• Title/Summary/Keyword: 동력학 계수

Search Result 93, Processing Time 0.029 seconds

Numerical Evaluation of Hovering Performance of Next Generation Rotor Blade(Nrsb-1) (차세대 로터 블레이드(NRSB-1)의 제자리 비행 성능 해석)

  • Lee,Gwan-Jung;Hwang,Chang-Jeon;Kim,Jae-Mu;Ju,Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.31 no.7
    • /
    • pp.69-74
    • /
    • 2003
  • By employing vane tip concept, a new rotor blade (NRSB-I) has been designed to enhance the noise characteristics of BERP blade. Numerical analyses have been performed for hovering rotor and the results are compared with respect to those of original BERP blade. Although the thrust of designed rotor decreases by 6-7% due to cutout at the tip region, the results indicate that the actual performance loss is negligible because power reduction is greater than thrust loss. It is also found that aerodynamic fence is required at the outboard kink to obtain clearly separated twin-vortices because the vortex generated at kink is diffused during the convection over the blade surface.

Study on numerical analysis of debris flow considering driftwood and entrainment-erosion (유목과 연행침식을 고려한 토석류거동의 수치해석적 연구)

  • Tae Un Kang;Hyun Uk An;Seung Soo Lee
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2023.05a
    • /
    • pp.138-138
    • /
    • 2023
  • 본 연구에서는 유목과 연행침식을 고려한 토석류 수치모형을 개발하여 2011년 발생한 우면산 산사태의 관측데이터를 기반으로 수치모의를 수행하였다. 토석류 모형개발을 위해 천수방정식 기반의 침수모형인 Nays2DFlood 모형에 혼합유사농도의 이송확산, 토석류 지면전단응력, 연행침식모듈을 추가하였으며 유목생성과 유목거동 모의를 위해 입자법 기반의 유목동력학 모형을 결합하였다. 개발된 모형을 검증하기 위해, 민감도분석을 수행하였으며, 모의결과, 우면산 산사태 당시 래미안 APT에 피해를 끼친 충격수심과 충격유속, 최종 토석류 체적을 양호하게 재현한 것으로 판단된다. 또한 토석류를 구성하는 토사입경이 작을수록 토사점성에 의한 전단응력의 증가로 토석류 유속과 수심이 감소했지만 연행침식량이 증가하였으며, 토사입경이 증가하면 유속과 수심이 증가하고 연행침식량은 감소한 것으로 나타났다. 또한 본 연구에서 개발된 토석류 거동모형은 토사입경, 침식 및 퇴적계수 등의 다양한 토석류 매개변수가 요구되기 때문에, 이러한 물성치 데이터가 현장 또는 실내실험에서 충분히 확보되어야 모형의 정확도가 향상될 것으로 판단된다. 따라서, 향후 연구에서는 본 연구에서 고찰된 모형의 적용성과 한계점을 고려하여 토석류 거동을 예측모의 한다면 보다 세부적으로 토석류와 유목거동을 예측분석해 볼 수 있을 것으로 사료된다. 또한 본 연구의 결과는 기후변화로 인한 강우발생의 불확실성과 이로 야기되는 토석류 발생을 사전에 예측하여 토석류 저감대응방안을 구축하는 일환으로 활용 될 수 있을 것으로 기대된다.

  • PDF

Adsorption Equilibrium, Kinetics and Thermodynamics Studies of Malachite Green Using Granular Activated Carbon (입상 활성탄을 이용한 말라카이트 그린의 흡착평형, 동력학 및 열역학 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
    • /
    • v.24 no.2
    • /
    • pp.184-189
    • /
    • 2013
  • In the present study, batch experiments were carried out for the utilizatioin of activated carbon as a potential adsorbent to remove a hazardous malachite green from an aqueous solution. The effects of various parameters such as temperature, contact time, initial concentration on the adsorption system were investigated. On the basis of adsorption data Langmuir and Freundlich adsorption isotherm model were also confirmed. The equilibrium process was described well by Langmuir isotherm model. From determined separation factor, the activated carbon could be employed as an effective treatment for removal of malachite green. From kinetic experiments, the adsorption process followed the pseudo second order model, and the adsorption rate constant ($k_2$) decreased with increasing both the initial concentration of malachite green and the adsoprtion temperature. Thermodynamic parameters like that activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the adsorption nature. The activation energy calculated from Arrhenius equation indicated that the adsortpion of malachite green on the zeolite was physical process. The negative Gibbs free energy change ($\Delta$G = -3.68~-7.76 kJ/mol) and the positive enthalpy change ($\Delta$H = +26.34 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption in the temperature range of 298~318 K.

Equilibrium, Kinetics and Thermodynamic Parameters Studies on Metanil Yellow Dye Adsorption by Granular Activated Carbon (입상활성탄에 의한 메타닐 옐로우 염료의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
    • /
    • v.25 no.1
    • /
    • pp.96-102
    • /
    • 2014
  • Adsorption of metanil yellow onto granular activated carbon were studied in a batch system. Various operation parameters such as adsorbent dosage, pH, initial concentration, contact time and temperature were optimized. Experimental equilibrium adsorption data were analyzed by Langmuir and Freundlich adsorption isotherm. The equilibrium process was described well by Freundlich isotherm model. From determined separation factor (1/n), adsorption of metanil yellow by granular activated carbon could be employed as effective treatment method. By analysis of kinetic experimental data, the adsorption process were found to confirm to the pseudo second order model with good correlation and the adsorption rate constant ($k^2$) decreased with increasing initial concentration. Thermodynamic parameters like activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The activation energy was determined as 23.90 kJ/mol. It was found that the adsortpion of metanil yellow on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G=-2.16{\sim}-6.55kJ/mol$) and the positive enthalpy change (${\Delta}H=+23.29kJ/mol$) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

A Study on the Flow Characteristics around Tidal Current Turbine (조류발전용 터빈 주위의 유동 특성에 관한 연구)

  • Kim, Bu-Gi;Yang, Chang-Jo
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.18 no.6
    • /
    • pp.610-616
    • /
    • 2012
  • All the countries in the world is currently facing the full scale of energy-climate era currently, and making strong energy policy that will lead to green growth of the future energy resources by utilizing renewable energy as the basis of entering the advanced country becomes the goal of development that satisfies the demand for energy in 21st century. Recently, ocean energy attracted the attention along with the necessity of developing renewable energy. Ocean energy is the one of most prominent recyclable and clean resources that has not been developed yet. So, it is highly required to develop good tidal current energy conversion system in coastal area. The inflow angle that acts against tidal current turbine, seabed effect and the change of efficiency along the occurrence of cavitation were investigated through the wake flow characteristics in this study. Power coefficient degradation by seabed effect did not appear in the condition of this calculation. Efficiency degradation appeared from above $10^{\circ}$ regarding inflow angle and power coefficient was calculated as lower by 7 % at $45^{\circ}$. Torque and power coefficient increased as inflow velocity rose, but power coefficient degradation appeared from above 3m/s when the cavitation happened. So, it was recognized that the larger inflow angle and occurrence of cavitation become the reason for power degradation through the flow characteristics.

Knowledge Production Function in South Korea : An Empirical Analysis (우리나라 지식생산함수 : 실증분석)

  • Cho, Sang-Sup;Jung, Dong-Jin
    • Journal of Korea Technology Innovation Society
    • /
    • v.10 no.3
    • /
    • pp.383-405
    • /
    • 2007
  • In this paper we estimate knowledge production function for 15 South Korean industry sectors using panel data. To accommodate the influence of inter-sectoral interactions on the creation of knowledge, we estimate parameters for related knowledge production functions using the Dynamic Seemingly Unrelated Regression(DSUR) model proposed by Mark et al. (2005). We find the elasticity of knowledge production with respect to the size of research staff to be 0.25 and that with respect to the existing stock of knowledge to be 0.35. The fact that the elasticity of new knowledge creation with regard to the existing knowledge stock is below 1 in South Korea corroborates the view that the rate of long-term growth of her economy is chiefly determined by the elasticity related to production functions of goods and services and the rate of population growth, and that her government policy, to ensure a continued growth for the Korean economy, must shift the focus of R&D policies from the current direct intervention-centered model to one consisting of indirect measures, namely supporting knowledge management and diffusion and the creation of a knowledge sharing system. In terms of R&D policy implications it could be consider that the national knowledge production system should strengthen the cumulative process of knowledge accumulation and population for research and development. Our country R&D policy, also, need to adopt a global approach to increase knowledge stock at the highest levels of a country.

  • PDF

Adsorption Characteristics and Parameters of Acid Black and Quinoline Yellow by Activated Carbon (활성탄에 의한 Acid Black과 Quinoline Yellow의 흡착특성 및 파라미터)

  • Yi, Kyung Ho;Hwang, Eun Jin;Baek, Woo Seung;Lee, Jong-Jib;Dong, Jong-In
    • Clean Technology
    • /
    • v.26 no.3
    • /
    • pp.186-195
    • /
    • 2020
  • The isothermal adsorption, dynamic, and thermodynamic parameters of Acid black (AB) and Quinoline yellow (QY) adsorption by activated carbon were investigated using the initial concentration, contact time, temperature, and pH of the dyes as adsorption parameters. The adsorption equilibrium data fits the Freundlich isothermal adsorption model, and the calculated Freundlich separation factor values found that activated carbon can effectively remove AB and QY. Comparing the kinetic data showed that the pseudo second order model was within 10% error in the adsorption process. The intraparticle diffusion equation results were divided into two straight lines. Since the slope of the intraparticle diffusion line was smaller than the slope of the boundary layer diffusion line, it was confirmed that intraparticle diffusion was the rate-controlling step. The thermodynamic experiments indicated that the activation energies of AB and QY were 19.87 kJ mol-1 and 14.17 kJ mol-1, which corresponded with the physical adsorption process (5 ~ 40 kJ mol-1). The adsorption reaction was spontaneous because the free energy change in the adsorption of AB and QY by activated carbon was negative from 298 to 318 K. As the temperature increased, the free energy value decreased resulting in higher spontaneity. Adsorption of AB and QY by activated carbon showed the highest adsorption removal rate at pH 3 due to the effect of anions generated by dissociation. The adsorption mechanism was electrostatic attraction.

Equilibrium, Kinetic and Thermodynamic Parameter Studies on Adsorption of Allura Red from Aqueous Solution by Granular Activated Carbon (입상활성탄에 의한 수용액으로부터 오로라 레드의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
    • /
    • v.25 no.4
    • /
    • pp.430-436
    • /
    • 2014
  • Allura Red (AR) is a water-soluble harmful tar-based food colorant (FD & C Red 40). Batch adsorption studies were performed for the removal of AR using bituminous coal based granular activated carbon as adsorbent by varying the operation parameters such as adsorbent dosage, initial concentration, contact time and temperature. Experimental equilibrium adsorption data were analyzed by Langmuir, Freundlich and Temkin isotherms. The equilibrium process was described well by Freundlich isotherm. From determined separation factor ($R_L$), adsorption of AR by granular activated carbon could be employed as effective treatment method. Temkin parameter, B was determined to 1.62~3.288 J/mol indicating a physical adsorption process. By estimation of adsorption rate experimental data, the value of intraparticle diffusion rate constant ($k_m$) increased with the increasing adsorption temperature. The adsorption process were found to confirm to the pseudo second order model with good correlation. Thermodynamic parameters like change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption in the temperature range of 298~318 K. The negative Gibbs free energy change (${\Delta}G$ = -2.16~-6.55 kJ/mol) and the positive enthalpy change (${\Delta}H$ = + 23.29 kJ/mol) indicated the spontaneous and endothermic nature of the adsorption process, respectively.

Quantification of Entacapone in Human Plasma by HPLC Coupled to ESI-MS/MS Detection: Application to Bioequavalence Study (체외에서 ESI-MS/MS 탐지에 연결된 HPLC에 의한 Entacapon의 수량화: 생물학적 동등성 연구에 적용)

  • Balasekhara Reddy., Ch.;Baburao., Ch.;Chandrasekhar., K.B.;Kanchanamala., K.;RihanaParveen., S.K.;Ravikumar., Konda
    • Journal of the Korean Chemical Society
    • /
    • v.54 no.5
    • /
    • pp.523-532
    • /
    • 2010
  • The proposed method is simple, sensitive and specific Liquid chromatography-tandem mass spectrometry (LCESI-MS/MS) method for the quantification of Entacapone (EA) in human plasma using Entacapone-d10 (EAD10) as an internal standard (IS). Chromatographic separation was performed on Zorbax SB-C18, $2.1{\times}50\;mm$, $5\;{\mu}m$ column, mobile phase composed of 10 mM Ammonium formate (pH 3.0): Acetonitrile (60:40 v/v), with a flow-rate of 0.7 mL/min, followed by Liquid-liquid extraction. EA and EAD10 were detected with proton adducts at m/z $306.1{\rightarrow}233.1$ and $316.3{\rightarrow}233.0$ in multiple reaction monitoring (MRM) positive mode respectively. The method was validated over a linear concentration range of 1.00 - 2000.00 ng/mL with correlation coefficient ($r^2$) $\geq$ 0.9993. Intra and inter-day Precision within 3.60 to 7.30 and 4.20 to 5.50% and Accuracy within 97.30 to 104.20 and 98.30 to 105.80% proved for EA. This method is successfully applied in the bioequivalence study of healthy Indian human volunteers.

Estimation of Kinetic Parameters for Biomass Growth Using Micro-nano Bubbles Reactor (마이크로-나노버블 반응조를 이용한 미생물성장 동력학 계수의 추정에 관한 연구)

  • Han, Young-Rip;Jung, Byung-Gil;Jung, Yoo-Jin;Cho, Do-Hyun;Sung, Nak-Chang
    • Journal of Environmental Science International
    • /
    • v.19 no.5
    • /
    • pp.647-653
    • /
    • 2010
  • The objectives of this research are to evaluate and compare the oxygen transfer coefficients($K_{La}$) in both a general bubbles reactor and a micro-nano bubbles reactor for effective operation in sewage treatment plants, and to understand the effect on microbial kinetic parameters of biomass growth for optimal biological treatment in sewage treatment plants when the micro-nano bubbles reactor is applied. Oxygen transfer coefficients($K_{La}$) of tap water and effluent of primary clarifier were determined. The oxygen transfer coefficients of the tap water for the general bubbles reactor and micro-nano bubbles reactor were found to be 0.28 $hr^{-1}$ and 2.50 $hr^{-1}$, respectively. The oxygen transfer coefficients of the effluent of the primary clarifier for the general bubbles reactor and micro-nano bubbles reactor were found be to 0.15 $hr^{-1}$ and 0.91 $hr^{-1}$, respectively. In order to figure out kinetic parameters of biomass growth for the general bubbles reactor and micro-nano bubbles reactor, oxygen uptake rates(OURs) in the saturated effluent of the primary clarifier were measured with the general bubbles reactor and micro-nano bubbles reactor. The OURs of in the saturated effluent of the primary clarifier with the general bubbles reactor and micro-nano bubbles reactor were 0.0294 mg $O_2/L{\cdot}hr$ and 0.0465 mg $O_2/L{\cdot}hr$, respectively. The higher micro-nano bubbles reactor's oxygen transfer coefficient increases the OURs. In addition, the maximum readily biodegradable substrate utilization rates($K_{ms}$) for the general bubbles reactor and micro-nano bubbles reactor were 3.41 mg COD utilized/mg active VSS day and 7.07 mg COD utilized/mg active VSS day, respectively. The maximum specific biomass growth rates for heterotrophic biomass(${\mu}_{max}$) were calculated by both values of yield for heterotrophic biomass($Y_H$) and the maximum readily biodegradable substrate utilization rates($K_{ms}$). The values of ${\mu}_{max}$ for the general bubbles reactor and micro-nano bubbles reactor were 1.62 $day^{-1}$ and 3.36 $day^{-1}$, respectively. The reported results show that the micro-nano bubbles reactor increased air-liquid contact area. This method could remove dissolved organic matters and nutrients efficiently and effectively.