• Proceedings of the Materials Research Society of Korea Conference
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• 2009.11a
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• pp.13.1-13.1
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• 2009

에어로젤은 인류가 개발한 소재 중에서 가장 가벼운 고체로, 기공률이 90%이상이고 비표면적은 ~1000m2/g, 기공의 크기는 10nm 크기로 이루어진 나노기공 물질이다. 1931년에 Kisley가 물유리로부터 실리카 에어로젤을 합성한 이래로 실리카 에어로젤에 대한 연구가 가장 많이 이루어져왔으며, 단열소재, 흡음재, 체렌코프우주선 디텍터, 반도체의 초저유전소재, 유출된 석유의 정제, 촉매 등에 대한 응용에 대해서도 연구가 많이 이루어져 왔다. 그리고TiO2와 같은 광촉매 에어로젤 소재, 카본 에어로젤 소재등 다양한 나노기공 소재에 대해서도 연구가 이루어지고 있으며, 카본 에어로젤의 경우 나노기공과 비표면적을이용한 전기이중층 커패시터 (EDLC)에 대한 연구도 이루어지고 이다. 본 연구에서는 첫째로, 실리카 에어로젤에 대한 연구결과를 소개하고 이의 단열소재로서의 응용가능성에대하여 언급하고자 한다. 실리카 에어로젤 나노기공 소재의 경우, 기공크기가 10nm크기로 매우 작고 공기의 자유이동길이와 거의 비슷하여서 대류에 의한 열전달을 낮출 수 있으며, 낮은 고체함량으로 인하여 포논에 의한 열전달을 낮출 수 있기 때문에 단열소재로서 최고의 성능을 나타낸다. 하지만, 문제는 높은 기공률로 인한 기계적인 취약성이 문제이다. 따라서 이를 보완하기 위항 섬유로 에어로젤을 보강할 수 있는데, 이를통하여 에어로젤 나노기공소재와 섬유보강에 의한 복합화에 대하여 말하고자 한다. 또 다른 하나의 연구방법은유기-무기 하이브리드 나노기공 소재를 합성하는 것이다. 여기서는하나의 방법으로 MTEOS-TEOS의 하이브리드화와 초임계 건조공정에 의한 나노기공 소재에 대한 연구결과를소개하고자 한다. 마지막으로 카본 에어로젤 나노기공소재의 합성과 나노기공 구조의 제어 및 물성평가에 대한 것을 말하고자하는데, 본 발표에서는 레소시놀과 포름알데히드를 촉매에 의한 중합반응을 통하여 유기 에어로젤 소재를 합성하고 분위기에서탄소화 공정을 통하여 카본에어로젤을 합성하였다. 또한 금속 니켈을 도입하는 것에 의하여 탄소/니켈 복합 하이브리드 에어로젤 소재를 합성하고 슈퍼커패시터 전기화학 특성에 대한 연구결과를 발표하고자 한다.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.9 no.2
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• pp.99-105
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• 2011

An integrated model for groundwater flow and radionuclide transport analyses is being developed incorporating six underground silos, an excavated damaged zone (EDZ), and fractured host rock. The model considers each silo as an engineered barrier system (EBS) consisting of a waste zone comprising waste packages and disposal container, a buffer zone, and a concrete lining zone. The EDZ is the disturbed zone adjacent to silos and construction & operation tunnels. The heterogeneity of the fractured rock is represented by a heterogeneous flow field, evaluated from discrete fractures in the fractured host rock. Radionuclide migration through the EBS in silos and the fractured host rock is simulated on the established heterogeneous flow field. The current model enables the optimization of silo design and the quantification of the safety margin in terms of radionuclide release.

• Journal of Soil and Groundwater Environment
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• v.7 no.1
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• pp.3-14
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• 2002

We analyzed hydrologic time-series data obtained from a fractured aquifer in Wonju and a porous shallow aquifer in Uiwang area. Auto-correlation, spectral density, and cross-correlation functions were used for the analyses. Water level at a shallow well in Wonju was weakly auto-correlated and it was sensitive to direct infiltration from rainfall through soil zone while that at a well screened in the fractured zone showed a relative stability to an outer stress (rainfall), which was derived from a delayed transmission of recharge stress through a fracture network from a remote area. Characteristics of time-series data in Uiwang area were similar to those in the fractured zone in Wonju. This was caused by a regional recharge from a distant area rather than a direct infiltration. This study demonstrated a usefulness of time series analyses for identification of recharge mechanism.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.2
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• pp.61-72
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• 1997

With increasing activities for groundwater withdrawal and for the construction of underground cavern in the coastal areas, the seaward flow of groundwater has been disturbed or even reversed, resulting in seawater intrusion in aquifers. This phenomenon would be attributed to the freshwater contamination and the corrosion of steel materials. The hydrogeological and geochemical investigations have performed to characterize the seawater intrusion into the underground caverns located in the coastal area. Assumimg the inland aquifer as unconfined one, we have found out that the theoretical interface of freshwater-seawater is far different from the pathways identified. In the study site, the main pathways of seawater intrusion into the underground cavern are characterized as the sub-horizontal fractures (zones). The seawater intrusion in granitic terrane would depend mainly on the characteristics of conductive fracture system developed along the coastal area.

• Journal of the Korean Association of Geographic Information Studies
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• v.16 no.4
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• pp.29-38
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• 2013

This study is to construe the spatio-temporal characteristics of temperature in cities and the changes of climatical regions by analyzing a climate change in Korea peninsular. We used daily mean air temperature data which were collected in South and North climate stations for the past 34 years from 1974 to 2007. We created temperature maps of 500m resolution with Inverse Distance Weight in application with adiabatic lapse rate per month in linear relation with height and temperature. In the urbanization area, the data analyzed population in comparison with temperature changes by the year. The south climate region in Korea by the Warmth index was expanded to the middle climate region by the latitude after 1990s. A rise of mean temperature was $0.5{\sim}1.2^{\circ}C$ in urban areas such as Seoul, metropolitan and cities which had a rapid urbanization and industrialization with the population increase between 1980s and 1990s. In case of North Korea, cities such as Pyeongyang, Anju, Gaecheon, and Hesan had the same pattern.

• The Journal of the Korea institute of electronic communication sciences
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• v.10 no.5
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• pp.587-592
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• 2015

According to increase in the use of the LED, the demand for low power consumption LED display design of the controller block has increased. In this paper, the low power LED controller block was designed through the power source supply that leads adiabatic operation from constant current source circuit operated by digital signal control. The proposed circuit was implemented using a 0.35um CMOS process. and it demonstrated linear operation of the circuit. From the simulation result, the proposed circuit was evaluated with about 82% power consumption reduction effect in comparison with conventional LED controller block. This research is expected to be helpful for the low power operation and the solution for heat problem of LED display.

• Journal of the Korea Institute of Military Science and Technology
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• v.14 no.3
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• pp.524-531
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• 2011

The cryogenic vessel, storing a liquified solutions as LOX and $LN_2$, consists of a external vessel, internal vessel, thermal insulator and internal support. The internal support should be satisfied with mechanical strength not only to support weight of internal tank but also to maintain uniform space between external and internal tank in spite of external mechanical shock. However, excessive structure design of internal supports is able to increase the amount of heat conduction and the rate of vaporization. The thermal insulator, filled with space between a external and internal vessel, reduces the rate of heat transfer and guarantees the standing time of cryogenic vessel. Especially powder type of insulator has low thermal conductivity and reduce the specification of structure design. In order to evaluate the effect of insulator on structure design, the experiment set-up simulated cryogenic vessel was tested in shock environment according to thermal insulator. As a result, the behavior of internal support under external shock was understood and the design criteria was able to be suggested.

• The Journal of the Petrological Society of Korea
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• v.8 no.3
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• pp.171-182
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• 1999

The Myeonbongsan caldera, 10.2X8.0 km, developed within older sequences of sedimentary formations and intermediate composition volcanis in the southern Cheongsong area. Volcanic rocks in the caldera block include lower intermediate volcanics, middle tuffaceous sequences and upper silicic ones. The silicic volcanics, which is named Myeonbongsan Tuff, are composed of crystal-rich ash-flow tuff(300 m) , bedded tuff(30 m) and pumice-rich ash-flow tuff(700 m) in ascending order. Several intrusions dominate the early sequences within the caldera. The caldera collapsed in a trapdoor type when silicic ash-flow tuffs erupted fro major vent area in the caldera. Normal faulting along a ring fault system except the southwestern part dropped the tuffs down to the northrase with a maximum displacement of about 820 m. The Myeonbongsan Tuff is just about 1,030 m thick inside the northeastern caldera, with its base not exposed, and southwestward thinning down. Rhyolitic plug and ring dikes are emplaced along the central vent and the caldera margins, and the ring dikes are cut by plutonic stocks in the southeastern and northwestern parts. The caldera volcanism eviscerated the magma chamber by a series of explosive eruptions during which silicic magma was erupted to form the Myeonbongsan Tuff. Following the last ash-flow eruption, collapse of the chamber roof resulted in the formation of the Myeonbongsan caldera, a subcircular trapdoor-type depression subsiding about 820 m deep. After the collapse, stony to flow-banded rhyolites were emplaced as circular plugs and ring dikes along the central vent and the caldera margins respectively. Finally after the intrusions, another plutons were emplaced as stocks outside the caldera.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.158-158
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• 2016

최근 화석연료의 고갈과 환경 보전 및 에너지 절약에 대한 관심이 높아짐에 따라 화석연료의 소비를 최소화하고 실내조건을 쾌적하게 유지하려는 연구가 진행되고 있다. 국내의 경우 전체 에너지 소비의 30%이상을 차지하고 있는 건물부문에서의 에너지 소비를 줄이기 위한 활발한 연구가 진행되고 있으며 이에 따른 에너지절약 소재개발이 활발하게 진행되고 있다. 1975년 이후 여러 차례에 걸친 단열강화 조치를 통해 건물에서의 에너지 소모를 줄이고 있었으나 건물의 외벽에 대한 사항으로 한정되어있었고, 또한 건물의 창 면적이 증가함에 따라 창을 통한 열손실량과 열획득량이 더욱 증가하게 되었다. 이러한 문제를 해결하기 위해 열반사유리에 대한 많은 연구가 진행되고 있다. 열반사유리는 근적외선(열선)영역의 빛을 반사시켜 실내의 열손실량 및 외부에서의 열획득량을 감소시켜 에너지의 소비를 줄일 수 있는 유리을 말한다. 이러한 열반사유리은 fresnel 방정식을 통해 빛의 파장대에 따른 반사율 및 투과도를 예측할 수 있는데, 다층박막구조인 Oxide-Metal-Oxide(OMO)구조는 Oxide의 높은 굴절률과 Metal의 낮은 굴절률을 통해 가시광영역대의 높은 투과도와 근적외선 영역의 높은 반사율을 얻을 수 있다. 또한 Metal층을 삽입함으로서 flexible한 코팅이 가능하고, 높은 carrier density와 mobility로 표면 플라즈몬 공명을 통해 특정 파장대의 반사율을 높일 수 있으므로 많은 연구가 진행되고 있다. $TiO_2$는 고굴절률 및 낮은 광흡수성의 특성을 가지는 산화물반도체로 기존의 $In_2O_3$계 산화물에 비해 값이 싸고 높은 안정성과 광촉매특성을 보이므로 외부에 노출된 환경에 적합한 재료이다. Ag는 저굴절률과 낮은 광흡수성을 가지는 재료로 금속층에 적합하다. 본 연구에서는 fresnel 방정식을 통해 반사도 및 투과도를 예측하고 마그네트론 스퍼터링법으로 다층박막을 열선인 적외선 영역에서의 반사율 및 반사 효율을 평가하였다. Index-matching 시뮬레이션을 통해 $TiO_2/Ag/TiO_2$ 다층박막의 투과도와 반사도를 이론적으로 검토하였다. 시뮬레이션 프로그램은 Macleod프로그램을 이용하였고 재료 각각의 굴절률은 Ellipsometry를 이용하여 측정하였다. 두께 40 nm 와 8 ~ 16 nm를 가지는 $TiO_2$층과 Ag층을 각각 RF/DC 마그네트론 스퍼터링법을 이용하여 Glass기판 위에 증착하였다. 직경 3 in 의 $TiO_2$, Ag 소결체 타깃을 이용하였고 스퍼터링 파워는 각각 200 W, 50 W로 설정하였고, 스퍼터링 가스는 Ar가스의 유량을 20 sccm으로 설정하였다. 작업압력은 모두 1 Pa로 설정하였고 타깃 표면의 불순물 및 이물질 제거를 위해 Pre-sputtering을 10분 진행하였다. 박막의 두께는 reflectometer와 Alphastep을 이용하여 측정하였고 Hall effect measurement를 이용하여 비저항, carrier density, mobility등 전기적 특성을 측정하였다. 또한 UV-VIS spectrometer와 USPM-RU-W NIR Micro-Spectrophotometer를 통해 광학적 특성을 측정하였고 계산 값과 비교분석하였다. 또한 열반사 특성을 평가하기 위해 직접 set-up한 장비를 이용하였다. 단열 박스에 샘플을 장착해 적외선 램프를 조사하였을 때의 열 반사효율을 평가하였고, IR Camera를 이용하여 단열 박스 내부의 온도 변화를 관찰하였다.

• The Journal of the Petrological Society of Korea
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• v.7 no.1
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• pp.53-68
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• 1998

Microstructural and rock structural analyses on the deformed Cheongsan granite characterized by abundant K-feldspar megacrysts have been carried out to understand the temperature condition for the ductile shear deformation. In K-feldspar, microkinks, microfractures and core-and-mantle structures without the development of subgrains in outer core-zone are the most common microstructures observed. Myrmekites and flame perthites are developed at the strain-localized areas along the microfractured K-feldspar. In plagioclase, microfractures, deformation twins and kink bands are predominant. The deformation twins cut across the igneous zonation of the plagioclase. Patterns of c-axis fabrics of dynamically recrystallized new quartz grains display single girdle and type II crossed girdle where prism slip system is predominant. These characteristic microstructures produced during the ductile shearing suggest that the ductile shear deformation in the Cheongsan granite occurred under epidote-amphibolite conditions($400-500^{\circ}C$). Three main shear zones are recognized at outcrop scale: discrete shear zone with anastomosing high-strain domain, shear zone with pervasive S-C structure and shear zone with homogeneously foliated domain. Geometric features of these shear zones produced during the ductile shear deformation are controlled by amount of strain under the $400-500^{\circ}C$ deformation temperature.