• Title/Summary/Keyword: 동시 열경화

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Dielectric Cure Monitoring of Thermosetting Matrix Composites (열경화성 수지 복합재료의 유전 정화 모니터링)

  • Kim, Hyoung-Geun;Lee, Dai-Gil
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.5
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    • pp.409-417
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    • 2003
  • Cure monitoring can be used to improve the quality and productivity of thermosetting resin matrix composite products during their manufacturing process. In this work, the sensitivity of dielectrometry was improved by adequate separation the efforts of sensor and externals on the measured signal. A new algorithm to obtain the degree of cure during dielectric cure monitoring of glass/polyester and glass/epoxy composites was developed by employing a function of both temperature and dissipation factor, in which five cure monitoring parameters were used to calculate the degree of cure. The decreasing pattern of dissipation factor was compared with the relationships between the degree of cure and the resin viscosity. The developed algorithm might be employed for the in situ cure monitoring of thermosetting resin composites.

Optimum Design of Co-cured Steel-Composite Tubular Single Lap Joints (동시경화 강철-복합재료 원형 단일 겹치기 조인트의 최적설계)

  • Jo, Deok-Hyeon;Lee, Dae-Gil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.5 s.176
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    • pp.1203-1214
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    • 2000
  • In this paper, a failure model for co-cured steel-composite tubular single lap joints has been proposed incorporating the nonlinear mechanical behavior of steel adherends and different failure mode s such as steel adherend failure and composite adherend failure. The characteristics of the co-cured steel-composite tubular single lap joint were investigated with respect to the test temperature, the stacking sequence of composite adherend, the thickness ratio of steel adherend to composite adherend, and the scarf ratio of steel adherend. Thus, the optimum design method for the co-cured steel-composite tubular single lap joint was suggested.

Effect of the Curing Behavior on Electrical and Mechanical Properties of Multifunctional Structural Electrolyte (경화 거동에 따른 다기능 구조 전해질의 전기적 기계적 특성 연구)

  • Kwon, Suk Jin;Choi, U Hyeok;Jung, Byung Mun;Kim, Yang Do;Lee, Sang Bok
    • Composites Research
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    • v.29 no.6
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    • pp.395-400
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    • 2016
  • Recently, many research groups have studied on the epoxy-based multifunctional electrolyte to develop the structural composite bearing high mechanical properties without sacrificing the ionic conductivity at the same time. The studies on the optimal content and material selection for structural electrolyte have been published, while its curing behavior has not much analyzed yet. In this study, epoxy-based structural electrolyte containing solid electrolyte was prepared by varying the curing temperature and time. In addition, the ionic conductivities and mechanical properties of specimens were measured. We also find out the optimal hardening condition where the epoxy domain enables to be hardened within the range of temperature at which the thermal decomposition of electrolyte does not occur. Finally, we propose the multifunctional structural electrolyte showing achievable electrical and mechanical properties (282 MPa and $9{\times}10^{-6}S/cm@25^{\circ}C$).

T-and cross-reactive B-cell epitopes of Porphyromonas gingivalis and human heat shock protein 60 in atherosclerosis (동맥경화증에 있어서 Porphyromonas gingivalis와 인체 열충격단백의 T-세포 및 교차성 B-세포 epitope)

  • Choi, Jeom-Il
    • Journal of Periodontal and Implant Science
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    • v.33 no.3
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    • pp.331-340
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    • 2003
  • 본 연구의 목적은 인간의 동맥경화증에서 Porphyromonas gingivalis (P. gingivalis)와 인체 열충격단백 60의 T-세포 및 교차성 B-세포 epitope를 규명하고 수립된 T-세포주의 T-세포 주요조직적합체 양상을 파악하려는 데 있다. P. gingivalis 열충격단백-반응성 T 세포주와 환자의 혈청을 이용하여 P. gingivalis 열충격단백60 분자를 구성하는 104개의 중복성 합성 펩타이드의 T-세포 epitope과 B-세포 epitope을 규명하였다. 인체 열충격단백60에 대한 B-세포 epitope도 같은 방법으로 파악하였다. P. gingivalis, P. gingivalis 열충격단백60 또는 인체 열충격단백60에 대한 IgG 항체는 모든 동맥경화증 환자에서 상승하였다. P. gingivalis 열충격단백60의 3, 15, 24, 33, 45, 53, 64, 84, 88, 99번 펩타이드가 주요한 T-세포 epitope였고 이것들은 T-세포 및 B-세포 공동 epitope이기도 했다. 또한 인체 열충격단백60 교차반응 B-세포 epitope은 15, 29, 53, 56, 69, 74번 펩타이드로 판명되었다. 대부분 환자의 주요조직적합체는 $HLA-DRB1^{\ast}1504$$HLA-DZB1^{\ast}0603$으로 나타났다. 결론적으로 P. gingivalis 열충격단백60은 제 2급 주요조직적합제-제한적으로 분해되고 전달되었으며 이 단백질이 공통적인 T-세포 및 B-세포 epitope를 가지면서 동시에 인체 열충격단백60과 교차성 B-세포 epitope을 가지면서 동맥경화증의 면역조절기능에 관여한다고 볼 수 있다.

Investigation of cure cycle for co-cured metal/composite hybrid structures without fabricating thermal residual stress (동시경화 하이브리드 금속/복합재료 구조물의 제조 잔류 열응력 제거를 위한 경화사이클에 관한 연구)

  • Kim Hak Sung;Park Sang Wook;Lee Dai Gil
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.83-87
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    • 2004
  • In this work, the cure cycle of co-cured metal/composite structure was investigated to decrease fabricating thermal residual stresses between the metal and the composite material. DSC (Differential scanning calorimetry) experiment and static lap shear test of co-cured aluminum/composite double lap joint as well as the curvature experiment of co-cured steel/composite strip were performed to investigate the effect of curing cycle on the thermal residual stress of co-cured hybrid structures. From the experiments, it was found that post curing method after abrupt cooling of co-cured aluminum/composite hybrid structure at certain point of degree of cure during curing process could eliminate fabricating the thermal residual stresses.

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A study on the improvement of thermostability and dielectric breakdown strength for packaging and impregnating epoxy composite materials for electrical machines and apparatus (전기 기기용 봉지 및 함침 에폭시 복합 재료의 내열성 및 절연파괴 특성 개선에 관한 연구)

  • 김명호;김재환
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.527-533
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    • 1994
  • In this study, it was studied on dielectric breakdown strength and thennostability properties due to the structure variation of matrix resin and treatment of coupling agent of epoxy insulating materials. The interpenetrating network structure was formed by simultaneous heating curing the epoxy resin with single network structure and the methacrylic acid resin. Also inner structure was observed and the glass transition temperature was measured on these three type specimens. Dielectric breakdown properties were investigated by applying DC, AC and impulse voltage. As a result, the glass transition temperature and the dielectric breakdown strength of specimen with interpenetrating network structure was more higher than another two type specimens.

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Improving Curing Rate and Physical Properties of Korean Dendropanax Lacquer with Thermal and Photo Initiator by Dual Curing (이중경화법을 이용한 열개시제 및 광개시제가 배합된 황칠도료의 경화속도 촉진 및 물성향상 연구)

  • Hwang, Hyeon-Deuk;Moon, Je-Ik;Park, Cho-Hee;Kim, Hyun-Joong;Hwang, Baik
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.4
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    • pp.333-340
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    • 2010
  • The Korean Dendropanax lacquer, made from a natural resinous sap from Dendropanax orbifera Lev., was used as a golden and transparent varnish for the traditional artifacts (armor uits, helmets, arrowheads, etc.) to make them be brilliant golden color. The cured film of the acquer has excellent protective properties such as weatherability, water resistance, and nticorrosive. But, one of disadvantages is that takes a long time and much energy to fulfill curing the lacquer. The chemical constituents of the lacquer contained conjugated diene compounds s the photopolymerizable monomers. These monomers easily polymerized in sunlight to form olden-colored, hard-coating films in a short time. Photooxidation may be one of the most mportant reactions in the chemistry of the lacquer. Although the Korean Dendropanax Lacquer hould be dried to a thoroughly dry stage to achieve optimal film properties, curing with elevated emperatures may be required for the protracted curing time at atmospheric temperature. So we ntended to accelerate the curing rate of the lacquer by dual curing of thermal and radiation uring. The effect of thermal initiator on the thermal curing reaction was evaluated by monitoring he changes in double bond peak with FT-IR. Then the curing rate of the lacquer blended with hermal initiator and photoinitiator together was measured during dual curing using a RPT with V spot curing machine. Thermal initiator not only accelerated the curing rate but also improved he physical property. And the curing rate of the Korean Dendropanax lacquer was improved by ual curing method of thermal and UV curing. According to these results, the application area of he Korean Dendropanax lacquer could be expanded to surface coatings for electronic devices uch as mobile phones or electronics.

스테인리스강 프로펠러축의 가공에 따른 재질특성에 관한 연구

  • Son, Yeong-Tae;Gang, Byeong-Jae
    • 선박안전기술공단연구보고서
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    • s.1
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    • pp.1-146
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    • 2007
  • 본 연구의 목적은 STS 304 프로펠러축의 육성가공 및 STS 630 프로펠러축의 열 가공에 따른 강도 및 내식성 등의 재질특성변화 등을 조사 분석하여 선박기관기준 제8조 제2항에서 규정하고 있는 ‘용접수리 불가’에 대한 근거자료 제시(동조동항의 단서조항에 대해서는 일반적으로 알려진 스테인리스강의 용접에 대한 적정방법 이외에 연구결과를 바탕으로 적정 기준을 제시할 수 있는지에 대한 부분도 동시에 검토 하고자 함)는 물론, 선박기관기준 제65조 제1호(총 톤수 20톤 이상의 경우는 제59조 제1항 적용)에서 규정하고 있는 석출경화계 스테인리스강의 제1종축으로써의 인정 여부에 대한 유효성을 제시하여 프로펠러축의 가공(육성․열)과정에 필요한 기본 방향을 제시하고자 함. 따라서 본 연구에서는 STS 304, STS 630 프로펠러축의 가공에 따른 결과를 바탕 으로 위에서 언급한 사항들에 대한 근거자료 확보 및 프로펠러축의 가공에 따른 방향을 제시하기 위한 일환으로 ‘스테인리스강 프로펠러축의 가공에 따른 재질 특성에 관한 연구’를 실시함으로써 프로펠러축 검사와 관련한 평가 기준 정립의 근본적인 지침 자료를제시하고자 함. 또한 본 연구과제는 스테인리스강 프로펠러축에 대한 가공(육성․열) 특성을 살펴 봄으로써 기존에 이미 발표된 판 형태의 스테인리스강 용접에 대한 연구와는 다소 구별되는 과제일 뿐만 아니라 단순한 스테인리스강의 용접특징을 나타낸 실험들과는 다르게 스테인리스강 프로펠러축에 대한 특징들을 분석하고 평가함으로써 현장중심의 연구가 될 수 있도록 하였음. 이번 연구의 결과는 일반적으로 알려진 스테인리스강의 용접관련 특성들을 통해어느 정도의 결과 추정은 가능하나 앞에서 언급한 기준들에 대한 구체적인 근거자료를 확보하여 필요시 적절하게 활용할 수 있는 자료가 될 수 있도록 하고자 하였음.

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Preparation of Graphene/Polybenzoxazine Conductive Composite Thin Film through Thermal Treatment (열 처리를 통한 그래핀/폴리벤족사진 전도성 복합 박막 제조)

  • Ko, Young Soo;Cha, Ji-Jung;Yim, Jin-Heong
    • Polymer(Korea)
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    • v.37 no.4
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    • pp.513-517
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    • 2013
  • A novel conductive composite thin film was prepared for the first time by hybridization between polybenzoxazine (PBZ) having high heat resistance property and conductive graphene. Mechanically robust conductive graphene/PBZ composite thin films could effectively be prepared by a simple thermal treatment, which simultaneously induces reduction of graphene oxide (GO) and crosslinking reaction of benzoxazine monomer. Graphene sheets seem to be uniformly dispersed up to 3 wt% graphene content in the composite thin film as shown in the results of chemical/crystal structural and morphological analyses. This efficient route for making graphene/PBZ composite thin film would provide simultaneous improvement of mechanical property as well as electrical conductivity.

Selection Methodology of Tool for Co-cured Composite Materials (동시경화용 복합재료의 특성에 따른 금형의 선택방법)

  • 홍중표;이종옥;이원곤;홍정수;지우석;조한준
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.183-188
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    • 2002
  • Co-cured composite materials has its own characteristics, so its thermal expansion is different each other. The selection of tool material for co-cured composite part in high temperature more over $350^{circ}F$ and 50 Psi pressure have to consider part thermal expansion, size, shape, and economic aspect in production line. So it is important choose tooling material in manufacturing composite parts. We called the tool for airplane composite parts as BAJ (Bonding Assembly Jig). Composite parts are cured on the BAJ in autoclave. BAJ have to stable at high temperature over $350^{circ}F$ and 50 Psi pressure, Considering composite parts' dimensional tolerance compare to heat up in autoclave. This paper come from the results of the experiment at the composite parts production line and review other aircraft company's method for tooling This is for the engineer engaged in composite parts manufacturing.

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