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http://dx.doi.org/10.7464/ksct.2020.26.3.186

Adsorption Characteristics and Parameters of Acid Black and Quinoline Yellow by Activated Carbon  

Yi, Kyung Ho (Department of Environmental Engineering, University of Seoul)
Hwang, Eun Jin (Department of Environmental Engineering, University of Seoul)
Baek, Woo Seung (Department of Environmental Engineering, University of Seoul)
Lee, Jong-Jib (Department of Chemical Engineering, Kongju National University)
Dong, Jong-In (Department of Environmental Engineering, University of Seoul)
Publication Information
Clean Technology / v.26, no.3, 2020 , pp. 186-195 More about this Journal
Abstract
The isothermal adsorption, dynamic, and thermodynamic parameters of Acid black (AB) and Quinoline yellow (QY) adsorption by activated carbon were investigated using the initial concentration, contact time, temperature, and pH of the dyes as adsorption parameters. The adsorption equilibrium data fits the Freundlich isothermal adsorption model, and the calculated Freundlich separation factor values found that activated carbon can effectively remove AB and QY. Comparing the kinetic data showed that the pseudo second order model was within 10% error in the adsorption process. The intraparticle diffusion equation results were divided into two straight lines. Since the slope of the intraparticle diffusion line was smaller than the slope of the boundary layer diffusion line, it was confirmed that intraparticle diffusion was the rate-controlling step. The thermodynamic experiments indicated that the activation energies of AB and QY were 19.87 kJ mol-1 and 14.17 kJ mol-1, which corresponded with the physical adsorption process (5 ~ 40 kJ mol-1). The adsorption reaction was spontaneous because the free energy change in the adsorption of AB and QY by activated carbon was negative from 298 to 318 K. As the temperature increased, the free energy value decreased resulting in higher spontaneity. Adsorption of AB and QY by activated carbon showed the highest adsorption removal rate at pH 3 due to the effect of anions generated by dissociation. The adsorption mechanism was electrostatic attraction.
Keywords
Acid black; Quinoline yellow; Dye adsorption; Adsorption; kinetics; Thermodynamic;
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Times Cited By KSCI : 8  (Citation Analysis)
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