• Journal of the Korean Ceramic Society
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• v.31 no.11
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• pp.1337-1345
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• 1994

Glasses in the system of 45CaO-25TiO2-30P2O5 containing 1 mole% of M2O(M=Li, Na, K) were melted and crystallized. And their crystal phases were Ca3(PO4)2, CaTi4(PO4)6, and TiO2. Porous glass-ceramics with skeleton of two crystal phase CaTi4(PO4)6 and TiO2 were prepared by selective leaching of Ca3(PO4)2 with 0.1 N-HCl. Glass transition temperature(Tg) and crystallization temperature(Tc) were decreased by addition of 1 mole% alkali metal oxide. Pore size of porous glass-ceramics was increased with increasing heat treatment temperature and its dependence on heat treatment temperature was decreased with addition of Na2O and K2O. It was found that porous glass-ceramics of parent glass and containing 1mole% M2O(M=Li, Na, K) composition had maximum specific surface area, porosity and maximum of crystallzed phase by heat treatment at 80$0^{\circ}C$, 76$0^{\circ}C$, 78$0^{\circ}C$, 80$0^{\circ}C$ respectively.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.372-372
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• 2011

염료 감응형 태양전지는 상,하판 투명전극(TCO), 나노입자의 다공질 TiO2, 염료 고분자 층으로 구성된 광전극과 투명전극 및 백금(Pt) 박막으로 구성된 상대전극 그리고 두 전극 사이를 산화 환원용 전해질 용액으로 채우고 있는 구조이다. 이 구조에서 투명전극(TCO)은 재료비의 많은 부분을 차지하므로 제작비용 절감을 위한 TCO-less에 관한 연구가 활발히 진행 중이다. 본 연구에서는 TCO-less 염료 감응형 태양전지 제작을 위해 이중층 Ti 전극 구조를 제안하였다. 제작과정은 광조사 부분을 확보한 유리기판에 e-beam 증착법을 이용해 Ti 전극을 증착시킨 후 TiO2를 Ti전극과 일부 중첩하여 인쇄하고 그 위에 두 번째 Ti전극을 제작한다. 이중층 Ti전극 구조는 SEM, EIS 등의 분석장비를 사용하였고 기존 FTO 구조에 비해 단락전류밀도, 에너지 변환효율은 감소하였으나 직렬 내부저항이 약 27% 감소하여 fill factor가 28% 향상된 결과를 얻을 수 있었다.

• Journal of the Korean Ceramic Society
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• v.25 no.1
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• pp.59-65
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• 1988

To develop porous glass membranes used for a effective membrane-separation process, porous glasses and glass membranes were prepared from the sodium borosilicate parent glass by the phaseseparation technique and effects of heat-treatment and leaching conditions on their characteristics were investigated. The crack-free glass membranes could be fabricated from the 9.4 Na2-O-30.7 B2O3-59.2 SiO2-0.7 Al2O3(wt%) parent glass by heat-treatment at the lower temperature(550-570$^{\circ}C$) and for longer than 45 hrs for the phase separation, followed by leaching with 3N-HCl＋60% ethylene glycol solution at 90$^{\circ}C$ over 25 hrs. Porous glasses prepared in this work showed large specific surface areas(400㎡/g) and narrow pore size distribution with the mean pore radius of 14${\AA}$ enough for the application as reverse osmosis membranes. The salt-rejection efficiency and product-flux of the glass membranes heat-treated at 570$^{\circ}C$ for 80 hrs were found to be 51.8% and 270cc/㎡. hr, respectively. This result suggests that the porous glass membranes fabricated in this study could be applied for the reverse osmosis process.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.6
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• pp.697-702
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• 2017

A preliminary study was carried out to investigate the feasibility of replacing honeycomb cores with pyramidal truss cores in the doors of urban transit railway vehicles. The doors in current operation are sandwich structures comprising a honeycomb core and reinforcements between two facesheets. The structural requirements of doors for urban transit vehicle are specified in the KRS and KRT and standards, according to which the deflections from three-point bending tests must be limited. To this end, two types of pyramidal truss cores with equivalent mass to a honeycomb core were designed. The structural stiffness of doors with pyramidal truss cores and honeycomb cores were numerically calculated via finite element analysis. The three-point bending models were constructed and simulated, and then the calculated deflections were compared with the requirements specified in the regulations. The results show that doors with pyramidal truss cores satisfied the stiffness requirements, although their deflections were 2.5% larger than that of the honeycomb cores. Therefore, the pyramidal truss cores could replace the aluminum honeycomb cores, and their multi-functional capability could be exploited.

• Journal of the Korean Ceramic Society
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• v.31 no.10
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• pp.1218-1230
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• 1994

In manufacturing process of porous glass-ceramics by the filler method, the sintering behaviour of crystallizable glass powder mixed with various salts was studied and also the effects of precipitated crystal phases on the properties of porous glass-ceramics were investigated. Fine-grained crystallizable glass powder was homogeneously mixed with various slat having grain size 100~200 ${\mu}{\textrm}{m}$ and sintered for densification. After washing out the inorganic salt with distilled water, the porous sintered body was heat treated additionly for crystallization. The MgO-Al2O3-SiO2 base glass was used as crystallizable glass powder and the water soluble salts such as K2SO4 and MgSO4 were used as filler. When K2SO4 was used, leucite crystal phase was formed as a result of the ion exchange and porous glass-ceramics which exhibit high temperature resistance and high thermal expansion coefficient of 17$\times$10-6/$^{\circ}C$ could be obtained. On the contrary, when MgSO4 was used, only slight ion exchange is observed and $\mu$-cordierite and $\alpha$-cordierite crystal phases were formed and porous glass-ceramics which exhibit low thermal expansion coefficient schedule were determined with the results of DTA curves, thermal shrinkage curves and XRD patterns analysis. From DTA curves and thermal shrinkage curves, it was found that the sintering densification have been completed at the temperature range of exothermic peak for crystallization. The pore size distributions and pore diameters were measured by mercury porosimeter. The pore diameter of porous glass-ceramics was 10~15 ${\mu}{\textrm}{m}$ when 100~200${\mu}{\textrm}{m}$ grain size of K2SO4 was used and it was 25~30 ${\mu}{\textrm}{m}$ when the same grain size of MgSO4 was used. The porous glass-ceramics K2SO4 used shows bimodal pore size distribution and its porous skeleton structure was ascertained by SEM observation.

• Journal of the Korean Ceramic Society
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• v.26 no.6
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• pp.771-782
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• 1989

Synthesis of $\beta$-Sialon powder was attempted with carbothermal reduction of porous glass. The porous glass was prepared by heat and hydrothermal treatments of 9.32 Li2O.46.5B2O3.37.2SiO2.6.98Al2O3 glass. Carbon pyrolyzed from propane gas was deposited on the porous glass, thereafter activated carbon was added as reducing agents. The synthesized $\beta$-Sialon powder was pressureless sintered at 175$0^{\circ}C$ for 1hr in N2 atmosphere. The characterization of the $\beta$-Sialon powder was performed with XRD, BET, SEM and particle size analysis. The sinterability and mechanical properties of the sintered bodies were investigated in terms of bulk density, M.O.R., fracture toughness, morphology of microstructure and etc. The reduction effect of deposited carbon was better than that of activated carbon mechanically added. The formation of SiC was precominant over that of Si2ON2 and $\beta$-Sialon owing to low partial pressure of N2 inside the pore, wehreas on the surface of porous glass the formation of Si2ON2 and $\beta$-Sialon were predominant. Thereafter, SiC reduced unreacted glass to be $\beta$-Sialon. Single phase of $\beta$-Sialon(Z=1.92) was obtained from PGA porous glass having the largest pore radius by the simultaneous reduction and nitridation method at 145$0^{\circ}C$ for 5hrs. The bulk density, M.O.R., and KIC of the sitered body are 3.17g/cc, 434.4MPa and 4.1MPa.m1/2, respectively.

• Journal of the Korean Ceramic Society
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• v.40 no.3
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• pp.273-278
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• 2003

The effects of content and particle size of sewage sludge slag on the sound absorption was investigated and the physical$.$mechanical properties of porous ceramics for sound absorbent material was studied. The physical$.$mechanical properties of specimens have depended on sintering temperature and slag content without particle size effect of slag. As water glass content increase and particle size of slag decrease at the same slag content, physical$.$mechanical properties of them have been improved. The bulk density and compressive strength of specimens with the batch composition of 77∼89 wt% of slag content and particles with 1∼3 mm, and sintered at 1,050$^{\circ}C$ for 2 h were 1.48∼1.71 and 86∼163 kgf/$\textrm{cm}^2$, respectively. The specimens with 1∼3 mm and <1 mm of particles size showed good sound absorption property at low frequency and high frequency region. With increasing thickness of specimens, sound absorption properties at low frequency region were increased.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.3
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• pp.187-193
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• 2019

Regarding physical absorption mechanism for fine particles(Dust), internal pore-bridging is a major parameter in porous media. In this paper, internal bridging pore system is invented through FA-based geopolymer and incorporated PLA (Polylactic Acid) fiber with biodegradability. With various mix proportions, compressive strength over 20MPa is obtained but PLA is little dissolved in the condition of NaOH 5mole and $30^{\circ}C$ of temperature, which was found that temperature rising accelerates PLA solubility. Within 24hours, beads type PLA is completely dissolved under $90{\sim}130^{\circ}C$ and NaOH 5~12mole of alkali. In room condition, geo-polymerization is limitedly occurs so that the internal pore after PLA dissolution is thought to be effective to absorption and storage of fine particles.

• Applied Chemistry for Engineering
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• v.18 no.6
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• pp.568-574
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• 2007

Crack-free dried gel monoliths of the composition $Li_2O1{\cdot}7Al_2O_3{\cdot}8.6SiO_2$ have been prepared as a precursor of transparent glass-ceramic by the hydrolysis and polycondensation of mixed metal alkoxides in solutions containing N,N-dimethylformamide as the drying control chemical additive, alcohols, and water. It was investigated that activation energy for gelation according to the variation of water concentration ranged from 13 to 14 kcal/mol. Only when the amount of water for gelation was 3 times higher than the stoichiometric amount, monolithic dry gels were successfully prepared after drying at $70{\sim}75^{\circ}C$ and at a rate of 0.1~0.3%/h. The specific surface area, the pore volume, the average pore diameters of dried gel at $180^{\circ}C$ were about $239.40m^2/g$, 0.001~0.03 mL/g, and $145.62{\AA}$, respectively. It showed that the dried monolithic gel had a porous body. The DTA curve had the first exothermic peak around $800^{\circ}C$ and the 2nd peak around $980^{\circ}C$, which may correspond to crystallization of the gel.

• Applied Biological Chemistry
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• v.32 no.3
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• pp.278-285
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• 1989

Effects of cooking and drying methods on the taste component and microstructure of shrimp, Metapenaeus joyneri, were investigated. The nucleotides and their related compounds of fresh shirmp such as ATP, ADP, AMP, IMP, inosine and hypoxanthine were detected. AMP was detected as a trace amount in fresh shrimp, however, it increased up to $23.5{\sim}45.7{\mu}$ moles with cooking and drying due to the decomposition of ATP and ADP to AMP during cooking and drying. The major component of the free amino acids of fresh shrimp was arginine followed by glycine, lysine, proline and alanine. These free amino acids contents were 70% of the total free amino acids. One hundred grams of fresh shrimp contained 1,198mg (dry basis) of the total free amino acids. However, for hot air and freeze dried cooked shrimps it was decreased down to 342mg (dry basis) and 503mg (dry basis), respectively. It might be due to the dissolution of soluble amino acids during cooking. Hot air-and freeze-dried fresh shrimps was higher in hardness and brittleness but lower in cohesiveness and gumminess than hot air-and freeze-dried ones with boiling and microwave heating. Freeze dried shrimp had softer myofibril texture than hot air dried one. At the same time, more dense and multiporous structure in the tissue could be obtained from the hot air and freeze drying, respectively, after microwave heating of shrimps.