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http://dx.doi.org/10.17137/korrae.2015.23.3.060

Adsorption Characteristics of Aqueous Phosphate Using Biochar Derived from Oak Tree  

Choi, Yong-Su (Department of Agricultural Environment, National Academy of Agricultural Science, Rural Development Administration)
Hong, Seung-Gil (Department of Agricultural Environment, National Academy of Agricultural Science, Rural Development Administration)
Kim, Sung-Chul (Bio Environmental Chemistry, College of Agriculture & Life sciences, Chungnam National University)
Shin, Joung-Du (Department of Agricultural Environment, National Academy of Agricultural Science, Rural Development Administration)
Publication Information
Journal of the Korea Organic Resources Recycling Association / v.23, no.3, 2015 , pp. 60-67 More about this Journal
Abstract
Objective of this study was to investigate adsorption characteristics of $PO_4-P$ to biochar produced from oak tree in respective to reduce eutrophication from runoff water in the cropland. For adsorption experiment, input amount of biochar was varied from 4 to 20 g/L with 30 mg/L $PO_4-P$ solution. Adsorption amounts and removal rates of $PO_4-P$ was increased at 3 times in 4~14 g/L, and increased at 28.6% in 4~16 g/L, respectively. The maximum adsorption amount ($q_m$) and binding strength constant(b) were calculated as 0.10 mg/g and 0.06 L/mg, respectively. The sorption of $PO_4-P$ to biochar was fitted well by Langmuir model because it was observed that dimensionless constant($R_L$) was 0.37. It was indicated that biochar is favorably adsorbed $PO_4-P$ because this value lie within 0 < $R_L$ < 1. Therefore, biochar produced from oak tree could be used as adsorbent for reduce eutrophication from runoff water in the cropland.
Keywords
Cropland; Eutrophication; Nutrients; Langmuir isotherm;
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Times Cited By KSCI : 7  (Citation Analysis)
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1 Bennett, E. M., Carpenter, S. R. and Caraco, N. F., "Human impact on erodable phosphorus and eutrophication: a global perspective increasing accumulation of phosphorus in soil threatens rivers, lakes, and coastal oceans with eutrophication". BioScience, 51(3), pp. 227-234. (2001).   DOI   ScienceOn
2 Abe, K. and Ozaki, Y., "Comparison of useful terrestrial and aquatic plant species for removal of nitrogen and phosphorus from domestic wastewater". Soil Sci. Plant Nutr., 44(4), pp. 599-607. (1998).   DOI
3 Seo, B. S., Park, C. M., Song, U. and Park, W. J., "Nitrate and phosphate removal potentials of three willow species and a bald cypress from eutrophic aquatic environment". Landscape Ecol. Eng., 6(2), pp. 211-217. (2010).   DOI
4 Lu, Q., He, Z. L., Graetz, D. A., Stoffella, P. J. and Yang, X., "Phytoremediation to remove nutrients and improve eutrophic stormwaters using water lettuce (Pistia stratiotes L.)". Environ. Sci. Pollut. Res., 17(1), pp. 84-96. (2010).   DOI
5 Woo, S. H., "Biochar for soil carbon sequestration", Clean techn., 3, pp. 201-211. (2013).
6 Zeng, Z., Zhang S. D., Li, T. Q., Zhao, F. L., He, Z. L., Zhao, H. P., Yang, X. E., Wang, H. L., Zhao, J. and Rafiq, M. T., "Sorption of ammonium and phosphate from aqueous solution by biochar derived from phytoremediation plants". Zhejiang Univ.-Sci. B, 14(12), pp. 1152-1161. (2013).   DOI
7 Shin, J. D, Lee, S. I., Park, W. K., Choi, Y. S., Hong, S. G. and Park, S. W., "Carbon Sequestration in Soil Cooperated with Organic Composts and Bio-Char during Corn (Zea mays) Cultivation". J. Agri. Chem. Environ., 3(4), pp. 151--55. (2014).
8 Choi, I. W., Seo, D. C., Kang, S. W., Lee, S. G., Seo, Y. J., Lim, B. J., Heo, J. S. and Cho, J. S., "Adsorption characteristics of heavy metals using sesame waste biochar", Korean J. Soil Sci. Fert., 46(1), pp. 8-15. (2013).   DOI
9 Inyang, M., Gao, B., Yao, Y., Xue, Y., Zimmerman, A. R., Pullammanappallil, P. and Cao, X. "Removal of heavy metals from aqueous solution by biochars derived from anaerobically digested biomass". Bioresour. Technol., 110, pp. 50--6. (2012).   DOI   ScienceOn
10 Choi, Y. S., Shin, J. D., Lee, S. I. and Kim, S. C., "Adsorption Characteristics of Aqueous Ammonium Using Rice hull-Derived Biochar", Korean J. Environ. Agri., 34(3), pp. 1-6. (2015)   DOI   ScienceOn
11 Na, C. K., Jeong, J. H. and Park, H. J., "Applicability of Theoretical Adsorption Models for Studies on Adsorption Properties of Adsorbents(I)", J. Korea Soc. Environ. Eng., 34(4), pp. 260-269. (2011).   DOI
12 Kizito, S., Wu, S., Kirui, W. K., Lei, M., Lu, Q., Bah, H. and Dong, R., "Evaluation of slow pyrolyzed wood and rice husks biochar for adsorption of ammonium nitrogen from piggery manure anaerobic digestate slurry". Sci. Total Environ., 505, pp. 102-112. (2015).   DOI   ScienceOn
13 APHA-AWWA-WPCF, "Standard methods for the examination of water and wastewater", 14th ed., pp. 476-478. (1975)
14 Choi, I. W., Kim, S. U., Seo, D. C., Kang, B. H., Sohn, B. K., Rim, Y. S., Heo, J. S. and Cho, J. S., "Biosorption of heavy metals by biomass of seaweeds, Laminaria species, Ecklonia stolonifera, Gelidium amansii and Undaria pinnatifida". Korean J. Environ. Agri., 24(4), pp. 370-378. (2005).   DOI   ScienceOn
15 Lee, J. J., "Study on equilibrium, kinetic and thermodynamic for adsorption of quinoline yellow by granular activated carbon", clean techn., 20(1), pp. 35-41. (2014)   DOI   ScienceOn
16 Hamid, S. B. A., Chowdhury, Z. Z. and Zain, S. M., "Base Catalytic Approach: A Promising Technique for the Activation of Biochar for Equilibrium Sorption Studies of Copper, Cu (II) Ions in Single Solute System". Materials, 7(4), pp. 2815-2832. (2014).   DOI
17 Bishop, M. J., Powers, S. P., Porter, H. J. and Peterson, C. H., "Benthic biological effects of seasonal hypoxia in a eutrophic estuary predate rapid coastal development". Estuar. Coast. Shelf Sci., 70(3), pp. 415-422. (2006).   DOI   ScienceOn
18 Shin, J. D., Lee, J. S., Kim, W. I., Jung, G. B., So, K. H., Lee, J. T. and Lee, M. S., "Run-off impact assessment of the steeped cornfield to small stream", Korea J. Environ. Agri., 24(4), pp. 334-340. (2005)   DOI   ScienceOn
19 Xu, G., Sun, J., Shao, H. and Chang, S. X., "Biochar had effects on phosphorus sorption and desorption in three soils with differing acidity". Ecol. Eng., 62, pp. 54-60. (2014).   DOI   ScienceOn
20 Yang, X. E., Wu, X., Hao, H. L. and He, Z. L., "Mechanisms and assessment of water eutrophication". J. Zhejiang Univ.-Sci. B, 9(3), pp. 197-209. (2008).   DOI   ScienceOn
21 Mainstone, C. P. and Parr, W., "Phosphorus in rivers—ecology and management". Sci. Total Environ., 282, pp. 25-47. (2002).
22 Zhao, S. C., "Mechanisms of Lake Eutrophication and technologies for controlling in China". Adv. Earth Sci., 19(1), pp. 138-140. (2004).
23 Carpenter, S. R., "Eutrophication of aquatic ecosystems: bistability and soil phosphorus". in Proceedings of Natl. Acad. Sci. U. S. A., 102(29), pp. 10002-10005. (2005).
24 Withers, P. J. A., Neal, C., Jarvie, H. P. and Doody, D. G., "Agriculture and eutrophication: Where do we go from here?". Sustainability, 6(9), pp. 5853--875. (2014).   DOI
25 Carpenter, S. R., Caraco, N. F., Correll, D. L., Howarth, R. W., Sharpley, A. N. and Smith, V. H., "Nonpoint pollution of surface waters with phosphorus and nitrogen". Ecol. Applic., 8(3), pp. 559-568. (1998).   DOI   ScienceOn