• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.263-266
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• 1998

In this study, the effect of the crystallinity of polyimide (Pl) and the birefringence of the nematic liquid crystal (NLC) for pretilt angle generation on rubbed PI surface containing thiophenylene moieties has been demonstrated. The induced optical retardation produced in rubbed Pl surfaces decreases on increasing the imidization temperature. We suggest that the pretilt angle of 4-cyano-4'-n-pentybiphenyl (5CB) depends on the crystallinity of the rubbed Pl. The order of pretilt angle in NLCs is 5CB>PCH5$\geq$CCH5 at rubbing strength(RS)=150mm (medium rubbing) on rubbed PI surfaces. We suggest that on rubbed Pl surfaces the pretilt angle increases with increasing number of phenylrings in the NLC core.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.13 no.10
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• pp.883-886
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• 2000

We have developed a novel vertical-alignment(VA) - 1/6$\pi$ mode that provides a wide viewing angle for nematic liquid crystal (NLC) with negative dielectric anisotropy on a homeotropic polyimide (PI) surfaces. Good voltage-transmittance curves were achieved with the new VA - 1/6$\pi$ cell model without a negative compensation film. The viewing angle of a new VA -1/6$\pi$ cell without a negative compensation film was wider than that of a conventional VA cell. Finally, the wide viewing angle using the new VA-1/6$\pi$ cell mode can be achieved.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.515-518
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• 2000

We studied the viewing angle characteristics of a negative dielectric anisotropy nematic liquid crystal (NLC) using the new vertical-alignment (VA)-1/6 cell on a rubbed polyimide (PI) surface. Good voltage-transmittance (V-T)characteristics using the new VA-1/6 cell without a negative compensation film were obtained. The iso-viewing angle characteristics using the new VA-1/6 cell without the negative compensation film can be achieved.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.390-391
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• 2007

We have studied improvement of light leakage of twisted nematic liquid crystal display (TN-LCD) in dark state using the hybrid aligned compensation film made of rod-like LC. When the voltage is applied properly to the TN-LCD, the director tilts up but LC director on the substrate don't tilts up due to surface anchoring energy of the LC cell. Accordingly, LC director from surface to middle LC of TN -LCD become hybrid state such as hybrid aligned film. Consequently, in this paper we achieve wide viewing angle performances of TN mode using developed hybrid aligned film which especially decreases light leakage at vertical direction in dark state.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.610-612
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• 1999

In this study, we used both displacement-current method and BAM(Brewster-Angle Microscope) to study on the molecular orientation of monolayer on the water surface. The displacement-current method measured behaviors of molecules by current and BAM was shown to be sensitive to film anisotropy even when the molecules were not tilted as long as the unit cell was anisotropic. Every transition was visible with BAM technique, either as a dramatic change in decree of contrast or as a sudden alteration of the mosaic domain texture.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.32 no.4
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• pp.302-306
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• 2019

We investigated a solution-derived $Y_2O_3$ film treated by ion beam (IB) irradiation as a liquid crystal (LC) alignment layer. With IB irradiation, homogeneous LC alignment was achieved irrespective of the annealing temperature. To verify the effect of IB irradiation, we conducted surface analyses such as X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). As $Y_2O_3$ is a high-k material, the electro-optical properties of the twisted nematic (TN) cells were superior to those of conventional TN cells based on a rubbed polymer, with an LC rising time of 4.1ms and falling time of 2.9ms. The IB-irradiated $Y_2O_3$ is a good alternative as an alignment layer for fast-switching TN LC displays.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.12
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• pp.5216-5220
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• 2010

Rheological measurement of a thermotropic liquid crystalline poymer (TLCP) is not an easy task since their rheological responses are strongly influenced by a thermal history during a processing and thus the reproducibility of the measurement is poor. In order to find out a cause for the strong influence of the thermal history, rheological measurements and DSC observations of the TLCP having various thermal histories were carried out. It was observed that the TLCP used in this study shows liquid-like behavior at a temperature above a crystal-nematic transition temperature ($280^{\circ}C$), but at the same time crystallization can occur at this temperature range and as a consequence the viscosity of the polymer continuously increases. When the samples are heated beyond the $320^{\circ}C$, all crystals thus formed and the thermal histories were observed to disappear. Crystallization rate of the samples annealed above $320^{\circ}C$ was very low at even the lowed temperature ($280^{\circ}C\;{\sim}\;320^{\circ}C$). Therefore, it is concluded that rheological measurements of TLCP used in this study must be performed after annealed above the nematic-isotropic transition temperature for better reproducibility.

• Journal of the Korean Chemical Society
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• v.44 no.2
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• pp.127-137
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• 2000

Eleven new compounds that are composed of bis(p-substituted phenyl) terephthalate unitand the decyloxy pendant as lateral were synthesized and their thermal and liquid crystalline properties were studied by the differential scanning calorimetry (DSC) and on a hot-stage of a polarizing microscope. The ter-minal substituent groups of the compound were varied; X= -H(II-H), -F(lI-F), -CII(II-CI), -Br(ll-Br), -I(II-I), -$NO_2(lI-NO_2$), $-CF_3(II-CF_3$), -$OC_2H_5(II-OC_2H_5$), -$OC_4H_9(II-OC_4H_9$), -$C_6H_5(Il-C_6H_5$). The compounds of $II-OC_2H_5,\;II-OC_4H_9$ and $II-C_6H_5$ were monotropically nematic. In contrast, the compounds of Il-H, II-F, II-Cl, II-Br, II-I, $lI-NO_2$, $II-CF_3$, and II-CN did not show liquid crystalline properties.

• Elastomers and Composites
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• v.37 no.4
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• pp.244-257
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• 2002

A thermotropic liquid crystalline polymer(TLCP) which has flexible butylene/hexylene spacers in the main chain and a triad aromatic ester type mesogenic unit containing a naphthyl group was prepared by solution polycondensation. The in-situ composites based on poly(ethylene 2,6-naphthalate) (PEN) and a thermotropic liquid crystalline polymer(TLCP) were prepared and melt spun at different TLCP contents and different draw ratios to produce monofilaments. Blends of the TLCP with PEN were investigated in terms of thermal, mechanical properties and morphology. The TLCP synthesized showed nematic mesophasic behavior and its transition temperature to isotropic melt from mesophase was 249℃. The blends showed well dispersed TLCP phases in the PEN matrix without macroscopic phase separation. Inclusion of TLCP in the blends decreased the cold crystallization temperature of PEN in the blend, therefore, the TLCP acts as a nucleating agent in the blend and showed good interfacial adhesion between the dispersed LCP phases and PEN matrix with domain sizes 40~50 nm in diameter and well developed fibrillation in the monofilaments. The TLCP acted effectively as a reinforcing material in the PEN matrix at the 10wt% level, it led to an increase of initial modulus up to 270% and tensile strength by 235%, while the elongation rate increasing with higher draw ratios.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.329-329
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• 2008

To date, rubbing has been widely used to align LC molecules uniformly. Although rubbing can be simple, it has fundamental problems such as the generation of defects by dust and static electricity, and difficulty in achieving a uniform LC alignment on a large substrate. Therefore, noncontact alignment has been investigated. Ion beam induced alignment method, which provides controllability, nonstop process, and high resolution display. In this study, we investigated liquid crystal (LC) alignment with ion beam (IB) that non contact alignment technique on polyimide and electro-optical characteristics of twisted nematic (TN)-liquid crystal display (LCD) on the poly imide under various ion beam angles. In this experiment, Polyimide layer was coated on glass by spin-coating and Voltage-transmittance(VT) and response time characteristics of the TN cell were measured by a LCD evaluation system. The good characteristics of the nematic liquid crystal (NLC) alignment with the ion beam exposure poly imide surface was observed. The tilt angle of NLC on the PI surface with ion beam exposure can be measured under $1^{\circ}4 for all of irradiation angles. In addition, it can be achieved the good ED properties, and residual DC property of the ion beam aligned TN cell on polyimide surface.