• Title/Summary/Keyword: 다공성 매질

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Phenol Removal Using Horseradish Peroxidase(HRP)-Mediated Polymerization Reaction in Saturated Porous Media (다공성 포화 매질에서 효소 중합반응을 이용한 페놀 제거)

  • Kim, Won-Gee;Lee, Seung-Mok
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.984-991
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    • 2008
  • This paper reports experimental results, demonstrating the feasibility of horseradish peroxidase(HRP) and H$_2$O$_2$ to reduce phenol transport in saturated porous media. A laboratory-scale packed column reactor(ID: 4.1 cm, sand-bed height 12 cm) column was utilized to simulate injection of HRP and H$_2$O$_2$ into an aquifer contaminated with phenol. Effluent concentrations of phenol and polymerization products were monitored before and after enzyme addition under various experimental conditions(enzyme dose: 0$\sim$2 AU/mL, [ionic strength]: 5$\sim$100 mM, pH: 5$\sim$9). The concentration of phenol in the column effluent was found to decrease by nearly 90% in the presence of HRP(2 AU/mL) and H$_2$O$_2$ in the continuous flow system at pH 7 and ionic strength 20 mM. The influent phenol was converted in the system to insoluble precipitate, which deposited in pore spaces. The remains were discharged as soluble oligomers. About 8% of total pore volume in column system was decreased by deposition of polymer produced.

Phase Equilibria of Ethane Hydrate in Porous Silica Gels (다공성 실리카 젤에서 에탄 하이드레이트의 상평형 측정)

  • Lee, Seung-Min;Cha, In-Uk;Lee, Ju-Dong;Seo, Yong-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.584-587
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    • 2008
  • 최근 새로운 천연가스 수송/저장 방법으로 가스 하이드레이트 형성법이 주목받고 있다. 본 연구에서는 천연가스의 저장 매체로 다공성 실리카 젤을 사용하였다. 다공성 매질을 사용할 경우 물이 기체와 접촉하는 면적이 극대화되어 하이드레이트로의 전환율이 높아진다. 기공의 직경이 각각 6.0, 15.0, 30.0 nm의 실리카 젤을 사용하여 270 - 285 K의 온도 범위와 0.5 - 3.0 MPa의 압력 범위에서 기공 크기의 분포를 고려하여 에탄 하이드레이트의 3상 평형점 (하이드레이트 (H) - 물 (LW) - 기상 (V))을 측정하였다. 기공의 크기가 작아질수록 벌크 상태의 에탄 하이드레이트에 비해 하이드레이트 평형 조건이 온도는 낮아지고 압력이 높아지는 저해효과가 커짐을 알 수 있었다. 천연가스 수송/저장으로의 응용을 고려할 경우 저해효과가 적은 30.0 nm 이상의 실리카 젤을 사용하는 것이 유용할 것으로 사료된다. 본 연구의 결과는 심해저 천연가스 개발, 이산화탄소 심해저장 등의 가스 하이드레이트 응용 연구에도 유용한 기초자료가 될 것이다.

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Porous Media Modelling and Verification of Thermal Analysis for Inlet and Outlet Ducts of Spent Fuel Storage Cask (사용후핵연료 저장용기 유로입출구의 다공성매질 모델링 및 열해석 검증평가)

  • Lee, Ju-Chan;Bang, Kyung-Sik;Choi, Woo-Seok;Seo, Ki-Seog;Ko, Sungho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.223-232
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    • 2018
  • Bird screen meshes are installed at the air inlet and outlet ducts of spent fuel storage casks to inhibit the intrusion of debris from the external environment. The presence of these screens introduces an additional resistance to air flow through the ducts. In this study, a porous media model was developed to simplify the bird screen meshes. CFD analyses were used to derive and verify the flow resistance factors for the porous media model. Thermal analyses were carried out for concrete storage cask using the porous media model. Thermal tests were performed for concrete casks with bird screen meshes. The measured temperatures were compared with the analysis results for the porous model. The analysis results agreed well with the test results. The analysis temperatures were slightly higher than the test temperatures. Therefore, the reliability and conservatism of the analysis results for the porous model have been verified.

Thermal Phenomena of an N2O Catalyst Bed for Hybrid Rockets Using a Porous Medium Approach (다공성 매질 접근법을 적용한 하이브리드 로켓 N2O 촉매 점화기의 열적 현상)

  • 유우준;김수종;김진곤;장석필
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.9
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    • pp.89-96
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    • 2006
  • In this study, fluid flow and thermal characteristics in a catalyst bed for nitrous oxide catalytic decomposition which is introduced as a hybrid rocket ignition system for small satellites were theoretically considered. To analyze the thermal phenomena of the catalyst bed, a so-called porous medium approach has been opted for modeling the honeycomb geometry of the catalyst bed. Using a Brinkman-extended Darcy model for fluid flow and the one-equation model for heat transfer, the analytical solutions for both velocity and temperature distributions in the catalyst bed are obtained and compared with experimental data to validate the porous medium approach. Based on the analytical solutions, parameters of engineering importance are identified to be the porosity of the catalyst bed, effective volumetric ratio, the ratio of the radius of the catalyst bed to the radius of a pore, heat flux generated by a heater, and pumping power. Their effects on thermal phenomena of the catalyst bed are studied.

A Numerical Study on Nonlinear Flow in Porous Medium (다공성 매질에서 비선형 흐름에 대한 수치적 연구)

  • Jeong, Woo Chang
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.384-384
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    • 2017
  • In this study, the numerical investigation of nonlinear flow in a porous medium was carried out. The applied numerical model is ANSYS CFX which is a three-dimensional fluid dynamic model, and the verification of this model was carried out by using the experimental data obtained from Mayer et al works(2011). The experimental and numerical results of velocity and Reynolds number-friction coefficient relationship show relatively a good agreement. Based on the experimental results, we analysed numerically the velocity and Reynolds number-friction coefficient relationship with the variation of permeability, dynamic viscosity and porosity and quantitatively the variation by applying the best curve fitting for each case.

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Comparison of Kramers-Krönig Relation and High-Frequency Acoustic Measurements in Water-Saturated Glass Beads (다공성 입자 매질에서 고주파 영역 음향 측정 자료와 Kramers-Krönig 관계식의 비교)

  • Yang, Hae-Sang;Lee, Keun-Hwa;Seong, Woo-Jae
    • The Journal of the Acoustical Society of Korea
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    • v.30 no.7
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    • pp.402-407
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    • 2011
  • The necessary and sufficient condition for causality of a physical system can be expressed as Kramers-Kr$\ddot{o}$nig (K-K) relation. K-K relation for acoustic wave is a Hilbert transforms pair between dispersion equations of phase speed and attenuation. In this study, we quantitatively compare the acoustic measurements in water-saturated glass beads for the frequency ranges from 400 kHz to 1.1 MHz with the predictions of differential form of K-K relation obtained by Waters et al. For media with attenuation obeying an arbitrary frequency power law, acoustic measurements show good agreements with the predictions of Kramers-Kr$\ddot{o}$nig relation.

3-Dimensional ${\mu}m$-Scale Pore Structures of Porous Earth Materials: NMR Micro-imaging Study (지구물질의 마이크로미터 단위의 삼차원 공극 구조 규명: 핵자기공명 현미영상 연구)

  • Lee, Bum-Han;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.4
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    • pp.313-324
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    • 2009
  • We explore the effect of particle shape and size on 3-dimensional (3D) network and pore structure of porous earth materials composed of glass beads and silica gel using NMR micro-imaging in order to gain better insights into relationship between structure and the corresponding hydrologic and seismological properties. The 3D micro-imaging data for the model porous networks show that the specific surface area, porosity, and permeability range from 2.5 to $9.6\;mm^2/mm^3$, from 0.21 to 0.38, and from 11.6 to 892.3 D (Darcy), respectively, which are typical values for unconsolidated sands. The relationships among specific surface area, porosity, and permeability of the porous media are relatively well explained with the Kozeny equation. Cube counting fractal dimension analysis shows that fractal dimension increases from ~2.5-2.6 to 3.0 with increasing specific surface area from 2.5 to $9.6\;mm^2/mm^3$, with the data also suggesting the effect of porosity. Specific surface area, porosity, permeability, and cube counting fractal dimension for the natural mongolian sandstone are $0.33\;mm^2/mm^3$, 0.017, 30.9 mD, and 1.59, respectively. The current results highlight that NMR micro-imaging, together with detailed statistical analyses can be useful to characterize 3D pore structures of various porous earth materials and be potentially effective in accounting for transport properties and seismic wave velocity and attenuation of diverse porous media in earth crust and interiors.