• Title/Summary/Keyword: 디젤 배출 질소산화물

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NFRI 연구활동 - 녹색성장의 시대 플라즈마 응용기술로 열어간다 - 대기압 플라즈마를 이용한 디젤 배기가스 처리장치 개발 -

  • 국가핵융합연구소
    • 핵융합뉴스레터
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    • s.42
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    • pp.10-11
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    • 2009
  • 지구온난화와 환경오염을 줄일 수 있는 하나의 방안으로 고연비의 경유를 사용하는 운송수단이 각광을 받아왔으나, 입자상 오염물질 및 질소산화물 배출량의 증가 등 경유 차량의 이용에도 문제점이 드러나고 있다. 주요 선진국들이 이와 관련한 규제를 강화함에따라 이에 대응할 수 있는 기술 개발이 요구되는 가운데 녹색 기술 개발을 이끄는 국가핵융합연구소는 플라즈마를 활용한 경유 차량의 후처리장치 개발을 추진하고 있다.

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A Study of the Reduction of Diesel-Engine Emissions for Off-Road Vehicles (비도로 차량용 디젤엔진의 배기가스 저감에 관한 연구)

  • Cho, Gyu-Baek;Kim, Hong-Suk;Kang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.6
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    • pp.577-583
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    • 2011
  • To meet the requirements of the Tier 4 interim regulations for off-road vehicles, emissions of particulate matter (PM) and nitrogen oxides (NOx) must be reduced by 95% and 30%, respectively, compared to current regulations. In this research, both the DPF and HPL EGR systems were investigated, with the aim of decreasing the PM and NOx emissions of a 56-kW off-road vehicle. The results of the experiments show that the DOC-DPF system is very useful for reducing PM emissions. It is also found that the back pressure is acceptable, and the rate of power loss is less than 5%. By applying the HPL EGR system to the diesel engine, the NOx emissions under low- and middle-load conditions are reduced effectively because of the high differential pressure between the turbocharger inlet and the intake manifold. The NOx emissions can be decreased by increasing the EGR rate, but total hydrocarbon (THC) emission increases because of the increased fuel consumption needed to compensate for the power loss caused by EGR and DPF.

Regulation on Sulphur Content in Fuel Oil for Marine Diesel Engine (선박 디젤기관 연료유 황 함량 규제)

  • Son, J.R.;Kang, C.M.;Kwon, O.S.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.115-116
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    • 2006
  • 보다 깨끗한 환경에서 살고 싶어 하는 인류의 욕구가 육상의 대기 배출물뿐만 아니라 선박까지도 보다 깨끗한 배기를 요구하기에 이르렀다. 이러한 요구에 부응하여 IMO(국제해사기구)뿐만 아니라 EU(유럽연합)과 미국 등에서 규제를 이미 시작하였거나 시작할 예정이다. 또한 많은 선급에서도 약 10년 전부터 자발적인 규칙을 도입해오고 있다. 그리고 스웨덴은 인센티브제를 오래 전부터 적용해오고 있다. 이러한 규제, 선급 규칙 및 인센티브제는 질소산화물, 황산화물 및 입자상물질 배출에 제한을 가하는데, 황산화물 및 입자상물질 배출 제한은 간접적으로 연료유에 함유되어 있는 황 함량 규제를 통하여 하고 있거나 하려고 한다. 여기에 이러한 규제, 선급 규칙 및 인센티브제에서 가하고 있거나 가할 예정인 선박 디젤기관 연료유의 황 함량 규제에 대하여 간략하게 소개한다.

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Selective Catalytic Reduction (SCR) Technology Trend for the Removal of Nitrogen Oxide from Ship Flue Gas (선박 배가스 내 질소산화물 제거를 위한 선택적촉매환원법(SCR) 기술동향)

  • Won, Jong Min;Hong, Sung Chang
    • Prospectives of Industrial Chemistry
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    • v.22 no.5
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    • pp.25-40
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    • 2019
  • 전 세계적으로 환경문제를 해결하기 위한 방안으로 환경규제를 강화시키며 특히 다양한 대기오염 물질 중 최근 큰 이슈인 초미세먼지 저감을 위해 전구물질로 알려진 질소산화물을 제어하기 위한 다양한 기술개발이 가속화되고 있다. 특히, 다양한 처리기술 중에 기술적·경제적인 이점을 갖춘 선택적 촉매환원법(selective catalytic reduction, SCR) 기술을 통하여 질소산화물 제거를 위해 암모니아를 환원제로 반응에 참여시켜 인체에 무해한 H2O, N2로 전환하는 기술이 대표적이다. 최근 전 세계적으로 다양한 산업군에서 질소산화물이 배출되고 있으며, 점오염원뿐만이 아니라 비점오염원(mobile sources)에 대한 규제가 강화되고 있다. 디젤엔진이 장착된 선박 배가스 처리장치 내 SCR 기술이 주목을 받고 있으며, NH3-SCR에 사용되는 촉매는 주로 VOx/TiO2, VOx/W/TiO2 촉매가 대표적이다. 한편 선박 디젤엔진에 사용되는 연료에 따라 연소배가스 특성이 다르다. 이러한 연료가 연소됨에 따라 SO2, SO3가 발생되고 환원제인 NH3와 결합하여 황산암모늄염((NH4)2SO4), ABS (ammonium bisulfate, NH4HSO4)과 같은 염을 형성시켜 탈질촉매의 비활성화 문제가 발생된다. 이러한 비활성화 물질이 침적된 탈질촉매를 재활성화 시키기 위하여 열 산화를 통해 재생시키고 있다. 이처럼 선박용 SCR 촉매는 강화되는 배출규제 및 엔진기술의 발달로 저감되는 운전 온도에 대비하여 저온 활성 재생이 가능한 고활성, 고내구성 촉매기술 개발이 필요하다.

A Study on NOx Reduction for a Small Marine Diesel Engine (소형 선박 디젤엔진의 질소산화물 저감에 관한 연구)

  • Sim, Han-Sub
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.5
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    • pp.79-84
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    • 2011
  • Air pollutants from a small marine diesel engine are increasing and the IMO(International Marine Organization) regulation asked for its reduction. In this study, NOx reduction technologies such as improvement of various cooling systems are applied to the small marine diesel engine. The various cooling systems are a intercooler, a heat exchanger for engine coolant, and an exhaust manifold by water cooling. These systems are tested on an engine dynamometer and a exhaust gas analyzer by a marine diesel engine test regulation. Test results are shows that the small marine engine are satisfied the IMO NOx regulations; Tire II.

The Effect of Engine Performance and Emission Characteristics in A HD Diesel Engine by The Application of Oxygen-enriched and EGR (디젤기관에서 산소과급과 EGR에 의한 기관성능 및 배출특성에 미치는 효과)

  • Baik, Doo-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.5
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    • pp.778-783
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    • 2006
  • Numerous researches have been conducted to investigate an optimal EGR rate which minimizes emission levels of NOx without increasing PM or loosing an engine power. In this research, the interrelation among engine parameters were intensively investigated and evaluated quantitatively, and proposed some directions in design of a heavy diesel engine by applying EGR and Oxygen-enriched system.

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Improvement in Reduction Performance of LNT-Catalyst System with Micro-Reformer in Diesel Engine (연료 개질장치의 적용에 따른 디젤 LNT 환원성능 개선 특성)

  • Park, Cheol-Woong;Kim, Chang-Gi;Kim, Kwan-Tae;Lee, Dae-Hoon;Song, Young-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.7
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    • pp.689-696
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    • 2010
  • The Because of its high thermal efficiency, the direct injection (DI) diesel engine has emerged as a promising potential candidate in the field of transportation. However, the amount of nitrogen oxides ($NO_x$) increases in the local high-temperature regions and that of particulate matter (PM) increases in the diffusion flame region during diesel combustion. In the de-$NO_x$ system the Lean $NO_x$ Trap (LNT) catalyst is used, which absorbs $NO_x$ under lean exhaust gas conditions and releases it in rich conditions. This technology can provide a high $NO_x$-conversion efficiency, but the right amount of reducing agent should be supplied to the catalytic converter at the right time. In this research, the emission characteristics of a diesel engine equipped with a micro-reformer that acts as a reductants-supplying equipment were investigated using an LNT system, and the effects of the exhaust-gas temperature were also studied.

Effects of Each Characteristics on NOx Emission Values for Marine 4-Stroke Diesel Engine (선박용 디젤기관(4-Stroke)의 특정인자가 질소산화물에 미치는 영향 고찰)

  • Lee, J.W.;Kwon, O.S.;Kim, J.T.;Lee, B.W.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.74-80
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    • 2005
  • It becomes necessary for engine manufactures to verify whether lots of engines on test bed during shop test are in compliance with NOx Technical Code for marine diesel engines more efficiently on the basis of engine group test concept which contains parent engine and member engines since all the engines are not needed to take NOx measurement. In addition, it becomes more obliged to consider parameters which affect NOx emission level and describe these parameters in NOx technical file as engine information and settings to define engine operation range with tolerance to make sure the engines are still in compliance with NOx emission limit on board after shop test. During preparation of engine group test for 4-stroke marine diesel engines, we evaluated NOx emission value under different engine operating conditions and found that there are certain parameters, for example, Charge air temperature and Max. cylinder pressure which have influence on NOx emission level. The NOx emission shall be satisfied with NOx technical code by means of controlling such parameters.

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A Study for NOx Discharge Characteristics of Diesel Engines (디젤엔진의 NOx 배출 특성에 관한 연구)

  • 남정길;최주열
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.3
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    • pp.373-380
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    • 2003
  • According to the NOx regulations of annex Vi to IMO MARPOL 73/78, all diesel engines with a power output of more than 130 kW should be delivered so as to comply with the IMO speed dependent NOx limit. It is inevitable to adopt this regulations for marine engines Therefore, most of diesel engines which are being currently built should be designed and tested in accordance with the NOx technical code In this study, NOx concentrations of 4 type engines were measured with portable NOx measuring system recommended by ISO-8178. As the results NOx concentrations of each engine by variation of engine speed and engine load were visualized Also these results can be utilized for the basic design and development of diesel engine for NOx reduction.

The Effect of Hydrogen Added into In-let Air on Industrial Diesel Engine Performance (흡기중의 수소첨가가 산업용 디젤기관의 성능에 미치는 영향)

  • Park, Kweon-Ha;Lee, Jin-A;Lee, Wha-Soon
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.8
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    • pp.1050-1056
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    • 2010
  • Diesel engines introduce only air into the cylinder, and the air is high lycompressed. Fuel is directly injected into the combustion chamber in high temperature and pressure. Therefore diesel engines have high thermal efficiency because of the high compression ratio, while having high level of particulate matter and nitrogen oxide emissions because of the direct fuel injection. Many technologies have been developed to reduce particulate matter and nitrogen oxide emissions from diesel engines. One of the technologies is hydrogen fuel introduced into the combustion chamber with diesel fuel. In this thesis tiny amount of hydrogen is supplied into the combustion chamber in order to enhance the combustion performance. The engine, in which hydrogen is introduced, is tested. There are 20 test conditions given as 5 torque values of 100%, 75%, 50%, 25%, 0%, and 4 engine speeds of 700rpm, 1000rpm, 1500rpm and 2000rpm for the two cases with or without hydrogen addition. Maximum torques and Idle torques at each engine speed are measured, then the torque values are divided into 4 levels with 25% increasing step. The result shows that the fuel consumption, smoke, CO are reduced while the NOx emission is slightly increased, and the hydrogen addition has not a great effect on the performance at low loads but a great effect at a maximum load.