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A Study on Na Removal Method in H2WO4(Aq) by Electrodialysis in APT(S) Manufacturing (APT(S) 제조 시 전기투석법을 이용한 H2WO4(Aq)내의 Na 제거 방법에 관한 연구)

  • Kang, Yong-Ho;Hyun, Soong-Keun
    • Resources Recycling
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    • v.26 no.6
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    • pp.65-72
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    • 2017
  • APT (Ammonium paratungstate) is widely used in various industries such as metal cutting tools, drill bits, mining tools, and military inorganic materials. In order to produce high purity APT(S), an impurity purification step in an aqueous $Na_2WO_4$ convert $H_2WO_4$ solution is required. It is difficult to remove impurity Na of 200 ppm or less when $H_2WO_4(S)$ is prepared by adding HCl(Aq) to an aqueous solution of $Na_2WO_4$, which is a well-known conventional wet method. However, in this study, a more economical and efficient method of removing Na through electrodialysis using a cationic membrane was studied. A large amount of Na in aqueous solution of $H_2WO_4$ due to $Na_2CO_3(S)$ which was added to dissolve waste tungsten carbide drill and scrap was removed to 20ppm or less through electrodialysis process, and it was confirmed that the effect of Na removal was great when using electrodialysis.

Cortical bone strain during the placement of orthodontic microimplant studied by 3D finite element analysis (3차원 유한요소법을 이용한 교정용 마이크로임플란트 식립 시의 피질골 스트레인 해석)

  • Nam, Ok-Hyun;Yu, Won-Jae;Kyung, Hee-Moon
    • The korean journal of orthodontics
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    • v.38 no.4
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    • pp.228-239
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    • 2008
  • Objective: The aim of this study was to evaluate the strain induced in the cortical bone surrounding an orthodontic microimplant during insertion. Methods: A 3D finite element method was used to model the insertion of a microimplant (AbsoAnchor SH1312-7, Dentos Co., Daegu, Korea) Into 1 mm thick cortical bone with a pre-drilled hole of 0.9 mm in diameter. A total of 1,800 analysis steps was used to simulate the 10 turns and 5 mm advancement of the microimplant. A series of remesh in the cortical bone was allowed to accommodate the change in the geometry accompanied by the implant insertion. Results: Bone strains of well higher than 4,000 microstrain, the reported upper limit for normal bone remodeling, was observed in the bone along the whole length of the microimplant. At the bone in the vicinity of the screw tip, strains of higher than 100% was recorded. The insertion torque was calculated at approximately 1.2 Ncm which was slightly lower than those measured from the animal experiment using rabbit tibias. Conclusions: The insertion process of a microimplant was successfully simulated using the 3D finite element method which showed that bone strains from a microimplant insertion might have a negative impact on physiological remodeling of bone.

Effect of h-BN Content on Microstructure and Mechanical Properties of Si3N4 (질화규소의 미세조직과 기계적 성질에 미치는 h-BN 첨가의 영향)

  • 김승현;이영환;조원승;김준규;조명우;이은상;이재형
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.867-873
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    • 2003
  • $Si_{3}N_{4}$-BN based machinable ceramics were fabricated by hot-pressing at $1800^{\circ}C$ for 2 h under a pressure of 25 MPa. The microstructure, mechanical properties, and machinability were investigated. With increasing h-BN content from 5 vol% to 30 vol%, three point flexural strength decreased from 1000 MPa of monolithic S $i_3$ $N_4$ to 720~400 MPa. The fracture toughness, $K_{IC}$ , was decreased from 7.6 MPaㆍ$m^{1/2}$ of monolithic S $i_3$ $N_4$ to 6.5~4.1 MPaㆍ$m^{1/2}$. The grain size and aspect ratio of $\beta$-S $i_3$ $N_4$ slightly decreased with increasing h-BN content. S $i_3$ $N_4$ monolith could not be machined due to brittle fracture, but S $i_3$ $N_4$-BN based machinable ceramics could be machined without fracture, showing excellent machinability. With increasing h-BN content, the thurst force during cutting and micro-drilling process was decreased.

Thermo-mechanical Behavior Characteristic Analysis of $B^2it$(Buried Bump Interconnection Technology) in PCB(Printed Circuit Board) (인쇄회로기판 $B^2it$(Buried Bump Interconnection Technology) 구조의 열적-기계적 거동특성 해석)

  • Cho, Seung-Hyun;Chang, Tae-Eun
    • Journal of the Microelectronics and Packaging Society
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    • v.16 no.2
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    • pp.43-50
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    • 2009
  • Although thin PCBs(Printed Circuit Boards) have recently been required for high density interconnection, high electrical performance, and low manufacturing cost, the utilization of thin PCBs is severely limited by warpage and reliability issues. Warpage of the thin PCB leads to failure in solder-joints and chip. The $B^2it$(Buried Bump Interconnection Technology) for PCB has been developed to achieve a competitive manufacturing price. In this study, chip temperature, package warpage, chip stress and solder-joints stress characteristics of the PCB prepared with $B^2it$ process have been calculated using thermo-mechanical coupled analysis by the FEM(Finite Element Method). FEM computation was carried out with the variations in bump shapes and kinds of materials under 1.5W power of chip and constant convection heat transfer. The results show that chip temperature distribution reached more quickly steady-state status with PCB prepared with $B^2it$ process than PCB prepared with conventional via interconnection structure. Although $B^2it$ structures are effective on low package warpage and chip stress, with high strength bump materials arc disadvantage for low stress of solder-joints. Therefore, it is recommended that optimized bump shapes and materials in PCB design should be considered in terms of reliability characteristics in the packaging level.

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A Comparative Study on Power Tool Manufacturers' Products Spec. and Design Development Features - By the Case Study on BOSCH, BLACK&DECKER and KEYANG Electrics- (전동공구 회사의 제품사양별 디자인개발특성 비교연구 -보슈(BOSCH), 블랙앤데커(BLACK&DECKER), 계양전기 사례를 중심으로 -)

  • 채승진
    • Archives of design research
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    • v.17 no.1
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    • pp.383-392
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    • 2004
  • The power tools is the product using working power generated by electric motor. Many companies are manufacturing numerous devices. Main features of tools are included various assembled products, small, light and solid and durable enough to match several standards. Fundamental requirements for the product is excellent performance and convenience for use. The quality of them depends on the equipped motor'(s) capability, accuracy of gear and endurance against worn-out. By adapting the state-of-the-art parts, they could be used in the place from home to heavy industry broadly. They can be classified electronic drills, grinders, saws and sanders families for the household appliances. For industrial tools, bore drill, grinder, polisher, and driver drill are classified as special and high priced group. This study presents the strategy of power tool development of BOSCH, BLACK&DECKER and KEYANG. Their products were analyzed in terms of product line and product mix concept. Then they are examined by design elements, such as color, shape and material for housing. As an analysis method, the image scale parameter and criteria were applied to each company's product.

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Trend of the welding technology for surface modification (표면개질을 위한 오버레이용접 기술개발 현황)

  • 백응률
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.11a
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    • pp.19-20
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    • 1998
  • 오버레이용접에 의한 표면개질기술(Weld Surfacing or Hardfacing Technology)은 내식성, 내 마모성, 또는 내열성을 갖는 합금의 용접재료를 모재 표면에 균일하게 용착(오버레이:Ovedayer)시킴으로써 목적하는 재료의 표면성질을 향상시키는 표면처리의 한 방법이으로써 1922년 Stoody가 Steel Tube에 Cr합금 분말을 충진한 용접봉을 제조하여 석유시추용 회전드릴의 선단 표면을 오버 레이 용접시켜 내마모성을 획기적으로 개선시킴으로써 이루어 졌다. 초기 오버레이 용접기술은 발전설비I 제철설비I 시벤트설비, 그리고 제지설비 등 주로 설비 부품들의 표면부 내마모성을 개선시키는 방향으로 주로 연구 개발이 이루어졌으나, 기술개발의 진전으로 탈황설비 둥의 표면부 내식성 향상, 연속주조롤 표면부의 내산화성, 내열피로성, 내마모 성 향상 둥을 위해 점차 산업전반에 널리 이용되고 있으며, 설비의 고도화 및 장수명화가 요구되 면서 본 기술의 중요성 또한 점차 부각되고 있다. 그림 1은 연강의 모재 위에 셀프쉴드플럭스코어드와이어(Self-Shield Flux Cored Wire:SS-FCW, 이하 55-FCW라 기술함)를 사용하여 오버레이 용접올 하는 장면을 도식적으로 나 타낸 것이다. 모재와 전극재인 용접봉(S5-FCW) 사이에서 아크가 발생되고, 아크열에 의해서 용접 봉 및 모재 일부가 용융되면서 모재 표면에 새로운 오버레이 표면층이 형성된다. 통상 오버레이 층의 1층 두께는 2-6mm 내외이며, 단층 혹은 다충 오버레이를 자유롭게 실시한다. 오버레이층의 물성은 아크열에 의한 모재로의 용입정도에 따라 1층부에서는 모재의 영향을 크게 받지만 오버레 이충 수가 증가된 3층부에서 부터는 전적으로 용접봉의 성분에 좌우된다. 사진 1은 연강(55-41)의 모재위에 크롬탄화물이 다량 함유된 고크롬 탄화물형 내마모재가 오버 레이된 내마모 복합강판 (wear plate)의 단면 미세조직 사진으로써 모재부와 오버레이충을 함께 보여주고 있다. 모재와 오버레이 충간의 경계면은 모재 일부가 용융된 후 웅고하면서 형성됨으로 인해서 도금이나 용사층과는 달리 매우 견고하게 결합되어 있다. 따라서 계면부의 탈락이라는 문 제점은 거의 없어 심한 응력을 받는 기계구조물 및 부품에도 본 기술은 널리 적용되고 있다. 그리고 사진 1에서 알 수 있는 바와 같이 모재와는 전혀 상이한 재료를 자유로이 선택하여 표면 유효층 일부만 오버레이시키며I 주조 및 단조가 불가능한 재료까지도 표면부에 오버레이 시킴으로 서 부품 및 설비의 제조에 있어 재료비의 절감과 제품의 수명이 획기적으로 개선될 수 있다. 그리고 최근에는 도금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다.

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Strength Analyses of New 2- and 3-Axis-Type Small Multiplying Gears in Dental Hand-Pieces (치과드릴 구동용 신 소형 2축 및 3축형 증속기어 강도특성 비교)

  • Kim, Cheol;Kim, Ju-Yeong;Lee, Jung-Ho;Kwak, Se-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.9
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    • pp.1027-1032
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    • 2012
  • Two types of very small multiplying gears and arrays have been developed for new dental hand-pieces, and the increased speed ratios, modules, number of teeth, gear diameters, and gear types were calculated based on the dynamics of the machinery. The contacting and bending strengths were evaluated for gear teeth with two design concepts using AGMA equations and finite element analyses, and the contacting stresses on teeth with and without DLC (diamond-like-carbon) coating layers were calculated. Fatigue and tension tests were performed to obtain an S-N curve, the Young's modulus, and the strength of the gear material, and these were utilized in the analyses. Slightly larger stresses were found for 2-axis-type gears than for other types of gears, and the S-N curves showed that a gear lifetime of 109 cycles was satisfied. The contacting stresses in gears coated with DLC were reduced by 30%. A new prototype model of a hand-piece with small gears was successfully fabricated and tested.

Microsurgical Anatomy in Transoral Odontoidectomy (경구강 치상돌기제거술의 수술해부학)

  • Park, Kwan;Lee, Sang Koo;Cho, Tae Goo;Nam, Do-Hyun;Lee, Jung-Il;Kim, Jong-Soo;Hong, Seung-Chyul;Shin, Hyung-Jin;Eoh, Whan;Kim, Jong-Hyun
    • Journal of Korean Neurosurgical Society
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    • v.29 no.3
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    • pp.309-316
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    • 2000
  • Objective :The transoral approach allows direct view of the ventral craniovertebral junction and provides useful management of the various lesions of this area. We present a step by step guide to the performance of the transoral excision of the odontoid process in the cadaveric model. Methods : Ten cadaver heads were used in fixed or unfixed state. We describe the relevant surgical anatomy in the cadaveric dissection and surgical technique of transoral transpharyngeal odontoidectomy. Results : The surgical procedure of transoral odontoidectomy was categorized by six steps;soft palate, posterior pharyngeal wall, muscular structures, osseous structures, odontoid process and ligaments, cruciate ligament and dura. Conclusion : With anatomical knowledge of these regions neurosurgeons can deal with wide variety of lesions in the ventral craniovertebral junction.

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Arthroscopic Reduction and Fixation of an Anterior Cruciate Ligament Avulsion Fracture From the Tibial Eminence Using Bioabsorbable Pins - Technical Note - (생흡수성 핀을 이용한 소아 경골 과간부 견열 골절의 관절경적 정복 및 고정 방법 - 수술 술기 -)

  • Lee, Su-Chan;Yang, Il-Soon;Seo, Hee-Soo
    • Journal of the Korean Arthroscopy Society
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    • v.13 no.2
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    • pp.183-187
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    • 2009
  • Purpose: We describe a new and simple technique for arthroscopic fixation of tibial intercondylar eminence avulsion fracture using bioabsorbable pins in skeletally immature patients. Operative Technique: Diagnostic knee arthroscopy is performed using anterolateral and anteromedial portals. Fracture debris and blood clot are debrided to expose the injured site well. The fragment is reduced with the probe and fixed temporarily with a 1.1-mm diameter K-wire that is inserted percutaneously from the anterosuperior aspect of the knee joint. The drill guide is introduced into the joint and the fragment is secured by bioabsorbable, poly-p-dioxanone 1.3-mm pins inserted from different angles. The pins are 40 mm in length. The knee is placed in a long leg cast in extension for 4 weeks to assure that full extension is obtained. Conclusion: Arthroscopic fixation of an tibial intercondylar eminence avulsion fracture using bioabsorbable pins is not a technically demanding, suitable method that ensures fracture healing and restores the stability of the joint.

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Study on Q-value prediction ahead of tunnel excavation face using recurrent neural network (순환인공신경망을 활용한 터널굴착면 전방 Q값 예측에 관한 연구)

  • Hong, Chang-Ho;Kim, Jin;Ryu, Hee-Hwan;Cho, Gye-Chun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.3
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    • pp.239-248
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    • 2020
  • Exact rock classification helps suitable support patterns to be installed. Face mapping is usually conducted to classify the rock mass using RMR (Rock Mass Ration) or Q values. There have been several attempts to predict the grade of rock mass using mechanical data of jumbo drills or probe drills and photographs of excavation surfaces by using deep learning. However, they took long time, or had a limitation that it is impossible to grasp the rock grade in ahead of the tunnel surface. In this study, a method to predict the Q value ahead of excavation surface is developed using recurrent neural network (RNN) technique and it is compared with the Q values from face mapping for verification. Among Q values from over 4,600 tunnel faces, 70% of data was used for learning, and the rests were used for verification. Repeated learnings were performed in different number of learning and number of previous excavation surfaces utilized for learning. The coincidence between the predicted and actual Q values was compared with the root mean square error (RMSE). RMSE value from 600 times repeated learning with 2 prior excavation faces gives a lowest values. The results from this study can vary with the input data sets, the results can help to understand how the past ground conditions affect the future ground conditions and to predict the Q value ahead of the tunnel excavation face.