• Title/Summary/Keyword: 대기기원

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Estimation of the major sources for organic aerosols at the Anmyeon Island GAW station (안면도에서의 초미세먼지 유기성분 주요 영향원 평가)

  • Han, Sanghee;Lee, Ji Yi;Lee, Jongsik;Heo, Jongbae;Jung, Chang Hoon;Kim, Eun-Sill;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.135-144
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    • 2018
  • Based on a two-year measurement data, major sources for the ambient carbonaceous aerosols at the Anmyeon Global Atmosphere Watch (GAW) station were identified by using the Positive Matrix Factorization (PMF) model. The particulate matter less than or equal to $2.5{\mu}m$ in aerodynamic diameter (PM2.5) aerosols were sampled between June 2015 to May 2017 and carbonaceous species including ~80 organic compounds were analyzed. When the number of factors was 5 or 6, the performance evaluation parameters showed the best results, With 6 factor case, the characteristics of transported factors were clearer. The 6 factors were identified with various analyses including chemical characteristics and air parcel movement analysis. The 6 factors with their relative contributions were (1) anthropogenic Secondary Organic Aerosols (SOA) (10.3%), (2) biogenic sources (24.8%), (3) local biomass burning (26.4%), (4) transported biomass burning (7.3%), (5) combustion related sources (12.0%), and (6) transported sources (19.2%). The air parcel movement analysis result and seasonal variation of the contribution of these factors also supported the identification of these factors. Thus, the Anmyeon Island GAW station has been affected by both regional and local sources for the carbonaceous aerosols.

Moisture Transport Observed by Water Vapor Isotopes in the Vicinity of Coastal Area, Incheon, Korea (수증기안정동위원소를 이용한 해안지역 수분의 이동경로에 관한 연구)

  • Lee, Jeonghoon;Choi, Heejin;Oh, Jinman;Na, Un-Sung;Kwak, Hoje;Hur, Soon Do
    • Economic and Environmental Geology
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    • v.46 no.4
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    • pp.339-344
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    • 2013
  • Water vapor isotopes can be excellent tools for understanding complex mechanisms in the water cycle and atmospheric hydrological cycle and they can be applied to various fields of paleoclimatology, atmospheric science, hydrogeology, oceanography, and ecohydrology. Thus, studies of global or local transport of water vapor may be able to provide a very useful clue to better understand the movements of water and energy in the atmosphere, hydrosphere and biosphere. In this study, the isotopic compositions of water vapor have been observed for moisture transport during the passage of Typhoon Bolaven at Korea Polar Research Institute (KOPRI), Incheon, in the western part of Korea, from August 27 to August 29, 2012. In the clear sky, the isotopic compositions of water vapor at KOPRI exhibited relatively higher isotopic ratios, which were near isotopic equilibrium with sea surface water (${\delta}^{18}O$=-14‰). On the other hand, a largely depleted isotopic ratios in surface water vapor were observed in association with the passage of Typhoon Bolaven (approximately 10‰ depleted compared to the clear sky). The fact that the isotopic minima in water vapor are encountered during the onset period of the Typhoon Bolaven with increases of relative humidity, which is consistent with, so called, "the amount effect".

Sr and Pb Isotopic Properties in Limnetic Gastropod (Semisulcospira libertina) Shell in the Jinan, Jeonbuk Area. (하천에 서식하는 민물고동(다슬기)의 Sr, Pb 동위원소 특성)

  • Jeon Seo-Ryeong;Chung Jae-il
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.129-134
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    • 2005
  • The $^{87}Sr/^{86}Sr$ ratios between water and biogenic material are similar in marine and lacustrine environment. Pb isotope ratios we, however, reported not to have been corresponding between the biological tissues and ambient water in aquatic system, contrary to the Sr isotope ratios. In order to explore the potential application of two isotopes as environmental tracers, we report here the isotopic compositions of strontium and lead of gastropod shell in fresh water in Jinan area. The $^{87}Sr/^{86}Sr$ ratios of carbonate shells of gastropod living in fresh stream water, are similar as that of ambient water but are different by sites. The different $^{87}Sr/^{86}Sr$ ratios of stream water between the sites is likely caused by the difference of the isotopic composition of Sr derived form rocks in the basin. In contrast, there is a distinct difference of the lead isotopic values between the water and the gastropod shell, suggesting that shell-fish available lead in aquatic system is different from dissolved lead in water. It is assumed that the majority of Pb in stream water is derived from atmospheric Pb accumulated on soil materials over years rather than from rock.

태양계의 물: 기원과 진화

  • Choe, Byeon-Gak;Choe, Hye-Rim
    • 한국지구과학회:학술대회논문집
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    • 2005.09a
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    • pp.3-8
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    • 2005
  • 지구는 현재 태양계에서 액체 상태의 물이 표면에 존재하는 유일한 천체이다. 하지만, 고체 또는 기체 상태의 물은 태양계의 다른 행성이나, 위성, 소행성, 혜성 등에도 풍부하게 존재하고 있다. 풍부한 액체 상태의 물은 지구 표면에서 일어나고 있는 기후의 변화, 해류의 이동, 퇴적 및 침식 작용, 화산활동과 같은 여러 지구과학적 현상에 밀접하게 관여하고 있을 뿐 아니라 생명의 탄생과 진화에도 매우 중요한 역할을 하였다. 현재 지구 표면에 액체 상태의 물이 존재할 수 있는 이유는 태양으로부터의 거리, 지구의 조성 및 크기 등과 관련된 지구 표면의 물리-화학적 조건이 액체 상태의 물이 존재할 수 있는 조건과 일치하고 있기 때문이다. 이와는 달리 지구보다 태양에 더 가깝게 위치하고 있고, 두터운 이산화탄소 대기를 갖고 있어 표면의 온도가 매우 높은 금성의 경우 H2O는 기체 상태로 존재하며, 지구보다 더 멀리 떨어져 있고 희박한 대기를 갖고 있는 화성의 경우에는 현재 H2O가 고체 즉 얼음의 형태로 존재한다. 태양계를 탄생시킨 태양계 성운에서는 압력이 너무 낮아 액체 상태의 물이 존재할 수 없으며, 고온에서는 기체 상태로 매우 낮은 저온에서는 얼음의 형태, 또는 함수 광물 내에 포함되어 존재할 수 있다. 지구와 같은 규모의 행성은 비교적 중력이 작아 태양계 성운의 기체를 거의 끌어들이지 못했다. 따라서 현재 지구에 존재하는 물은 대부분은 고체 상태로 지구에 집적되었을 것이다. 하지만 지구가 탄생한 위치에서 초기 태양계의 온도는 얼음이 형성되기에는 너무 높았기 때문에 좀 더 먼 곳에서(현재의 목성 위치보다 바깥쪽)에서 생성된 얼음 즉, 혜성이 태양계 안쪽으로 들어와 지구에 물을 공급했거나 함수광물을 포함하고 있는 소행성(예를 들어 CI chondrites와 같은 조성의)이 물을 가져왔을 것으로 생각되고 있다.서의 활성화는 어미 변환과 관련된 영역이라기보다는 산출시 관련되는 articulation, motor coordinate관련 영역으로 추정되고, 측두엽의 활성화는 형태소, 의미 관련 지식의 data base로 추정된다. 또한 우반구 전두엽 부분에서 관찰된 활성화는 억제관련 영역으로 짐작된다.러한 동물실험이 그 기초를 제공해 줄 수 있을 것이다. 또한 행동성향 및 기억의 종류에 따른 약물효과의 차이는 기억과 관련된 질병인 알츠하이머 환자에 있어 개개인에게 맞는 적절한 특징적인 치료약물이 존재할 것이라는 가능성을 제공해줄 뿐만 아니라 학습과 기억력 증진 효과를 기대해 볼 수 있을 것이라고 생각된다. 및 지역산업발전의 기획${\sim}$조정기구로서, 선진국의 지역발전기구(Regional Development Agency : RDA)인 지역전략산업기획단이 2002년도부터 산업자원부와 9개 시도에 의해 설립되어 지역네트워크의 활성화와 클러스터의 형성 촉진을 하게 되었고 2004년도에는 13개시도로 확대${\sim}$운영되고 있고, 지역특화사업(H/W)과 지역산업기술개발과제(S/W)와 함께 패케지 형태로 지원되며, 주요역할은 크게 지역산업의 정책기획 분야와 평가관리, 지역혁신역량 조사 및 DB구축 등으로 구분된다. 그중에서도 권역별, 지역별, 지역산업진흥사업 육성과 중장기 산업발전계획을 수립하기 위하여 지역혁신역량을 바탕으로 한 지역 Technology Road Map(TRM)작성사업은 전국공통의 1단계 사업으로 실시 ?榮쨉?, 2005년 3월 기준으로 9개 지역(강원, 대전, 충남, 충북, 경북, 울산, 전남, 전북, 제주) 26개 산업분야를 대상으로 23개가 완료된 상황이다. 이를 근거로 한 지역정책과 R&D 과제 및 필요 인프라의 도출이 체계적으로 구축되어 지역산업 발전을 위한

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Estimation of Chemical Speciation and Temporal Allocation Factor of VOC and PM2.5 for the Weather-Air Quality Modeling in the Seoul Metropolitan Area (수도권 지역에서 기상-대기질 모델링을 위한 VOC와 PM2.5의 화학종 분류 및 시간분배계수 산정)

  • Moon, Yun Seob
    • Journal of the Korean earth science society
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    • v.36 no.1
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    • pp.36-50
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    • 2015
  • The purpose of this study is to assign emission source profiles of volatile organic compounds (VOCs) and particulate matters (PMs) for chemical speciation, and to correct the temporal allocation factor and the chemical speciation of source profiles according to the source classification code within the sparse matrix operator kernel emission system (SMOKE) in the Seoul metropolitan area. The chemical speciation from the source profiles of VOCs such as gasoline, diesel vapor, coating, dry cleaning and LPG include 12 and 34 species for the carbon bond IV (CBIV) chemical mechanism and the statewide air pollution research center 99 (SAPRC99) chemical mechanism, respectively. Also, the chemical speciation of PM2.5 such as soil, road dust, gasoline and diesel vehicles, industrial source, municipal incinerator, coal fired, power plant, biomass burning and marine was allocated to 5 species of fine PM, organic carbon, elementary carbon, $NO_3{^-}$, and $SO_4{^2-}$. In addition, temporal profiles for point and line sources were obtained by using the stack telemetry system (TMS) and hourly traffic flows in the Seoul metropolitan area for 2007. In particular, the temporal allocation factor for the ozone modeling at point sources was estimated based on $NO_X$ emission inventories of the stack TMS data.

Achieving Carbon Neutrality: Technology Innovations and Research Needs in the Division of Groundwater and Soil (탄소중립 달성을 위한 지하수토양분야 혁신기술 및 선도연구 소개)

  • Jongbok Choi;Younggyu Son;Young-Soo Han;Man Jae Kwon;Seunghak Lee;Kitae Baek;Yongseok Hong
    • Journal of Soil and Groundwater Environment
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    • v.28 no.spc
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    • pp.40-54
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    • 2023
  • 산업혁명 이후 화석연료의 광범위한 사용, 삼림 벌채, 토지사용의 변화 등과 같은 인위적 활동은 대기 중 온실가스(GHGs, greenhouse gases) 농도를 지속적으로 증가시켜 지구의 기후위기를 유발하였다. 우리나라의 경우 최근 30년 사이 평균 온도가 1.4℃ 상승하였으며, 국제사회의 일원으로 책임을 다하기 위해 2016년 11월 3일 파리협정을 비준하였다. 이에 파리협정의 목표인 산업화 이전 대비 지구 평균온도 상승을 2℃ 아래, 가능한 1.5℃ 아래로 억제하기 위해 2050년까지 CO2 순배출량을 0으로 만들어야 하며, 이를 위해 다양한 정책 마련과 함께 경제 및 사회 전반에 걸쳐 많은 노력이 경주되고 있는 실정이다. 탄소중립을 달성하기 위해서는 첫 번째로 GHGs 배출을 줄이고, 두번째로 대기에서 CO2 포집을 촉진하기 위해 현재 가동되는 다양한 산업분야의 생산 시스템을 개혁하는 것이 가장 중요한 과제로 고려되고 있다. 그동안 지하수토양 관련 연구분야에서는 지속가능성(sustainability), 복원성(resilience), 녹색성장(green growth) 등과 같은 사회적 요구에 부응하여, 녹색정화(green remediation), 자연 저감(natural attenuation), 탄소포집저장(carbon capture and sequestration), 지열발전등의 기술이 초기단계로 개발이 되고 연구가 되어 왔다. 이러한 기존 연구들은 탄소중립2050의 달성을 위해 고도화되어야하며, 추가적으로 자연 및 인위기원 탄소배출 연구, 토양의 역할을 고려한 저탄소 토지이용 기술, 광물탄산화 등의 연구 및 기술개발이 필요하다고 판단된다. 본 논문에서는 탄소중립2050의 간단한 내용과 함께, 이를 달성하기 위한 지하수토양 분야의 혁신기술 및 선도연구를 소개하였다.

Two Different Enclosure-based Measurements Applications for Trace Gas Surface Emission and Sensitivity Analysis for Soil NO Emission by Using a Flow-through Dynamic System (지표 미량기체 방출에 대한 두 가지 다른 형태의 Enclosure 기반 측정 방법의 응용 및 Flow-through Dynamic System을 이용한 토양 NO 방출의 민감도 분석)

  • Kim, Deug-Soo
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.9 no.3
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    • pp.170-178
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    • 2007
  • Rapid increases in the concentrations of greenhouse gases and many other chemically important trace gases have occurred over the last several centuries. For understanding the roles of these important gases in global change, it is essential to identify their sources and sinks, to characterize biogenic gas fluxes between the biosphere and atmosphere, and to understand the processes that control them. In this paper, enclosure-based measurements are described in a practical manner for field experiments. Theoretical reviews of mass balance equation in the enclosure and sensitivity of the flow-through dynamic flux chamber technique are presented; specifically for the case of NO flux measurements from soil surface. The physical system and theory behind the flow-through dynamic flux chamber method are examined. New calculation flux formula was introduced by considering NO chemical loss on chamber wall and uncertainties of the NO flux calculation were discussed.

The distribution characteristics of trace elements of fine ambient particulate in Korea

  • Lim, Jong-Myoung;Lee, Jin-Hong;Kim, Ki-Hyun
    • Analytical Science and Technology
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    • v.18 no.3
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    • pp.241-249
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    • 2005
  • In this study, instrumental neutron activation analysis was used to measure the concentrations of about 30 trace elements in airborne particulate (PM2.5) samples at urban area of Daejeon city located in the southwestern region of Korea. An inspection of the measurement data indicates that the distribution patterns of trace elements could clearly distinguish the elements with their concentrations ranging over five orders of magnitude. The mean values for Lu and Dy were found to be the lowest at values of 0.01 and $0.04ng/m^3$, while those for K and Fe showed the highest value of 671 and $653ng/m^3$, respectively. The results of correlation analysis showed that PM2.5 concentrations can exhibit much more enhanced correlations with the elements of earth crustal components. The results of factor analysis further indicated that there are no more than six factors with statistical significance, which may exert dominant roles in regulating the elemental concentration levels in the study area. Enrichment factor analysis supports explicit interpretation of results found by this factor analysis.

Grain Size Characteristics of the Asian Dust in Seoul and Relationship to Loess Sediments in the West Coast of Korea during the Spring (봄철 서울 지역에 발생한 황사의 입도 특성과 뢰스와의 관련성)

  • YOON, Soon-Ock;PARK, Chung-Sun;HWANG, Sangill
    • Journal of The Geomorphological Association of Korea
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    • v.17 no.3
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    • pp.77-88
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    • 2010
  • The grain size characteristics of the Asian Dust(AD) in Seoul during the spring 2010 are analyzed by the different pretreatment procedures. The mean values of the AD samples by the minimal dispersion are 19~56㎛ and the NAD(Non-Asian Dust) samples are 37~92㎛. Contrastively, the mean values of AD and NAD samples by the ultimate dispersion are 13~20㎛ and 14~30㎛, respectively. It is revealed that the particles less than approximately 20㎛ and 40㎛ by the minimal and ultimate dispersion, respectively, are introduced into the atmosphere in the Korean Peninsular by the AD events with the peaks of approximately 0.5㎛, 1.5㎛ and 8.5㎛ by the minimal dispersion, and 0.5㎛ and 7.5㎛ by the ultimate dispersion. Also, the charateristics of AD samples showing similar grain size characteristics to the loess samples rather than the NAD samples indicates long distance origin from China so on. The differences of grain size characteristics between the AD and loess samples may result in duration and intensity of weathering processes.

Hydrochemistry and Nitrogen and Sulfur Isotopes of Emergency-use Groundwater in Daeieon City (대전지역 민방위 비상급수용 지하수에 대한 수리화학과 질소 및 황 동위원소 연구)

  • 정찬호
    • The Journal of Engineering Geology
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    • v.13 no.2
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    • pp.239-256
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    • 2003
  • The purpose of this study is to investigate the hydrochemical characteristics of emergency-use groundwater in the Daejeon area, and to elucidate the contamination source of $NO_3-N$ and the origin of sulfate in the groundwater. The groundwater shows weak acidic pH, the electrical conductivity ranging from 142 to $903{\;}\mu\textrm{S}/cm$, and the hydrochemical types of $Ca-HCo_3$ and $Ca-Cl(SO_4,{\;}NO_3)$. The Box-Whisker analysis and the Krigging analysis of chemical data of groundwater were made to demonstrate the concentration distribution of hydrochemical composition, and to compare the trend of hydrochemical data. The groundwater in the area of Dong-gu, Jung-gu and Daeduk-gu, where are old town, shows higher electrical conductivity, nitrate content, sulfate and $EpCO_2$ levels than groundwater in new town area of Seo-gu and Yusung-gu. ${\delta}^{15}N$ of groundwater in the area of Seo-gu and Yusung-gu ranges from +7.4 to $+9.6{\textperthousand}$, indicating that major contamination source of $NO_3-N$ is the leakage from municipal sewage pipe lines. ${\delta}^{15}N$ of groundwater in the old town area of Tong-gu, Jung-gu and Daeduk-gu shows the range between +10.2 and $+23.5{\textperthousand}$, meaning that major contamination source is leakage of septic tank. ${\delta}^{34}S$ of groundwater shows the range of $+3~13.4{\;}{\textperthousand}$. Sulfur isotope indicates the possibility of a sulfate reduction and the input of anthrophogenic source.