• Title/Summary/Keyword: 동역학적 과정

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Melt and Recrystallization Behavior of Syndiotactic Polypropylene and Isotactic Polypropylene (신디오택틱 폴리프로필렌과 아이소택틱 폴리프로필렌의 용융과 재결정화)

  • Lee, Sang-Won;Huh, Wan-Soo;Hyun, Uk;Lee, Dong-Ho;Noh, Seok-Kyun
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.521-527
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    • 2003
  • It was found that polypropylene shows rearrangement of crystal structure during the melting process. For the analysis of recrystallization behavior, the change of dynamic mechanical property, crystallinity, and crystal structure were studied by DSC, FT-IR, SAXS, and DMA. Melt-recrystallization-remelting behavior of iPP was clearly observed when iPP was cooled down kom the melt more rapidly. Elastic modulus of iPP increased during the recrystallization process but crystallinity of iPP shows constant value. Furthermore, the full width of half mean of SAXS pattern decreased about 30%, and intra-lamella ordering of iPP increased during the melt process but is was not found for sPP.

Interactive Animation of Articulated Bodies using a Procedural Method (절차적 방법을 이용한 다관절체의 대화형 동작생성)

  • Bae, Hui-Jeong;Baek, Nak-Hun;Lee, Jong-Won;Yu, Gwan-U
    • Journal of KIISE:Computer Systems and Theory
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    • v.28 no.12
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    • pp.620-631
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    • 2001
  • In interactive environments including computer games and virtual reality applications, we have increased need for interactive control of articulated body motions. Recently, physically based methods including constrained dynamics techniques are introduced to this area, in order to produce more realistic animation sequences. However, they are hard to achieve real-time control of articulated bodies, due to their heavy computations. In this paper, we present a procedural method for interactive animation of articulated bodies. In our method, each object of the constrained body is first moved according to their physical properties and external forces, without considering any constraints. Then, the locations of objects are adjusted to satisfy given constraints. Through adapting this two-stage approach, we have avoided the solving of large linear systems of equations, to finally achieve the interactive animation of articulated bodies. We also present a few example sequences of animations, which are interactively generated on PC platforms. This method can be easily applied to character animations in virtual environments.

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Mathematical Modeling and Simulation for Steady State of a 75-ton Liquid Propellant Rocket Engine (75톤급 액체로켓엔진 정상상태 과정의 수학적 모델링 및 시뮬레이션)

  • Lee, Kyelim;Cha, Jihyoung;Ko, Sangho;Park, Soon-Young;Jung, Eunhwan
    • Journal of Aerospace System Engineering
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    • v.11 no.5
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    • pp.6-12
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    • 2017
  • This paper deals with mathematical modeling of a 75-ton open-cycle Liquid Propellant Rocket Engine (LPRE) and the steady state simulation based on a nominal operating point. Each component of open-cycle LPRE may be classified into seven major categories using thermodynamics and dynamics characteristics. To simplify the simulation model of LPRE in this paper, we used four govern equations with assuming no heat transfer process. We confirmed the mathematical model of LPRE by using the error ratio and comparing the experiment data and simulation data in steady state, and checked the stability with the linearized model. Finally, we demonstrated the simulation model as compared to the transient response of experimental data.

Characteristics of Microwave-Assisted Drying of Plant Cells of Taxus chinensis for Moisture Removal (수분 제거를 위한 식물세포 Taxus chinensis의 마이크로웨이브를 이용한 건조 특성)

  • Nam, Hyeon-Woo;Kim, Jin-Hyun
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.208-214
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    • 2020
  • In this study, the characteristics and mechanism of microwave-assisted drying were investigated to improve the efficiency of the storage and extraction of biomass through the removal of moisture from plant cell Taxus chinensis. The efficiency of microwave-assisted drying increased with increasing microwave power. When the experimental data were fitted to typical drying kinetic models, the page and modified Page models were the most appropriate. The microwave-assisted drying was determined to be a spontaneous endothermic process, and randomness increased during the drying process. The effective diffusion coefficient (3.445 × 10-9~7.163 × 10-7 ㎡/s) and mass transfer coefficient (3.1529 × 10-5~1.2895 × 10-2 m/s) increased with increasing microwave power. The small Biot number (0.3890~0.7198) indicated that the mass transfer process was externally controlled.

Evaluation of Adsorption Characteristics of 2-Picoline onto Sylopute (실로퓨트에 대한 2-피콜린의 흡착 특성 평가)

  • Yang, Ji-Won;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.57 no.2
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    • pp.210-218
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    • 2019
  • Batch experiment studies were carried out on the adsorption of the major tar compound, 2-picoline, derived from the plant cell cultures of Taxus chinensis, using Sylopute while varying parameters such as initial 2-picoline concentration, contact time and adsorption temperature. The experimental data were fitted to the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. Comparison of results revealed that the Langmuir isotherm model could account for the adsorption isotherm data with the highest accuracy among the four isotherm models considered. From the analysis of adsorption isotherms, it was found that adsorption capacity decreased with increasing temperature and the adsorption of 2-picoline onto Sylopute was favorable. The kinetic data were well described by the pseudo-second-order kinetic model, while intraparticle diffusion and boundary layer diffusion did not play a dominated role in 2-picoline adsorption according to the intraparticle diffusion model. Thermodynamic parameters revealed the exothermic, irreversible and non-spontaneous nature of adsorption. The isosteric heat of adsorption decreased as surface loading ($q_e$) increased, indicating a heterogeneous surface.

Estimation of water surface evaporation in Yongdam Dam using Empirical wind function (경험적 바람공식을 적용한 용담댐 내의 수면증발량 추정)

  • Minwoo Park;Sumiya Uranchimeg;Ho-Jun Kim;Min-kyu Jung;Hyun-Han Kwon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.291-291
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    • 2023
  • 증발량을 산정하는 방법 중 증발접시를 활용한 방법은 하천의 증발량을 직접적으로 측정할 수 있는 장점이 있는 반면, 장기간의 증발접시를 활용한 증발량 추정은 현실적으로 쉽지 않다. 대표적인 증발량 산정식으로는 에너지 수지 및 공기동역학적 원리의 혼합적용 방법(PCE, Penman combination equation)과 경험적 바람공식(PWF, Penman wind function)이 있다. PCE로 산정된 증발량의 경우 하천 내 바닥열(bed heat flux)과 물기둥의 열저장 변화율이 장기간 규모의 순 복사량에 비해 작은 값을 가져 식에서 제외되므로 전반적으로 증발량이 과대 추정되는 문제가 발생한다. 반면, PWF로 산정한 증발량에서는 광범위한 매개변수 범위와 기상자료의 부족으로 모형의 불확실성을 증대시키는 요인으로 작용한다. 본 연구의 최종적인 목표는 하천 수로의 수면증발량을 추정하는 것이지만, 실제 하천 중심에서 증발량을 추정하기 위한 수문학적 자료는 매우 부족한 실정이다. 따라서, 본 연구에서는 유역단위에서의 증발량을 전이하는 방안을 모색하고자 하며, 구체적인 연구과정은 다음과 같다. 첫째, 유역단위 수문학적 자료를 수집하여(flux tower 자료 활용) 유역단위의 증발량을 산정한다. 둘째, PCE와 PWF으로 산정한 증발량과 관측된 증발량을 이용하여 각 식의 매개변수를 최적화한다. 마지막으로 최적화된 매개변수를 적용한 증발량과 관측값의 유사성을 분석한다. 본 연구에서는 하천단위의 증발량을 산정하기 위해 PWF을 적용하였으며 용담댐 내의 기상자료를 활용하여 산정한 증발량과 실제 용담댐 내의 수면증발량의 상관성을 분석한 결과 높은 상관성 확인할 수 있었다. 따라서 하천 주변에 증발량 추정을 위한 최소한의 기상정보가 존재하는 지역에서, 하천단위의 증발량을 산정할 수 있으며 장기간의 증발량도 산정할 수 있을 것으로 판단된다.

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Opening Size Determination of Geotextiles Using Dry and Wet Methods (건식/습식 방법을 이용한 토목섬유의 유효구멍크기 측정방법 평가)

  • Kim, Ju-Hyong;Cho, Sam-Deok
    • Journal of the Korean Geotechnical Society
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    • v.23 no.2
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    • pp.19-27
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    • 2007
  • Dry and wet test methods established by Korean industrial standards to estimate opening size of 3 types of geotextile which are widely used for filter of plastic drain board in Korea are performed to evaluate characteristics of the test methods and to compare the test results. Judging from test results, dry method is a relatively poor test, having lots of problems causing many errors but a simple-quick test. Wet method is a very specific test avoiding many of the problems of dry method such as electrostatic charges, trapping in the geotextiles and so on. However, one of wet test methods, KS K ISO 12956, takes long time to complete a test and is too strict to handle loss of granular material. Generally, opening size of a geotextile by wet test method is smaller than that of dry test method. Especially, opening size by KS F 2126 which is called hydrodynamic method but at present is not used anymore is similar to or smaller than that by KS K ISO 12956 method.

분무진공동결건조기 개발

  • Ryu, Gyeong-Ha;Ban, Byeong-Min;Kim, Jae-Hyeong;Son, Sang-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.258-258
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    • 2013
  • 최근 건조 제품의 양질화, 고급화 및 편의화가 요구되어 이를 충족시키기 위한 새로운 건조방법이 계속 개발 되어 왔다. 이러한 방법들 중에서 저온과 진공하에서 건조가 이루어지는 진공 동결 건조는 가장 완벽한 건조 방법으로 최근 실용화 되고 있다. 진공동결건조란 건조의 한 종류로 수분을 함유한 시료를 동결시킨 후 진공펌프를 이용하여 수증기압을 3중점 이하로 낮추어 얼음을 직접 증기로 만드는 승화의 원리에 의해서 얻어진다. 분무진공동결건조의 특징은 (1) 물리적구조의 보존성, (2) 화학적인 안정성, (3) 생물학적인 활동의 보존성, (4) 제품의 높은 복원성 및 재생성이다. 따라서 분무진공동결건조 기술은 크게 진공, 분무, 동결, 건조, 멸균 등과 같은 요소기술의 복합기술이라 할 수 있다. 분말을 제조하기 위해서 진공동결건조 후 분쇄하는 방법을 사용하나 본 방법에서는 정밀화학품 제조를 위해서 분무진공동결건조 방식을 사용한다. 이를 통하여 적당한 크기인 5~10 um의 입경 제조가 가능하고, 공기동력학적인 입경이 기존 방식에 비해 작아서 허파까지의 운반효율이 1.5~2배 우수하다. 화학, 의학 분야에서의 분무동결 건조는 주로 민감한 제품, 즉 생물학적 고유성의 손상 없이 물을 제거하는데 사용되어 영구적으로 저장 가능한 상태로 보관할 수 있으며 물의 첨가로 원상태로 복구할 수 있어서 매우 각광을 받고 있다. 의약용 냉동건조 제품은 항생물질, 박테리아, 혈청, 백신, 검사 약물, 단백질을 포함하는 생물공학 제품들, 세포, 섬유, 화학제품 등이 있으며 주로 vial 또는 ampule 상태로 건조가 이루어진다.본 연구에서는 원료를 $-194^{\circ}C$의 액체질소에 분무시켜 동결된 미립자를 형성한 후 진공 및 저온상태에서얼음의 승화(sublimation)에 기반한 1차 건조와 수증기 탈착(desorption)에 기초한 2차 건조 과정으로 구성된 분무진공동결건조기를 개발하였다. 분무동결 과정의 해석을 통해 2유체식 노즐을 통해 분무된 미세 입경의 액적이 액체 질소 표면까지 도달하는 회수률, 분무 노즐의 위치, 운전 조건 및 용기의 설계의 최적화를 수행하였다. 초기 액적속도, 분무노즐의 높이, 흡입구 추가에 따른 액적 유동 및 회수의 특성을 제시하였으며 이를 통한 분사시스템 고도화 가능성을 제시하였다. 구형의 미세 입자가 적층된 제품의 동결건조 공정의 해석은 흡착승화 모델(sorption sublimation model)을 기반으로 다음과 같은 열전달, 물질전달, 상변화 모델을 고려하여 유도되었다. 분무노즐 및 냉동/진공 배기계 시작품을 개발하여, 표면의 고다공도를 갖춘 입경 3~20 m 정도의 시료를 얻을 수 있으며, 동역학적 입경 5 m 충족함을 확인하였다.

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Investigation of the Characteristic Velocity of Geomorphologic Instantaneous Unit Hydrograph (지형형태학적 순간단위도의 특성속도에 대한 고찰)

  • Kim, Sang-Dan;Yu, Cheol-Sang;Yun, Yong-Nam
    • Journal of Korea Water Resources Association
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    • v.33 no.3
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    • pp.315-330
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    • 2000
  • The GIUH (Geomorphologic Instantaneous Unit Hydrograph) is to be applied to the ungauged or insufficiently gauged basins. For tIris purpose, an accurate estimation of the charactenstlc velocity is one very important part, but any proper method for this has not been developed yet. In case that we have enough rainfall and runoff clata, the estimation of the characteristic velocity may be an easy job, but it is out of the purpose of the GIUH. Remindmg that the purpose of GIUH the characterisbc veloclty should be estimated based on the geomorpholog1c analysis and also be snnple for easy apphcation. In tIris research analysis cmd application of the GruH was given to several sub-basins in Wi-stream river basin, Gono, Donggok and Hyoryung. After deriving the characteristic velocity througn a optimizatlOn process with real data, it is compared w1th several velOCIties der1ved from geOlnoI1Jhoclimatic instantaneous unit hydrograph theory and several other concentration time formulae. The estimated charactenstic velocities using Kerby, Kim, KInematic Wave, and Brasby- Williams formulae found to g1ve the appropriate results. Hmvever, as the Kerby, and the Kinematic Wave require user's decision of the IvIanning's n value, the K1m and the Braby-Williams seem to be more applicable and recommended as characteristic velocity formula.

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Forecast of the Daily Inflow with Artificial Neural Network using Wavelet Transform at Chungju Dam (웨이블렛 변환을 적용한 인공신경망에 의한 충주댐 일유입량 예측)

  • Ryu, Yongjun;Shin, Ju-Young;Nam, Woosung;Heo, Jun-Haeng
    • Journal of Korea Water Resources Association
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    • v.45 no.12
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    • pp.1321-1330
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    • 2012
  • In this study, the daily inflow at the basin of Chungju dam is predicted using wavelet-artificial neural network for nonlinear model. Time series generally consists of a linear combination of trend, periodicity and stochastic component. However, when framing time series model through these data, trend and periodicity component have to be removed. Wavelet transform which is denoising technique is applied to remove nonlinear dynamic noise such as trend and periodicity included in hydrometeorological data and simple noise that arises in the measurement process. The wavelet-artificial neural network (WANN) using data applied wavelet transform as input variable and the artificial neural network (ANN) using only raw data are compared. As a results, coefficient of determination and the slope through linear regression show that WANN is higher than ANN by 0.031 and 0.0115 respectively. And RMSE and RRMSE of WANN are smaller than those of ANN by 37.388 and 0.099 respectively. Therefore, WANN model applied in this study shows more accurate results than ANN and application of denoising technique through wavelet transforms is expected that more accurate predictions than the use of raw data with noise.