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Isotherm, Kinetic, Thermodynamic and Competitive for Adsorption of Brilliant Green and Quinoline Yellow Dyes by Activated Carbon (활성탄에 의한 Brilliant Green과 Quinoline Yellow 염료의 흡착에 대한 등온선, 동력학, 열역학 및 경쟁흡착)

  • Lee, Jong Jib
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.565-573
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    • 2021
  • Isotherms, kinetics and thermodynamic properties for adsorption of Brilliant Green(BG), Quinoline Yellow(QY) dyes by activated carbon were carried out using variables such as dose of adsorbent, pH, initial concentration, contact time, temperature and competitive. BG showed the highest adsorption rate of 92.4% at pH 11, and QY was adsorbed at 90.9% at pH 3. BG was in good agreement with the Freundlich isothermal model, and QY was well matched with Langmuir model. The separation coefficients of isotherm model indicated that these dyes could be effectively treated by activated carbon. Estimated adsorption energy by Temkin isotherm model indicated that the adsorption of BG and QY by activated carbon is a physical adsorption. The kinetic experimental results showed that the pseudo second order model had a better fit than the pseudo first order model with a smaller in the equilibrium adsorption amount. It was confirmed that surface diffusion was a rate controlling step by the intraparticle diffusion model. The activation energy and enthalpy change of the adsorption process indicated that the adsorption process was a relatively easy endothermic reaction. The entropy change indicated that the disorder of the adsorption system increased as the adsorption of BG and QY dyes to activated carbon proceeded. Gibbs free energy was found that the adsorption reaction became more spontaneous with increasing temperature. As a result of competitive adsorption of the mixed solution, it was found that QY was disturbed by BG and the adsorption reduced.

Evaluation of Retrieval Accuracy of NO2 Column Density from Pandora Raw Data According to Wavelength Range and Absorption Cross-section Using DOAS Method (Pandora 원시자료로부터 차등흡수분광법을 이용하여 이산화질소 칼럼 농도 산출 시 파장 구간 및 흡수단면적에 따른 산출 정확도 평가)

  • Kim, Serin;Kim, Daewon;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.38 no.2
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    • pp.215-222
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    • 2022
  • In this study, the effect of wavelength range and absorption cross-section used to retrieve nitrogen dioxide (NO2) vertical column density (VCD) from Pandora was analyzed using Differential Optical Absorption Spectroscopy (DOAS). During the GEMS Map of the Air Pollution (GMAP) 2020 campaign, data from direct sunlight observation with Pandora instrument in Seosan was used, and NO2 VCD was retrieved under four conditions. The average NO2 VCD under the four conditions ranged from 1.22×1016~1.38×1016 molec. cm-2, with a maximum difference of 0.16×1016 molec. cm-2 between each condition. The fitting error averaged 3.19~9.59%, showing an error within 10% in all cases, and the RMS was 5.11×10-3~7.16×10-3 molec. cm-2. The retrieved NO2 VCD using 4 conditions shows a slope in the range of 0.98 to 1.09 and correlation of 0.96 to 0.98 in comparison with Pandonia Global Network (PGN).

Mathematising process analysis of linear function concept based on Freudenthal's didactical phenomenology (Freudenthal의 교수학적 현상학에 기반한 일차함수 개념 수학화 과정 사례 분석)

  • Kim, Eun suk;Cho, Wan Young
    • The Mathematical Education
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    • v.61 no.3
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    • pp.419-439
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    • 2022
  • This study is based on Freudenthal's mathmatising process and the didactical phenomenology of linear function concept, I have described and examined the process in which students represent the constant rate of change into tables, graphs and equations and, in this way, how they construct mental objects and essence of the linear function concept. The students used the proportionality as composite units, when they represented the phenomenon with constant rate of change into tables. When representing in graphs, all but one student represented it into a line. There were differences among the students in the level they were using the given conditions, co-variation perspective, and corresponding rules when formulating equations. The students compared the relationship between two variables in a multiplicative way, and under the guidance of teachers they reached to the understanding that its relationship becomes a constant. Moreover, they could construct mental objects of a constant rate of change, understanding the situation where the relationship between time difference and distance difference becomes one value, namely speed. The students had difficulties in connecting the rate of change with the inclination of a line. The students constructed the essence (concept) of linear functions, after building and organizing the image that the rate of change is constant, the graph is linear, and the equation is formulated as y=ax+b (a: inclination, b: intercept).

Analysis of Dynamic Behavior on Group Piles in Two-Layered Sandy Ground (이층지반에 설치된 무리말뚝의 동적 거동 분석)

  • Heungtae Kim;Hongsig Kang;Kusik Jeong;Kwangkuk Ahn
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.10
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    • pp.51-58
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    • 2023
  • The dynamic behavior of the group piles supporting the superstructure in an earthquake is influenced by different complex dynamic mechanisms by the inertia force of the superstructure and the kinematic force of the ground. In an earthquake, The dynamic p-y curve is used to analyze the dynamic behavior of the pile foundation in consideration of the interaction of the ground, pile foundation, and superstructure due to the inertia force and the kinematic force. Most of the research has been conducted in order to confirm the dynamic p-y curve of the pile foundation by applying to the pile foundation installed on the single layered ground consisting of sand and clay, but the research for the multiple layered ground is insufficient. In this study, 1g shaking table tests were conducted to analyze the effect of the strata ratio of the top and bottom ground of the two layered sandy ground which has different relative densities on the dynamic behavior of group piles supporting the superstructure. The result shows that the maximum acceleration in the ground, the pile cap, and the superstructure increases as the strata ratio increases, and the location of the maximum bending moment of the pile foundation is changed. In addition, it was confirmed that the slope of the dynamic p-y curve of the pile foundation increased and decreased according to the strata ratio.

Effect of Sensory Integration Therapy Combined with Eye Tracker on Sensory Processing and Visual Perception of Children with Developmental Disabilities (아이트래커를 병행한 감각통합치료가 발달장애아동의 감각처리 및 시지각에 미치는 영향)

  • Kwon, So-Hyun;Ahn, Si-Nae
    • The Journal of Korean Academy of Sensory Integration
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    • v.21 no.3
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    • pp.39-53
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    • 2023
  • Objective : The purpose was the effect of sensory integration therapy combined with an eye tracker on the sensory processing and visual perception of children with developmental disabilities. Methods : It was a single-subject study with a multiple baseline design between subjects, and the intervention applied sensory integration therapy combined with an eye tracker. Visual-motor speed and saccadic eye movements were assessed at each session of baseline and intervention periods. As pre- and post-evaluation, sensory profile, Korean-Developmental Test of Visual Perception and Trail Making Test were conducted. The results of each session evaluation and pre- and post-evaluation researched the effectiveness of the intervention through visual analysis and trend line analysis. Results : As a result of the evaluation for each session, the slope of the trend line for all children in visual-motor speed and saccadic eye movement increased sharply during the intervention compared to the baseline. As a result of the pre- and post-evaluation, the sensory processing of movement, body position, and visual changed from more than that of peers to a level similar to that of peers. In visual perception, all children's ability of Visual Closure increased. As a result of Trail Making Test conducted to confirm the improvement of children's visual tracking and visual-motor abilities, all children showed a decrease in performance time after the test compared to before. Conclusion : It was confirmed that sensory integration therapy combined with an eye tracker for developmental disabilities has effect on sensory processing and visual perception. It is expected to play an important role clinically as it can stimulate children's interest and motivation in line with recent technological improvements and the spread of smart devices.

Pretreatment prognostic Factors in Early Stage Caricinoma of the Uterine Cervix (초기 자궁 경부암에서 치료전 예후 인자)

  • Kim, Mi-Sook;Hua, Sung-Whan
    • Radiation Oncology Journal
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    • v.10 no.1
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    • pp.59-67
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    • 1992
  • From March 1979 through December 1986, 124 patients with early stage carcinoma of the uterine cervix received curative radiation therapy. According to FIGO classification, 35 patients were stage IB and 89 were stge II A. In stage IB, five year locoregional control, five year disease free survival, and five year overall survival was $79.0\%$, $76.4\%$ and $81.8\%$, respectively. In stage II A, five year locoregional control, five year disease free survival, and five year overall survival were $78.0\%$, $66.8\%$, and $72.1\%$, respectively. To identify prognostic factors, pretreatment parameters including age, ECOG performance status, number of pregnancies, history of diabetes mellitus and hypertension, histology, size and shape of primary tumor, CT findings and blood parameters were retrospectively analyzed in terms of locoregional control, disease free survival and overall survival using univariate analysis and multivariate analysis. In univariate analysis, tumor size on physicai examination and rectal invasion on CT significantly affected locoregional control, disease free survival and overall survival. Parametrial involvement on CT was a significant prognostic factor on locoregional control and disease free survival. Hemoglobin level affected disease free survival and overall survival. Histology and age were significant prognostic factors on locoregional control. In multivariate analysis excluding CT finding, tumor size on physical examination was a significant factor in terms of locoregioal control and overall survival. Hemoglobin level was significant in terms of disease free survival. In multivariate analysis including CT, histology was a prognostic factor on locoregional control and disease free survival. Hemoglobin level and rectal invasion on CT were significant factors on locoregional control.

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Estimation of Surface Solar Radiation using Ground-based Remote Sensing Data on the Seoul Metropolitan Area (수도권지역의 지상기반 원격탐사자료를 이용한 지표면 태양에너지 산출)

  • Jee, Joon-Bum;Min, Jae-Sik;Lee, Hankyung;Chae, Jung-Hoon;Kim, Sangil
    • Journal of the Korean earth science society
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    • v.39 no.3
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    • pp.228-240
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    • 2018
  • Solar energy is calculated using meteorological (14 station), ceilometer (2 station) and microwave radiometer (MWR, 7 station)) data observed from the Weather Information Service Engine (WISE) on the Seoul metropolitan area. The cloud optical thickness and the cloud fraction are calculated using the back-scattering coefficient (BSC) of the ceilometer and liquid water path of the MWR. The solar energy on the surface is calculated using solar radiation model with cloud fraction from the ceilometer and the MWR. The estimated solar energy is underestimated compared to observations both at Jungnang and Gwanghwamun stations. In linear regression analysis, the slope is less than 0.8 and the bias is negative which is less than $-20W/m^2$. The estimated solar energy using MWR is more improved (i.e., deterministic coefficient (average $R^2=0.8$) and Root Mean Square Error (average $RMSE=110W/m^2$)) than when using ceilometer. The monthly cloud fraction and solar energy calculated by ceilometer is greater than 0.09 and lower than $50W/m^2$ compared to MWR. While there is a difference depending on the locations, RMSE of estimated solar radiation is large over $50W/m^2$ in July and September compared to other months. As a result, the estimation of a daily accumulated solar radiation shows the highest correlation at Gwanghwamun ($R^2=0.80$, RMSE=2.87 MJ/day) station and the lowest correlation at Gooro ($R^2=0.63$, RMSE=4.77 MJ/day) station.

A Study on Chinese Characters Play of Edo Period in Japan by Comparison with the Pattern of Tungp'o(東坡体)'s Characters Play and Paza(破字), the Method to Make an Analysis of Chinese Characters; Focused Nanji and Iruiimyo (동파체(東坡体)·파자(破字)와의 비교를 통해 본 일본근세 한자문자유희 - 난지(難字)·이루이 이묘(異類異名)를 중심으로 -)

  • Keum, Young-Jin
    • Cross-Cultural Studies
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    • v.48
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    • pp.193-222
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    • 2017
  • In this study, I examined the relationship between the pattern of Tungp'o (東坡体)'s characters play, Paza(破字) and Nanji(難字), Iruiimyo(異類異名) the Chinese characters play, developed in the Edo period in Japan. I found out the following. First, Nanji and Iruiimyo's method of Chinese character transformation is like Tungp'o(東坡体)'s characters play and Paza(破字), that is to make an analysis of Chinese character. For example, to extend or shorten to character's length, and to increase or reduce the character's size. And, I also found out there is no block type characters play in Nanji and Iruiimyo. Second, I also found that the similarity of the method of Chinese character transformation between the pattern of Tungp'o(東坡体)'s characters play, Paza(破字) and Nanji(難字), Iruiimyo(異類異名). The method of to flip character (180 degrees) and to letting character lie down (90 degrees) is very similar each other. But there is no method to make incline of character (45 degrees) in Nanji and Iruiimyo. Third, I found that the method to extract part of character also exists in Chinese and Japanese characters play. And, I also found that the method to decompose characters in half from the pattern of Tungp'o(東坡体)'s characters play, but I can't find this method from Nanji and Iruiimyo. To decompose characters in half is very like the method of paja. So, we can understand that Nanji and Iruiimyo is located in the middle stage of the pattern of between Tungp'o(東坡体)'s characters play and Paza(破字).

Feasibility study of using Halcyon LINAC for Double-target spine stereotactic body radiation therapy (이중 표적 척추 전이암의 체부정위방사선치료 시 Halcyon LINAC의 치료 유용성 평가)

  • Jeong Hee Ju;An Ye Chan;Park Byung Suk;Park Myung Hwan;Park Yong Chul
    • The Journal of Korean Society for Radiation Therapy
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    • v.34
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    • pp.51-60
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    • 2022
  • Objectives: The purpose is to evaluate dosimetric performance and delivery efficiency of VMAT with Halcyon LINAC for double target spine SBRT Materials and Methods: 12 patients with spine oligometastases were retrospectively studied. Single-isocenter spine SBRT plans was established using Halcyon® with Dual Layer MLC and Truebeam® with High Definition MLC. All patients' plans were created in Eclipse TPS through the identical conditions and optimization. C.I, H.I, G.I (Gradient Index), maximal and volumetric doses to spinal cord and low dose area were evaluated for comparison of both plans. Also, total MU and BOT(Beam On Time) were evaluated. Results: Halcyon plans was no Statistical differences in C.I and H.I. However, the average of G.I was 4.64 for Halcyon, which decreased to 5.5% compared to Truebeam (P<0.001). Halcyon plans demonstrated statistically significant reduced G.I. The average of 50% and 25% isodose volume was 487.56 cc (-3.82%, P<0.001), 1859.45 cc (-4.75%, P<0.001) in Halcyon, respectively. Significantly reduced low dose spill were observed in Halcyon plans. In the evaluation of the spinal cord, the average of Dmean and V10 of Halcyon plans in the sample group with an overlap volume of less than 1 cc was 6.802 Gy (-3.504%, P=0.067), 5.766±1.683 cc (-8.199%, P=0.002), respectively. Halcyon plans demonstrated statistically significant reduced Dmean and V10. For delivery efficiency, MU and BOT(maximum dose rate for each machine), on average, increased in Halcyon plans. However, the average of BOT(800MU/min for each machine) was 648.33 sec for Halcyon (-1.74%, P<0.001). Conclusion: Halcyon plan for double-target spine SBRT demonstrated advantages in the low dose area with a steep dose gradient, while having dosimetrically equivalent target dose distribution and spinal cord protective effect. As a result, Halcyon LINAC produced a dosimetrically improved plan for double-target spine SBRT.