• Title/Summary/Keyword: 대체에너지

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Development of Reduced Graphene Oxide/Sr0.98Y0.08TiO3-δ Anode for Methane Fuels in Solid Oxide Fuel Cells (메탄연료사용을 위한 고체산화물 연료전지용 Reduced Graphene Oxide/Sr0.98Y0.08TiO3-δ 연료극 개발)

  • Hyung Soon Kim;Jun Ho Kim;Su In Mo;Gwang Seon Park;Jeong Woo Yun
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.296-301
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    • 2023
  • Solid oxide fuel cell has received more attention recently due to the fuel flexibility via internal reforming. Commonly used Ni/YSZ anode, however, can be easily deactivated by carbon coking in hydrocarbon fuels. The carbon deposition problem can minimize by developing alternative perovskite anode. This study is focused on improving conductivity and catalytic activity of the perovskite anode by introducing rGO (reduced graphene oxide). Sr0.92Y0.08TiO3(SYT) anode with perovskite structure was synthesized with 1wt% of rGO. The presence of rGO during anode fabricating process and cell operation is confirmed through XPS and Raman analysis. The maximum power density of rGO/SYT anode improved to 3 times in H2 and 6 times in CH4 comparing to that of SYT anode due to the high electrical conductivity and good catalytic activity for CH4.

A Study of a Pilot Test for a Blasting Performance Evaluation Using a Dry Hole Charged with ANFO (건공화 공법의 발파 성능 평가를 위한 현장 시험에 관한 연구)

  • Lee, Seung Hun;Chong, Song-Hun;Choi, Hyung Bin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.2
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    • pp.197-208
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    • 2022
  • The existence of shallow bedrock and the desire to use underground space necessitate the use of blasting methods. The standard blasting method under water after drilling is associated with certain technical difficulties, including reduced detonation power, the use of a fixed charge per delay, and decoupling. However, there is no blasting method to replace the existing blasting method. In this paper, a dry hole charged with ANFO blasting is assessed while employing a dry hole pumping system to remove water from the drill borehole. Additional standard blasting is also utilized to compare the blasting performances of the two methods. The least-squares linear regression method is adopted to analyze the blasting vibration velocity quantitatively using the measured vibration velocity for each blasting method and the vibration velocity model as a function of the scaled distance. The results show that the dry hole charged with ANFO blasting will lead to greater damping of the blasting vibration, more energy dissipation to crush the surrounding rock, and closer distances for the allowable velocity of the blasting vibration. Also, standard blasting shows much longer influencing distances and a wider range of the blasting pattern. The pilot test confirms the blasting efficiency of dry hole charged with ANFO blasting.

Sea Ice Drift Tracking from SAR Images and GPS Tracker (SAR 영상과 GPS 추적기를 이용한 여름철 해빙 이동 궤적 추적)

  • Jeong-Won Park;Hyun-Cheol Kim;Minji Seo;Ji-Eun Park;Jinku Park
    • Korean Journal of Remote Sensing
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    • v.39 no.3
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    • pp.257-268
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    • 2023
  • Sea ice plays an important role in Earth's climate by regulating the amount of solar energy absorbed and controlling the exchange of heat and material across the air-sea interface. Its growth, drift, and melting are monitored on a regular basis by satellite observations. However, low-resolution products with passive microwave radiometer have reduced accuracy during summer to autumn when the ice surface changes rapidly. Synthetic aperture radar (SAR) observations are emerging as a powerful complementary, but previous researches have mainly focused on winter ice. In this study, sea ice drift tracking was evaluated and analyzed using SAR images and tracker with global positioning system (GPS) during late summer-early autumn period when ice surface condition changes a lot. The results showed that observational uncertainty increases compared to winter period, however, the correlation coefficient with GPS measurements was excellent at 0.98, and the performance of the ice tracking algorithm was proportional to the sea ice concentration with a correlation coefficient of 0.59 for ice concentrations above 50%.

A Multi-Degree of Freedom Measurement System for Determining Geometric Errors in Miniaturized Machine Tool (소형공작기계의 기하학적 오차 평가를 위한 다자유도 측정시스템)

  • S. H., Kweon;Y., Liu;S. H., Yang
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.638-643
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    • 2004
  • 소형화된 기계가공시스템은 사용재료의 다양화와 에너지 및 공간의 감소와 같은 장점을 가지고 작고 정밀한 부품을 가공할 수 있는 시스템으로 주목받고 있다. 이러한 시스템이 비록 그 크기가 일반적인 가공시스템에 비해 작지만 정렬 및 조립공정, 기계요소의 불완정성에 의한 기하학적 오차는 여전히 존재한다. 기하학적 오차 평가는 기계시스템의 정밀도를 효과적으로 적은 비용으로 향상시킬 수 있는 오차보정기술을 적용할 수 있는 토대가 된다. 일반적으로, 3 축의 직선축으로 이루어진 공작기계는 21 개의 오차요소를 가진다. 레이져간섭계는 이러한 오차요소를 평가하는데 널리 사용되고 있지만 광학계를 정렬하고 설치하는 데 많은 어려움이 있으며 한번의 설치로 한 개의 오차요소만이 측정 가능하다. 또한, 소형공작기계의 경우, 그 크기로 인해 기존의 레이져 간섭계를 직접적으로 적용할 수 없다. 따라서, 본 연구에서는 소형공작기계를 포함한 소형가공시스템의 기하학적 오차 평가를 위한 새로운 다자유도 측정시스템을 제안하였다. 5 개의 정전용량변위센서를 사용하는 이 시스템을 통해 한 축의 움직임에 따른 5 개의 오차요소를 동시에 측정 가능하다. 균질 변환행렬을 이용한 측정알고리듬을 구성하고 이를 모의시험을 통해 평가하였다. 수학적 모델링을 통해 각 센서의 출력값을 유도하고 이를 이용하여 각 오차요소를 계산하기 위한 식을 유도하였다. 여기서, 단순화된 식을 적용한 경우, 임의의 오차에 대한 측정 알고리듬의 정확도를 평가하였다. 또한, 측정 시스템의 설치시 발생하는 셋업오차에 대한 측정 알고리듬의 민감도 분석을 행하였다. 제안하는 측정 시스템은 구조가 간단하고 고가의 부가장비가 필요치 않다. 또한, 적은 비용으로 구성할 수 있으며 높은 측정 정밀도를 가지고 소형가공시스템에 필요한 오차 평가를 행할 수 있다.가 함유된 계란을 생산하고 섭취하였을 때 특정항체들의 결합을 통해 병원성 미생물의 성장이나 군체를 형성하는 것을 무력화시켜 결과적으로 병원균을 감소시키거나 억제시킨다는 점이다. 오늘날 약물에 내성을 지닌 박테리아의 출현으로 질병감염을 막는데 항생제의 사용효과가 점차 감소하고 있기 때문에 이러한 항생제를 대체할 수 있는 방안으로 계란항체를 이용할 수 있다.한 중공 플랜지 형상의 단조 방법 중 보다 적절한 단조방법인 압조 단조에 있어서 일반적으로 사용되고 있는 SM10C에 대한 유한요소 해석을 수행하였으며, 제품의 형상비에 따라 폴딩 결함의 발생 유무를 검토하고, 폴딩 결함 없이 단조하기 위한 중공 플랜지의 형상한계 비를 제시하였다.도 경미하게 나타났으나, 경련이 나타난 쥐에서는 KA만을 투여한 흰쥐와 구별되지 않았다. 이상의 APT의 항산화 효과는 KA로 인한 뇌세포 변성 개선에 중요한 인자로 작용할 것으로 사료되나, 보다 명확한 APT의 기전을 검색하고 직접 임상에 응응하기 위하여는 보다 다양한 실험 조건이 보완되어야 찰 것으로 생각된다. 항우울약들의 항혈소판작용은 PKC-기질인 41-43 kD와 20 kD의 인산화를 억제함에 기인되는 것으로 사료된다.다. 것으로 사료된다.다.바와 같이 MCl에서 작은 Dv 값을 갖는데, 이것은 CdCl$_{4}$$^{2-}$ 착이온을 형성하거나 ZnCl$_{4}$$^{2-}$ , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어떠한 용리액에서던지 NH$_{4}$$^{+}$의 경

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Transfer of Arsenic and Mercury from Stabilized Farmland Soil to Lettuce using Calcium Sulfate Fertilizer with Different Physical Properties as a Stabilizing Agent (안정화제로 사용된 황산칼슘비료의 물리적 형태에 따른 토양 비소 및 수은의 안정화와 식물체 전이특성)

  • Il-Ha Koh;Yo Seb Kwon;Min-Hyeon Lee;Jung-Eun Kim;So-Young Park;Ju In Ko;Won Hyun Ji
    • Economic and Environmental Geology
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    • v.56 no.5
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    • pp.619-628
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    • 2023
  • In this study, we investigated the feasibility of calcium sulfate fertilizer as a stabilizing agent for As and Hg contaminated farmland soil and its stabilization characteristics in 3 different physical forms (particulate, powder, and solution) through a pot experiment including 34 days of lettuce growth. As and Hg contents of the lettuce grown in the stabilized soils were decreased by at least 70%. However the lettuce yield of the soil stabilized with the solution agent was decreased by 46% due to the overabundance of the nutrients from the solution agent. Thus, if a solution-type agent is planned for agricultural farmland soil stabilization, additional tests for optimal dosage are needed to preserve vegetation growth. In Hg fractionation, a lower concentration of elemental fractions and a higher concentration of residual/sulfide fractions were identified in the soils stabilized with the solution, powder, and pariculate agents in descending order while there were no significant changes in As fractionation. Overall results suggest that calcium sulfate fertilizer can be used as a stabilizing agent, and a solution-type agent could be used when the operation of heavy machinery for the soil stabilization process is impossible.

Comparative Analysis of Growth and Development of Paddy Rice (Oryza sativa L.) by Light Intensity under Farm-type Solar Photovoltanic Power Station (추적식 영농형 태양광발전시스템 구축에 따른 음영별 하부작물 벼(Oryza sativa L.)의 생육비교)

  • Eon-Yak Kim;Ye-Jin Lee;In-Jin Kang;Hye-Min Son;Min-Ho Shin;Chang-Hyu Bae
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2022.09a
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    • pp.85-85
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    • 2022
  • 영농형 태양광발전은 태양의 일사량을 전기발전과 영농에 공유하는(solar-sharing) 방식이다. 본 연구는 신재생에너지의 활용의 극대화를 위하여 추적식 영농형 태양광발전시스템을 구축하고 시설하부에서 일정 기간 재배중인 작물의 하부 환경과 생육을 조사하여 영농형태양광 하부작물개발을 위한 기초자료를 확보하고자 하였다. 구축한 추적식 영농형 태양광발전시스템은 4열 6단의 24장 모듈(8m × 6m)을 가지며, 발전시설 중심축 기둥 간 중심간격 14m로 단일지주식 스크루 공법으로 순천대학교 부속농장 답작포(순천시 죽평리)에 설치하여 하부 환경과 하부작물의 생육을 조사하였다. 태양광발전시설 하부작물의 생육을 조사하기 위하여 순천 농협육묘장에서 벼(신동진)를 육묘하여 2022년 6월 16일 이앙하였다. 태양광발전시스템 하부 지역을 4방위 방향에 따라 강음영(중심축으로부터 1~3m), 중음영(5m), 약음영(7~9m) 구역으로 설정하여 생육을 조사한 결과, 방위에 따른 초장은 남쪽에서 음영간 차이가 상대적으로 낮게 나타났으며, 1번기 태양광 발전시설에 의하여 음영이 중첩된 2번기 시설의 동쪽에서 대조구 대비 초장이 상대적으로 낮은 경향을 나타내었다. 음영강도에 따른 초장은 대체로 강음영구에서 낮게 나타났으며, 약음영구로 갈수록 높게 나타났다. 엽수는 방위에 따라서, 그리고 음영의 강도에 따른 차이가 초장에 비하여 작게 나타났다. 출수기의 경우 방위별로는 남쪽에서 음영별 차이가 작게 나타났으며, 음영강도에 따라서 차이를 보였다. 또한 태양광시설 하부에 데이터수집장치(Model 1650, Spctrum Technonogies, USA)를 설치하여 음영에 따른 토양전도도, 토양함수량, 토양온도, par light 등 생육환경을 조사, 비교하였다.

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Analysis of Rollover Angle According to Arrangement of Main Parts of Electric Tractor Using Dynamic Simulation (시뮬레이션을 이용한 전기 트랙터 주요 부품 배치에 따른 전도각 분석)

  • Jin Ho Son;Yeong Su Kim;Yu Shin Ha
    • Journal of the Korea Society for Simulation
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    • v.32 no.4
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    • pp.77-84
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    • 2023
  • In the agricultural sector, power sources are being developed that use alternative energy sources such as electric tractors and hydrogen tractors, away from internal combustion engine tractors. As parts such as engines and transmissions used in conventional internal combustion engine tractors are replaced with motors and batteries, the center of gravity changes, and thus the risk of rollover should be considered. The purpose of this study is to analyze the overturn angle of the main parts of the electric tractor through dynamic simulation to minimize the overturn accident and to derive the optimal arrangement of parts to improve stability. A total of nine dynamics simulations were conducted by designing three components of the PTO motor, drive motor and the battery pack, and three factors of the arrangement method. As a result of the experiment, it was confirmed that Type3 Level3, in which the drive motor and the PTO motor are located at the front and rear of the tractor, and two battery packs are located in the middle of the tractor, has a high rollover angle. As a result of this study, the stability increased as the center of gravity was placed backward and located below. Future research needs to be done to find the optimal location of parts considering their performance and placement efficiency.

Effects of Mo co-doping into Fe doped β-Ni(OH)2 microcrystals for oxygen evolution reactions (Fe-doped β-Ni(OH)2의 산소발생반응 증가를 위한 Mo의 동시도핑효과)

  • Je Hong Park;Si Beom Yu;Tae Kwang An;Byeong Jun Kim;Jeong Ho Ryu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.34 no.1
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    • pp.30-35
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    • 2024
  • In order to improve the efficiency of the water splitting system for hydrogen production, the high overvoltage in the electrochemical reaction caused by the catalyst in the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) must be reduced. Among them, transition metal-based compounds are attracting attention as catalyst materials that can replace precious metals such as platinum that are currently used. In this study, nickel foam, an inexpensive metal porous material, was used as a support, and Fe-doped β-Ni(OH)2 microcrystals were synthesized through a hydrothermal synthesis process. In addition, in order to improve OER properties, changes in the shape, crystal structure, and water splitting characteristics of Fe-Mo co-doped β-Ni(OH)2 microcrystals synthesized by co-doping with Mo were observed. The changes in the shape, crystal structure, and applicability as a catalyst for water splitting were examined.

A Study on the Prior Leaching and Recovery of Lithium from the Spent LiFePO4 Cathode Powder Using Strong Organic Acid (강유기산을 이용한 폐LiFePO4 양극분말로부터 리튬의 선침출에 대한 연구)

  • Dae-Weon Kim;Soo-Hyun Ban;Hee-Seon Kim;Jun-Mo Ahn
    • Clean Technology
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    • v.30 no.2
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    • pp.105-112
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    • 2024
  • Globally, the demand for electric vehicles has surged due to greenhouse gas regulations related to climate change, leading to an increase in the production of used batteries as a consequence of the battery life issue. This study aims to selectively leach and recover valuable metal lithium from the cathode material of spent LFP (LiFePO4) batteries among lithium-ion batteries. Generally, the use of inorganic acids results in the emission of toxic gases or the generation of large quantities of wastewater, causing environmental issues. To address this, research is being conducted to leach lithium using organic acids and other leaching agents. In this study, selective leaching was performed using the organic acid methane sulfonic acid (MSA, CH3SO3H). Experiments were conducted to determine the optimal conditions for selectively leaching lithium by varying the MSA concentration, pulp density, and hydrogen peroxide dosage. The results of this study showed that lithium was leached at approximately 100%, while iron and phosphorus components were leached at about 1%, verifying the leaching efficiency and the leaching rates of the main components under different variables.

Physicochemical characteristics of carotenoid-enriched extract prepared from persimmon peels by ultrasound-assisted extraction with soybean oil solvent (초음파와 대두유 용매를 이용한 감 껍질 추출물의 이화학적 특성 )

  • Hun Sik Chung;Kwang Sup Youn;Soo Won Lee;Hey Kyung Moon;Jong Kuk Kim
    • Food Science and Preservation
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    • v.30 no.1
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    • pp.122-131
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    • 2023
  • Persimmon peels are mostly discared as a by-product of dried persimmon manufacturing, but effective use is required as it contains various functional constituents. This study covers the preparation of carotenoid-enriched oil by ultrasound treatment of persimmon peel in soybean oil solvent, and the investigation of its physicochemical characteristics. Using the Box-Behnken design and response surface methodology, the optimal extraction conditions (temperature, 62℃; time, 32 min; and persimmon peel to oil ratio, 1:3.1) were determined based on the carotenoid concentration of the extract. The physicochemical characteristics of the extract obtained under optimal conditions and the untreated soybean oil (control) were compared. The total carotenoid content of the extract increased. The carotenoid-enriched soybean oils had a lighter color than the controls, but with high redness and yellowness values. The effect of sonication and a component of the persimmon peel on the oxidation and heating stability of soybean oil was weak. The viscosity and activation energy of carotenoid-enriched soybean oil were slightly higher than those of the control. Thus, it was possible to prepare yellow-red carotenoid-enriched soybean oil by applying ultrasonic-soybean oil solvent extraction to persimmon peel. The oil is expected to be useful as an additive as well as a substitute for general edible oils.