• Title/Summary/Keyword: 네마틱 액정

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Synthesis and Properties of Liquid Crystal Compounds and Epoxy Resin Based Side Chain Liquid Crystal Polymers II. Linear and Crosslinked Epoxy LC Polymers (방향족 액정동족체 및 Epoxy형 측쇄 액정고분자의 합성 및 성질 II. 선형 및 가교형 측쇄 액정고분자)

  • Ahn, Wonsool;Chang, Jin Gyu;Keum, Chang Dae;Park, Lee Soon
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.71-75
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    • 1998
  • Liquid crystalline compounds with amine terminal group and related linear and cross-linked liquid crystal polymers with epoxy resin structure were synthesized and characterized to develope matrix materials for polymer dispersed liquid display applications. Both linear and crosslinked side chain type liquid crystal polymers made with aromatic amine mesogens and ethylene glycol diglycidyl ether exhibited nematic texture as shown by polarized optical microscope(POM) and their transition temperatures were determined both by DSC and POM. Liquid crystal polymer samples also showed even-odd effect as the spacer length of aromatic amine mesogens were varied, however, the effect was samller than that of low molecular weight mesogens. Changes of nematic-to-isotropic transition($T_{NI}$) of crosslinked type polymer liquid crystals were also disscussed in relation to the concentration change of crosslinking agent 1,10-diaminodecane.

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Synthesis and Characterization of Organo-Clay Based Thermotropic Liquid Crystalline Polyester Nanocomposites (유기화 점토를 이용한 열방성 액정 폴리에스테르 나노복합재료의 합성과 특성 연구)

  • 서보수;장진해
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.876-883
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    • 2001
  • A thermotropic liquid crystalline polyester (TLCP) containing a side group was, synthesized from ethoxyhydroquinone and bromoterephthalic acid. Intercalation of TLCP in layered clays is accomplished by heating the polymer with hexadecyl ammonium-montmorillonite ($C_{16}$) above melting transition temperature ($T_m$). Liquid crystallinity of the TLCP/$C_{16}$-hybrid was observed up to 6 wt% $C_{16}$-MMT. Some of the $C_{16}$-MMTs in TLCP were highly dispersed in a nanometer scale, but some of them were agglomerated. Thermal and morphological properties of the nanocomposites were examined by differential scanning calorimetry (DSC), thermogravimetric analyzer (TGA), polarized optical microscope, and electron microscopes (SEM and TEM).

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Reduction of Color Shift Using Dichroic Dyes in a Cholesteric Liquid Crystal Cell (콜레스테릭 액정 셀에서 염료를 이용한 Color Shift 제거)

  • Park, Jun-Hee;Oh, Seung-Won;Yoon, Tae-Hoon
    • Korean Journal of Optics and Photonics
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    • v.26 no.2
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    • pp.110-114
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    • 2015
  • We propose a reflective cholesteric liquid crystal cell with reduced color shift, using dichroic dyes. Color-shifted light is absorbed by dye molecules in the proposed dye-doped cholesteric liquid crystal (DDCLC) cell. We have shown that the color shift can be reduced by increasing the concentration of dye molecules in the proposed DDCLC cell.

Synthesis and mesomorphic properties of biphenly thioester series in ferroelectric liguke crystal (Biphenyl thioester 계열 강유전성액정의 합성 및 물성에 관한 연구)

  • Jeon, Yeong-Jae
    • Korean Journal of Materials Research
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    • v.3 no.1
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    • pp.72-83
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    • 1993
  • Abstract A new and versatile method for the preparation of biphenyl thioester series was studied in ferroelectric liquid crystal. Many of the resulting liquid crystal showed a ferroelectric chiral smectic C phase in addition to the chiral nematic and smectic A phase. We obtained a large spontaneous polarization exceeding $10^{-8}$C/c$m^2$ in new biphenyl thioester series. It was found that the size and polarity of the substituent in chiral carbon influenced the magnitude of spontaneous polarization. The series allow us to determine the influence of substituent size in the chiral carbon the existence and the stability of the Sc* phase.

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Nes ferroelectric liquid crystal having bipeny1 ester core group (중심그룹으로 Bipheny1 ester기를 갖는 새로운 강유전성 액정)

  • Jeon, Yeong-Jae;Lee, Jong-Cheon;Kim, Yong-Bae
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.695-703
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    • 1994
  • Some 4-(4-alkyloxybenzoyloxy)-4'-(S)-$\alpha$-chloro-alkanoyloxybiphenyls have been synthesized and their mesomorphic properties were studied. They show a ferroelectric chiral smectic C phase in addition to the chiral nematic and smectic A phase. We obtained a large spontaneous polarization exceeding $10^{-7}\textrm{cm}^2$ in new biphenyl ester series.

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Synthesis and Properties of Liquid Crystal Compounds and Epoxy Resin Based Side Chain Liquid Crystal Polymers I. Low Molecular Weight Liquid Crystal Compounds (방향족 액정동족체 및 Epoxy형 측쇄 액정고분자의 합성 및 성질 I. 저분자 액정 동족체)

  • Park, Se Kwang;Ahn, Wonsool;Keum, Chang Dae;Park, Lee Soon
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.66-70
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    • 1998
  • Several liquid crystalline monomers were synthesized and characterized to utilize as new matrix materials of liquid crystal/polymer composite films for display application. Liquid crystalline compounds which have azo group as center link, cyano group at one of the terminal position in common and bromoalkyl(azo(n)), azidoalkyl(AZI(n)), aminoalkyl(ALC(n)) as the terminal group were synthesized and identified respectively by FT-lR, $^1H-NMR$ spectrometer and elemental analysis. All these compounds exhibited nematic liquid crystalline region in the certain temperature range as determined by DSC and polarized optical microscope. These liquid crystalline compounds also showed a typical even-odd effect in both $T_{KN}$ and $T_{NI}$ due to conformational change as the length of terminal alkyl chain, $-(CH_2)n-$. was varied.

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