• Title/Summary/Keyword: 농축지수

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Availability of Heavy Metals in Soil and Their Translocation to Water Dropwort (Oenanthe javanica DC.) Cultivated near Industrial Complex (토양내 중금속 유효도와 미나리중의 흡수이행성 평가)

  • Jung, Goo-Bok;Kim, Won-Il;Lee, Jong-Sik;Shin, Joung-Du;Kim, Jin-Ho;Lee, Jeong-Taek
    • Korean Journal of Environmental Agriculture
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    • v.25 no.4
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    • pp.323-330
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    • 2006
  • This experiment was conducted to investigate heavy metal transition and bioavailability from soil to the edible pare of water dropwort near industrial complex. The soils were collected from the paddies cultivating water dropwort stream sediments, and background soils near industrial complex. The pH values, organic matter, Av. $P_2O_5$, Ex. Ca content of paddy soils were higher than those measured for nor-contaminated paddy fields in 2003. The contents of Cd and Cu was higher than those of standard level for soil contamination by Soil Environmental Conservation Act in Korea. The pollution index in stream sediments were higher than those of paddies cultivating water dropwort. The geoaccumulation index of heavy metals in paddy soils and stream sediment were in the order Cu>Cd>Ni>Zn>Pb. The rates of 0.1N-HCl extractable heavy metals to total contents in soils were in the order Cd>Cu>Zn>Ni>Pb. In case of Cd and Ni in paddy soils near industrial complex, 0.1N-HCl extractable heavy metals and total content were highly correlated with each other. Heavy metal contents in mot parts were higher than those in top pare of water dropwort. The Zn and Cu transfer factor from soil to the top pare of water dropwort were higher than those of other heavy metals. The bioavailability of water dropwort varied considerably between the different parts and heavy metals. Cd, Cu and Ni contents in water dropwort were correlated with each elements in paddy soils.

Distributions of Organic Matter and Heavy Metals in the Surface Sediment of Jaran Bay, Korea (자란만 표층 퇴적물 중 유기물과 중금속 농도분포)

  • Hwang, Hyunjin;Hwang, Dong-Woon;Lee, Garam;Kim, Hyung-Chul;Kwon, Jung-No
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.1
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    • pp.78-91
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    • 2018
  • In order to understand the distributions of organic matter and heavy metal concentrations in the surface sediment of Jaran Bay, we measured the grain size, total organic carbon (TOC), total nitrogen (TN), and heavy metals (As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, and Zn) in surface sediments collected at 15 stations in this bay in November 2014. The sediment consisted of finer sediment such as mud and clay, with 8.6-9.8Ø($9.3{\pm}0.3$Ø) of mean grain size. The concentrations of TOC and TN in the sediment ranged from 1.51-2.39 % ($1.74{\pm}0.22%$) and 0.20-0.33 % ($0.23{\pm}0.03%$), respectively, and did not show spatial difference. The carbon to nitrogen ratio (C/N ratio) ranged from 5-10, indicating that organic matter in the sediment originated from oceanic sources such as animal by-products from fish and shellfish farms. The concentrations of Cr, Fe, and Mn were much higher in the mouth of the bay than in the inner bay, and the concentrations of As, Cd, Cu, Hg, Pb, and Zn showed an opposite distribution pattern. Based on the results of the sediment quality guidelines (SQGs), enrichment factor (EF), geoaccumulation index ($I_{geo}$), pollutant load index (PLI), and ecological risk index (ERI), the surface sediment in Jaran Bay is not polluted or only slightly polluted with Cd, Cr, Cu, Hg, Pb, and Zn, whereas it is moderately to strongly polluted with As. In particular, some regions in the bay were identified as having a considerable risk status, indicating that metal concentration in the sediment could impact benthic organisms. Thus, the systematic management for marine and land sources of organic matter and heavy metals around Jaran Bay is necessary in order to ensure seafood safety and maintain sustainable production on shellfish farms.

Sensitivity Analysis of Finite Element Parameters for Estimating Residual Stress of J-Groove Weld in RPV CRDM Penetration Nozzle (원자로 CRDM 관통노즐 J-Groove 용접부 잔류응력 예측을 위한 유한요소 변수 민감도 해석)

  • Bae, Hong-Yeol;Kim, Ju-Hee;Kim, Yun-Jae;Oh, Chang-Young;Kim, Ji-Soo;Lee, Sung-Ho;Lee, Kyoung-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.10
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    • pp.1115-1130
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    • 2012
  • In nuclear power plants, the reactor pressure vessel (RPV) upper head control rod drive mechanism (CRDM) penetration nozzles are fabricated using J-groove weld geometry. Recently, the incidences of cracking in Alloy 600 CRDM nozzles and their associated welds have increased significantly. The cracking mechanism has been attributed to primary water stress corrosion cracking (PWSCC), and it has been shown to be driven by welding residual stresses and operational stresses in the weld region. The weld-induced residual stress is the main factor contributing to crack growth. Therefore, an exact estimation of the residual stress is important for ensuring reliable operation. This study presents the residual stress computation performed for an RPV CRDM penetration nozzle in Korea. Based on two and three dimensional finite element analyses, the effect of welding variables on the residual stress variation is estimated for sensitivity analysis.

Evaluation of Yeongsan Lake Ecosystem Using Various Environment Parameters (다각적 수환경지표를 이용한 영산호의 생태영향 평가)

  • Choi, Ji-Woong;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.41 no.2
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    • pp.155-165
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    • 2008
  • The purpose of this study was to evaluate the ecosystem of Yeongsan Lake using physical, chemical, and biological indicators. We evaluated the integrative ecosystem health using Lentie Ecosystem Health Assessment (LEHA) model, Qualitative Health Evaluation Index (QHEI) model, and chemical water quality. The models of LEHA and QHEI were modified as 10 and 7 metries attributes, respectively. Also, we analyzed bioaccumulation of total mercury on various fish tissues by method of U.S. EPA 7473 using Direct Mercury Analyzer (Model DMA-80). Model values of LEHA model averaged 19 (range: $14{\sim}26$, n=15), which indicated a "poor" condition, and had slightly spatial variations. Values of the QHEI in the all sites averaged 72, which were judged as a "fair" to "good" condition. The QHEI values varied from 48 (fair condition) to 99 (good condition) and showed large longitudinal gradients between the upper and lower reach. Conductivity and salinity were increased from the up-lake to downlake reach. Analysis of total mercury in fish tissues showed that levels of total Hg ranged between 0.002 and $0.087\;mg\;L^{-1}$ depending on the types of tissues. Overall, the ecosystem health in the Yeongsan Lake was judged as a "poor" and the effects of bioaccumulation on the fish tissues were minor. Therefore, it is necessary to keep an efficient management for the lake environment to maintain their ecological health.

A Numerical Model for Predicting the Radial Power Profile in CANDU-PHWR Fuel Pellet (CANDU-PHWR 핵연료 소결체의 반경방향 출력분포 수치모형)

  • Woan Hwang;Suk, Ho-Chun;Jae, Won-Mok
    • Nuclear Engineering and Technology
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    • v.23 no.4
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    • pp.444-455
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    • 1991
  • An accurate and fast running NEDAR model for calculating radial power profile throughout fuel life in both solid and annular pellets for existing and advanced CANDU-PHWR-fuel was developed in this work. This model contains resultant flux depression equations and neutron depression data tables which have been developed for CANDU-PHWR fuel of pellet with the diameter 8.0 to 19.5 mm and enrichment 0.71-6.0 wt % U-235, over a bumup range of 0 to 840 MWh /kgU (35000 MWD/T). In order to obtain the neutron flux distribution in the fuel pellet, the CE-HAMMER physics code was run for a neutron flux spectrum appropriate to a CANDU-PHWR to give predictions of radial power profile for several ranges of fuel design parameters. The results, which were calculated by the CE-HAMMER physics code, were fitted to an equation which is solved in terms of Bessel and exponential functions in order to obtain the parameters, $textsc{k}$, $\beta$ and λ in the resultant equation. The present NEDAR model produce a radial profile which, when normalized to unity at the pellet surface, is slightly higher than the profile of the original ELESIM data table. The predictions of the fission gas release by KAFEPA-NEDAR are in slightly better agreement with the experiments than those of ELESIM. The NEDAR model described in this study has been shown to provide an effective, reliable, and accurate method for determining radial power profiles in CANDU-PHWR fuel rods without incurring a significant increase in computing time.

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Studies on Color and Rheological Properties in Strawberry Jam (딸기쨈의 색깔과 물성에 관한 연구)

  • Lee, Jong Hyeouk;Chang, Kyu Seob;Yoon, Han Kyo
    • Korean Journal of Agricultural Science
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    • v.14 no.1
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    • pp.134-143
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    • 1987
  • In order to observe the strawberry as the raw materials and to compare the color of strawberry's products, Hunter L,a,b tristimulate color values were measured physically by color difference meter. Food textural properties of strawberry were measured by Rheo textural meter for rheological properties of strawberry jam. According to results obtained, it showed that Hunter L,a,b tristimulus color values were affected by ripening time of strawberry and Hunter color values changed regularly on different pH. Deformation of red color pigment Hunter color values changed linearlly on different pH, therefore red color pigment of elderberry showed to be used as a food color agent. The first peak of strawberry in TPA curve was high as cherry, grape and pineapple Strawberry jam showed pseudoplastic characteristic and time dependence.

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Antioxidant and Synergistic Activities of Fruit and Vegetable Concentrates (과채류 농축액의 항산화 및 상승효과)

  • Jeong, Su Ji;Shim, Hee Ryung;Lee, Ji-Soo;Nam, Hee Sop;Lee, Hyeon Gyu
    • Korean Journal of Food Science and Technology
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    • v.47 no.2
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    • pp.240-245
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    • 2015
  • The principal objective of this study was to investigate the antioxidant and synergistic effects of fruit and vegetable concentrates. Ten foods from two categories, including fruits (raspberry, blackberry, blueberry, acai berry, aronia, cranberry, wild berry, and red grape) and vegetables (spinach and cabbage) were combined in pairs. The antioxidant activity of the individual and combined samples was measured using DPPH (2,2-diphenyl-1-picryl-hydrazyl-hydrate) and FRAP (ferric reducing antioxidant power) assays. Synergistic antioxidant activities of the combinations of cabbage and acai berry, and blueberry and cranberry showed the most significant (p<0.05) increase in the DPPH and FRAP assays, respectively. In addition, the combination of cabbage and red grape demonstrated significantly high synergistic interaction in both DPPH and FRAP assays (p<0.05). These results indicate the importance of strategic selection of foods and their composition ratio for maximum synergistic antioxidant activity.

Investigation on Natural Radioactivity of Environmental Samples Near the Bauxite Processing Facility (보오크사이트 사용업체 주변 환경시료의 자연방사능 조사)

  • Moon, Dong-Hyeok;Koh, Sang-Mo;Chang, Byung-Uck;Kim, Tong-Kwon;Kim, Yong-Ug
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.347-356
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    • 2010
  • Bauxite is a main raw material for the production of alumina and aluminum hydroxide in the processing plant of KC company. It is a NORM (Naturally Occurring Radioactive Materials), and its waste, red mud, is a TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials). The purpose of the geochemical and mineralogical investigations of the bedrock and soils in and around the plant, a large NORM source, was to provide basic data for measuring the radiation dose and protecting from radioactive hazards. Soils were mixtures of minerals derived from the country rock (quartz, feldspar, mica, kaolin, gibbsite, and sepiolite) and bauxite (hematite, boehmite, and calcite) of open-air storage. Average U and Th contents of the soil samples were 4.7 ppm and 23 ppm, respectively, indicating somewhat Th anomaly. The average concentrations of radionuclides are $^{40}K$ 100~1,433 Bq/kg, $^{226}Ra$ anomaly in the red mud open-air storage. Soil external hazard indices range from 0.10 to 1.66 with an average of 0.63. Although most of the indices are below 1.0 that is a regulation value, those of 4 samples of total 41 soil samples exceed 1.0, requiring further detailed investigation.

Analysis of Glyphosate and Glufosinate in Animal Feeds using LC-MS/MS (LC-MS/MS를 이용한 동물 사료 내 글라이포세이트 및 글루포시네이트 분석)

  • Lee, Ji-Su;Kim, Wanseo;Yang, Heedeuk;Park, Na-Youn;Jung, Woong;Kim, Junghoan;Kho, Younglim
    • Journal of the Korean Chemical Society
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    • v.63 no.5
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    • pp.342-345
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    • 2019
  • The standards for the contents of glyphosate and glufosinate in foods are specific and well categorized. However, the standard of content in animal feeds is relatively inadequate and the classification is insufficient. There is also constant debate about the risk of glyphosate and glufosinate to human health, but the risk to animals has not been well studied. In this study, we established an analytical method in feeds that is estimated to be the path for animals to ingest glyphosate. The solvent extraction was carried out using 25% methanol. After centrifugation, samples were purified using solid phase extraction (SPE) and quantitatively analysed using LC-MS/MS after concentrated. Assessment of validation was conducted through detection limits, accuracy, and precision tests. The detection limits for the established method were 1.8 of ${\mu}g/kg$ of glufosinate and $2.4{\mu}g/kg$ of glyphosate. Accuracy was ranged from 94.4% to 103.4% and precision was range from 1.5% to 7.2%. Glufosinate was detected in one sample ($ND{\sim}8.8{\mu}g/kg$) and glyphosate was detected in all but one sample ($ND{\sim}337.0{\mu}g/kg$) by applying the analytical method to animal feeds (n=13).

Acid treatment effects on the contents of quercetin glycosides and aglycone in red onion powder (산처리에 의한 적양파 분말의 quercetin 배당체와 aglycone의 농도변화)

  • Kim, Mi-Ryung;Lim, Jun-Hyung;Song, Ji-Su
    • Korean Journal of Food Science and Technology
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    • v.54 no.2
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    • pp.115-125
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    • 2022
  • Flavonoids are bioactive plant metabolites that have a range of beneficial effects on human health. Quercetin 4'-glycoside (Q4'G), quercetin 3,4'-diglycoside (Q3,4'G), and quercetin aglycone (QA) are the main flavonoids found in onions. QA, in particular, is likely to have a greater biological effect than glycosides. To develop an onion extract with high quercetin content, the optimal extraction conditions for red onion powder containing the outer layer of the onion were determined. The effects of acid treatment on the concentration of quercetin glycosides and QA were evaluated. The flavonoids of red onion powder were optimally extracted under 60-70% ethanol at 70℃ for 2 h. The deglycosylation of Q3,4'G and an increase in Q4'G content occurred within 6 h of 0.2% acetic acid treatment. The QA content and deglycosylation of Q4'G eventually peaked at 24 h. In addition, QA content and 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activity were highly correlated, with a correlation coefficient of 0.90.