• Title/Summary/Keyword: 단전지

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Development of SOFC stack module (SOFC 모듈평가장치 기술개발)

  • Choi, YoungJae;Lee, InSung;Jun, JoongHwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.81.2-81.2
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    • 2010
  • 고체 산화물 연료전지(SOFC) 시스템은 스택과 기계적 주변 장치인 MBOP(Mechanical Balance of Plant), 그리고 전기적 주변장치인 EBOP(Electrical Balance of Plant)로 구성되어있다. SOFC는 일반적으로 $700^{\circ}C$ 이상의 고온에서 작동되기 때문에 효율적인 열 이용 및 열 관리가 중요하다. SOFC 시스템의 MBOP에는 상온의 연료가스들을 고온으로 가열하여 스택에 유입 시기키 위한 열교환기 및 촉매연소기 등의 장치들이 필요하며, 효율적인 열관리를 위해서는 고온에서 작동하는 장치들을 한곳에 통합하여 구성하는 것이 필수적이다. 본 연구에서는 SOFC 시스템의 MBOP(Mechanical Balance of Pant) 중 고온부에 해당하는 촉매연소기, 열교환기 및 스택이 통합된 스택 모듈을 제작에 앞서 개념 검증을 위해 열교환기 및 촉매연소기로 이루어진 프로토타입(prototype)의 SOFC 모듈평가 장치를 제작하였다. 열교환기는 Plate형으로 총 6개로 구성되어 있으며, 연료극과 공기극 가스라인에 각각 3개씩 배치하여 스택에 유입되는 연료 및 공기가 촉매연소기에서 나오는 고온의 배가스와 열교환되어 가열되도록 구성하였다. 촉매연소기는 honeycomb 타입의 촉매를 사용하였고, 촉매연소기로 유입되는 연료극 배가스와 공기의 균일혼합과 hot spot을 방지하기 위한 장치를 삽입하여 제작하였다. 제작된 SOFC 모듈평가장치는 시운전을 통해 각 장치의 성능 확인 후 반응면적이 $20{\times}20cm^2$ 인 단전지를 적층하여 연계 운전을 수행하였다.

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Manufacture of Pt-transition Metal Alloy Catalyst for PAFC (PAFC용 합금 촉매 제조)

  • Kim, Yeong-Woo;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.692-700
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    • 1993
  • Corrosivities and catalytic activities of platinum-transition metal alloy catalyses loaded on carbon substrate and were studied by electrochemical method using a unit cell. And the analysis of Pt-alloy catalyst was conducted by x-ray diffractometer. Among the catalysts, the Pt-Mo/carbon, Pt-Fe-Co/carbon and Pt-Fe/carbon catalyst showed more excellent cathodic current densities than others. It was found that most of cathodic current density for the Pt-Mo/carbon electrode was $120mA/cm^2$. The current density of the Pt-Fe-Co/carbon was much higher than that of Pt/carbon, reaching $200mA/cm^2$.

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Development of a new Li-Ion Pack-Battery for improving the electrical properties (전기적인 특성향상을 위한 리튬이온전지팩 개발)

  • Gang, Young-Gu;Kweon, Hyun-Kyu;Seo, Myung-Su;Park, Chang-Yong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.8 no.2
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    • pp.90-95
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    • 2009
  • This paper presents a new lithium ion unit-cell and pack battery by using a new formulation ratio of material. The three types of formulation ratio for the unit-cell were used. The life cycle and basic properties of the lithium ion unit-cell$({\Psi}18{\times}65(mm))$ about one of them were acquired by the charge-discharge experiment. The nominal voltage, nominal capacity and cycle life output of the lithium ion unit-cell is respectively 3.7V, 2.4Ah, and above 500cycle. Pack type lithium ion battery has the size of $29.5{\times}73.5{\times}115(mm)$ and the weight of 300g. As the results, the weight and bulk of lithium ion battery used to a safety lamp were decreased to 1/4 and 1/7. In addition, the comparison of the new lithium ion battery and lead storge battery for confirming the effectiveness of the new lithium ion battery have been performed.

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Lightweight Metallic Bipolar Plates of PEMFC for a Small Reconnaissance UAV (소형 정찰 UAV를 위한 고분자 전해질막 연료전지의 경량의 금속 분리판)

  • Kim, Ki-In;Lee, Jong-Kwang;Jang, Bo-Sun;Kwon, Se-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.38 no.10
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    • pp.1031-1037
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    • 2010
  • This paper proposed lightweight aluminum bipolar plates as an alternative for conventional graphite bipolar plates in fuel cell systems used as a power source for small reconnaissance UAVs. Since bipolar plates occupy more than 80% of the total weight of the fuel cell system, lightweight aluminum bipolar plates can improve the overall payload and flight time of the fuel cell UAV. The aluminum and graphite bipolar plates were fabricated to compare the performance of each of them. A 15% higher performance per weight was obtained from aluminum bipolar plates than the graphite bipolar plates. Also, the performance of a single cell using aluminum bipolar plates was evaluated under various operating conditions.

Single Cell Stacked Planar Type SOFC Assembled Using a Ag-Current Collector (Ag 집전체를 적용한 평판형 SOFC 단전지)

  • Cho, Nam-Ung;Hwang, Soon-Cheol;Lee, In-Sung
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.720-726
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    • 2007
  • Current collectors of SOFC play a significant role on the performance of power generation. In this study a single cell stacked SOFC was assembled using Ag-mesh as a cathode current collector, and evaluated its performance. No gas leakages of the single cell stack occurred in the tests of gas detection and OCV measurement. The OCV and initial power of the stack were 1.09V and $0.45W/cm^2$, respectively, under the flow rates of air at 2,500 cc/min and $H_2$ at 1,000 cc/min at the test temperature of $750^{\circ}C$. A degradation rate of 44.0% was measured during the prolonged time of 307 h. The relatively low durability of the tested single cell stack was found to be the evaporation of Ag-mesh at the current corrector.

A Simulated Prediction for Influences of Operating Condition in an Alkaline Fuel Cell

  • Jo Jang-Ho;Yi Sung-Chul
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.163-170
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    • 1999
  • The effects of the operating conditions in AFC single cells have not been studied in detail. In this study, by using a one-dimensional isothermal model a computational simulation was conducted to investigate the effects of the initial electrolyte concentration and the operating gas pressure. According to the result, the optimum electrolyte concentration at the base-case was found to be within $3.0\~3.5$ M. The variation of the cell performance according to the electrolyte concentration was found to be caused mainly by the charge transfer resistances of both electrodes, Henry's constant and the liquid phase diffusivity of the dissolved gases. It was also found that an increase in operating pressure increased the reaction rates and the solubilities of the gases, which led to a considerable enhancement of the cell performance.

Development of Tubular Solid Oxide Fuel Cells with Advanced Anode Current Collection (연료극 집전체 최적화를 적용한 원통형 고체산화물 연료전지 단전지 성능 향상)

  • Kim, Wanje;Lee, Seungbok;Song, Rakhyun;Park, Seokjoo;Lim, Takhyoung;Lee, Jongwon
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.6
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    • pp.480-486
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    • 2013
  • In this study, tubular SOFC unit cell with advanced anode current collector was fabricated to improve the cell performance. First, we prepared two types of single cells having the same manufacture processes such as the same electrolyte, electrode coating condition and sintering processes. And then to compare the developed single cell performance with conventional cells, we changed the anode current collecting methods. From the impedance analysis and I-V curve analysis, the cell performance of advanced cell is much higher than that of conventional cell.

An Ethnographic Research on the Phenomenon of A Dan-Jeon Breathing Training Center (단전호흡 수련에 관한 일상 생활 기술적 연구)

  • 박은주;전성숙
    • Journal of Korean Academy of Nursing
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    • v.29 no.6
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    • pp.1244-1253
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    • 1999
  • The purpose of this study was to explore and describe the experience of Dan-Jeon breathing training and of Qi as a essential substance in forming human body. The sample consists of 7 participants who are Dan-Jeon Breathing training in a Training center, Pusan, Korea. They were asked open-ended questions in order for them to talk about their experiences. With permission of the subjects, the interviews were recorded and transcribed. The summarized results of this research are following. 1. The purpose of Dan-Jeon Breathing The interview data was organized by themes into 4 categories : hope for health recovery, a concern about Dan-Jeon Breathing, seeking meaning of life, change of lifestyle 2. The experience of Qi during Dan-Jeon Breathing training The interview data was organized by themes into 3 categories : an autonomic movement of body, spiritual experience, conviction of existence of Qi. 3. The change after Dan-Jeon Breathing training. The interview data was organized by themes into 7 categories : physical health promotion, emotional relaxation, promoting brain function, positive attitude about life, love to others, investigation for self, improvement on Qi feeling..

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Fabrication of Anode-Supported SOFC Single Cells via Tape-Casting of Thin Tapes and Co-Firing (박막 테이프캐스팅과 동시소성에 의한 연료극 지지형 SOFC 단전지 제조)

  • Moon, Hwan;Kim, Sun-Dong;Hyun, Sang-Hoon;Kim, Ho-Sung
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.788-797
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    • 2006
  • An anode-supported SOFC single cell having $5{\mu}m$ thin electrolyte was fabricated cost-effectively by tape casting, laminating, and co-filing of anode (NiO-YSZ), cathode (LSM-YSZ), and electrolyte (YSZ) components. The optimal slurry compositions of the green tapes for SOFC components were determined by an analysis of the mean diameter, the slurry viscosity, the tensile strength/strain of the green tapes, and their green microstructures. The single cells with a dense electrolyte and porous electrodes could be co-fired successfully at $1325\sim1350^{\circ}C$ by controlling the contents of pore former and the ratio of coarse YSZ and fine YSZ in the anode and the cathode. The single cell co-fired at $1350^{\circ}C$ showed $100.2mWcm^{-2}$ of maximum power density at $800^{\circ}C$ but it was impossible to apply it to operate at low temperature because of low performance and high ASR, which were attributed to formation of the secondary phases in the cathode and the interface between the electrolyte and the cathode.

Effect of Anode Gas Channel Height on Gas Diffusion and Cell Performance in a Molten Carbonate Fuel Cell (용융탄산염 연료전지 연료극 기체 유로 높이에 따른 가스 확산 및 단전지 성능 변화 연구)

  • Lee, Jung-Hyun;Kim, Do-Hyung;Kim, Beum-Ju;Kang, Seung-Won;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.6
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    • pp.479-484
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    • 2009
  • The effect of anode gas channel height on gas diffusion and cell performance in a 100 $cm^2$ class molten carbonate single cell is investigated. Single cell separators with three different channel height are used. The effect of the gas channel height on the distribution of the reactive gas concentration is evaluated by the two-dimensional concentration diffusion equation. The overpotential caused by concentration drop with different channel height is estimated by the voltage decay related to diffusion of reactants, well known as concentration polarization, using limiting current density. The estimation could have the possibility to identify the reactant mass transfer polarization in the complicate factors of the overall electrodes.