• 제목/요약/키워드: 다공질 재료

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초음파 트랜스듀서용 PZT-고분자 3-3형 복합압전체의 유전 및 압전특성 (Dielectric and piezoelectric properties of PZT-polymer 3-3 type composite for ultrasonic transducer applications)

  • 박정학;이수호;최헌일;사공건;배진호
    • E2M - 전기 전자와 첨단 소재
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    • 제9권2호
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    • pp.146-151
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    • 1996
  • PZT powders were prepared by the molten salt synthesis method. The porous PZT ceramics were made from a mixture of PZT and polyvinylalcohol(PVA) by BURPS(Bumout Plastic Sphere) technique. The 3-3 type composites were fabricated by impregnating an sintered porous PZT ceramics with various polymer matrices. The relative permittivity of 3-3 type composite specimens was shown 860-1,100 smaller than that of solid PZT ceramics(2,100), and the dissipation factors of composite specimens were about 0.02 to 0.03. The piezoelectric coefficient d$_{33}$ of composite specimens(285-328*10$^{12}$ C/N) was comparable with that of single phase PZT specimens(364*10$^{-12}$ C/N). The thickness mode coupling factor k$_{t}$(O.5-0.6) of composite specimens was comparable with that of single phase PZT specimens(k$_{t}$-0.7), and the mechanical quality factor of composite specimens was smaller than 10, and thus these 3-3 type composite specimens would be believed as a good candidates for broad band transducer applications.ons.

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벌크형 와이어직조 카고메 트러스 PCM의 압축거동 (II) - 결함의 영향 - (Mechanical Behaviors under Compression in Wire-woven Bulk Kagome Truss PCMs (II) - Effects of Geometric and Material Imperfections -)

  • 현상일;최지은;강기주
    • 대한기계학회논문집A
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    • 제31권7호
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    • pp.792-799
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    • 2007
  • A newly developed cellular metal based on kagome lattice is an ideal candidate for multifunctional materials achieving various optimal properties. Intensive efforts have been devoted to develop efficient techniques for mass production due to its wide potential applications. Since a variety of imperfections would be inevitably included in the realistic fabrication processes, it is highly important to examine the correlation between the imperfections and material strengths. Previous performance tests were mostly done by numerical simulations such as finite element method (FEM), but only for perfect structures without any imperfection. In this paper, we developed an efficient numerical framework using nonlinear random network analysis (RNA) to verify how the statistical imperfections (geometrical and material property) contribute to the performance of general truss structures. The numerical results for kagome truss structures are compared with experimental measurements on 3-layerd WBK (wire-woven bulk kagome). The mechanical strength of the kagome structures is shown relatively stable with the Gaussian types of imperfections.

알루미늄 나선형 와이어로 직조된 다층 Kagome Truss PCM의 유동 및 열전달 특성에 관한 연구 (A Study on the Fluid Flow and Heat Transfer Characteristics for the Wire-woven Bulk Kagome(WBK) Composed of Aluminum Helix Wires)

  • 주재황;강보선;강기주
    • 대한기계학회논문집B
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    • 제32권1호
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    • pp.15-22
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    • 2008
  • Recently, ultra-lightweight materials with open, periodic cell structures take much attention owing to its potential for multi-functionality such as load bearing, thermal dissipation, and actuation. This paper presents experimental results on the fluid flow and heat transfer characteristics for the Wire-woven Bulk Kagome (WBK) composed of aluminum 1100 wires. The overall pressure drop and heat transfer of the WBK specimen was experimentally investigated under forced air convection condition. The pressure loss and heat transfer performance of the aluminum WBK were compared with other heat dissipation media. It was shown that heat transfer characteristics depended on relative density and surface area density. Comparison with metal foams and other heat dissipation media such as packed beds, lattice frame materials, louvered fins, and others suggests that the aluminum WBK competes favorably with the best available heat dissipation media in heat transfer performance.

벌크형 와이어직조 카고메 트러스 PCM 의 압축거동- 제 2 보: 결함의 영향 (Mechanical Behaviors under Compression in Wire-woven Bulk Kagome Truss PCMs-Part II: Effects of Geometric and Material Imperfections)

  • 현상일;최지은;강기주
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.78-83
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    • 2007
  • A newly developed cellular metal based on kagome lattice is an ideal candidate for multifunctional materials achieving various optimal properties. Intensive efforts have been devoted to develop efficient techniques for mass production due to its wide potential applications. Since a variety of imperfections would be inevitably included in the realistic fabrication processes, it is highly important to examine the correlation between the imperfections and material strengths. Previous performance tests were mostly done by numerical simulations such as finite element method (FEM), but only for perfect structures without any imperfection. In this paper, we developed an efficient numerical framework using nonlinear random network analysis (RNA) to verify how the statistical imperfections (geometrical and material property) contribute to the performance of general truss structures. The numerical results for kagome truss structures are compared with experimental measurements on 3-layerd WBK (wire-woven bulk kagome). The mechanical strength of the kagome structures is shown relatively stable with the Gaussian types of imperfections.

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이중층 Ti전극이 적용된 TCO-less 염료 감응형 태양전지에 관한 연구

  • 김민태;김윤기;위성석;김동현;이해준;이호준
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.372-372
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    • 2011
  • 염료 감응형 태양전지는 상,하판 투명전극(TCO), 나노입자의 다공질 TiO2, 염료 고분자 층으로 구성된 광전극과 투명전극 및 백금(Pt) 박막으로 구성된 상대전극 그리고 두 전극 사이를 산화 환원용 전해질 용액으로 채우고 있는 구조이다. 이 구조에서 투명전극(TCO)은 재료비의 많은 부분을 차지하므로 제작비용 절감을 위한 TCO-less에 관한 연구가 활발히 진행 중이다. 본 연구에서는 TCO-less 염료 감응형 태양전지 제작을 위해 이중층 Ti 전극 구조를 제안하였다. 제작과정은 광조사 부분을 확보한 유리기판에 e-beam 증착법을 이용해 Ti 전극을 증착시킨 후 TiO2를 Ti전극과 일부 중첩하여 인쇄하고 그 위에 두 번째 Ti전극을 제작한다. 이중층 Ti전극 구조는 SEM, EIS 등의 분석장비를 사용하였고 기존 FTO 구조에 비해 단락전류밀도, 에너지 변환효율은 감소하였으나 직렬 내부저항이 약 27% 감소하여 fill factor가 28% 향상된 결과를 얻을 수 있었다.

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금속기질에 앓은 마이크로 다공질 스케폴드 코팅에 관한 연구 (Thin Micro-Porous Scaffold Layer on Metallic Substrate)

  • 신동춘;자이젱 미아오;김원철
    • 동력기계공학회지
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    • 제14권5호
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    • pp.41-47
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    • 2010
  • 티타늄과 티타늄 합금은 재료적 특이성 때문에 심장 혈관 임플란트에서 일반적으로 사용되어 왔다. 일찍이 적용된 예로는 인공심장판막, 심박조율기의 보호케이스, 혈액 순환 장치 등이 있다. 하지만 물질유도혈전증(Material-induced thrombosis)은 혈전폐색에 의해 기인한 기능 손실로 심장혈관 임플란트 장치의 주된 합병증으로 존재하고 있으며, 심장혈관 임플란트의 혈전유전자는 심장혈관장치의 발달에 주된 난관 중 하나로 남아있다. 그리고 텍스처 혈액 접합 물질(Textured blood-contacting material)은 1960년대 초반 이후부터 혈액순환 보조 장치의 임상실험에 사용되고 있다. 접합 물질에 내장된 텍스처 섬유조직 표면은 형성, 성장, 안정적 부착, 생물학적 내벽(neointimal layer) 등 유도 혈액(entrapping blood) 성분에 의해 형성된다. 공동(cavity) 형상의 용해 가능한 미립자를 사용하는 SCPL법(Solvent casting/particulate leaching method)은 티타늄 기질 이전에 형성된 폴리우레탄 위에 텍스처(texture)를 생성하기 위해 사용되었다. 또한 콜라겐의 부동화(不動化)에 의한 공동(cavity)은 혈액 접합면에 잔존하기 위한 내피세포를 고정할 수 있는 효과가 있다. cpTi로 층화된 PU 기소공성(microporous)은 구조적 특성과 혈전증 감소를 위한 생물학적 내벽 사용의 잠재성을 평가하기 위한 세포 공동체 실험을 통해서 평가되었다.

다공질 Ni 및 Ni-Cr으로 강화한 AC4C 복합재료의 제조 및 특성연구 (A Study for Characteristic and Manufacturing of Porous Ni/AC4C and Ni-Cr/AC4C Composites)

  • 김용현;김억수;여인동;이광학
    • 한국주조공학회지
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    • 제20권1호
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    • pp.21-28
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    • 2000
  • Ni and Ni-Cr porous metals which are estimated to be easy to fabricate by squeeze casting are used as strengtheners for composite materials. As a matrix material, Al-7%wtSi-0.3 wt%Mg(AC4C) has been used. In case of Ni/AC4C and Ni-Cr/AC4C composite, $750^{\circ}C$ melt temperature and minimum 25 MPa squeezing pressure are needed to produce sound composite materials. The observation of interfacial reaction zone at various heat treatment condition showed that solutionizing temperature of above 520^{\circ}C$, the interfacial reaction zone increased proportionally with increasing heat treatment tim and reaction products formed by interfacial reaction are mainly composed of $Al_3Ni$ and $Al_3Ni_2$ phases. The tensile strength of Ni/AC4C and Ni-Cr/AC4C composite is lower than the matrix metal and this can be explained by the brittle intermetallic compounds formed at the interface of Ni and Ni-Cr reinforcements. But the properies of hardness, wear resistance and thermal expansion are better than the matrix due to the strengthening effect of Ni-Cr porous metals.

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열처리 온도 및 분위기에 따른 다공질 실리콘의 구조 및 광학적 특성 (Effects of Annealing Temperature and Atmosphere on Properties of Porous Silicon)

  • 최현영;임광국;전수민;조민영;김군식;김민수;이동율;김진수;김종수;임재영
    • 한국전기전자재료학회논문지
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    • 제23권8호
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    • pp.581-586
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    • 2010
  • The porous Si (PS) was annealed at various temperature in air, argon, and nitrogen atmosphere. Structural and optical properties of the annealed PS were investigated by scanning electron microscopy (SEM) and photoluminescence (PL). It is found that the shape of pore is changed from circle to channel as increasing annealing temperature which was annealed in air and argon atmosphere. In case of PS annealed in nitrogen atmosphere, the shape of pore is changed from channel to circle with increase annealing temperature from 600 to $800^{\circ}C$. The PL peak position is blue-shifted with increasing annealing temperature. As annealing temperature increases, the PL intensity of the PS annealed in argon is decreased but that of the PS annealed in nitrogen is increased. It might be due to the formation of Si-N bonds and it passivates the non-radiative centers which is Si dangling bonds on the surface of the PS.

질소가 도핑된 다공질 3C-SiC 박막의 열적, 기계적 특성 (Thermal and Mechanical Properties of a N2 Doped Porous 3C-SiC Thin Film)

  • 김강산;정귀상
    • 한국전기전자재료학회논문지
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    • 제23권8호
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    • pp.651-654
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    • 2010
  • This paper describes the thermal and mechanical properties of doped thin film 3C-SiC and porous 3C-SiC. In this work, the in-situ doped thin film 3C-SiC was deposited by using atmospheric pressure chemical vapor deposition (APCVD) method at $120^{\circ}C$ using single-precursor hexamethyildisilane: $Si_2(CH_3)_6$ (HMDS) as Si and C precursors. 0~40 sccm $N_2$ gas was used as doping source. After growing of doped thin film 3C-SiC, porous structure was achieved by anodization process with 380 nm UV-LED. Anodization time and current density were fixed at 60 sec and 7.1 mA/$cm^2$, respectively. The thermal and mechanical properties of the $N_2$ doped porous 3C-SiC was measured by temperature coefficient of resistance (TCR) and nano-indentation, respectively. In the case of 0 sccm, the variations of TCR of thin film and porous 3C-SiC are similar, but TCR conversely changed with increase of $N_2$ flow rate. Maximum young's modulus and hardness of porous 3C-SiC films were measured to be 276 GPa and 32 Gpa at 0 sccm $N_2$, respectively.

카고메 트러스로 보강한 콘크리트 부재의 전단 보강효과에 관한 기초 연구 (Pilot Study on the Shear Strengthening Effect of Concrete Members Reinforced by Kagome Truss)

  • 김우;강기주;이기열
    • 대한토목학회논문집
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    • 제32권4A호
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    • pp.237-244
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    • 2012
  • 콘크리트는 재료적으로 인장에 취약하고 변형에 취성이 크다는 태생적 단점을 갖고 있다. 콘크리트 조직에 인장에 강한 작은 섬유를 혼합한 섬유보강콘크리트는 이러한 취약점을 보완할 수 있는 좋은 방법으로 간주되었으며, 많은 종류의 섬유재료와 방법들이 제안되었다. 그러나 이 섬유보강콘크리트에도 아직까지 해결하지 못한 문제로서 균질한 배합이 힘들고 높은 체적비를 갖는 섬유 혼입의 어려움 등이 있다. 최근에 새로운 개념의 규칙적 다공질 금속(periodic cellular metal)이 개발되어 기계 분야에 많이 적용되고 있는 철선으로 직조된 카고메 트러스가 있다. 이 논문은 기존 강섬유보강콘크리트의 현실적 문제점을 해결하기 위한 방법의 일환으로 카고메 트러스의 적용 가능성을 검토하기 위한 기초 실험 연구 결과를 정리한 것이다. 3종류의 카고메 트러스로 보강된 실험체와 동일한 제원의 수직스터럽으로 보강된 보 실험 결과와 비교하였다. 그 결과, 카고메 트러스 보강 실험체에서는 강도와 연성이 보통 스터럽 보강 보 보다 더 우수한 결과를 나타냈으며, 복부 보강재로서 우수한 기능을 할 수 있는 것으로 판명되었다.