Therefore, this paper analyzed the strength characteristics and the effect of alkalic-silica reaction on the expansion of shielding concrete that used waste glass as fine aggregate. Where, suitable admixture materials were used as a measure to suppress the expansion.

Buildability for Concrete 3D Printing According to Printing Time Gap (콘크리트 3D프린팅의 적층시간 간격에 따른 적층 성능)

  • Lee, Yoon Jung;Song, Jin-Soo;Choi, Seung-Ho;Kim, Kang Su
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.131-136
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    • 2019
  • Buildability of fresh concrete, a key element of Concrete 3D printing, is the ability to build filaments at a desirable height without excessive deformation or collapse. Buildability is closely related to yield stress, and the higher the yield stress, the better. Also, the shear stress of fresh concrete increases as it hardens over the time after extruded, and consequently the buildability increases. Therefore, in concrete 3D printing, proper time gaps between printed layers (Printing Time Gap, PTG) are required to ensure the buildability of fresh concrete. As the PTG increases, the buildability increases; however, an excessive PTG reduces the bond performance between the printed layers, and the extrudability can be lowered as the printing time increases. In this research, therefore, 3D printing experiments were conducted with the variable of PTG to examine the buildability of 100 MPa-high strength concrete. In addition, a pseudo-layer loading method was applied to simulate the buildability test for 3D concrete printing and its applicability was examined.

Influence of Various Replacing Ratios of SCMs on Properties of High Fluidity Concrete (광물질 혼화재의 치환율 변화가 고유동 콘크리트의 특성에 미치는 영향)

  • Han, In-Deok
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.12
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    • pp.165-172
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    • 2019
  • The aim of the research is to evaluate the influence of various replacing ratios of supplementary cementitious materials(SCMs) such as fly ash(FA), blast furnace slag(BS), and both FA and BS on general properties including segregation resistance as a powder based high fluidity concrete of normal strength grade with water-to-cement ratio 0.40. Specifically, by replacing the SCMs with low density powders, it was assessed that the decreased segregation resistance due to the decreased viscosity by J-ring test. As a result of the experiment, from the general test, the mixtures with SCMs showed increased segregation resistance by increased viscosity as the references, while some segregation was shown from J-ring test due to the decreased density of fresh state mixture related with the capacity of delivering coarse aggregate.

Rheological Properties of Chitosan Manufactured from the Pens of Domestic (Todarodes pacificus) and Foreign (Ommastrephes bartrami) Squid (연안산 및 남미산 오징어 연골로부터 제조한 Chitosan의 레올로지 특성)

  • KIM Sang-Moo;PARK Seong-Min;CHOI Hyeon-Mee;LEE Keun-Tai
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.859-867
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    • 1997
  • In order to utilize the processing wastes of squid, chitosans were manufactured from the pens of domestic squid, Todarbdes pacificus and foreign squid, Ommastrephes bartrami and then, its rheological properties were studied. The amounts of nitrogen and minerals of the domestic squid pens were $11.4\%\;and\;0.1\%$ respectively, whereas those of its chitosan were $7.5\%\;and\;0.2\%$. In case of foreign squid pen and chitosan, the amounts of nitrogen and minerals were $12.1\%,\;0.8\%\;and\;7.8\%,\;0.2\%$ respectively. Intrinsic viscosity $([\eta]) $ of domestic and foreign squid pen chitosans were decreased with increasing pH from 3.4 to 5.4 which might be due to the reduced repulsion in inter- of intra- chitosan molecules. Intrinsic viscosity of the domestic and foreign squid pen chitosans were decreased with increasing NaCl concentration thus indicated that the domestic and foreign squid pen chitosans were polyelectrolyte molecules and stiffness of squid pen thitosans were 0.11 similar to that of k-carrageenan. Flow type of squid pen chitosan solutions were pseudoplastic fluids without yield stress by the viscosity measurement. But the squid pen chitosan solutions showed newtonian fluid up to $0.15\~0.24\%$ concentration for domestic and $0.21\~0.24\%$ concentration for foreign at $10\~50\%$. Concentration dependence of consistency index in infinitive dilute domain (Kc) were higher in the dilute domain than entangled domain. Activation energies (Ea) of the squid pen chitosans were 3.7, 6.3, 3.6, 4.0 and 4.1 Kcal/g moi for domestic and 3.2, 3.1, 3.4, 3.8 and 3.6 Kcal/g mol for foreign at 0.1, 0.15, 0.25, 0.35 and $0.5\%$, respectively.

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Rheological Properties of Antiphlamine-S® Lotion (안티푸라민-에스® 로션의 레올로지 특성 연구)

  • Kuk, Hoa-Youn;Song, Ki-Won
    • Journal of Pharmaceutical Investigation
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    • v.39 no.3
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    • pp.185-199
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    • 2009
  • Using a strain-controlled rheometer [Advanced Rheometric Expansion System (ARES)], the steady shear flow properties and the dynamic viscoelastic properties of $Antiphlamine-S^{(R)}$ lotion have been measured at $20^{\circ}C$ (storage temperature) and $37^{\circ}C$ (body temperature). In this article, the temperature dependence of the linear viscoelastic behavior was firstly reported from the experimental data obtained from a temperature-sweep test. The steady shear flow behavior was secondly reported and then the effect of shear rate on this behavior was discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters. The angular frequency dependence of the linear viscoelastic behavior was nextly explained and quantitatively predicted using a fractional derivative model. Finally, the strain amplitude dependence of the dynamic viscoelastic behavior was discussed in full to elucidate a nonlinear rheological behavior in large amplitude oscillatory shear flow fields. Main findings obtained from this study can be summarized as follows : (1) The linear viscoelastic behavior is almostly independent of temperature over a temperature range of $15{\sim}40^{circ}C$. (2) The steady shear viscosity is sharply decreased as an increase in shear rate, demonstrating a pronounced Non-Newtonian shear-thinning flow behavior. (3) The shear stress tends to approach a limiting constant value as a decrease in shear rate, exhibiting an existence of a yield stress. (4) The Herschel-Bulkley, Mizrahi-Berk and Heinz-Casson models are all applicable and have an equivalent validity to quantitatively describe the steady shear flow behavior of $Antiphlamine-S^{(R)}$ lotion whereas both the Bingham and Casson models do not give a good applicability. (5) In small amplitude oscillatory shear flow fields, the storage modulus is always greater than the loss modulus over an entire range of angular frequencies tested and both moduli show a slight dependence on angular frequency. This means that the linear viscoelastic behavior of $Antiphlamine-S^{(R)}$ lotion is dominated by an elastic nature rather than a viscous feature and that a gel-like structure is present in this system. (6) In large amplitude oscillatory shear flow fields, the storage modulus shows a nonlinear strain-thinning behavior at strain amplitude range larger than 10 % while the loss modulus exhibits a weak strain-overshoot behavior up to a strain amplitude of 50 % beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (7) At sufficiently large strain amplitude range (${\gamma}_0$>100 %), the loss modulus is found to be greater than the storage modulus, indicating that a viscous property becomes superior to an elastic character in large shear deformations.

Feasibility Analysis of Wasted Limestone Powder as a Viscosity Reducing Material for Cement Based Materials (시멘트 계열 재료의 점도 저하용 혼화재료로서 폐석회석 미분말의 사용 가능성 분석)

  • Lee, Hyang-Seon;Jeon, Jong-Un;Son, Bae-Geun;Han, Dongyeop
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.123-129
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    • 2018
  • The aim of the research is providing a fundamental idea of reducing viscosity of cement based materials by replacing powder based material. With developing concrete technology, high performance concrete with high solid volume fraction has been used widely. Under the conditions of the high solid volume fraction due to the low w/c and replacement of SCMs, decreased fluidity is one of the critical problem, and thus plasticizer has been used to improve fluidity of the mixture. However, in rheological aspect, the fluidity of cement based materials can be defined with yield stress and viscosity, and using plasticizer only decreases yield stress without least controlling on viscosity. Therefore, based on the idea of Krieger-Dougherty model, a feasibility of wasted limestone powder from cement manufacturing process was used to decrease the viscosity of the mixture by replacing cement powder. According to a series of experiment, by replacing wasted limestone powder solely, there was a possibility of reducing viscosity was observed. Thus, in this research scope, it is considered to contribute on providing a fundamental idea of reducing viscosity with powder replacement and it is expected to contribute on further research using various conditions of replacing powders for reducing viscosity of cementitious materials.

Optimum Mix Proportions of In-fill Slurry for High Performance Steel Fiber Reinforced Cementitious Composite (초고성능 강섬유보강 시멘트 복합체의 충전슬러리 최적배합 도출)

  • Kim, Seung-Won;Park, Cheol-Woo;Kim, Seong-Wook;Cho, Hyun-Myung;Jeon, Sang-Pyo;Ju, Min-Kwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.3
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    • pp.196-201
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    • 2014
  • As political circumstances in oversea countries and Korea varies, the risk of vulnerability from unexpected extreme loading conditions, such as explosions or extreme impacts, also increased. In addition, construction companies in Korea recently have taken chances of overseas expansion to countries where their domestic situations are not in rest. Therefore, the resistance of construction materials for blast or impact loading become taking more consideration from engineering field. This study is a part of the research to develop a high performance fiber reinforced cementitious composite materials with high volume steel fibers and primary purpose of this study is to find an optimum mix proportions of in-fill slurry. In order to accomplish the tasks this study performed experimental investigations on the slurry for consistency, compressive strength, flowability, J-penetration, bleeding and rheology properties as well as mechanical properties, compressive and flexural strength, with respect to different mix proportions.

Quality Characteristics of White Pan Bread Added with Perilla Leaf Powder (들깻잎 분말을 첨가한 식빵반죽의 레올로지 및 품질 특성에 관한 연구)

  • Choi, Sang-Ho
    • Culinary science and hospitality research
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    • v.17 no.3
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    • pp.172-180
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    • 2011
  • This study explores the quality characteristics of white pan bread added with perilla leaf powder, and the results are as follows. The WRC(water retention capacity) of PLP (perilla leaf powder) added to the bread dough increased as the addition increased, and the initiation temperature during the rapid visco analysis (RVA) increased with more additions, showing significant differences. The highest and the lowest viscosity of the sample decreased as the powder added increased. The brightness(L value) of the bread without the powder was the highest, and the redness (a value) and the yellowness (b value) showed significant differences among the samples. Hardness increased showing significant differences among the samples as the powder added increased Chewiness was the highest but preference value was the lowest in the sample with 7% of the powder. The lowest score was shown in the color of the sample with the most PLP added. Flavor was the lowest of 4.93 in the comparison sample without the leaf powder added while bitter taste scored the highest of 5.21 in the sample of 3% powder added. It was also the highest in overall acceptance while the sample with the most powder showed the lowest of 4.03. From these results, it can be said that the preference of bread with PLP seems to decrease when more than 5% of PLP is added.

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Rheological Behavior of Semi-Solid Ointment Base (Vaseline) in Steady Shear Flow Fields (정상전단유동장에서 반고형 연고기제(바셀린)의 레올로지 거동)

  • Song, Ki-Won;Kim, Yoon-Jeong;Lee, Chi-Ho
    • Journal of Pharmaceutical Investigation
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    • v.37 no.3
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    • pp.137-148
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    • 2007
  • Using a strain-controlled rheometer [Rheometrics Dynamic Analyzer (RDA II)], the steady shear flow properties of a semi-solid ointment base (vaseline) have been measured over a wide range of shear rates at temperature range of $25{\sim}60^{\circ}C$. In this article, the steady shear flow properties (shear stress, steady shear viscosity and yield stress) were reported from the experimentally obtained data and the effects of shear rate as well as temperature on these properties were discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters (yield stress, consistency index and flow behavior index). Main findings obtained from this study can be summarized as follows : (1) At temperature range lower than $40^{\circ}C$, vaseline is regarded as a viscoplastic material having a finite magnitude of yield stress and its flow behavior beyond a yield stress shows a shear-thinning (or pseudo-plastic) feature, indicating a decrease in steady shear viscosity as an increase in shear rate. At this temperature range, the flow curve of vaseline has two inflection points and the first inflection point occurring at relatively lower shear rate corresponds to a static yield stress. The static yield stress of vaseline is decreased with increasing temperature and takes place at a lower shear rate, due to a progressive breakdown of three dimensional network structure. (2) At temperature range higher than $45^{\circ}C$, vaseline becomes a viscous liquid with no yield stress and its flow character exhibits a Newtonian behavior, demonstrating a constant steady shear viscosity regardless of an increase in shear rate. With increasing temperature, vaseline begins to show a Newtonian behavior at a lower shear rate range, indicating that the microcrystalline structure is completely destroyed due to a synergic effect of high temperature and shear deformation. (3) Over a whole range of temperatures tested, the Herschel-Bulkley, Mizrahi-Berk, and Heinz-Casson models are all applicable and have an almostly equivalent ability to quantitatively describe the steady shear flow behavior of vaseline, whereas the Bingham, Casson,and Vocadlo models do not give a good ability.