• 해양환경안전학회지
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• 제18권1호
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• pp.55-60
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• 2012

매연과 다중고리 방향족 탄화수소의 생성에 대하여 n-헵탄의 혼합의 영향을 알아보기 위하여 순수에틸렌 대향류 확산화염에 n-헵탄을 소량 혼합하여 실험을 수행하였다. 매연체적분율과 PAH의 생성 계측에서는 레이저 유도 형광법 (laser-induced fluorescence; LIF)과 레이저 유도 백열법(laser-induced incandescence; LII)의 레이저 계측법을 이용하였다. 실험결과로 순수 에틸렌 화염에 소량의 n-헵탄을 혼합한 경우에는 매연과 다중고리 방향족 탄화수소가 상승하였다. 그러나 20% n-헵탄 혼합화염의 경우 LIF 신호가 감소하였다. 소량의 혼합화염의 경우, 다중고리 방향족 탄화수소와 매연의 상승은 n-헵탄 혼합에 의해 저온 영역에서의 메틸 라디칼의 증가로 의한다고 사료된다. 10% n-헵탄 혼합화염에 대한 화학반응 프로세스를 살펴본 결과 H 라디칼에 의한 반응율이 벤젠 생성에 결정적인 역할을 한다는 것을 알 수 있었다.

• 한국자동차공학회논문집
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• 제7권5호
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• pp.40-54
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• 1999

The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2004년도 추계학술대회 논문집
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• pp.108-111
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• 2004

Laser induced incandescence and laser induced fluorescence techniques have been investigated to measure the concentrations of soot and PAH, respectively. The Nd:YAG and dye lasers were used to form a sheet beam, and its wavelength were modulated to obtain a optimized signals of soot and PAH. Results showed that the relative size groups of soot and PAH can be measured by using our laser techniques.

• 한국연소학회:학술대회논문집
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• 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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• pp.89-102
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• 1997

대향류 확산 화염의 매연 생성 특성에 대한 실험적 연구가 수행되었으며, 그 결과 에틸렌 ($C_2H_4$)-프로판($C_3H_8$) 혼합 연료의 경우 매연 생성 상승 효과 (synergistic effect)가 관측되었다. 프로판과 에틸렌의 PAH 생성 양상이 상이하게 나타났으며, 소량의 프로판을 에틸렌 확산 화염에 첨가할 경우 순수 연료에 비하여 매연 및 PAH (다중 고리 방향족 탄화수소; polycyclic aromatic hydrocarbon) 생성이 증대되었다. 단조적으로 변화하는 아세틸렌($C_2H_2$) 농도와 단열 화염 온도를 고려할 때, 이러한 결과는 HACA (H-abstraction-$C_2H_2$-addition) 반응만으로는 확산 화염에서의 매연 발생 및 성장을 설명할 수 없음을 의미한다. 수치해석과 실험 결과의 비교로부터 초기 PAH의 생성 과정을 규명하였으며 이 과정에서 C3 화학종의 재결합 반웅이 매우 중요함을 확인할 수 있었다. 또한, 이러한 C3 화학종과 C2 화학종의 상호 보완적인 역할에 의하여 에틸렌-프로판 혼합 연료에서 매연 생성이 증대됨을 밝혔다.

• 한국자동차공학회논문집
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• 제13권1호
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• pp.51-59
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• 2005

Co-flow laminar diffusion flames' temperature has been studied experimentally for ethylene$(C_2H_4)$ using a co-flow burner in order to investigate the characteristics of diffusion flame's temperature distribution. The temperature distributions in the flame were measured by rapid insertion of a R-type thermocouple. The measurement area was divided into three zones. 1st area was expect to created PAH zone, Il nd area was expect to form soot zone, which is known to generate most soot volume fraction, and III rd area was expect to from soot oxidization zone. Also The temperature along the flame y-axis as a fuel quantity was measured. As a results, we have measured temperature neglecting the effect of soot particles attached to the thermocouple junction, which is close to the nozzle and upstream zone has a unstable flow in co-flow diffusion flame and acquires that the flame y-axis temperature has a uniform temperature in the generated soot volume fraction zone(II nd).

• 한국자동차공학회논문집
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• 제13권2호
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• pp.178-185
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• 2005

The synergistic effect of ethylene/propane mixture on soot formation is studied experimentally using a concentric co-flow diffusion burner, which provides the stratified fuel mixture. The soot volume fraction, soot particle diameter, number density and PAH concentrations are measured with various fuel supply configurations and compared to the homogeneously mixed case. When propane is supplied through the inner nozzle, an increase of soot formation is observed. However, when propane is supplied through the outer nozzle, a decrease is observed. The reaction path of PAH's formed from the pyrolysis process of propane is likely to be responsible to the observed differences. When propane is supplied through the outer nozzle, PAH's are formed in the relatively near oxidation region and exposed to the oxidization environment; on the other hand, when propane is supplied through the inner nozzle, PAH's are not likely to be oxidized and thus get involved in soot formation process. The synergistic effect in ethylene/propane diffusion flames is found to be affected not only by the com position of the mixture but also by the way of mixing.

• 대한기계학회논문집B
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• 제28권7호
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• pp.863-870
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• 2004

The temperature and soot particle measurement technique in a laminar diffusion flame has been studied to investigate the characteristics of soot particle with temperature using a co-flow burner. The temperature distribution in the flame were measured by rapid insertion of a R-type thermocouple and the soot particles by LEM/LIS techniques. In these measurement, soot volume fraction, number density and soot diameters were analyzed experimentally. As a results, the spacial distributions of particle volume fraction, soot diameter, and number density are mapped throughout the flame using the Rayleigh theory for the scattering of light by particles. A laser extinction method was used to measure the soot volume fraction and laser induced scattering method was used to measure the soot particle diameter and number density. Also, we measured temperature without the effect of soot particles attached to the thermocouple junction, which is close to the nozzle. In this result, we found that upstream zone has a unstable flowing in co-flow diffusion flame and the y-axis temperature of flame has a uniform temperature distribution in the most soot volume fraction zone.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.1267-1273
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• 2004

The temperature and soot particle measurement technique in a laminar diffusion flame have been studied to investigate the characteristics of soot particle with temperature using a co-flow burner. The temperature distributions in the flame were measured by rapid insertion of a R-type thermocouple and the soot particles were detected were detected by LEM/LIS techniques. In these measurement, soot volume fraction, number density and soot diameters were analyzed experimentally. As a results, the spacial distributions of particle volume fraction, soot diameter, and number density are mapped throughout the flame using the Rayleigh theory for the scattering of light by absorbing particles. A laser extinction method was used to measure the soot volume fraction and Laser induced scattering method was used to measure the soot particle diameter and number density. Also, we measured temperature without the effect of soot particles attached to the thermocouple junction, which is close to the nozzle. In this result, we found that upstream zone has a unstable flowing in co-flow diffusion flame and the y-axis temperature of flame has a uniform temperature distribution in the most soot volume fraction zone.

• 한국자동차공학회논문집
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• 제10권6호
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• pp.80-89
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• 2002

The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2006년도 제27회 추계학술대회논문집
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• pp.150-153
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• 2006

액체 로켓 엔진의 가스발생기는 터빈 블레이드의 열적 손상을 막기 위해 온도의 제한이 있으며 이를 위해 농후 또는 희박 연소를 하게 된다. 따라서 비평형 화학 반응이 주로 발생하며 이를 해석하는 것은 매우 어렵다. 본 연구에서는 케로신과 액체산소를 추진제로 하는 가스발생기에 대하여 Dagaut이 제안한 상세 화학 반응 단계를 사용하여 완전 혼합 반응기 연소 모델의 수정을 통해 계산하였으며, Frenklach의 soot 모델을 적용하여 예측 결과의 몰 분율, 가스 물성치 등의 결과에 대한 개선 방향을 제시하였다.