• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.8
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• pp.639-648
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• 2013

This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1994.11a
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• pp.116-121
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• 1994

에너지 자원의 고갈과 환경오염 문제가 심각히 대두되고 있는 현재 액체연료에 비하여 청정 에너지인 가스의 연료화에 대한 연구는 과거 어느때보다도 그 중요성이 높이 인식되고 있다. 이에 본 연구에서 제시하는 연소기는 다공성 물질을 이용하는 연소장치로서 연소 경로를 바꾸어줌으로써 공기를 예열하는 효과를 극대화시킴과 대류열및 복사열을 방출하는 것이 큰 특징이다. 본 연구의 결과에 의하면 당량비의 감소에 따른 화염온도는 이론단열화염온도보다 높게 나타나서 당량비의 감소에 비례하여 더욱 좋은 효과를 얻을수 있었으며, 또한 왕복주기시간의 감소함에 따라 화염온도는 약간씩 증가하는 경향을 보여주었다. 이것들은 초희박 연소의 가능성을 보여준 것으로 저발열량의 연료 의 연소로 인한 에너지 절약 또는 유기화합물 즉, 페놀류나 알데히드류와 같은 공해물질들을 제거하는 연소메카니즘에 기여한 할 것이다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.457-462
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• 2011

This paper presents a numerical investigation of deflagration to detonation transition (DDT) induced by shock wave and flame interaction in ethylene-air mixtures. Also shows the change of DDT triggering time by wall cooling effect. A model is consisted of the compressible reactive Navier-Stokes equations. And the effect of viscosity, thermal conduction, molecular diffusion, chemical reaction and wall effect are included. Using this model, the generation of hot spot by repeated shock and flame interaction, occurrence of detonation, and wall cooling effect of detonation confining boundaries are studied.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.1
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• pp.75-81
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• 2012

Autoignited lifted flames in laminar jets with hydrogen-enriched methane fuels have been investigated experimentally in heated coflow air. The results showed that the autoignited lifted flame of the methane/hydrogen mixture, which had an initial temperature over 920 K, the threshold temperature for autoignition in methane jets, exhibited features typical of either a tribrachial edge or mild combustion depending on fuel mole fraction and the liftoff height increased with jet velocity. The liftoff height in the hydrogen-assisted autoignition regime was dependent on the square of the adiabatic ignition delay time for the addition of small amounts of hydrogen, as was the case for pure methane jets. When the initial temperature was below 920 K, where the methane fuel did not show autoignition behavior, the flame was autoignited by the addition of hydrogen, which is an ignition improver. The liftoff height demonstrated a unique feature in that it decreased nonlinearly as the jet velocity increased. The differential diffusion of hydrogen is expected to play a crucial role in the decrease in the liftoff height with increasing jet velocity.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.6
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• pp.593-600
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• 2019

The combustion characteristics of methane/hydrogen pre-mixed flame have been investigated with swirl stabilized flame in a laboratory-scale pre-mixed combustor with constant heat load of 5.81 kW. Hydrogen/methane fuel and air were mixed in a pre-mixer and introduced to the combustor through a burner nozzle with different degrees of swirl angle. The effects of hydrogen addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using particle image velocimetry (PIV), micro-thermocouples, various optical interference filters and gas analyzers to provide information about flow velocity, temperature distributions, and species concentrations of the reaction field. The results show that higher swirl intensity creates more recirculation flow, which reduces the temperature of the reaction zone and, consequently, reduces the thermal NO production. The distributions of flame radicals (OH, CH, C₂) are dependent more on the swirl intensity than the percentage of hydrogen added to methane fuel. The NO concentration at the upper part of the reaction zone is increased with an increase in hydrogen content in the fuel mixture because higher combustibility of hydrogen assists to promote faster chemical reaction, enabling more expansion of the gases at the upper part of the reaction zone, which reduces the recirculation flow. The CO concentration in the reaction zone is reduced with an increase in hydrogen content because the amount of C content is relatively decreased.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.6
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• pp.780-787
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• 2019

As a carbon-free, green growth alternative, internal and external interest in hydrogen energy and technology is growing. Hydrogen was added to co-axial methane, methane-propane, and methane-propane-ethane diffusion flames, which are the main ingredients of LNG, to evaluate its effect on flame formation and combustion products. The variation in combustion products produced by adding hydrogen gradually to diffusion pyrolysis at room temperature and normal pressure conditions was observed experimentally by using a gas analyzer, and the shape of diffusion pyrolysis was observed step by step using a digital camera. The experimental results showed that the production volume of nitrogen oxides tended to increase and became close to linear as hydrogen was added to the diffusion pyrotechnic. This is because the relatively high temperature of heat insulation and fast combustion speed of hydrogen facilitated the production of thermal NOx. On the other hand, CO2 production tended to decrease as hydrogen was added to reduce the overall carbon ratio contained in the mixed diffusion flame of methane, methane-propane, and methane-ethane-propane. This means that the mixed fuel use of LNG-hydrogen in ships may potentially reduce emissions of CO2, a greenhouse gas.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.3
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• pp.251-257
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• 2012

This work presents an experimental investigation of NOx emissions according to inlet air temperature (550-660 K), stoichiometric air ratio (${\lambda}$, 1.4-2.1), and elevated pressure (2-5 bar) in a High Press Combustor (HPC) equipped with a double cone burner, which was designed by Pusan Clean Coal Center (PC3). The exhaust-gas temperature and NOx emissions were measured at the end of the combustion chamber. The NOx emissions generally decreased as a function of increasing ${\lambda}$. On the other hand, NOx emissions were influenced by ${\lambda}$, inlet air temperature and pressure of the combustion chamber. In particular, when the inlet air temperature increased, the flammability limit was extended to leaner conditions. As a result, a higher adiabatic temperature and lower NOx emissions could be achieved under these operation conditions. The NOx emissions that were governed by thermal NOx were greatly increased under elevated pressures, and slightly increased at sufficiently low fuel concentrations (${\lambda}$ >1.8).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.9
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• pp.727-734
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• 2015

Recently, because of the increased oil prices globally, there have been studies investigating the improvement of fuel-conversion efficiency in internal combustion engines. The improvements realized in thermal efficiency using lean combustion are essential because they enable us to realize higher thermal efficiency in gasoline engines because lean combustion leads to an increase in the heat-capacity ratio and a reduction of the combustion temperature. Gasoline direct injection (GDI) engines enable lean combustion by injecting fuel directly into the cylinder and controlling the combustion parameters precisely. However, the extension of the flammability limit and the stabilization of lean combustion are required for the commercialization of GDI engines. The reduction characteristics of three-way catalysts (TWC) for lean combustion engines are somewhat limited owing to the high excess air ratio and low exhaust gas temperature. Therefore, in the present study, we assess the reaction of exhaust gases and their production in terms of the development of efficient TWCs for lean-burn GDI engines at 2000 rpm / BMEP 2 bar operating conditions, which are frequently used when evaluating the fuel consumption in passenger vehicles. At the lean-combustion operating point, $NO_2$ was produced during combustion and the ratio of $NO_2$ increased, while that of $N_2O$ decreased as the excess air ratio increased.