• Title/Summary/Keyword: 등온 조건

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A Study on the improving Dyeing properties of Natural Dyes (천연염료의 염색성 향상에 관한 연구)

  • 서명희
    • Proceedings of the Korea Contents Association Conference
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    • 2004.05a
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    • pp.473-477
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    • 2004
  • Cotton fabric was treated with Cationon UK(tertiary ammonium salt) to improve the dyeability to black tea colorants. In order to investigate the efficacy of Cationon UK for improving dyeing properties of cotton fabric, the effect of Cationon UK treatment conditions and dyeing conditions on dye uptake of the cotton fabrics treated with Cationon UK were examined and the colorfastness to washing, perspiration, rubbing and light was also evaluated for practical uses. Cationized cotton treated with Cationon UK showed high dye uptake at lower dyeing concentration and shorter dyeing time, compared with untreated. Dyeing temperature did not affect significantly dye uptake and the maximum dye uptake was obtained at pH 5. Most colorfastness was relatively good, showing 4/5∼5 rating.

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Improvement of Magnetic Properties of Nano-crystalline Nd-Fe-B Alloys (나노 결정형 Nd-Fe-B 합금의 자기적 특성 향상)

  • Lee Dae Hoon;Jang Taesuk
    • Proceedings of the KAIS Fall Conference
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    • 2005.05a
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    • pp.67-70
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    • 2005
  • [ $a-Fe/Nd_2Fe_{14}B$ ]기 이상나노복합합금(two-phase nanocompositie alloy)의 자기적 특성 향상을 위하여, $Nd_9Fe_{84}B_7$ 조성의 합금을 급속 응고법과 등온열처리를 이용하여 제조한 후, 공정 조건의 변화에 따른 상, 미세조직, 자기특성의 변화 등을 조사하였다. 주어진 Nd-Fe-B 삼원계 합금을 35 m/s 이상에서 급랭 응고하였을 때 완전한 비정질 합금을 얻을 수 있었으며, 최적 자기특성을 얻기 위한 적정 열처리 구역은 $700^{\circ}C$/10 - 15분, 725$^{\circ}C$/7 - 12분, $750^{\circ}C$/5 - 7분으로 조사되었다. 이 구역들에서 열처리된 합금들은 모두 매끄러운 감자곡선(demagnetization curve)을 나타내, a-Fe와 $Nd_2Fe_{14}B$사이의 교환상호결합이 잘 일어나고 있음을 알 수 있었으며, 이때 a-Fe와 $Nd_2Fe_{14}B$의 평균 입자 크기는 각각 약 10nm와 40$\~$60 nm였다. 한편 상 전개의 차이에도 불구하고 열처리 후에는 모든 합금들이 $60\%$ 이상의 $M_r/M_s$ 비율을 나타내 열처리 조건의 변화에 관계없이 교환상호작용은 일어나고 있음을 알 수 있었다.

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Prediction of Moisture Migration of Concrete Including Internal Vaporization in Fire (화재시 내부증발을 고려한 콘크리트의 수분이동)

  • Lee, Tae-Gyu
    • Fire Science and Engineering
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    • v.23 no.5
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    • pp.17-23
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    • 2009
  • Moisture evaporates, when concrete is exposed to fire, not only at concrete surface but also at inside the concrete to adjust the equilibrium and transfer properties of moisture. The equilibrium properties of moisture are described by means of water vapor sorption isotherms, which illustrate the hysteretical behavior of materials. In this paper, the prediction method of the moisture distribution inside the concrete members at fire is presented. Finite element method is employed to facilitate the moisture diffusion analysis for any position of member. And the moisture diffusivity model of high strength concrete by high temperature is proposed. To demonstrate the validity of this numerical procedure, the prediction by the proposed algorithm is compared with the test result of other researcher. The proposed algorithm shows a good agreement with the experimental results including the vaporization effect inside the concrete.

Prediction of Complex Turbulent Flows in Can-type Gas Turbine Combustor and Scroll (원통형 가스터빈 연소기와 Scroll 내부유동장 해석)

  • 김용모;김성구;김명환;민대기
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.04a
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    • pp.9-9
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    • 1998
  • 가스터빈 연소기의 난류유동장을 구성하는 기본적인 유동형태는 크게 밀폐관내의 돌연 확대를 가지는 동축제트, 선회유동, 그리고 연소공기공 및 회석공기공을 통해 연소실에 수직방향으로 유입되는 제트유동 등으로 분류할 수 있다. 실제 가스터빈 연소기내의 난류유동장을 수치해석하기 위해서는 임의의 형상을 갖는 3차원 유동장을 모사할 수 있는 수치해석법과 고차정확도를 유지하면서도 수렴안정성을 만족시키는 대류항 처리기법 등과 같은 수치모델의 개발이 선행되어야 하며, 이와 함께 복잡한 난류연소유동장을 정확히 묘사할 수 있는 난류모델 및 난류연소모델의 개발 및 검증이 가장 중요한 요인이 된다. 또한 가스터빈 연소기의 최적 설계는 넓은 작동구간에서 높은 효율, NOx 및 CO 배기량의 저감, 희박연소 가연한계의 확장, 연소계통에서의 낮은 압력강하, 낮은 연소벽면온도와 온도구배를 유지시키기 위한 공기에 의한 충분한 냉각 같은 서로 상충되는 설계조건을 만족해야 한다. 그리고, 이러한 상충된 연소설계조건들을 충족시키는 최적 연소기의 설계를 위해서는 실험적인 연구뿐만 아니라 연소기내의 물리적인 현상을 잘 반영할 수 있는 물리적 모델을 바탕으로 한 연소유동의 해석적인 연구를 필요로 한다. 본 연구에서는 원통형 가스터빈 연소기의 등온 및 연소유동장, 그리고 연소기와 연결되는 Scroll 내부의 난류유동장에 대한 수치해석을 수행하여 수치 및 물리모델의 예측능력을 검증하였고, 가스터빈 연소유동장 해석에 관련된 중요 논점들에 대하여 심도있게 분석하였다.

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Numerical Modeling of Heat Transfer Due to Particle Impact on a Wall (벽면에서의 입자 고찰에 의한 열전달 수치 모델)

  • 권오붕
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.3
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    • pp.296-305
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    • 1995
  • A numerical study was undertaken to clarify the mechanisms of heat transfer in fluid-particle suspension flows. Such flows, including fluidization, are of considerable industrial importance. The present study uses 2-D numerical computations of collisions of normal incidence between a particle and a wall. By comparing the results using (a) adiabatic boundary conditions on the particle and (b) uniform, elevated temperature conditions on the particle, the contributions of fluid-mediated conduction and particle induced convection were successfully separated. Computational expedience led to the use of a transient conduction thermal layer as the background thermal field for the analysis. The results shows that the effect of particle movement is very small until the particle reaches a distance of one to one half diameter away from the wall. The gas-mediated conduction effect is dominant over the induced gas convection effect when Pe is small and the induced gas convection effect becomes significant as Pe increases.

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Study on the Thermal Property and Aging Prediction for Pressable Plastic Bonded Explosives through ARC(Heat-wait-search method) & Isothermal Conditions (ARC(Heat-wait-search method)와 Isothermal 조건을 이용한 압축형 복합화약의 열적 특성 및 노화 예측 연구)

  • Lee, Sojung;Kim, Seunghee;Kwon, Kuktae;Jeon, Yeongjin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.4
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    • pp.55-60
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    • 2018
  • The thermal property is one of the most important characteristics in the field of energetic materials. Because energy materials release decomposition heat, differential scanning calorimetry (DSC) is frequently used for thermal analysis. However, thermodynamic events, such as melting can interfere with DSC kinetic analysis. In this study, we use isothermal mode for DSC measurement to avoid thermodynamic issues. We also merge accelerating rate calorimetry(ARC) data with DSC data to obtain a robust prediction results for small scale samples and for large scale samples as well. For the thermal property prediction, advanced kinetics and technology solutions(AKTS) programs are used.

Studies on the Stabilization of Rayon Fabrics: 3. Effects of Long-Term Isothermal Stabilization at Low Temperatures and Chemical Pre-treatment (레이온직물의 안정화에 관한 연구: 3. 저온 장시간 등온 안정화 및 화학전처리 영향)

  • Cho, Chae Wook;Cho, Donghwan;Park, Jong Kyoo;Lee, Jae Yeol
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.15-25
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    • 2010
  • In the present study, isothermal stabilization processes for rayon fabrics were performed at two relatively low temperatures $180^{\circ}C$ and $200^{\circ}C$ for a long period of time. The results of weight loss, dimensional shrinkage, X-ray diffraction and scanning electron microscopic observations studied with the rayon fabrics before and after the isothermal stabilization indicated that the chemical and physical changes of rayon precursor fibers proceeded continuously and slowly at the stabilization temperature below $200^{\circ}C$. And the pre-treatment with four different chemical compounds done prior to stabilization process influenced differently the characteristics of rayon fabrics. As a result, it was noticed that under the given stabilization conditions, $H_3PO_4$ and $Na_3PO_4$ played a role in catalyzing the stabilization reaction of rayon fabric whereas $NH_4Cl$ and $ZnCl_2$ played a role in delaying or retarding the reaction. $H_3PO_4$ showed the lowest percent weight loss of the fabric in the second stabilization conducted at $350^{\circ}C$. It was considered that phosphoric acid, which has a function of flame retardant, contributed to retarding somewhat the subsequent reaction even in the second stabilization step.

A Proposition for the Removal of Algae and Phosphorus from River Water Using Multi-Purpose filtration pond (다목적 여과저류지를 이용한 하천수의 조류와 인 제거방안 제안)

  • Choi, Hong-Gyu;Jeong, Il-Hwa;Bae, Gha-Ram;Park, Jae-Young;Lee, Jong-Jin;Kim, Yong-Woon;Jung, Kwan-Sue;Kim, Seung-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.7
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    • pp.525-531
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    • 2013
  • In an effort to find a solution to the eutrophication of major Korean rivers, a method to utilize multi-purpose filtration pond was investigated. As literature showed that oyster shell is known to be the most adequate for the removal of dissolved phosphorus in Korean rivers, batch and column experiments were performed using oyster shell as an adsorbent in this study. The results of the batch experiment showed that the removal of dissolved phosphorus from river water through adsorption as a way of preventing algal growth was not practical. The results obtained from the column experiment, however, suggested that oyster shell may be utilized as an adsorbent under limited conditions. Based on the results of the experiments a methodology was proposed to remove algae from river water through the use of multi-purpose filtration pond. This method involves mechanically removing the accumulated algae cake from the surface of the artificial stream in the pond towards the condensing part located at the lower reach of the stream, where particles gather before the final removal. In addition, employment of oyster shell as an adsorbent in the condensing part allows prevention of phosphorus released from the dead algae re-entering the river water.

Characteristics of Heavy Metal Biosorption by Pseudomonas cepacia KH410 (Pseudomonas cepacia KH410의 중금속 흡착특성)

  • 박지원;김영희
    • Korean Journal of Microbiology
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    • v.37 no.3
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    • pp.197-203
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    • 2001
  • An ubiquitous bacterium, Pseudomonar cepacia KH410 was isolated from fresh water plant root and identified. Adsorption of heavy metals of lead, cadmium and copper by this strain was investigated. Optimal conditions foradsorption was 1.0 dry g-biomass, at pH 4.0 and temperature of $40^{\circ}C$. Adsorption equilibrium reached max-imum after 120 min in 1000 mg/l metal solutions. The adsorption capacity (K) of lead was 5.6 times higher thancadmium and 4.0 times higher than that of copper. Adsorption of lead was applicable for Langmuir modelwhereas Freundlich model for cadmium and copper, respectively. Adsorption strength (1/n) of heavy metal ionswere in the order of lead>copper>cadmium. Uptake capacity of lead, cadmium and copper by dried cell was83.2,42.0,65.2 mg/g-biomass, respectively. Effective desorption was induced 0.1 M HCI for lead and 0.1 $HNO_3$ for cadmium and copper. Pretreatment to increase ion strength was the most effective with 0.1 M KOH.Uptake by immobilized cell was 77.8,58.5,71.2 mg/g-biomass for lead, cadmium and copper, respectively. Theimmobilized cell was more effective than ion exchange resin on removal of heavy metals in solution containinglight metals.

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Adsorption Characteristics of Aqueous Phosphate Using Biochar Derived from Oak Tree (참나무 바이오차의 인산염 인(PO4-P) 흡착특성)

  • Choi, Yong-Su;Hong, Seung-Gil;Kim, Sung-Chul;Shin, Joung-Du
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.3
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    • pp.60-67
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    • 2015
  • Objective of this study was to investigate adsorption characteristics of $PO_4-P$ to biochar produced from oak tree in respective to reduce eutrophication from runoff water in the cropland. For adsorption experiment, input amount of biochar was varied from 4 to 20 g/L with 30 mg/L $PO_4-P$ solution. Adsorption amounts and removal rates of $PO_4-P$ was increased at 3 times in 4~14 g/L, and increased at 28.6% in 4~16 g/L, respectively. The maximum adsorption amount ($q_m$) and binding strength constant(b) were calculated as 0.10 mg/g and 0.06 L/mg, respectively. The sorption of $PO_4-P$ to biochar was fitted well by Langmuir model because it was observed that dimensionless constant($R_L$) was 0.37. It was indicated that biochar is favorably adsorbed $PO_4-P$ because this value lie within 0 < $R_L$ < 1. Therefore, biochar produced from oak tree could be used as adsorbent for reduce eutrophication from runoff water in the cropland.